CN107497286A - A kind of biology enzyme formaldehyde scavenger - Google Patents

A kind of biology enzyme formaldehyde scavenger Download PDF

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Publication number
CN107497286A
CN107497286A CN201710835161.6A CN201710835161A CN107497286A CN 107497286 A CN107497286 A CN 107497286A CN 201710835161 A CN201710835161 A CN 201710835161A CN 107497286 A CN107497286 A CN 107497286A
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China
Prior art keywords
formaldehyde scavenger
formaldehyde
zein
biology enzyme
pure water
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Pending
Application number
CN201710835161.6A
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Chinese (zh)
Inventor
孙新文
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Anhui Zhonghong Technology Development Co Ltd
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Anhui Zhonghong Technology Development Co Ltd
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Priority to CN201710835161.6A priority Critical patent/CN107497286A/en
Publication of CN107497286A publication Critical patent/CN107497286A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/95Specific microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/704Solvents not covered by groups B01D2257/702 - B01D2257/7027
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

The present invention relates to formaldehyde treated technical field, in particular a kind of biology enzyme formaldehyde scavenger, it is made up of the component of following weight percent:Protein 10.0 20.0%, surfactant 0.2 7.0%, bleeding agent 0.1 17.0%, Tea Polyphenols 1.0 2.0%, biology enzyme 0.2 0.5%, citric acid 3.0 5.0%, adding pure water, biology enzyme formaldehyde scavenger is zein enzyme formaldehyde scavenger or soybean protein enzyme formaldehyde scavenger to 100%.The principle that the present invention absorbs formaldehyde relies primarily on bioenzyme activity, actively absorption, absorption, seizure formaldehyde, then reacted with formaldehyde, both can effectively degrade harmful organic matter, antibacterial effect can be played again, will not also cause secondary pollution, can effectively dispel the new home because decoration produces formaldehyde pernicious gas and stink, solve air pollution problem inside rooms well, simultaneously can be used for cleaning the public places such as hospital, hotel, restaurant, school.

Description

A kind of biology enzyme formaldehyde scavenger
Technical field
The present invention relates to formaldehyde treated technical field, specially a kind of biology enzyme formaldehyde scavenger.
Background technology
In recent years, with the improvement of people's living standards, requirement of the people to interior decoration standard also more and more higher, household Decoration modernizes increasingly, but room air chemical contamination problem is following caused by material and finishing.These Chemicals have had a strong impact on resident's health, have caused the great attention of countries in the world and domestic relevant department.In numerous dirts In dye source, formaldehyde is to measure big, strong toxicity, absorption is strong, scope is wide, has been classified as No.1 pollutant.Formaldehyde is that one kind has larger poison The volatile organic matter of property.Chemical molecular formula HCHO, molecular weight:30.03, it is a kind of colourless, there is the gas of intense irritation smell Body.Soluble in water, alcohol ether.Formaldehyde is gaseous state at normal temperatures, is generally occurred as an aqueous solution.Its 40% aqueous solution is referred to as good fortune You are Malin, and this solution boiling point is 19 DEG C.Therefore the highly volatile in room temperature, accelerate with the rising evaporation rate of temperature.
The pollution of formaldehyde indoors has the characteristics that multipath, disguise, characteristic of concentration.Its distribute approach include building materials, Ornament materials and articles for daily use etc., it is not easy to be therefore easily perceived by humans simultaneously because the slow release characteristics of formaldehyde are past, and itself is not It can decompose quickly, the extent of injury that this allows for formaldehyde is even more serious compared with other polluters, in consideration of it, it is proposed that a kind of raw Thing enzyme formaldehyde scavenger.
The content of the invention
It is an object of the invention to provide a kind of biology enzyme formaldehyde scavenger, is asked with solve to propose in above-mentioned background technology Topic.
To achieve the above object, the present invention provides following technical scheme:
A kind of biology enzyme formaldehyde scavenger, the biology enzyme formaldehyde scavenger by following weight percent component group Into:Protein 10.0-20.0%, surfactant 0.2-7.0%, bleeding agent 0.1-17.0%, Tea Polyphenols 1.0- 2.0%, biology enzyme 0.2-0.5%, citric acid 3.0-5.0%, add pure water to 100%.
Preferably, the biology enzyme formaldehyde scavenger is zein enzyme formaldehyde scavenger, the zein enzyme formaldehyde Scavenger is made up of the component of following weight percent:Zein 15.0%, surfactant 2.0%, bleeding agent 0.3%, Tea Polyphenols 1.0%, proteinase-10 .3%, citric acid 4.0%, add pure water to 100%.
Preferably, the manufacturing process of the zein enzyme formaldehyde scavenger is as follows:
S1 feeds intake:Zein 150g, Tea Polyphenols 10g, adding citric acid 40g, adding pure water to adjust pH value, heating rises to 3.0 Warm to 90 DEG C, sour water solution 3.5h;
S2 is digested:50 DEG C are cooled to, adds protease 3 .0g, 3h is digested at 50 DEG C;
S3 is aoxidized:After 3h is digested, enzymolysis degree is determined, such as reaches requirement, then 2% divided by zein amount quality oozes Saturating agent 3.0g, is aoxidized, pays attention to suitably being cooled to 75 DEG C or so, time about 4h;
S4 activating agents decolourize:After being changed into pure color to oxidation solution, add surfactant 20g and decolourized, temperature can rise Temperature extremely keeps 95-100 DEG C, heat time 1.5h-2.5h;
S5 is filtered:Using plate and frame filter press, filtered in the case where temperature is kept for more than 90 DEG C, the clarification filtered out Solution is zein formaldehyde scavenger mother liquor, is cooled down immediately;
S6 dilutes:Mother liquor in S5 is added into the laggard luggage case processing of pure water dilution finished product.
Preferably, the soybean protein enzyme formaldehyde scavenger is made up of the component of following weight percent:Soybean protein 10%, surfactant 4.0%, bleeding agent 3.0%, Tea Polyphenols 1.5%, proteinase-10 .4%, citric acid 3.5%, add pure water To 100%.
Preferably, the manufacturing process of the soybean protein enzyme formaldehyde scavenger is as follows:
S1 feeds intake:Soybean protein 100g, Tea Polyphenols 15g, adding citric acid 3.5g, adding pure water to adjust pH value, heating rises to 3.0 Warm to 90 DEG C, sour water solution 3.5h;
S2 is digested:50 DEG C are cooled to, adds protease 4g, 3h is digested at 50 DEG C;
S3 is aoxidized:After 3h is digested, enzymolysis degree is determined, such as reaches requirement, then 3% divided by soybean protein amount quality oozes Saturating agent 3.0g, is aoxidized, pays attention to suitably being cooled to 75 DEG C or so, time about 4h;
S4 activating agents decolourize:After being changed into pure color to oxidation solution, add surfactant 40g and decolourized, temperature can rise Temperature extremely keeps 95-100 DEG C, heat time 1.5h-2.5h;
S5 is filtered:Using plate and frame filter press, filtered in the case where temperature is kept for more than 90 DEG C, the clarification filtered out Solution is soybean protein formaldehyde scavenger mother liquor, is cooled down immediately;
S6 dilutes:Mother liquor in S5 is added into the laggard luggage case processing of pure water dilution finished product.
Compared with prior art, the beneficial effects of the invention are as follows:This biology enzyme formaldehyde scavenger absorbs the principle master of formaldehyde Bioenzyme activity is relied on, actively absorption, absorption, seizure formaldehyde, then react, both can effectively degrade has to human body with formaldehyde Harmful organic matter, antibacterial effect can be played again, will not also cause secondary pollution, can effectively dispel the new home because decoration produces Formaldehyde pernicious gas and stink, solve air pollution problem inside rooms well, simultaneously can be used for cleaning hospital, hotel, meal The public places such as shop, school.
Embodiment
To further appreciate that present disclosure, the present invention is described in detail in conjunction with the embodiments.It is it should be appreciated that real Apply example be only the present invention is explained and and it is non-limiting.
Embodiment 1
A kind of biology enzyme formaldehyde scavenger is present embodiments provided, is made up of the component of following weight percent:Albumen Matter 10.0-20.0%, surfactant 0.2-7.0%, bleeding agent 0.1-17.0%, Tea Polyphenols 1.0-2.0%, biology enzyme 0.2-0.5%, citric acid 3.0-5.0%, add pure water to 100%.
In the present embodiment, the biology enzyme formaldehyde scavenger is zein enzyme formaldehyde scavenger, the zein enzyme Formaldehyde scavenger is made up of the component of following weight percent:Zein 15.0%, surfactant 2.0%, bleeding agent 0.3%, Tea Polyphenols 1.0%, proteinase-10 .3%, citric acid 4.0%, add pure water to 100%.
In the present embodiment, the manufacturing process of the zein enzyme formaldehyde scavenger is as follows:
S1 feeds intake:Zein 150g, Tea Polyphenols 10g, adding citric acid 40g, adding pure water to adjust pH value, heating rises to 3.0 Warm to 90 DEG C, sour water solution 3.5h;
S2 is digested:50 DEG C are cooled to, adds protease 3 .0g, 3h is digested at 50 DEG C;
S3 is aoxidized:After 3h is digested, enzymolysis degree is determined, such as reaches requirement, then 2% divided by zein amount quality oozes Saturating agent 3.0g, is aoxidized, pays attention to suitably being cooled to 75 DEG C or so, time about 4h;
S4 activating agents decolourize:After being changed into pure color to oxidation solution, add surfactant 20g and decolourized, temperature can rise Temperature extremely keeps 95-100 DEG C, heat time 1.5h-2.5h;
S5 is filtered:Using plate and frame filter press, filtered in the case where temperature is kept for more than 90 DEG C, the clarification filtered out Solution is zein formaldehyde scavenger mother liquor, is cooled down immediately;
S6 dilutes:Mother liquor in S5 is added into the laggard luggage case processing of pure water dilution finished product.
Embodiment 2
A kind of biology enzyme formaldehyde scavenger is present embodiments provided, is made up of the component of following weight percent:Albumen Matter 10.0-20.0%, surfactant 0.2-7.0%, bleeding agent 0.1-17.0%, Tea Polyphenols 1.0-2.0%, biology enzyme 0.2-0.5%, citric acid 3.0-5.0%, add pure water to 100%.
In the present embodiment, the soybean protein enzyme formaldehyde scavenger is made up of the component of following weight percent:Soybean Protein 10 %, surfactant 4.0%, bleeding agent 3.0%, Tea Polyphenols 1.5%, proteinase-10 .4%, citric acid 3.5%, add pure Water purification is to 100%.
In the present embodiment, the manufacturing process of the soybean protein enzyme formaldehyde scavenger is as follows:
S1 feeds intake:Soybean protein 100g, Tea Polyphenols 15g, adding citric acid 3.5g, adding pure water to adjust pH value, heating rises to 3.0 Warm to 90 DEG C, sour water solution 3.5h;
S2 is digested:50 DEG C are cooled to, adds protease 4g, 3h is digested at 50 DEG C;
S3 is aoxidized:After 3h is digested, enzymolysis degree is determined, such as reaches requirement, then 3% divided by soybean protein amount quality oozes Saturating agent 3.0g, is aoxidized, pays attention to suitably being cooled to 75 DEG C or so, time about 4h;
S4 activating agents decolourize:After being changed into pure color to oxidation solution, add surfactant 40g and decolourized, temperature can rise Temperature extremely keeps 95-100 DEG C, heat time 1.5h-2.5h;
S5 is filtered:Using plate and frame filter press, filtered in the case where temperature is kept for more than 90 DEG C, the clarification filtered out Solution is soybean protein formaldehyde scavenger mother liquor, is cooled down immediately;
S6 dilutes:Mother liquor in S5 is added into the laggard luggage case processing of pure water dilution finished product.
Remove testing program:
1st, 30m just renovated between 2 is chosen2Room (concentration of formaldehyde is identical) and 2 between just renovated 100m2Room (first Aldehyde concentration is identical).
2nd, the concentration of formaldehyde in each room is measured, is designated as initial content of formaldehyde.
3rd, in closed room, zein enzyme formaldehyde scavenger and soybean protein enzyme formaldehyde scavenger are uniformly sprayed The occupation of land face of being sprinkled upon is 30m2It is interior, room air sample was gathered again by 24 hours, was designated as content of formaldehyde after 24h.
4th, in closed room, zein enzyme formaldehyde scavenger and soybean protein enzyme formaldehyde scavenger are uniformly sprayed The occupation of land face of being sprinkled upon is 100m2It is interior, room air sample was gathered again by 24 hours, was designated as content of formaldehyde after 24h.
5th, to the sample foundation QB/T2761-2006 of collection《Indoor air purification product clean-up effect assay method》Inspection The concentration of formaldehyde in air sample is surveyed, the principle for absorbing formaldehyde relies primarily on bioenzyme activity, actively absorption, absorption, seizure first Aldehyde, then reacted with formaldehyde.According to the concentration detected in sample, the removal efficiency of formaldehyde scavenger PARA FORMALDEHYDE PRILLS(91,95) is calculated.
It can be seen from above example and upper table data in the space of formed objects, zein enzyme formaldehyde is clear Except agent than soybean protein enzyme formaldehyde scavenger except effect of formaldehyde is good, and space is bigger, and formaldehyde removing effect is poorer.Biology enzyme first Aldehyde scavenger both can effectively degrade harmful organic matter, can play antibacterial effect again, will not also cause secondary Pollution, the new home can be effectively dispelled because decoration produces formaldehyde pernicious gas and stink, room air pollution is solved well and asks Topic, it simultaneously can be used for cleaning the public places such as hospital, hotel, restaurant, school.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry For personnel it should be appreciated that the present invention is not limited to the above embodiments, that described in above-described embodiment and specification is only the present invention Preference, be not intended to limit the present invention, without departing from the spirit and scope of the present invention, the present invention also have it is various Changes and improvements, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by institute Attached claims and its equivalent thereof.

Claims (5)

  1. A kind of 1. biology enzyme formaldehyde scavenger, it is characterised in that:The biology enzyme formaldehyde scavenger is by following weight percent Component composition:Protein 10.0-20.0%, surfactant 0.2-7.0%, bleeding agent 0.1-17.0%, Tea Polyphenols 1.0- 2.0%, biology enzyme 0.2-0.5%, citric acid 3.0-5.0%, add pure water to 100%.
  2. A kind of 2. biology enzyme formaldehyde scavenger according to claim 1, it is characterised in that:The biology enzyme formaldehyde scavenger For zein enzyme formaldehyde scavenger, the zein enzyme formaldehyde scavenger is made up of the component of following weight percent: Zein 15.0%, surfactant 2.0%, bleeding agent 0.3%, Tea Polyphenols 1.0%, proteinase-10 .3%, citric acid 4.0%, add pure water to 100%.
  3. A kind of 3. biology enzyme formaldehyde scavenger according to claim 2, it is characterised in that:The zein enzyme formaldehyde is clear Except the manufacturing process of agent is as follows:
    S1 feeds intake:Zein 150g, Tea Polyphenols 10g, adding citric acid 40g, pure water is added to adjust pH value to be heated to 3.0 90 DEG C, sour water solution 3.5h;
    S2 is digested:50 DEG C are cooled to, adds protease 3 .0g, 3h is digested at 50 DEG C;
    S3 is aoxidized:After 3h is digested, enzymolysis degree is determined, such as reaches requirement, then by 2% bleeding agent of zein amount quality point 3.0g, aoxidized, pay attention to suitably being cooled to 75 DEG C or so, time about 4h;
    S4 activating agents decolourize:After being changed into pure color to oxidation solution, add surfactant 20g and decolourized, temperature can be warming up to Kept for 95-100 DEG C, heat time 1.5h-2.5h;
    S5 is filtered:Using plate and frame filter press, filtered in the case where temperature is kept for more than 90 DEG C, the settled solution filtered out As zein formaldehyde scavenger mother liquor, is cooled down immediately;
    S6 dilutes:Mother liquor in S5 is added into the laggard luggage case processing of pure water dilution finished product.
  4. A kind of 4. biology enzyme formaldehyde scavenger according to claim 1, it is characterised in that:The soybean protein enzyme formaldehyde is clear Except agent is made up of the component of following weight percent:Soybean protein 10%, surfactant 4.0%, bleeding agent 3.0%, tea Polyphenol 1.5%, proteinase-10 .4%, citric acid 3.5%, add pure water to 100%.
  5. A kind of 5. biology enzyme formaldehyde scavenger according to claim 4, it is characterised in that:The soybean protein enzyme formaldehyde is clear Except the manufacturing process of agent is as follows:
    S1 feeds intake:Soybean protein 100g, Tea Polyphenols 15g, adding citric acid 3.5g, pure water is added to adjust pH value to be heated to 3.0 90 DEG C, sour water solution 3.5h;
    S2 is digested:50 DEG C are cooled to, adds protease 4g, 3h is digested at 50 DEG C;
    S3 is aoxidized:After 3h is digested, enzymolysis degree is determined, such as reaches requirement, then by 3% bleeding agent of soybean protein amount quality point 3.0g, aoxidized, pay attention to suitably being cooled to 75 DEG C or so, time about 4h;
    S4 activating agents decolourize:After being changed into pure color to oxidation solution, add surfactant 40g and decolourized, temperature can be warming up to Kept for 95-100 DEG C, heat time 1.5h-2.5h;
    S5 is filtered:Using plate and frame filter press, filtered in the case where temperature is kept for more than 90 DEG C, the settled solution filtered out As soybean protein formaldehyde scavenger mother liquor, is cooled down immediately;
    S6 dilutes:Mother liquor in S5 is added into the laggard luggage case processing of pure water dilution finished product.
CN201710835161.6A 2017-09-15 2017-09-15 A kind of biology enzyme formaldehyde scavenger Pending CN107497286A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108671714A (en) * 2018-01-25 2018-10-19 蔡进 It is a kind of to remove formaldehyde while have both the bio protease to eliminate the unusual smell
CN108786432A (en) * 2018-04-29 2018-11-13 广州长裕化工科技有限公司 A kind of biological enzyme air purifying preparation and the preparation method and application thereof
CN109395573A (en) * 2018-11-29 2019-03-01 河北迪酷环保科技有限公司 A kind of nanogold compound biological enzyme removes aldehyde eliminating smell agent
CN109731461A (en) * 2019-02-18 2019-05-10 浙江健煦环境科技有限公司 A kind of biological enzyme formaldehyde scavenger and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101549198A (en) * 2009-05-22 2009-10-07 朱君山 Formaldehyde scavenger and its application in producing timber flooring
CN104645819A (en) * 2013-11-21 2015-05-27 马啸天 Production process of soybean protein formaldehyde removing agent
CN105964133A (en) * 2016-06-15 2016-09-28 张园 Method for eliminating formaldehyde with biological protease

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101549198A (en) * 2009-05-22 2009-10-07 朱君山 Formaldehyde scavenger and its application in producing timber flooring
CN104645819A (en) * 2013-11-21 2015-05-27 马啸天 Production process of soybean protein formaldehyde removing agent
CN105964133A (en) * 2016-06-15 2016-09-28 张园 Method for eliminating formaldehyde with biological protease

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108671714A (en) * 2018-01-25 2018-10-19 蔡进 It is a kind of to remove formaldehyde while have both the bio protease to eliminate the unusual smell
CN108786432A (en) * 2018-04-29 2018-11-13 广州长裕化工科技有限公司 A kind of biological enzyme air purifying preparation and the preparation method and application thereof
CN109395573A (en) * 2018-11-29 2019-03-01 河北迪酷环保科技有限公司 A kind of nanogold compound biological enzyme removes aldehyde eliminating smell agent
CN109731461A (en) * 2019-02-18 2019-05-10 浙江健煦环境科技有限公司 A kind of biological enzyme formaldehyde scavenger and preparation method thereof

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Application publication date: 20171222