CN107490552A - A kind of ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system - Google Patents

A kind of ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system Download PDF

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Publication number
CN107490552A
CN107490552A CN201710286794.6A CN201710286794A CN107490552A CN 107490552 A CN107490552 A CN 107490552A CN 201710286794 A CN201710286794 A CN 201710286794A CN 107490552 A CN107490552 A CN 107490552A
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China
Prior art keywords
ultraviolet
probe
visible
signal
water
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Pending
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CN201710286794.6A
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Inventor
陈根南
吴清泉
姚琳
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ANHUI HARME TECHNOLOGY DEVELOPMENT Co Ltd
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ANHUI HARME TECHNOLOGY DEVELOPMENT Co Ltd
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Priority to CN201710286794.6A priority Critical patent/CN107490552A/en
Publication of CN107490552A publication Critical patent/CN107490552A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/314Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/314Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths
    • G01N2021/3155Measuring in two spectral ranges, e.g. UV and visible

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

The invention discloses a kind of ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system, it is characterised in that:The incident probe, the both sides for being arranged on detection water tank of outgoing probe opposition, the ultraviolet-visible that light source is sent is transmitted to incidence probe through optical fiber and is irradiated in detection water tank, water sample produces absorption to ultraviolet-visible, ultraviolet-visible after absorption is radiated on outgoing probe, ultraviolet-visible after absorption is transmitted through the fiber to spectrometer by outgoing probe, spectrometer converts optical signals to digital spectrum signal and transmitted to signal processor, signal processor carries out noise reduction process to receiving spectral signal, host computer is compared by the spectral signal after noise reduction process with standard spectrum, calculate COB in water sample, BOD, TOC data, and by concentration data storage in memory, the present invention has multiple functional, accuracy of detection is high, testing cost is low, the advantages of non-secondary pollution.

Description

A kind of ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system
Technical field
The invention belongs to detection device technology field, and in particular to a kind of ultraviolet, visible spectrum multi-parameter water-quality measurement inspection Examining system.
Background technology
Water is Source of life, and water is the base of dream.Although water resource belongs to renewable resource, but be not inexhaustible use It is inexhaustible.However, recent decades, China is with the system such as sharply increase developed rapidly with population of industrialization, urbanization Row factor, cause China's water pollution situation startling.According to statistics, in domestic 1200 monitored a plurality of rivers, 850 a plurality of incidents It is stained significantly, fishes and shrimps disappearance;In state's control emphasis lake, water quality accounts for 39.3% for pollution level, a large amount of natural lakes disappear or Large area is reduced;Marine pollution also allows of no optimist.
At present, China's water-quality COD, BOD, TOC detection be mainly by artificial collection water sample, using laboratory chemical analysis as Main Means, because chemical method resolution sample needs the regular hour, and contain the weight such as silver ion, chromium ion in digestion agent Metal, secondary pollution, detection cycle length, and complex operation are caused frequently, it is necessary to the experimenter of specialty.Laboratory chemical Analysis method is offline inspection, can not promptly and accurately reflect water pollution situation, lose validity, can not meet to examine water quality Survey the online, requirement of real-time.Most of water-quality CODs that China uses at present, BOD, TOC detecting instrument, also substantially belong to In chemical analysis, cycle length, fault rate are high, costly, can not adapt to modernize environment measuring technical requirements.
The content of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, there is provided a kind of ultraviolet, visible spectrum water quality is joined more Number measurement detecting system.
A kind of ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system, including:Incidence probe, outgoing probe, light source, Signal processor, host computer, spectrometer;It is characterized in that:What the incident probe, outgoing probe opposed is arranged on detection water tank Both sides, the ultraviolet-visible light that light source is sent through optical fiber transmit to incidence probe be irradiated to detection water tank in, water sample to it is ultraviolet- Visible ray produce absorption, the ultraviolet-visible light after absorption be radiated at outgoing probe on, outgoing probe by after absorption it is ultraviolet-can See that light is transmitted through the fiber to spectrometer, spectrometer converts optical signals to digital spectrum signal and transmitted to signal processor, letter Number processor carries out wavelet decomposition to receiving spectral signal, selects optimal wavelet function, it is determined that optimal Decomposition order, is utilized Mallat algorithms decompose to signal;Each layer of high-frequency wavelet coefficient carries out threshold process after decomposition, selects appropriate threshold, Threshold value quantizing is carried out to wavelet coefficient;Wavelet coefficient after being quantified according to value reconstructs to obtain the spectral signal after noise reduction process, on Position machine is compared by the spectral signal after noise reduction process with standard spectrum, calculates the data of COB, BOD, TOC in water sample, And by concentration data storage in memory.
Preferably, when COB, BOD, TOC data exceed setting value in the water sample, host computer sends startup to alarm Signal.
Preferably, the wavelength for the ultraviolet-visible light that the light source is sent is 195-1000nm.
Compared with prior art, beneficial effects of the present invention:
The present invention realizes the detection of COB, BOD, TOC data in water sample by non-contacting mode, has multiple functional, detection essence The advantages of degree is high, testing cost is low, non-secondary pollution.
Brief description of the drawings
Fig. 1 is the structural representation that a kind of ultraviolet, visible spectrum multi-parameter water-quality of the present invention measures detecting system.
In figure, 1, detection water tank, 2, incident probe, 3, outgoing probe, 4, light source, 5, signal processor, 6, host computer, 7, Spectrometer, 8, alarm.
Embodiment
Referring to Fig. 1, a kind of ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system, including:Incidence probe 2, outgoing are visited First 3, light source 4, signal processor 5, host computer 6, spectrometer 7;It is characterized in that:The incident probe 2, the opposition of outgoing probe 3 The both sides for being arranged on detection water tank 1, the ultraviolet-visible light that light source 4 is sent transmits to incidence probe through optical fiber and 2 is irradiated to detection In water tank 1, water sample produces absorption to ultraviolet-visible light, and the ultraviolet-visible light after absorption is radiated on outgoing probe 3, and outgoing is visited Ultraviolet-visible light after absorption is transmitted through the fiber to spectrometer 7 by first 3, and spectrometer 7 converts optical signals to digital spectrum letter Number transmitting to signal processor 5, signal processor 5 carries out wavelet decomposition to receiving spectral signal, selects optimal wavelet function, It is determined that optimal Decomposition order, is decomposed using Mallat algorithms to signal;Each layer of high-frequency wavelet coefficient is carried out after decomposition Threshold process, appropriate threshold is selected, threshold value quantizing is carried out to wavelet coefficient;Wavelet coefficient after being quantified according to value, which reconstructs, to be dropped The spectral signal made an uproar after handling, host computer 6 are compared by the spectral signal after noise reduction process with standard spectrum, calculate water outlet COB, BOD, TOC data in sample, and by concentration data storage in memory.
When COB, BOD, TOC data exceed setting value in the water sample, host computer 6 sends the letter of startup to alarm 8 Number.
The wavelength for the ultraviolet-visible light that the light source 4 is sent is 195-1000nm.
Invention is exemplarily described above in conjunction with accompanying drawing for technical solution of the present invention, it is clear that present invention specific implementation It is not subject to the restrictions described above, as long as the various unsubstantialities for employing inventive concept and technical scheme of the present invention progress change Enter, or it is not improved the design of invention and technical scheme are directly applied into other occasions, in protection scope of the present invention Within.

Claims (3)

1. a kind of ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system, including:Incidence probe(2), outgoing probe(3), light Source(4), signal processor(5), host computer(6), spectrometer(7);It is characterized in that:The incident probe(2), outgoing probe (3)Opposition is arranged on detection water tank(1)Both sides, light source(4)The ultraviolet-visible light sent is transmitted to incidence through optical fiber pops one's head in (2)It is irradiated to detection water tank(1)In, water sample produces absorption to ultraviolet-visible light, and the ultraviolet-visible light after absorption is radiated at out Penetrate probe(3)On, outgoing probe(3)Ultraviolet-visible light after absorption is transmitted through the fiber to spectrometer(7), spectrometer(7) Digital spectrum signal is converted optical signals to transmit to signal processor(5), signal processor(5)Carried out to receiving spectral signal Wavelet decomposition, optimal wavelet function is selected, it is determined that optimal Decomposition order, is decomposed using Mallat algorithms to signal;Point Each layer of high-frequency wavelet coefficient carries out threshold process after solution, selects appropriate threshold, and threshold value quantizing is carried out to wavelet coefficient;According to Wavelet coefficient after value quantifies reconstructs to obtain the spectral signal after noise reduction process, host computer(6)Pass through the spectrum after noise reduction process Signal is compared with standard spectrum, calculates the data of COB, BOD, TOC in water sample, and concentration data is stored in into memory In.
A kind of 2. ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system as claimed in claim 1, it is characterised in that:Institute When stating the data of COB, BOD, TOC in water sample and exceeding setting value, host computer(6)To alarm(8)Send the signal of startup.
A kind of 3. ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system as claimed in claim 1, it is characterised in that:Institute State light source(4)The wavelength of the ultraviolet-visible light sent is 195-1000nm.
CN201710286794.6A 2017-04-27 2017-04-27 A kind of ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system Pending CN107490552A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710286794.6A CN107490552A (en) 2017-04-27 2017-04-27 A kind of ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system

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Application Number Priority Date Filing Date Title
CN201710286794.6A CN107490552A (en) 2017-04-27 2017-04-27 A kind of ultraviolet, visible spectrum multi-parameter water-quality measurement detecting system

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107907528A (en) * 2017-12-28 2018-04-13 杭州电子科技大学 A kind of water quality on-line monitoring device based on wide spectrum multi-parameter
CN114184549A (en) * 2021-12-10 2022-03-15 西湖大学 Aquatic TOC and COD quick detection device based on AI degree of depth study
CN115586150A (en) * 2022-10-08 2023-01-10 吉林省正真检测有限公司 Water body vertical detection system based on ultraviolet visible spectrum

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101608998A (en) * 2009-07-09 2009-12-23 陈渝阳 Multiparameter water quality quick detection device based on the ARM technology
CN102047097A (en) * 2008-06-17 2011-05-04 株式会社岛津制作所 Water quality analyzer
CN102661923A (en) * 2012-05-03 2012-09-12 四川碧朗科技有限公司 Complex monitor for automatically monitoring multiple parameters of water on line

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102047097A (en) * 2008-06-17 2011-05-04 株式会社岛津制作所 Water quality analyzer
CN101608998A (en) * 2009-07-09 2009-12-23 陈渝阳 Multiparameter water quality quick detection device based on the ARM technology
CN102661923A (en) * 2012-05-03 2012-09-12 四川碧朗科技有限公司 Complex monitor for automatically monitoring multiple parameters of water on line

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107907528A (en) * 2017-12-28 2018-04-13 杭州电子科技大学 A kind of water quality on-line monitoring device based on wide spectrum multi-parameter
CN114184549A (en) * 2021-12-10 2022-03-15 西湖大学 Aquatic TOC and COD quick detection device based on AI degree of depth study
CN115586150A (en) * 2022-10-08 2023-01-10 吉林省正真检测有限公司 Water body vertical detection system based on ultraviolet visible spectrum

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