CN107488486A - A kind of antifreeze hydraulic oil - Google Patents

A kind of antifreeze hydraulic oil Download PDF

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Publication number
CN107488486A
CN107488486A CN201710781054.XA CN201710781054A CN107488486A CN 107488486 A CN107488486 A CN 107488486A CN 201710781054 A CN201710781054 A CN 201710781054A CN 107488486 A CN107488486 A CN 107488486A
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parts
hydraulic oil
compound
antifreeze
antifreeze hydraulic
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徐加树
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NANTONG RUNDE MECHANICAL TECHNOLOGY Co Ltd
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NANTONG RUNDE MECHANICAL TECHNOLOGY Co Ltd
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Priority to CN201710781054.XA priority Critical patent/CN107488486A/en
Publication of CN107488486A publication Critical patent/CN107488486A/en
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M161/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M167/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022Ethene
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024Propene
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/06Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/08Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing non-conjugated dienes
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
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    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/047Thioderivatives not containing metallic elements
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02Pour-point; Viscosity index
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18Anti-foaming property
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention relates to a kind of antifreeze hydraulic oil, it is characterised in that:The antifreeze hydraulic oil is made up of the raw material of following mass fraction:100 105 parts of machine oil;30 35 parts of dibastic alcohol compound;Double 10 30 parts of lipoid substances;13 parts of antioxidant;0.6 0.8 parts of antirust agent;10 18 parts of tackifier;0.02 0.06 parts of anti-coagulants;15 parts of antiwear additive;0.5 4 parts of antifreezing agent;79 parts of ethyl silicon oil;Antifreeze hydraulic oil provided by the invention is by controlling the comprehensive function of the dosage and various composition of each composition, and making it have preferable cryogenic property, flash-point is higher simultaneously.Test result indicates that antifreeze hydraulic oil provided by the invention can use at 55 DEG C, while its flash-point is 170 DEG C~180 DEG C.

Description

A kind of antifreeze hydraulic oil
Technical field
The present invention relates to antifreeze hydraulic oil field, more particularly to a kind of antifreeze hydraulic oil.
Background technology
Hydraulic drive is the kind of drive transmitting energy He be controlled by the use of liquid as working media.Antifreeze hydraulic oil Exactly using the hydraulic medium that uses of hydraulic system of liquid pressure energy, played in hydraulic system energy transmission, it is wear-resistant, be The effects such as system lubrication, anti-corrosion, antirust, cooling.For antifreeze hydraulic oil, hydraulic means should be met in operating temperature first The lower requirement with start-up temperature to liquid viscosity, due to oil body change directly with hydraulic operation, transmission efficiency and Transmitting accuracy is relevant, and the viscosity temperature characteristic and shear stability for also requiring oil should meet the various demands that different purposes are proposed.Greatly The fact that amount, shows that more than 70% hydraulic fault is as caused by working media, therefore, correctly selects and use hydraulic medium Service behaviour and functional reliability, the security and extension life cycle for improving hydraulic system are all of great significance. The problems such as corrosion metal and bad lubricity in use be present in antifreeze hydraulic oil most widely used at present.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of antifreeze hydraulic oil, antifreeze hydraulic oil provided by the invention has Flash-point is higher simultaneously for preferable cryogenic property.
In order to solve the above technical problems, the technical scheme is that:A kind of antifreeze hydraulic oil, its innovative point are:Institute Antifreeze hydraulic oil is stated to be made up of the raw material of following mass fraction:Machine oil 100-105 parts;Dibastic alcohol compound 30-35 parts;Double fat Class compound 10-30 parts;Antioxidant 1-3 parts;Antirust agent 0.6-0.8 parts;Tackifier 10-18 parts;Anti-coagulants 0.02-0.06 parts; Antiwear additive 1-5 parts;Antifreezing agent 0.5-4 parts;Ethyl silicon oil 7-9 parts;
The machine oil is I, II, III class base oil of the high viscosity index (HVI) that viscosity index (VI) is more than 125.
Further, kinematic viscosity of the machine oil at 45 DEG C is 3mm2/s~50mm2/s.
Further, dibastic alcohol compound includes one in ethylene glycol, propane diols, butanediol, decanediol and nonanediol Kind is a variety of.
Further, the di esters compound include di-n-octyl sebacate, dioctyl azelate, dioctyl adipate and One or several kinds in the isotridecanol of adipic acid two.
Further, it is compound anti-to include organic phenol kind antioxidant, aminated compounds antioxidant and sulphur nitrogen type for the antioxidant One or more in oxygen agent.
Further, the antirust agent is included in sulfonate, aliphatic acid and its derivative and compound phosphoric acid esters compound One or more.
Further, the antiwear additive includes phosphate compounds, phosphite ester compound, organic sulfur compound, phosphorus One or more in nitrogen compound, sulphur phosphorus-nitrogen compound and organic chloride.
Further, the antifreezing agent be triphenyl phosphate, triphenyl connect even phosphorus sulfate, trithiophenyl phosphate and One or more in chlorinated paraffin.
Further, it is common to include hy drogenated styrene-diene copolymer, polymethacrylates, ethylene, propylene for the tackifier One or more in polymers and polyisobutene.
The advantage of the invention is that:
1)Antifreeze hydraulic oil provided by the invention makes its tool by controlling the comprehensive function of the dosage and various composition of each composition Having preferable cryogenic property, flash-point is higher simultaneously.Test result indicates that antifreeze hydraulic oil provided by the invention can be at -55 DEG C Use, while its flash-point is 170 DEG C~180 DEG C.
2)In addition, the viscous warm nature of antifreeze hydraulic oil provided by the invention is preferable, make antifreeze hydraulic oil in wider temperature model Enclose to use and there is preferable viscosity and oil film thickness;Burning-point is higher, can ensure the security of antifreeze hydraulic oil, be advantageous to Transport, storage and the use of antifreeze hydraulic oil;Anti-foaming property is preferable, prevents antifreeze hydraulic oil from being emulsified into a small amount of moisture; Oxidation stability is preferable.Test result indicates that kinematic viscosity of the antifreeze hydraulic oil provided by the invention at -54 DEG C is 2545mm2/s~2710mm2/s, 45 DEG C of kinematic viscosity rate of descent are 1.7%~2.3%, burning-point is 214 DEG C~ 226 DEG C, foam tendentiousness and foam stability are preferable, 45 DEG C of motions under the conditions of 135 DEG C, 168h, 83mL air/min Viscosity B coefficent is 1.1%~4.2%.
Embodiment
The following examples can make professional and technical personnel that the present invention be more fully understood, but therefore not send out this It is bright to be limited among described scope of embodiments.
Embodiment 1:
A kind of antifreeze hydraulic oil, the antifreeze hydraulic oil are made up of the raw material of following mass fraction:100 parts of machine oil;Di-alcohols 30 parts of compound;Double 10 parts of lipoid substances;1 part of antioxidant;0.6 part of antirust agent;10 parts of tackifier;0.02 part of anti-coagulants;It is anti- 1 part of grinding agent;0.5 part of antifreezing agent;7 parts of ethyl silicon oil.
Machine oil is I class base oil of the high viscosity index (HVI) that viscosity index (VI) is more than 125.
Kinematic viscosity of the machine oil at 45 DEG C is 3mm2/s.
Dibastic alcohol compound includes the one or more in ethylene glycol, propane diols, butanediol, decanediol and nonanediol.
Di esters compound includes di-n-octyl sebacate, dioctyl azelate, dioctyl adipate and adipic acid two different ten One or several kinds in three alcohol esters.
Antioxidant include organic phenol kind antioxidant, aminated compounds antioxidant and one kind in sulphur nitrogen type composite antioxidant or It is several.
Antirust agent includes the one or more in sulfonate, aliphatic acid and its derivative and compound phosphoric acid esters compound.
Antiwear additive includes phosphate compounds, phosphite ester compound, organic sulfur compound, phosphorus-nitrogen compound, sulphur phosphorus One or more in nitrogen compound and organic chloride.
Antifreezing agent be triphenyl phosphate, triphenyl connect in even phosphorus sulfate, trithiophenyl phosphate and chlorinated paraffin one Kind is several.
Tackifier include hy drogenated styrene-diene copolymer, polymethacrylates, ethylene propylene copolymer and poly- isobutyl One or more in alkene.
Embodiment 2:
A kind of antifreeze hydraulic oil, the antifreeze hydraulic oil are made up of the raw material of following mass fraction:102 parts of machine oil;Di-alcohols 32 parts of compound;Double 20 parts of lipoid substances;2 parts of antioxidant;0.7 part of antirust agent;14 parts of tackifier;0.04 part of anti-coagulants;It is anti- 3 parts of grinding agent;2 parts of antifreezing agent;8 parts of ethyl silicon oil.
Machine oil is II class base oil of the high viscosity index (HVI) that viscosity index (VI) is more than 125.
Kinematic viscosity of the machine oil at 45 DEG C is 25mm2/s.
Dibastic alcohol compound includes the one or more in ethylene glycol, propane diols, butanediol, decanediol and nonanediol.
Di esters compound includes di-n-octyl sebacate, dioctyl azelate, dioctyl adipate and adipic acid two different ten One or several kinds in three alcohol esters.
Antioxidant include organic phenol kind antioxidant, aminated compounds antioxidant and one kind in sulphur nitrogen type composite antioxidant or It is several.
Antirust agent includes the one or more in sulfonate, aliphatic acid and its derivative and compound phosphoric acid esters compound.
Antiwear additive includes phosphate compounds, phosphite ester compound, organic sulfur compound, phosphorus-nitrogen compound, sulphur phosphorus One or more in nitrogen compound and organic chloride.
Antifreezing agent be triphenyl phosphate, triphenyl connect in even phosphorus sulfate, trithiophenyl phosphate and chlorinated paraffin one Kind is several.
Tackifier include hy drogenated styrene-diene copolymer, polymethacrylates, ethylene propylene copolymer and poly- isobutyl One or more in alkene.
Embodiment 3:
A kind of antifreeze hydraulic oil, the antifreeze hydraulic oil are made up of the raw material of following mass fraction:105 parts of machine oil;Di-alcohols 35 parts of compound;Double 30 parts of lipoid substances;3 parts of antioxidant;0.8 part of antirust agent;18 parts of tackifier;0.06 part of anti-coagulants;It is anti- 5 parts of grinding agent;4 parts of antifreezing agent;9 parts of ethyl silicon oil.
Machine oil is III class base oil of the high viscosity index (HVI) that viscosity index (VI) is more than 125.
Kinematic viscosity of the machine oil at 45 DEG C is 50mm2/s.
Dibastic alcohol compound includes the one or more in ethylene glycol, propane diols, butanediol, decanediol and nonanediol.
Di esters compound includes di-n-octyl sebacate, dioctyl azelate, dioctyl adipate and adipic acid two different ten One or several kinds in three alcohol esters.
Antioxidant include organic phenol kind antioxidant, aminated compounds antioxidant and one kind in sulphur nitrogen type composite antioxidant or It is several.
Antirust agent includes the one or more in sulfonate, aliphatic acid and its derivative and compound phosphoric acid esters compound.
Antiwear additive includes phosphate compounds, phosphite ester compound, organic sulfur compound, phosphorus-nitrogen compound, sulphur phosphorus One or more in nitrogen compound and organic chloride.
Antifreezing agent be triphenyl phosphate, triphenyl connect in even phosphorus sulfate, trithiophenyl phosphate and chlorinated paraffin one Kind is several.
Tackifier include hy drogenated styrene-diene copolymer, polymethacrylates, ethylene propylene copolymer and poly- isobutyl One or more in alkene.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation Merely illustrating the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also have Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention By appended claims and its equivalent thereof.

Claims (9)

  1. A kind of 1. antifreeze hydraulic oil, it is characterised in that:The antifreeze hydraulic oil is made up of the raw material of following mass fraction:Machine oil 100-105 parts;Dibastic alcohol compound 30-35 parts;Double lipoid substance 10-30 parts;Antioxidant 1-3 parts;Antirust agent 0.6-0.8 Part;Tackifier 10-18 parts;Anti-coagulants 0.02-0.06 parts;Antiwear additive 1-5 parts;Antifreezing agent 0.5-4 parts;Ethyl silicon oil 7-9 parts;
    The machine oil is I, II, III class base oil of the high viscosity index (HVI) that viscosity index (VI) is more than 125.
  2. A kind of 2. antifreeze hydraulic oil according to claim 1, it is characterised in that:Motion of the machine oil at 45 DEG C is glued Spend for 3mm2/s~50mm2/s.
  3. A kind of 3. antifreeze hydraulic oil according to claim 1, it is characterised in that:Dibastic alcohol compound include ethylene glycol, One or more in propane diols, butanediol, decanediol and nonanediol.
  4. A kind of 4. antifreeze hydraulic oil according to claim 1, it is characterised in that:The di esters compound includes decanedioic acid One or several kinds in dioctyl ester, dioctyl azelate, dioctyl adipate and the isotridecanol of adipic acid two.
  5. A kind of 5. antifreeze hydraulic oil according to claim 1, it is characterised in that:The antioxidant includes organic phenol class antioxygen One or more in agent, aminated compounds antioxidant and sulphur nitrogen type composite antioxidant.
  6. A kind of 6. antifreeze hydraulic oil according to claim 1, it is characterised in that:The antirust agent includes sulfonate, fat One or more in acid and its derivative and compound phosphoric acid esters compound.
  7. A kind of 7. antifreeze hydraulic oil according to claim 1, it is characterised in that:The antiwear additive includes phosphoric acid ester chemical combination Thing, phosphite ester compound, organic sulfur compound, phosphorus-nitrogen compound, sulphur phosphorus-nitrogen compound and one kind in organic chloride or It is several.
  8. A kind of 8. antifreeze hydraulic oil according to claim 1, it is characterised in that:The antifreezing agent is triphenyl phosphate, three Phenyl connects the one or more in even phosphorus sulfate, trithiophenyl phosphate and chlorinated paraffin.
  9. A kind of 9. antifreeze hydraulic oil according to claim 1, it is characterised in that:It is double that the tackifier include hydrogenated styrene One or more in alkene copolymer, polymethacrylates, ethylene propylene copolymer and polyisobutene.
CN201710781054.XA 2017-09-01 2017-09-01 A kind of antifreeze hydraulic oil Pending CN107488486A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109652178A (en) * 2018-12-29 2019-04-19 苏州统明机械有限公司 A kind of high viscosity index (HVI) ultralow temperature energy-saving engineering mechanical hydraulic oil
CN112175588A (en) * 2020-11-10 2021-01-05 江苏艾德露环保科技有限公司 Wear-resistant engine coolant

Citations (1)

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Application publication date: 20171219