CN107476067A - A kind of Reflection fabric of high-efficient and lasting and preparation method thereof - Google Patents
A kind of Reflection fabric of high-efficient and lasting and preparation method thereof Download PDFInfo
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- CN107476067A CN107476067A CN201710648757.5A CN201710648757A CN107476067A CN 107476067 A CN107476067 A CN 107476067A CN 201710648757 A CN201710648757 A CN 201710648757A CN 107476067 A CN107476067 A CN 107476067A
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- 239000004744 fabric Substances 0.000 title claims abstract description 47
- 230000002045 lasting effect Effects 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 77
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000002131 composite material Substances 0.000 claims abstract description 31
- 239000012790 adhesive layer Substances 0.000 claims abstract description 28
- 239000002245 particle Substances 0.000 claims abstract description 28
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 claims abstract description 20
- 235000010215 titanium dioxide Nutrition 0.000 claims abstract description 16
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- 239000013530 defoamer Substances 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 11
- 229920002635 polyurethane Polymers 0.000 claims abstract description 11
- 239000004814 polyurethane Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 7
- 238000009941 weaving Methods 0.000 claims abstract description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 238000009987 spinning Methods 0.000 claims description 10
- -1 Sodium alkyl benzene Chemical class 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical class C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 claims description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 235000013922 glutamic acid Nutrition 0.000 claims description 2
- 239000004220 glutamic acid Substances 0.000 claims description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims 1
- 229940043264 dodecyl sulfate Drugs 0.000 claims 1
- 125000002943 quinolinyl group Chemical class N1=C(C=CC2=CC=CC=C12)* 0.000 claims 1
- 239000010410 layer Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 239000004753 textile Substances 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 8
- 238000002310 reflectometry Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000004816 latex Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- KZRXPHCVIMWWDS-AWEZNQCLSA-N (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O KZRXPHCVIMWWDS-AWEZNQCLSA-N 0.000 description 2
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229940071085 lauroyl glutamate Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 229920005573 silicon-containing polymer Polymers 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to technical field of textile fabric, specifically a kind of Reflection fabric of high-efficient and lasting and preparation method thereof, described Reflection fabric is obtained by the composite fiber blended weaving of the natural fiber including 32 75% and 25 68%, described natural fiber and composite fiber surface is enclosed with polymeric adhesive layer, and described composite fibre includes the polymer that at least two melt-spinnables form fiber；Described polymeric adhesive layer includes the material of following parts by weight：70 86 parts of aqueous polyurethane emulsion, 0.5 8 parts of rutile type titanium white, 1.2 5.5 parts of PBMA particles, 0.03 0.21 parts of levelling agent, 0.05 0.18 parts of defoamer, 0.01 0.2 parts of age resistor, 0.5 3 parts of surfactant, 150 200 parts of water, the processing of polymer rubberised layer is carried out before Nature Fibre Textile, the reflective function of fiber is effectively raised, the luminescent fabric of high-efficient and lasting is obtained after fabric is woven into；Being rich in described polymeric adhesive layer has rutile type titanium white and PBMA particles, it is possible to achieve to being reflected and being reflected through the light of fabric, realizes excellent reflecting effect.
Description
Technical field
The present invention relates to technical field of textile fabric, the Reflection fabric of specifically a kind of high-efficient and lasting and its preparation side
Method.
Background technology
Reflection fabric plays obvious warning with its bright colors on daytime and rented, in night or the situation of insufficient light
Under, its bright reflecting effect can effectively strengthen the recognition capability of people, see target clearly, arouse vigilance, so as to avoid accident
Generation, reduce casualties, reduce economic loss, turn into the essential security guard of road traffic, there is obvious society
Can benefit.Reflection fabric product in the market, the reflective membrane on its fabric are produced using screen printing technique, silk screen
The defects of print production, is：First, the thinner thickness printed every time, general only 5 μm or so, if to reach 20-30 μm
Thickness, it just has to chromatography repeatedly more than 5 times, this to reflecting effect shaping efficiency have a great influence；Second, silk-screen printing
The version print technology of use, it is the printing of one edition one edition, and the slitless connection between version and version can not solve；Third, using silk screen
The full wafer reflective membrane of printing is not water-fastness and easily comes off, and structure is single so that the existing staff to be worked on road,
Poor using reflective clothing reflecting properties made of reflective membrane with it, performance is unstable, and poor air permeability, service life is short, can not
Long-acting reflective function is kept, is unfavorable for promoting the use of on a large scale.
The content of the invention
For the problems of the prior art, it is an object of the invention to provide a kind of Reflection fabric of high-efficient and lasting.
To achieve these goals, the present invention is achieved using following technical scheme：A kind of reflective surface of high-efficient and lasting
Material, described Reflection fabric is obtained by the natural fiber including 32-75% and 25-68% composite fiber blended weaving, described
Natural fiber and composite fiber surface be enclosed with polymeric adhesive layer,
Described composite fibre includes the polymer that at least two melt-spinnables form fiber；
Described polymeric adhesive layer includes the material of following parts by weight：Aqueous polyurethane emulsion 70-86 parts, rutile type titanium
White powder 0.5-8 parts, PBMA particle 1.2-5.5 parts, levelling agent 0.03-0.21 parts, defoamer 0.05-0.18 parts, age resistor 0.01-
0.2 part, surfactant 0.5-3 parts, water 150-200 parts.
According to the present invention, described levelling agent, defoamer are well known to those skilled in the art, can be selected from silicone oil,
One kind or more in dimethyl silicone polymer class, polydimethylsiloxane, polyethers or polyester modified organic siloxane, esters of acrylic acid
Kind；One or more of the described defoamer in tributyl phosphate, isooctanol, dimethicone, silicone grease class, SPA-202.
Using two kinds of fiber blends, the intensity and toughness of fiber are improved；Described fiber surface is coated with polymer latex
Layer, rutile type titanium white and PBMA particles in polymeric adhesive layer can effectively realize the reflection of light, due to polymer
Glue-line is coated on the surface of natural fiber and composite fibre before weaving, it can be ensured that realizes the high-efficient and lasting of reflective function.
According to the present invention, reflective function deficiency when the thickness of polymeric adhesive layer is relatively low, and when thickness is higher, to reflective function
It is not obviously improved, the thickness of heretofore described polymeric adhesive layer is 20-40 μm；
According to the present invention, rutile type titanium white is added with the spinning solution of described composite fibre, addition is spinning
The 0.02-0.3% of silk stock solution total amount.
According to the present invention, described PBMA particles include the small particle and average grain diameter model that average particle size range is 5-8 μm
Enclose the big particle diameter for 15-20 μm, the weight ratio of small particle and big particle diameter is 1：(0.5-1)；Using the PBMA particles of big small particle
Mixing filling glue-line, realizes tightly packed effect, effectively raises the reflection efficiency of light.
According to the present invention, what heretofore described surfactant was well known to those skilled in the art, it can be selected from
Such as sodium n-alkylbenzenesulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, laruyl alcohol sulfuric acid
Sodium, lauroyl glutamate, Nonyl pheno (10) ether, one kind in lignosulfonates or at least two combination
Thing.
According to the present invention, described age resistor is 4.4 a pair ofs (2.2- dimethyl benzyls) diphenylamines, N-N`- diphenyl-right
Phenylenediamine, N- phenyl-N`- isopropyls-p-phenylenediamine, N- phenyl-N`- cyclohexyl p-phenylenediamine, N- phenyl-β-naphthylamines, N- benzene
At least one of base-α-aniline, 6- ethyoxyls -2,2,4- trimethyl -1,2- dihyaroquinolines.
Present invention also offers the preparation method of the Reflection fabric of the high-efficient and lasting, comprise the following steps：
(1) prepared polymer glue, aqueous polyurethane emulsion, rutile type titanium white, PBMA grains are weighed by recipe ingredient
Son, levelling agent, defoamer, age resistor, surfactant and water, it is put into agitator and mixes to uniformly；
(2) natural fiber and composite fibre are deployed respectively, by it by coating unit, in natural fiber and composite fibre table
Face forms polymeric adhesive layer, then toasts 3-5min under conditions of 75-80 DEG C in an oven, must both be enclosed with polymeric adhesive layer
Fiber；The speed of described coating is 8-10m/min；
(3) take the fiber of step (2) to carry out blending, obtain Reflection fabric.
Compared with prior art, Reflection fabric provided by the invention, polymer rubberised layer is carried out before Nature Fibre Textile
Processing, effectively raise the reflective function of fiber, the luminescent fabric of high-efficient and lasting obtained after fabric is woven into；
Being rich in described polymeric adhesive layer has rutile type titanium white and PBMA particles, it is possible to achieve to through fabric
Light is reflected and reflected, and realizes excellent reflecting effect.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is furture elucidated.
Embodiment 1
A kind of Reflection fabric of high-efficient and lasting, described Reflection fabric by including 40% natural fiber and 60% it is compound
Fiber blend is weaved to obtain, and described natural fiber and composite fiber surface are enclosed with polymeric adhesive layer, described polymer latex
The thickness of layer is 30 μm；
Described composite fibre includes PET and PBT；
Described polymeric adhesive layer includes the material of following parts by weight：80 parts of aqueous polyurethane emulsion, rutile titanium dioxide
5 parts of powder, 0.1 part of levelling agent, 0.11 part of defoamer, 0.12 part of age resistor, 1.5 parts of surfactant, 200 parts of water；
1.5 parts of PBMA particles that average grain diameter is 7 μm, 1.5 parts of the PBMA particles that average grain diameter is 17 μm；
Rutile type titanium white is added with the spinning solution of described composite fibre, addition is spinning solution total amount
0.1%；
The preparation method of the Reflection fabric of the high-efficient and lasting comprises the following steps：
(1) prepared polymer glue, aqueous polyurethane emulsion, rutile type titanium white, PBMA grains are weighed by recipe ingredient
Son, levelling agent dimethyl silicone polymer class, defoamer tributyl phosphate, a pair of of age resistor 4.4 (2.2- dimethyl benzyls) hexichol
Amine, surfactant sodium n-alkylbenzenesulfonate and water, it is put into agitator and mixes to uniformly；
(2) natural fiber and composite fibre are deployed respectively, by it by coating unit, the speed of coating is 9m/min,
Natural fiber and composite fiber surface form polymeric adhesive layer, then toast 4min under conditions of 75 DEG C in an oven, must both wrap
It is wrapped with the fiber of polymeric adhesive layer；
(3) take the fiber of step (2) to carry out blending, obtain Reflection fabric.
Embodiment 2
A kind of Reflection fabric of high-efficient and lasting, described Reflection fabric by including 32% natural fiber and 68% it is compound
Fiber blend is weaved to obtain, and described natural fiber and composite fiber surface are enclosed with polymeric adhesive layer, described polymer latex
The thickness of layer is 20 μm；
Described composite fibre includes PET and PBT；
Described polymeric adhesive layer includes the material of following parts by weight：70 parts of aqueous polyurethane emulsion, rutile titanium dioxide
0.5 part of powder, 0.03 part of levelling agent, 0.05 part of defoamer, 0.01 part of age resistor, 0.5 part of surfactant, 150 parts of water；
2 parts of PBMA particles that average grain diameter is 5 μm, 1.5 parts of the PBMA particles that average grain diameter is 15 μm；
Rutile type titanium white is added with the spinning solution of described composite fibre, addition is spinning solution total amount
0.15%；
The preparation method of the Reflection fabric of the high-efficient and lasting comprises the following steps：
(1) prepared polymer glue, aqueous polyurethane emulsion, rutile type titanium white, PBMA grains are weighed by recipe ingredient
Son, levelling agent polydimethylsiloxane, defoamer isooctanol, age resistor N-N`- diphenyl-p-phenylenediamines, surfactant fat
Alcohol polyethenoxy ether sodium sulfate and water, it is put into agitator and mixes to uniformly；
(2) natural fiber and composite fibre are deployed respectively, by it by coating unit, the speed of coating is 8m/min,
Natural fiber and composite fiber surface form polymeric adhesive layer, then toast 5min under conditions of 75 DEG C in an oven, must both wrap
It is wrapped with the fiber of polymeric adhesive layer；
(3) take the fiber of step (2) to carry out blending, obtain Reflection fabric.
Embodiment 3
A kind of Reflection fabric of high-efficient and lasting, described Reflection fabric by including 75% natural fiber and 25% it is compound
Fiber blend is weaved to obtain, and described natural fiber and composite fiber surface are enclosed with polymeric adhesive layer, described polymer latex
The thickness of layer is 40 μm；
Described composite fibre includes PET and PBT；
Described polymeric adhesive layer includes the material of following parts by weight：86 parts of aqueous polyurethane emulsion, rutile titanium dioxide
8 parts of powder, 0.21 part of esters of acrylic acid levelling agent, 0.18 part of silicone grease class defoamer, age resistor N- phenyl-N`- isopropyls-to benzene two
0.2 part of amine, 3 parts of surfactant lauroyl glutamate, 200 parts of water；
PBMA particles 2.2 that average grain diameter is 8 μm, 1.5 parts of the PBMA particles that average grain diameter is 20 μm；
Rutile type titanium white is added with the spinning solution of described composite fibre, addition is spinning solution total amount
0.2%；
The preparation method of the Reflection fabric of the high-efficient and lasting comprises the following steps：
(1) prepared polymer glue, aqueous polyurethane emulsion, rutile type titanium white, PBMA grains are weighed by recipe ingredient
Son, esters of acrylic acid levelling agent, silicone grease class defoamer, age resistor N- phenyl-N`- isopropyls-p-phenylenediamine, the surfactant moon
Osmanthus acyl glutamic acid and water, it is put into agitator and mixes to uniformly；
(2) natural fiber and composite fibre are deployed respectively, by it by coating unit, the speed of coating is 10m/min,
Natural fiber and composite fiber surface form polymeric adhesive layer, then toast 3min under conditions of 80 DEG C in an oven, must both wrap
It is wrapped with the fiber of polymeric adhesive layer；
(3) take the fiber of step (2) to carry out blending, obtain Reflection fabric.
Correlated performance is tested：
1st, reflectance test：Luminescent fabric sample 6cm*6cm piece samples prepared by Example 1-3, according to GB/T
3979-2008 standard, the UltraScan PRO superhigh precision specialty spectral photometric colour measurings produced using Hunterlab companies of the U.S.
Instrument, under D65 light conditions, by its reflectivity of d/8 ° of structured testing of integrating sphere, reflectivity data is that 350nm-1050nm is every
Every the weighted average of the reflectivity of the light wave of 5nm wavelength, weights correspond to the energy distribution curve of D65 light sources, test data note
Record in table 1.
2nd, weatherability (wet and heat ageing resistant)：Luminescent fabric sample 6cm*6cm piece samples prepared by Example 1-3, according to
GB/T 2423.1-2001 standard testings, 85 DEG C, ambient humidity 85%RH of environment temperature, surveyed using SH-241 environmental test chambers
Examination；The reflectivity of sample after test experiments simultaneously recorded test data in table 1.
The reflectivity for the Reflection fabric that the embodiment 1-3 of table 1 is obtained
| Embodiment | Reflectivity/% | Reliability back reflection rate/% |
| Embodiment 1 | 97.8 | 92.5 |
| Embodiment 2 | 97.6 | 91.8 |
| Embodiment 3 | 97.8 | 91.9 |
As can be seen from the above data, Reflection fabric provided by the invention has excellent reflectivity, meanwhile, it experienced double
85 test back reflection rates still maintain more than 91%, therefore, have the reflective function of high-efficient and lasting.
General principle, principal character and the features of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement is both fallen within the range of claimed invention.The scope of protection of present invention is by appended claims
And its equivalent thereof.
Claims (8)
- A kind of 1. Reflection fabric of high-efficient and lasting, it is characterised in that：Described Reflection fabric is by the natural fiber including 32-75% Composite fiber blended weaving with 25-68% obtains, and described natural fiber and composite fiber surface are enclosed with polymeric adhesive layer,Described composite fibre includes the polymer that at least two melt-spinnables form fiber；Described polymeric adhesive layer includes the material of following parts by weight：Aqueous polyurethane emulsion 70-86 parts, rutile type titanium white 0.5-8 parts, PBMA particle 1.2-5.5 parts, levelling agent 0.03-0.21 parts, defoamer 0.05-0.18 parts, age resistor 0.01-0.2 Part, surfactant 0.5-3 parts, water 150-200 parts.
- 2. the Reflection fabric of high-efficient and lasting according to claim 1, it is characterised in that：The thickness of described polymeric adhesive layer For 20-40 μm.
- 3. the Reflection fabric of high-efficient and lasting according to claim 1, it is characterised in that：Add in the spinning solution of composite fibre Added with rutile type titanium white, addition is the 0.02-0.3% of spinning solution total amount.
- 4. the Reflection fabric of high-efficient and lasting according to claim 1, it is characterised in that：Described PBMA particles include average The big particle diameter that the small particle and average particle size range that particle size range is 5-8 μm are 15-20 μm, small particle and the weight ratio of big particle diameter For 1：(0.5-1).
- 5. the Reflection fabric of high-efficient and lasting according to claim 1, it is characterised in that：Described surfactant is straight chain Sodium alkyl benzene sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, bay Acyl glutamic acid, Nonyl pheno (10) ether, one kind in lignosulfonates or at least two composition.
- 6. the Reflection fabric of high-efficient and lasting according to claim 1, it is characterised in that：Described age resistor is selected from 4.4 1 Double (2.2- dimethyl benzyls) diphenylamines, N-N`- diphenyl-p-phenylenediamines, N- phenyl-N`- isopropyls-p-phenylenediamine, N- benzene Base-N`- cyclohexyl p-phenylenediamine, N- phenyl-β-naphthylamines, N- phenyl-α-aniline, 6- ethyoxyls -2,2,4- trimethyls -1,2- bis- At least one of hydrogenated quinoline.
- A kind of 7. preparation method of the Reflection fabric of high-efficient and lasting as described in claim 1-6, it is characterised in that：Including following Step：(1) prepared polymer glue, aqueous polyurethane emulsion, rutile type titanium white, PBMA particles, stream are weighed by recipe ingredient Flat agent, defoamer, age resistor, surfactant and water, it is put into agitator and mixes to uniformly；(2) natural fiber and composite fibre are deployed respectively, by it by coating unit, in natural fiber and composite fiber surface shape Into polymeric adhesive layer, 3-5min then is toasted under conditions of 75-80 DEG C in an oven, must both be enclosed with the fibre of polymeric adhesive layer Dimension；(3) take the fiber of step (2) to carry out blending, obtain Reflection fabric.
- 8. the preparation method of the Reflection fabric of high-efficient and lasting according to claim 7, it is characterised in that：Described step (2) speed of coating is 8-10m/min in.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108118537A (en) * | 2018-02-07 | 2018-06-05 | 海宁市现代汽车座套有限公司 | A kind of Reflection fabric and preparation method thereof |
| CN108754671A (en) * | 2018-05-03 | 2018-11-06 | 安徽路政通新材料科技有限公司 | A kind of noctilucence silk and preparation method thereof that reflecting effect is good |
| CN113152076A (en) * | 2020-01-22 | 2021-07-23 | 东丽纤维研究所（中国）有限公司 | Visible fabric for liquid stain reduction |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105109166A (en) * | 2015-09-11 | 2015-12-02 | 宁波长阳科技有限公司 | Anti-adsorption coating type polyester film for reflection and preparation method thereof |
| CN106637591A (en) * | 2016-08-31 | 2017-05-10 | 浙江兆新织造有限公司 | Antibacterial skin-smoothing lining with natural faint scent |
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- 2017-08-01 CN CN201710648757.5A patent/CN107476067A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105109166A (en) * | 2015-09-11 | 2015-12-02 | 宁波长阳科技有限公司 | Anti-adsorption coating type polyester film for reflection and preparation method thereof |
| CN106637591A (en) * | 2016-08-31 | 2017-05-10 | 浙江兆新织造有限公司 | Antibacterial skin-smoothing lining with natural faint scent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108118537A (en) * | 2018-02-07 | 2018-06-05 | 海宁市现代汽车座套有限公司 | A kind of Reflection fabric and preparation method thereof |
| CN108754671A (en) * | 2018-05-03 | 2018-11-06 | 安徽路政通新材料科技有限公司 | A kind of noctilucence silk and preparation method thereof that reflecting effect is good |
| CN113152076A (en) * | 2020-01-22 | 2021-07-23 | 东丽纤维研究所（中国）有限公司 | Visible fabric for liquid stain reduction |
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