CN107476059A - Lighting wool fabric is prepared with inorganic sulfur-bearing reducing agent - Google Patents

Lighting wool fabric is prepared with inorganic sulfur-bearing reducing agent Download PDF

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Publication number
CN107476059A
CN107476059A CN201710787495.0A CN201710787495A CN107476059A CN 107476059 A CN107476059 A CN 107476059A CN 201710787495 A CN201710787495 A CN 201710787495A CN 107476059 A CN107476059 A CN 107476059A
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China
Prior art keywords
wool fabric
reducing agent
lysate
inorganic sulfur
wool
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Application number
CN201710787495.0A
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Chinese (zh)
Inventor
卢明
刘萍
刘一萍
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Southwest University
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Southwest University
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Priority to CN201710787495.0A priority Critical patent/CN107476059A/en
Publication of CN107476059A publication Critical patent/CN107476059A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06—Inorganic compounds or elements
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/08—Organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/53—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/54—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur dioxide; with sulfurous acid or its salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/262—Sulfated compounds thiosulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention provides a kind of method that lighting wool fabric is prepared with inorganic sulfur-bearing reducing agent, this method comprises the following steps：（1）The preparation of lysate：Inorganic sulfur-bearing reducing agent, urea and lauryl sodium sulfate are dissolved into water, then add hollow glass micropearl, is stirred vigorously down and obtains the lysate for being dispersed with hollow glass micropearl；（2）By wool fabric in step（1）Repeatedly padded in the lysate of gained；（3）Wool fabric after padding is irradiated under infrared ray；（4）Wool fabric after irradiation is impregnated in poly-vinyl alcohol solution and solidified, then washes, dry.This technology of preparing is simple and easy, and cost is cheap, small to the strength damage of wool fabric, does not change wool surface performance, and hollow glass micropearl has good fastness on wool fabric；Any adhesive is not used in this preparation process, it is nontoxic.

Description

Lighting wool fabric is prepared with inorganic sulfur-bearing reducing agent
Technical field
It is especially a kind of to prepare lighting with inorganic sulfur-bearing reducing agent the present invention relates to a kind of preparation method of function fabric The method of wool fabric.
Background technology
Nano-particle is introduced into textile fabric, functional fiber material can be prepared.Nano-particle is drawn at present It is many to enter the preparation method of wool fiber, such as：Absorption method, sol-gal process, layer assembly method, coating etc..However, absorption method By mainly making nano-particle be adsorbed onto wool surface by intermolecular Van der Waals force and ionic forces, washing fastness compared with It is low；The technical process of sol-gal process and layer assembly method is longer, and more difficult control；Coating is to utilize adhesive by nanoparticle Son is adhered to wool surface, reduces skin-friendly of the wool fiber to human body.
Wool keratin is a kind of protein rich in cystine, the disulfide bond in cystine be it is intermolecular be cross-linked with each other, Stable network structure is formed, is wool protein essential reason not soluble in water.Inorganic sulfur-bearing reducing agent can be by disulfide bond also Original is widely used for the dissolving of wool keratin into sulfydryl.
The content of the invention
The technical problems to be solved by the invention are the shortcomings that presence for above prior art, are proposed a kind of with inorganic The method that sulfur-bearing reducing agent prepares lighting wool fabric.The technology of preparing is simple and easy, and cost is cheap, to the strong of wool fabric Power damage is small, does not change wool surface performance, hollow glass micropearl has good fastness on wool fabric；The preparation During be not used any adhesive, it is nontoxic.
To achieve these goals, the solution taken of the present invention is：It is a kind of to prepare lightweight with inorganic sulfur-bearing reducing agent Change the method for wool fabric, it is characterised in that comprise the following steps：
（1）The preparation of lysate：Inorganic sulfur-bearing reducing agent, urea and lauryl sodium sulfate are dissolved into water, then added Hollow glass micropearl, it is stirred vigorously down and obtains the lysate for being dispersed with hollow glass micropearl；
（2）By wool fabric in step（1）Repeatedly padded in the lysate of gained；
（3）Wool fabric after padding is irradiated into 10-30 minutes under infrared ray；
（4）Wool fabric after irradiation is impregnated in poly-vinyl alcohol solution and solidified, then washes, dry.
The beneficial effects of the present invention are,（1）Limited inorganic sulfur-bearing reducing agent is set to be distributed mainly on sheep using padding method The surface of wool fibre, the infrared irridiation of short time can only be partly dissolved to wool surface, without damaging wool Fibrous inside, reduce the damage to wool fiber and fabric；（2）In the partly soluble sheep of wool surface Hairless protein forms protein compression solution, has adhesive attraction to nano-particle；（3）The protein compression that wool surface is formed is molten Liquid solidifies again in poly-vinyl alcohol solution, plays bonding to nano-particle, package action；（4）It is not used in preparation process Any adhesive, it is nontoxic.
Embodiment
The present invention is described in detail below in conjunction with specific embodiment.It should be noted that the skill described in following embodiments The combination of art feature or technical characteristic is not construed as isolated, and they can be mutually combined so as to reach more preferable Technique effect.
Embodiment 1
（1）The preparation of lysate：6g vulcanized sodium, 30g urea and 1g lauryl sodium sulfate are dissolved into water, 100g is formed and mixes Solution is closed, 0.6g hollow glass micropearls is then added, is stirred vigorously down and obtains the lysate for being dispersed with hollow glass micropearl；
（2）By wool fabric in step（1）Repeatedly padded in the lysate of gained, pick-up 100%；
（3）Wool fabric after padding is irradiated into 10min under 250w infrared rays；
（4）Wool fabric after irradiation is impregnated in poly-vinyl alcohol solution（Mass fraction is 10%）Middle solidification 10min, Ran Houshui Wash, dry.
Embodiment 2
（1）The preparation of lysate：4g sodium pyrosulfites, 25g urea and 2g lauryl sodium sulfate are dissolved into water, formed 100g mixed solutions, 0.8g hollow glass micropearls are then added, is stirred vigorously down and obtains the dissolving for being dispersed with hollow glass micropearl Liquid；
（2）By wool fabric in step（1）Repeatedly padded in the lysate of gained, pick-up 100%；
（3）Wool fabric after padding is irradiated into 20min under 150w infrared rays；
（4）Wool fabric after irradiation is impregnated in poly-vinyl alcohol solution（Mass fraction is 12%）Middle solidification 10min, Ran Houshui Wash, dry.
Embodiment 3
（1）The preparation of lysate：3g sodium hydrogensulfites, 35g urea and 3g lauryl sodium sulfate are dissolved into water, formed 100g mixed solutions, 1g hollow glass micropearls are then added, is stirred vigorously down and obtains the lysate for being dispersed with hollow glass micropearl；
（2）By wool fabric in step（1）Repeatedly padded in the lysate of gained, pick-up 110%；
（3）Wool fabric after padding is irradiated into 30min under 100w infrared rays；
（4）Wool fabric after irradiation is impregnated in poly-vinyl alcohol solution（Mass fraction is 15%）Middle solidification 10min, Ran Houshui Wash, dry.
Although having been presented for some embodiments of the present invention herein, it will be appreciated by those of skill in the art that Without departing from the spirit of the invention, the embodiments herein can be changed.Above-described embodiment be it is exemplary, no Restriction that should be using the embodiments herein as interest field of the present invention.

Claims (2)

  1. A kind of 1. method that lighting wool fabric is prepared with inorganic sulfur-bearing reducing agent, it is characterised in that comprise the following steps：
    （1）The preparation of lysate：Inorganic sulfur-bearing reducing agent, urea and lauryl sodium sulfate are dissolved into water, then added Hollow glass micropearl, it is stirred vigorously down and obtains the lysate for being dispersed with hollow glass micropearl；
    （2）By wool fabric in step（1）Repeatedly padded in the lysate of gained；
    （3）Wool fabric after padding is irradiated into 10-30 minutes under infrared ray；
    （4）Wool fabric after irradiation is impregnated in poly-vinyl alcohol solution and solidified, then washes, dry.
  2. 2. a kind of method that lighting wool fabric is prepared using inorganic sulfur-bearing reducing agent according to claim 1, it is special Sign is：Inorganic sulfur-bearing reducing agent is vulcanized sodium, sodium hydrogensulfite, sodium pyrosulfite etc..
CN201710787495.0A 2017-09-04 2017-09-04 Lighting wool fabric is prepared with inorganic sulfur-bearing reducing agent Withdrawn CN107476059A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710787495.0A CN107476059A (en) 2017-09-04 2017-09-04 Lighting wool fabric is prepared with inorganic sulfur-bearing reducing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710787495.0A CN107476059A (en) 2017-09-04 2017-09-04 Lighting wool fabric is prepared with inorganic sulfur-bearing reducing agent

Publications (1)

Publication Number Publication Date
CN107476059A true CN107476059A (en) 2017-12-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710787495.0A Withdrawn CN107476059A (en) 2017-09-04 2017-09-04 Lighting wool fabric is prepared with inorganic sulfur-bearing reducing agent

Country Status (1)

Country Link
CN (1) CN107476059A (en)

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Application publication date: 20171215