CN107475660B - A kind of plasma ashing tungsten spraying production technology - Google Patents

A kind of plasma ashing tungsten spraying production technology Download PDF

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Publication number
CN107475660B
CN107475660B CN201710768703.2A CN201710768703A CN107475660B CN 107475660 B CN107475660 B CN 107475660B CN 201710768703 A CN201710768703 A CN 201710768703A CN 107475660 B CN107475660 B CN 107475660B
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workpiece
powder
spraying
spray
tungsten
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CN107475660A (en
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唐静波
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Wuxi Kurt Metal Surface Treatment Co Ltd
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Wuxi Kurt Metal Surface Treatment Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/134Plasma spraying
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/10Oxides, borides, carbides, nitrides or silicides; Mixtures thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

The invention discloses a kind of plasma ashing tungsten to spray production technology, and specific step is as follows: S1: workpiece pretreatment for the plasma ashing tungsten spraying production technology;S2: blasting treatment;S3: sanding and polishing processing;S4: tungsten carbide processing;S5: thermal response;S6: mechanical enhancer;S7: equipment adjustment;S8: powder supply;S9: spray distance and angle of spray;S10: workpiece the pre-heat treatment;S11 spraying;S12: workpiece cooling packing.The present invention is flat and smooth by coating that plasma spraying obtains, consistency is high, and powder deposition is very high, matrix is not charged, non-fusible in spraying process, matrix and spray gun relative moving speed are fast, so that matrix does not change, and tungsten-carbide powder is handled by mechanical enhancer, spraying penetration works well, and in the indoor progress of dust removal by ventilation in spraying and cooling procedure, effectively the adsorbing powder dust generated in the course of work can be filtered, guarantee working environment, is suitble to be widely popularized.

Description

A kind of plasma ashing tungsten spraying production technology
Technical field
The present invention relates to tungsten carbide spraying technology field, specially a kind of plasma ashing tungsten sprays production technology.
Background technique
Spraying is dispersed into uniform and fine droplet, applied by spray gun or dish-style atomizer by means of pressure or centrifugal force It is applied to the coating process on coated article surface.Aerial spraying, airless spraying, electrostatic spraying and above-mentioned basic spraying shape can be divided into The mode of the various derivations of formula, such as big flow low-pressure atomizing spraying, thermal spraying, automatic spraying, multiple groups spraying, spraying operation High production efficiency, is suitable for handwork and industrial automation produces, and having a wide range of application mainly has hardware, plastic cement, family property, army The fields such as work, ship are now using a kind of most common coating mode;Spraying operation needs environmental requirement to have million grades to hundred The dust-free workshop of grade, spraying equipment have spray gun, and paint spray booth, for paint room, curing oven/drying oven, spraying workpiece conveys operating equipment, Fog dispersal and waste water, waste gas treatment equipment etc..
Metal spraying is to be sprayed on matrix surface with the high-velocity particles stream of molten metal, to generate the material protection skill of coating Art is zinc, aluminium and alumin(i)um zinc alloy using most metal materials, mainly to protect the large-sized structural parts of steel.In nineteen fifty-two State once in 264 35 kilovolts of transmission tower top spraying zincs success of Huainan power plant, had saved a large amount of maintenance costs.Aluminium-plated ratio spraying Zinc is more suitable for the component to work in severe industrial atmosphere and marine atmosphere, at the same also have wear-resisting, resistance to high temperature oxidation and The performance of anti-sulfur-containing compound gas attack.Metal spraying is characterized in: workpiece size no maximum, and matrix is heated to be usually no more than 200 DEG C, the adhesive force between coating and matrix may be up to 7 megapascal.Surface roughness after spraying can drop to Ra1.25 microns, add Ra0.16~0.04 micron can be arrived after work.But the coating surface that arc process sprays is poor, can reach general accurate work after processed Part.
Traditional tungsten carbide spraying process is complicated, and the flat and smooth of coating, consistency be not high, and matrix is easy to happen change Change, cost of equipment maintenance is high, and a large amount of dust can be generated in spraying process, is easy pollution surrounding enviroment.
Summary of the invention
The purpose of the present invention is to provide a kind of plasma ashing tungsten to spray production technology, to solve in above-mentioned background technique The problem of proposition.
It to achieve the above object, should the invention provides the following technical scheme: a kind of plasma ashing tungsten sprays production technology Specific step is as follows for plasma ashing tungsten spraying production technology:
S1: workpiece pretreatment will need the workpiece that sprays to be drawn as CAD diagram paper matrix formula, according to drawing pattern to needing on workpiece Area to be protected is protected;
S2: blasting treatment will need the workpiece sprayed to use compressed air for power, to form high velocity spray beam for material spray High speed, which is ejected into, need to handle workpiece surface, and the appearance of workpiece surface or shape is made to change;
S3: sanding and polishing processing send the workpiece that blasting treatment in S2 is completed to progress sanding and polishing processing on polishing machine, The revolving speed of polishing machine is in 1500-2500 r/min, machining accuracy: surface roughness Ra≤0.25 μm;
S4: tungsten carbide raw material is crushed and is uniformly mixed by ball-milling technology by tungsten carbide processing;
S5: thermal response will obtain broken raw material and carry out thermal response in the ion stream of plasma generator to obtain in S4 Mixture of powders;
S6: the mixture of powders in S5 is put into the bronze drum of centrifugal planetary grinder by mechanical enhancer, with diameter 8mm Copper ball the grinding of 5min is carried out to powder, wherein copper ball weight 200g, powder are added at one time weight no more than 10g, obtain powder Expect spare;
S7: N is selected in equipment adjustment2Gas is adjusted as plasma gas, gas flow 2000L/h, pressure 0.8MPa Whole arc power, so that arc temperature control is at 2870 DEG C -2900 DEG C;
S8: powder supply will obtain powder by powder feeder and supply powder to spray gun in S6;
S9: spray distance and angle of spray adjust the nozzle face of spray gun to the linear distance of workpiece surface, and spray distance exists 70-150mm, angle of spray are 60 ° -80 °;
S10: workpiece the pre-heat treatment preheats the workpiece in S3, and preheating temperature is between 80 DEG C -150 DEG C;
S11: spraying sprays the workpiece in S10 using spray gun, and spray gun movement speed is the 30%- of pressure lid spot 50%, for thickness in 0.15 mm shallow layer below, the coating layer thickness sprayed every time does not exceed 0.02 mm, and spray gun is mobile Speed also has an impact to the temperature rise of workpiece, for Bu Shi matrix local temperature rise is excessively high and causes thermal deformation or thermal stress excessive, can mention The method of high workpiece linear velocity accelerates the movement speed of spray gun;
S12: workpiece cooling packing, the workpiece that spraying is completed carry out natural cooling, carry out packaging and storing after the completion of cooling.
Preferably, the material spray in the step S2 can be one in copper ore, quartz sand, diamond dust, iron sand and sea sand Kind.
Preferably, workpiece makes workpiece by impact and shear action of the blasting treatment to workpiece surface in the step S2 Surface obtain certain cleannes and different roughness, improve the mechanical performance of workpiece surface, improve workpiece Fatigue resistance, increase its adhesive force between coating, extend the durability of film, be conducive to the levelling and dress of coating Decorations.
Preferably, the ball milling in the step S4 carries out broken mixing using horizontal ball mill, and the revolving speed of mill tube is 45- 55r/min, charging volume are 20L-200L.
Preferably, the plasma generator in the step S5 use laminar-flow type plasmatron, laminar-flow type etc. from The state of the plasma jet of subflow generator is gradually transitions turbulent flow from laminar flow, in the process, is decreased obviously in adhesion strength While, the discreteness of data is also increasing, and the repeatability for finally resulting in coating performance degenerates, the oxidation spraying on side surface Layer, dielectric strength 1.5kV prevent occurring electric arc point on the inverted conductive wall of inside reactor and on surface after cooling Stream, to reduce the consumption of coolant liquid, the thermo parameters method in guarantee reactor section is more evenly.
Preferably, the powder feeder in the step S8 is using tall board-like powder feeder, and powder must be sent to flame during powder feeding The heart can make powder obtain optimal heating and speed.
Preferably, it is sprayed in workpiece fabrication in the step S11, the temperature for controlling entire workpiece heats up, heating temperature Degree is no more than 200 DEG C, enters auxiliary quenching using blower, facilitates the temperature of control workpiece.
Preferably, it needs in the spraying process of the step S11 and the cooling procedure of step S12 in the interior of dust removal by ventilation It carries out, the adsorbing powder dust of generation is filtered by filter screen and acticarbon, guarantees working environment.
Compared with prior art, the beneficial effects of the present invention are: the plasma ashing tungsten spraying production of strict control of the present invention Technique, by strict control plasma spray coating process data, the coating obtained by plasma spraying is flat and smooth, consistency Height, and powder deposition is very high, and matrix is not charged, non-fusible in spraying process, and matrix and spray gun relative moving speed are fast, makes Matrix is obtained not change.The shape and performance of matrix will not be impacted because of heated, working gas is inertia Gas protects matrix and powder not and will receive oxidation, and impurity is few in coating, and easy to operate, cost of equipment maintenance is low, modulability Can be good, and tungsten-carbide powder is handled by mechanical enhancer, and spraying penetration works well, and logical in spraying and cooling procedure The adsorbing powder dust generated in the course of work can be filtered effectively, guarantee working environment by the indoor progress of wind dedusting, be suitble to wide General popularization.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not For limiting the present invention.
Embodiment 1
A kind of plasma ashing tungsten spraying production technology, specific step is as follows for plasma ashing tungsten spraying production technology:
S1: workpiece pretreatment will need the workpiece that sprays to be drawn as CAD diagram paper matrix formula, according to drawing pattern to needing on workpiece Area to be protected is protected;
S2: blasting treatment will need the workpiece sprayed to use compressed air for power, to form high velocity spray beam for material spray High speed, which is ejected into, need to handle workpiece surface, and the appearance of workpiece surface or shape is made to change;
S3: sanding and polishing processing send the workpiece that blasting treatment in S2 is completed to progress sanding and polishing processing on polishing machine, The revolving speed of polishing machine is in 1500r/min, machining accuracy: surface roughness Ra≤0.25 μm;
S4: tungsten carbide raw material is crushed and is uniformly mixed by ball-milling technology by tungsten carbide processing;
S5: thermal response will obtain broken raw material and carry out thermal response in the ion stream of plasma generator to obtain in S4 Mixture of powders;
S6: the mixture of powders in S5 is put into the bronze drum of centrifugal planetary grinder by mechanical enhancer, with diameter 8mm Copper ball the grinding of 5min is carried out to powder, wherein copper ball weight 200g, powder are added at one time weight no more than 10g, obtain powder Expect spare;
S7: N is selected in equipment adjustment2Gas is adjusted as plasma gas, gas flow 2000L/h, pressure 0.8MPa Whole arc power, so that arc temperature control is at 2870 DEG C;
S8: powder supply will obtain powder by powder feeder and supply powder to spray gun in S6;
S9: spray distance and angle of spray adjust the nozzle face of spray gun to the linear distance of workpiece surface, and spray distance exists 70mm, angle of spray are 60 °;
S10: workpiece the pre-heat treatment preheats the workpiece in S3, and preheating temperature is at 80 DEG C;
S11: spraying sprays the workpiece in S10 using spray gun, and spray gun movement speed is the 30% of pressure lid spot, For thickness in 0.15 mm shallow layer below, the coating layer thickness sprayed every time does not exceed 0.02 mm, spray gun movement speed Also have an impact to the temperature rise of workpiece, for Bu Shi matrix local temperature rise is excessively high and causes thermal deformation or thermal stress excessive, work can be improved The method of part linear velocity accelerates the movement speed of spray gun;
S12: workpiece cooling packing, the workpiece that spraying is completed carry out natural cooling, carry out packaging and storing after the completion of cooling.
Material spray in the step S2 can be one of copper ore, quartz sand, diamond dust, iron sand and sea sand, described Workpiece makes the surface of workpiece obtain certain cleaning by impact and shear action of the blasting treatment to workpiece surface in step S2 Degree and different roughness, improve the mechanical performance of workpiece surface, improve the fatigue resistance of workpiece, increase it and Adhesive force between coating extends the durability of film, is conducive to the levelling and decoration of coating, the ball milling in the step S4 Broken mixing is carried out using horizontal ball mill, the revolving speed of mill tube is 45r/min, and charging volume is 20L, in the step S5 etc. Ion generator uses laminar-flow type plasmatron, and the state of the plasma jet of laminar-flow type plasmatron is from laminar flow It is gradually transitions turbulent flow, in the process, while adhesion strength is decreased obviously, the discreteness of data is also increasing, finally The repeatability of coating performance is caused to degenerate, the oxidation spray coating on side surface, dielectric strength 1.5kV is prevented in reactor There is electric arc divided on internal inverted conductive wall and on surface after cooling, to reduce the consumption of coolant liquid, guarantees More evenly, the powder feeder in the step S8 is using tall board-like powder feeder, powder feeding process for thermo parameters method in reactor section Middle powder must be sent to flame core, and powder can be made to obtain optimal heating and speed, spray workpiece fabrication in the step S11 In, the temperature for controlling entire workpiece heats up, and warming temperature is no more than 200 DEG C, enters auxiliary quenching using blower, side Just the temperature of workpiece is controlled, is needed in the spraying process of the step S11 and the cooling procedure of step S12 in the room of dust removal by ventilation The adsorbing powder dust of generation is filtered by filter screen and acticarbon, guarantees working environment by interior progress.
Embodiment 2
A kind of plasma ashing tungsten spraying production technology, specific step is as follows for plasma ashing tungsten spraying production technology:
S1: workpiece pretreatment will need the workpiece that sprays to be drawn as CAD diagram paper matrix formula, according to drawing pattern to needing on workpiece Area to be protected is protected;
S2: blasting treatment will need the workpiece sprayed to use compressed air for power, to form high velocity spray beam for material spray High speed, which is ejected into, need to handle workpiece surface, and the appearance of workpiece surface or shape is made to change;
S3: sanding and polishing processing send the workpiece that blasting treatment in S2 is completed to progress sanding and polishing processing on polishing machine, The revolving speed of polishing machine is in 2000r/min, machining accuracy: surface roughness Ra≤0.25 μm;
S4: tungsten carbide raw material is crushed and is uniformly mixed by ball-milling technology by tungsten carbide processing;
S5: thermal response will obtain broken raw material and carry out thermal response in the ion stream of plasma generator to obtain in S4 Mixture of powders;
S6: the mixture of powders in S5 is put into the bronze drum of centrifugal planetary grinder by mechanical enhancer, with diameter 8mm Copper ball the grinding of 5min is carried out to powder, wherein copper ball weight 200g, powder are added at one time weight no more than 10g, obtain powder Expect spare;
S7: N is selected in equipment adjustment2Gas is adjusted as plasma gas, gas flow 2000L/h, pressure 0.8MPa Whole arc power, so that arc temperature control is at 2880 DEG C;
S8: powder supply will obtain powder by powder feeder and supply powder to spray gun in S6;
S9: spray distance and angle of spray adjust the nozzle face of spray gun to the linear distance of workpiece surface, and spray distance exists 110mm, angle of spray are 70 °;
S10: workpiece the pre-heat treatment preheats the workpiece in S3, and preheating temperature is at 110 DEG C;
S11: spraying sprays the workpiece in S10 using spray gun, and spray gun movement speed is the 40% of pressure lid spot, For thickness in 0.15 mm shallow layer below, the coating layer thickness sprayed every time does not exceed 0.02 mm, spray gun movement speed Also have an impact to the temperature rise of workpiece, for Bu Shi matrix local temperature rise is excessively high and causes thermal deformation or thermal stress excessive, work can be improved The method of part linear velocity accelerates the movement speed of spray gun;
S12: workpiece cooling packing, the workpiece that spraying is completed carry out natural cooling, carry out packaging and storing after the completion of cooling.
Material spray in the step S2 can be one of copper ore, quartz sand, diamond dust, iron sand and sea sand, described Workpiece makes the surface of workpiece obtain certain cleaning by impact and shear action of the blasting treatment to workpiece surface in step S2 Degree and different roughness, improve the mechanical performance of workpiece surface, improve the fatigue resistance of workpiece, increase it and Adhesive force between coating extends the durability of film, is conducive to the levelling and decoration of coating, the ball milling in the step S4 Broken mixing is carried out using horizontal ball mill, the revolving speed of mill tube is 50r/min, and charging volume is 110L, in the step S5 Plasma generator uses laminar-flow type plasmatron, and the state of the plasma jet of laminar-flow type plasmatron is from layer Stream is gradually transitions turbulent flow, and in the process, while adhesion strength is decreased obviously, the discreteness of data is also increasing, most The repeatability of coating performance is caused to degenerate afterwards, the oxidation spray coating on side surface, dielectric strength 1.5kV prevents from reacting There is electric arc divided on inverted conductive wall and on surface after cooling inside device, to reduce the consumption of coolant liquid, protects More evenly, the powder feeder in the step S8 is using tall board-like powder feeder, powder feeding for thermo parameters method in card reactor section Powder must be sent to flame core in journey, and powder can be made to obtain optimal heating and speed, spray workpiece fabrication in the step S11 In, the temperature for controlling entire workpiece heats up, and warming temperature is no more than 200 DEG C, enters auxiliary quenching using blower, side Just the temperature of workpiece is controlled, is needed in the spraying process of the step S11 and the cooling procedure of step S12 in the room of dust removal by ventilation The adsorbing powder dust of generation is filtered by filter screen and acticarbon, guarantees working environment by interior progress.
Embodiment 3
A kind of plasma ashing tungsten spraying production technology, specific step is as follows for plasma ashing tungsten spraying production technology:
S1: workpiece pretreatment will need the workpiece that sprays to be drawn as CAD diagram paper matrix formula, according to drawing pattern to needing on workpiece Area to be protected is protected;
S2: blasting treatment will need the workpiece sprayed to use compressed air for power, to form high velocity spray beam for material spray High speed, which is ejected into, need to handle workpiece surface, and the appearance of workpiece surface or shape is made to change;
S3: sanding and polishing processing send the workpiece that blasting treatment in S2 is completed to progress sanding and polishing processing on polishing machine, The revolving speed of polishing machine is in 2500 r/min, machining accuracy: surface roughness Ra≤0.25 μm;
S4: tungsten carbide raw material is crushed and is uniformly mixed by ball-milling technology by tungsten carbide processing;
S5: thermal response will obtain broken raw material and carry out thermal response in the ion stream of plasma generator to obtain in S4 Mixture of powders;
S6: the mixture of powders in S5 is put into the bronze drum of centrifugal planetary grinder by mechanical enhancer, with diameter 8mm Copper ball the grinding of 5min is carried out to powder, wherein copper ball weight 200g, powder are added at one time weight no more than 10g, obtain powder Expect spare;
S7: N is selected in equipment adjustment2Gas is adjusted as plasma gas, gas flow 2000L/h, pressure 0.8MPa Whole arc power, so that arc temperature control is at 2900 DEG C;
S8: powder supply will obtain powder by powder feeder and supply powder to spray gun in S6;
S9: spray distance and angle of spray adjust the nozzle face of spray gun to the linear distance of workpiece surface, and spray distance exists 150mm, angle of spray are 80 °;
S10: workpiece the pre-heat treatment preheats the workpiece in S3, and preheating temperature is at 150 DEG C;
S11: spraying sprays the workpiece in S10 using spray gun, and spray gun movement speed is the 30%- of pressure lid spot 50%, for thickness in 0.15 mm shallow layer below, the coating layer thickness sprayed every time does not exceed 0.02 mm, and spray gun is mobile Speed also has an impact to the temperature rise of workpiece, for Bu Shi matrix local temperature rise is excessively high and causes thermal deformation or thermal stress excessive, can mention The method of high workpiece linear velocity accelerates the movement speed of spray gun;
S12: workpiece cooling packing, the workpiece that spraying is completed carry out natural cooling, carry out packaging and storing after the completion of cooling.
Material spray in the step S2 can be one of copper ore, quartz sand, diamond dust, iron sand and sea sand, described Workpiece makes the surface of workpiece obtain certain cleaning by impact and shear action of the blasting treatment to workpiece surface in step S2 Degree and different roughness, improve the mechanical performance of workpiece surface, improve the fatigue resistance of workpiece, increase it and Adhesive force between coating extends the durability of film, is conducive to the levelling and decoration of coating, the ball milling in the step S4 Broken mixing is carried out using horizontal ball mill, the revolving speed of mill tube is 55r/min, and charging volume is 200L, in the step S5 Plasma generator uses laminar-flow type plasmatron, and the state of the plasma jet of laminar-flow type plasmatron is from layer Stream is gradually transitions turbulent flow, and in the process, while adhesion strength is decreased obviously, the discreteness of data is also increasing, most The repeatability of coating performance is caused to degenerate afterwards, the oxidation spray coating on side surface, dielectric strength 1.5kV prevents from reacting There is electric arc divided on inverted conductive wall and on surface after cooling inside device, to reduce the consumption of coolant liquid, protects More evenly, the powder feeder in the step S8 is using tall board-like powder feeder, powder feeding for thermo parameters method in card reactor section Powder must be sent to flame core in journey, and powder can be made to obtain optimal heating and speed, spray workpiece fabrication in the step S11 In, the temperature for controlling entire workpiece heats up, and warming temperature is no more than 200 DEG C, enters auxiliary quenching using blower, side Just the temperature of workpiece is controlled, is needed in the spraying process of the step S11 and the cooling procedure of step S12 in the room of dust removal by ventilation The adsorbing powder dust of generation is filtered by filter screen and acticarbon, guarantees working environment by interior progress.
The plasma ashing tungsten of strict control of the present invention sprays production technology, passes through strict control plasma spray coating process number According to the coating obtained by plasma spraying is flat and smooth, consistency is high, and powder deposition is very high, base in spraying process Body is not charged, non-fusible, and matrix and spray gun relative moving speed are fast, so that matrix does not change.It will not be because of heated And the shape and performance of matrix are impacted, working gas is inert gas, and protecting matrix and powder not will receive oxidation, Impurity is few in coating, easy to operate, and cost of equipment maintenance is low, and regulation performance is good, and tungsten-carbide powder passes through at mechanical enhancer Reason, spraying penetration work well, and in the indoor progress of dust removal by ventilation in spraying and cooling procedure, can be effectively by work The adsorbing powder dust filtering generated in the process, guarantees working environment, is suitble to be widely popularized.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (6)

1. a kind of plasma ashing tungsten sprays production technology, it is characterised in that: the plasma ashing tungsten spraying production technology is specific Steps are as follows:
S1: workpiece pretreatment will need the workpiece that sprays to be drawn as CAD diagram paper matrix formula, according to drawing pattern to needing to protect on workpiece It protects in the region of shield;
S2: blasting treatment will need the workpiece sprayed to use compressed air for power, to form high velocity spray beam for material spray high speed Workpiece surface need to be handled by being ejected into, and the appearance of workpiece surface or shape is made to change;
S3: sanding and polishing processing send the workpiece that blasting treatment in S2 is completed to progress sanding and polishing processing, polishing on polishing machine The revolving speed of machine is in 1500-2500 r/min, machining accuracy: surface roughness Ra≤0.25 μm;
S4: tungsten carbide raw material is crushed and is uniformly mixed by ball-milling technology by tungsten carbide processing;
S5: thermal response will obtain broken raw material and carry out thermal response in the ion stream of plasma generator to obtain powder in S4 Mixture;
S6: the mixture of powders in S5 is put into the bronze drum of centrifugal planetary grinder by mechanical enhancer, with the copper of diameter 8mm Ball carries out the grinding of 5min to powder, wherein copper ball weight 200g, and powder is added at one time weight no more than 10g, and it is standby to obtain powder With;
S7: N is selected in equipment adjustment2Gas adjusts electric arc as plasma gas, gas flow 2000L/h, pressure 0.8MPa Power, so that arc temperature control is at 2870 DEG C -2900 DEG C;
S8: powder supply will obtain powder by powder feeder and supply powder to spray gun in S6;
S9: spray distance and angle of spray adjust the nozzle face of spray gun to the linear distance of workpiece surface, and spray distance is in 70- 150mm, angle of spray are 60 ° -80 °;
S10: workpiece the pre-heat treatment preheats the workpiece in S3, and preheating temperature is between 80 DEG C -150 DEG C;
S11: spraying sprays the workpiece in S10 using spray gun, and spray gun movement speed is the 30%-50% of pressure lid spot, For thickness in 0.15 mm shallow layer below, the coating layer thickness sprayed every time does not exceed 0.02 mm, spray gun movement speed Also have an impact to the temperature rise of workpiece, for Bu Shi matrix local temperature rise is excessively high and causes thermal deformation or thermal stress excessive, work can be improved The method of part linear velocity accelerates the movement speed of spray gun;
S12: workpiece cooling packing, the workpiece that spraying is completed carry out natural cooling, carry out packaging and storing after the completion of cooling.
2. a kind of plasma ashing tungsten according to claim 1 sprays production technology, it is characterised in that: in the step S2 Material spray can be one of for copper ore, quartz sand, diamond dust, iron sand and sea sand.
3. a kind of plasma ashing tungsten according to claim 1 sprays production technology, it is characterised in that: in the step S4 Ball milling broken mixing is carried out using horizontal ball mill, the revolving speed of mill tube is 45-55r/min, and charging volume is 20L-200L.
4. a kind of plasma ashing tungsten according to claim 1 sprays production technology, it is characterised in that: in the step S8 Powder feeder using tall board-like powder feeder, powder must be sent to flame core during powder feeding, so that powder obtains optimal heating And speed.
5. a kind of plasma ashing tungsten according to claim 1 sprays production technology, it is characterised in that: the step S11 In middle spraying workpiece fabrication, the temperature for controlling entire workpiece heats up, and warming temperature is no more than 200 DEG C, is entered using blower Quenching is assisted, so that facilitating the temperature of control workpiece.
6. a kind of plasma ashing tungsten according to claim 1 sprays production technology, it is characterised in that: the step S11 Spraying process and step S12 cooling procedure in need indoor progress in dust removal by ventilation, pass through filter screen and active carbon inhaled The attached dose of adsorbing powder dust by generation filters, so that guaranteeing working environment.
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