CN107474706B - A kind of house ornamentation aqueous wooden ware wiping color base material and preparation method thereof - Google Patents
A kind of house ornamentation aqueous wooden ware wiping color base material and preparation method thereof Download PDFInfo
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- CN107474706B CN107474706B CN201710657839.6A CN201710657839A CN107474706B CN 107474706 B CN107474706 B CN 107474706B CN 201710657839 A CN201710657839 A CN 201710657839A CN 107474706 B CN107474706 B CN 107474706B
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- base material
- color base
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- wooden ware
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of house ornamentation aqueous wooden wares to wipe color base material and preparation method thereof, which is made of the raw material of following mass percent: aqueous alkide resin: 10%~20%；Propylene glycol: 70%~80%；Alcohol ether cosolvent: 5%~10%；Defoaming agent: 0.1%~0.3%；Wetting agent: 0.2%~0.5%；Thickener: 0.5%~1%；Sterilization antiseptic: 0.1%~0.2%；Water: surplus.The wiping color base material the preparation method is as follows: aqueous alkide resin and mixed with propylene glycol is uniform, add alcohol ether cosolvent, defoaming agent, wetting agent and thickener, be uniformly mixed, be eventually adding water and sterilization antiseptic, be uniformly mixed.House ornamentation aqueous wooden ware of the invention wipes excellent color base material coloring effect, wiping color uniform in effect, can rub long time, wetability and good leveling property, will not generate the disadvantages such as shrinkage cavity, can significantly improve the bleed and bleeding efficiency of base-material.
Description
Technical field
The present invention relates to a kind of house ornamentation aqueous wooden wares to wipe color base material and preparation method thereof.
Background technique
Wiping color base material is that woodwork coating industry is common a kind of for handling the coating variety of ground, has protection to ground
Effect, can also impart to ground color, highlights ground texture, and there are also certain filling effects to ground for part wiping color base material.
Traditional oiliness, which is wiped, contains a large amount of volatile organic solvent in color base material, the ingredient being also harmful to the human body containing benzene, formaldehyde etc.,
Volatile organic compounds (VOC) discharge is very high in work progress, not only unfavorable to the health of construction personnel, but also can pollute
Ambient enviroment, the color base material of oiliness wiping at present is substantially replaced aqueous wiping color base material.
The aqueous coloring principle for wiping color is that product is applied to the coating surface that need to be coloured, and is tightly wrapped by water-based resin
Aqueous color essence is gradually coloured toward film micropore permeation, under the osmosis of cosolvent and lotion it can be considered that generally
It is not required to form a film, wipes film after erasing 15~60min colouring.Wherein, most important performance indicator is the bleeding of product
Property, erasing property and can rub the time.By the membrane formation mechanism of aqueous emulsion paint it is found that with moisture volatilization, emulsion particle phase
Mutually close, contact stacks and generates capillary pressure, makes to generate between particle and squeezes, interpenetrates and gradually form film.It is forming a film
Also erasing is acted gradually in the process and generates resistance, as time increases, this resistance gradually becomes larger, and erasing operation is caused to become
Must be difficult, it so that uniform coloring effect is not achieved, or even can be carried out erasing operation not.Until that cannot be further continued for since erasing
It rubs (ideal coloring effect cannot be reached at this time), is known as this period that the time can be rubbed.
Use nanoscale acrylic emulsion as film forming matter, tool currently, commercially available aqueous wooden ware wipes color base material multiselect
The permeability having had can reach good coloring effect, but the time is not long, and large area is applied than that comparatively fast, can rub for rate of drying
Work, which is be easy to cause, wipes the non-uniform problem of color, has certain limitation to the construction of large area.
Summary of the invention
The purpose of the present invention is to provide a kind of house ornamentation aqueous wooden wares to wipe color base material and preparation method thereof.
The technical solution used in the present invention is:
A kind of house ornamentation aqueous wooden ware wiping color base material, is made of the raw material of following mass percent:
Aqueous alkide resin: 10%~20%；
Propylene glycol: 70%~80%；
Alcohol ether cosolvent: 5%~10%；
Defoaming agent: 0.1%~0.3%；
Wetting agent: 0.2%~0.5%；
Thickener: 0.5%~1%；
Sterilization antiseptic: 0.1%~0.2%；
Water: surplus.
The aqueous alkide resin is long oil aqueous alkide resin.
The alcohol ether cosolvent is by alcohol ester 12 and dipropylene according to mass ratio 1:(0.2~0.5) mixing and
At.
The defoaming agent is polyether silicone defoaming agent.
The wetting agent is acetylenic glycols surfactant.
The thickener is nonionic polyurethane Associative thickener.
The sterilization antiseptic is benzoisothiazolinone derivative.
Above-mentioned house ornamentation wipes the preparation method of color base material with aqueous wooden ware, comprising the following steps: by aqueous alkide resin and third
Glycol is uniformly mixed, and adds alcohol ether cosolvent, defoaming agent, wetting agent and thickener, is uniformly mixed, is eventually adding water and sterilization
Preservative is uniformly mixed, and is obtained house ornamentation aqueous wooden ware and is wiped color base material.
The beneficial effects of the present invention are: house ornamentation of the invention is wiped with aqueous wooden ware, color base material coloring effect is excellent, wipes color is imitated
Fruit is uniform, can rub time length, wetability and good leveling property, will not generate the disadvantages such as shrinkage cavity, can significantly improve the infiltration of base-material
Color and bleeding efficiency.
1) present invention is by addition long oil aqueous alkide resin, and optimizes its dosage, the coloring effect of the paint film of acquisition
It is excellent；
2) present invention is by high boiling alcohol ester 12 and with the dipropylene and long oil water for dissolving film effect
Property alkyd resin be used cooperatively, the evaporation rate of moisture can be delayed, so can dramatically increase wipe when rubbing of color base material
Between, the time can be rubbed up to 2h, higher than similar product on the market；
3) present invention is added with a large amount of propylene glycol, good to the dissolubility of color essence, and propylene glycol has slow curing effect, so that
Wiping color base material has the sufficiently long levelling bleeding time, and it is more uniform to wipe color effect.
Specific embodiment
A kind of house ornamentation aqueous wooden ware wiping color base material, is made of the raw material of following mass percent:
Aqueous alkide resin: 10%~20%；
Propylene glycol: 70%~80%；
Alcohol ether cosolvent: 5%~10%；
Defoaming agent: 0.1%~0.3%；
Wetting agent: 0.2%~0.5%；
Thickener: 0.5%~1%；
Sterilization antiseptic: 0.1%~0.2%；
Water: surplus.
Preferably, the aqueous alkide resin is long oil aqueous alkide resin.
Preferably, the alcohol ether cosolvent is by alcohol ester 12 and dipropylene according to mass ratio 1:(0.2~0.5)
It mixes.
Preferably, the defoaming agent is polyether silicone defoaming agent.
Preferably, the wetting agent is acetylenic glycols surfactant.
Preferably, the thickener is nonionic polyurethane Associative thickener.
Preferably, the sterilization antiseptic is benzoisothiazolinone derivative.
Above-mentioned house ornamentation wipes the preparation method of color base material with aqueous wooden ware, comprising the following steps: by aqueous alkide resin and third
Glycol is uniformly mixed, and adds alcohol ether cosolvent, defoaming agent, wetting agent and thickener, is uniformly mixed, is eventually adding water and sterilization
Preservative is uniformly mixed, and is obtained house ornamentation aqueous wooden ware and is wiped color base material.
The present invention will be further explained combined with specific embodiments below and explanation.
Embodiment 1:
A kind of house ornamentation aqueous wooden ware wiping color base material, raw material composition are as shown in the table:
A kind of house ornamentation of table 1 forms table with the raw material that aqueous wooden ware wipes color base material
Embodiment 2:
A kind of house ornamentation aqueous wooden ware wiping color base material, raw material composition are as shown in the table:
A kind of house ornamentation of table 2 forms table with the raw material that aqueous wooden ware wipes color base material
Embodiment 3:
A kind of house ornamentation aqueous wooden ware wiping color base material, raw material composition are as shown in the table:
A kind of house ornamentation of table 3 forms table with the raw material that aqueous wooden ware wipes color base material
Embodiment 4:
A kind of house ornamentation aqueous wooden ware wiping color base material, raw material composition are as shown in the table:
A kind of house ornamentation of table 4 forms table with the raw material that aqueous wooden ware wipes color base material
Test case:
1) color base material is wiped with aqueous wooden ware to the house ornamentation of Examples 1 to 4 preparation to carry out that time test, test result can be rubbed
It is as shown in the table:
The house ornamentation aqueous wooden ware wiping color base material of 5 Examples 1 to 4 of table rubs time test result
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| The time (h) can be rubbed | 1.2 | 1.5 | 2.0 | 1.5 |
2) performance contrast test is carried out to the wiping color base material of embodiment 3, commercially available wiping color base material 1 and commercially available wiping color base material 2, surveyed
Test result is as shown in the table:
6 embodiment 3 of table wipes color base material, the commercially available performance comparison test result for wiping color base material 1 and commercially available wiping color base material 2
| Detection project | The wiping color base material of embodiment 3 | Commercially available wiping color base material 1 | Commercially available wiping color base material 2 |
| Condition in container | Uniformly without lump after stirring | Uniformly without lump after stirring | Uniformly without lump after stirring |
| Erasing property | Easily erasing | Easily erasing | Easily erasing |
| Coloring | Normally | Normally | Normally |
| The time (h) can be rubbed | 2.0 | 0.5 | 1.0 |
| Soak levelability | It is outstanding | Well | Well |
| Wipe Color uniformity | It is outstanding | Generally | Well |
| Low-temperature stability | It never degenerates | It never degenerates | It never degenerates |
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (5)
1. a kind of house ornamentation wipes color base material with aqueous wooden ware, it is characterised in that: be made of the raw material of following mass percent:
Aqueous alkide resin: 10%~20%；
Propylene glycol: 70%~80%；
Alcohol ether cosolvent: 5%~10%；
Defoaming agent: 0.1%~0.3%；
Wetting agent: 0.2%~0.5%；
Thickener: 0.5%~1%；
Sterilization antiseptic: 0.1%~0.2%；
Water: surplus；
The aqueous alkide resin is long oil aqueous alkide resin；
The alcohol ether cosolvent is by alcohol ester 12 and dipropylene according to mass ratio 1:(0.2~0.5) it mixes；
The wetting agent is acetylenic glycols surfactant.
2. house ornamentation according to claim 1 wipes color base material with aqueous wooden ware, it is characterised in that: the defoaming agent is polyethers
Silicone antifoam agent.
3. house ornamentation according to claim 1 with aqueous wooden ware wipe color base material, it is characterised in that: the thickener be it is non-from
Sub- polyurethane associative thickener.
4. house ornamentation according to claim 1 wipes color base material with aqueous wooden ware, it is characterised in that: the sterilization antiseptic is
Benzoisothiazolinone derivative.
5. house ornamentation described in any one of Claims 1 to 4 wipes the preparation method of color base material with aqueous wooden ware, feature exists
In: the following steps are included: aqueous alkide resin and mixed with propylene glycol is uniform, add alcohol ether cosolvent, defoaming agent, wetting agent
And thickener, it is uniformly mixed, is eventually adding water and sterilization antiseptic, be uniformly mixed, obtain house ornamentation aqueous wooden ware and wipe color base material.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710657839.6A CN107474706B (en) | 2017-08-03 | 2017-08-03 | A kind of house ornamentation aqueous wooden ware wiping color base material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710657839.6A CN107474706B (en) | 2017-08-03 | 2017-08-03 | A kind of house ornamentation aqueous wooden ware wiping color base material and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107474706A CN107474706A (en) | 2017-12-15 |
| CN107474706B true CN107474706B (en) | 2019-11-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710657839.6A Active CN107474706B (en) | 2017-08-03 | 2017-08-03 | A kind of house ornamentation aqueous wooden ware wiping color base material and preparation method thereof |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109627947A (en) * | 2018-12-13 | 2019-04-16 | 广东华兹卜新材料科技有限公司 | A kind of woodenware shows line coating and its manufacturing method and application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102226051A (en) * | 2011-03-30 | 2011-10-26 | 北京化工大学 | Glaze coloring agent for waterborne woodenware coating and preparation method thereof |
| CN102363679A (en) * | 2011-06-30 | 2012-02-29 | 成都倍大涂料有限公司 | Water-soluble glaze and preparation method thereof |
| CN103031022A (en) * | 2012-12-28 | 2013-04-10 | 天津市美冠科技有限公司 | Environment-friendly water based color-brushing agent and preparation method thereof |
| CN103360851A (en) * | 2012-03-30 | 2013-10-23 | 唐述华 | Development method of novel water-based timber rubbling coloring agent |
-
2017
- 2017-08-03 CN CN201710657839.6A patent/CN107474706B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102226051A (en) * | 2011-03-30 | 2011-10-26 | 北京化工大学 | Glaze coloring agent for waterborne woodenware coating and preparation method thereof |
| CN102363679A (en) * | 2011-06-30 | 2012-02-29 | 成都倍大涂料有限公司 | Water-soluble glaze and preparation method thereof |
| CN103360851A (en) * | 2012-03-30 | 2013-10-23 | 唐述华 | Development method of novel water-based timber rubbling coloring agent |
| CN103031022A (en) * | 2012-12-28 | 2013-04-10 | 天津市美冠科技有限公司 | Environment-friendly water based color-brushing agent and preparation method thereof |
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| CN107474706A (en) | 2017-12-15 |
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