CN107474695A - A kind of heat preservation energy-saving coating for building and preparation method thereof - Google Patents

A kind of heat preservation energy-saving coating for building and preparation method thereof Download PDF

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Publication number
CN107474695A
CN107474695A CN201710807023.7A CN201710807023A CN107474695A CN 107474695 A CN107474695 A CN 107474695A CN 201710807023 A CN201710807023 A CN 201710807023A CN 107474695 A CN107474695 A CN 107474695A
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Prior art keywords
parts
mixture
epoxy resin
heat preservation
building
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CN201710807023.7A
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Chinese (zh)
Inventor
陆日琪
汪治兴
梁毅颉
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Nanning Public Interspace Technology Ltd
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Nanning Public Interspace Technology Ltd
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Priority to CN201710807023.7A priority Critical patent/CN107474695A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of heat preservation energy-saving coating for building, it is made up of following raw material according to parts by weight:46 parts of 20 30 parts of perlite, 12 16 parts of mica powder, 12 26 parts of epoxy resin, 5 10 parts of powdered whiting, 48 parts of zircon sand, 25 parts of polypropylene monofilament fiber, 8 14 parts of flyash, 22 30 parts of plant ash, 35 parts of sodium soil powder, 6 15 parts of bauxite, 6 12 parts of titanium dioxide, 8 13 parts of ethylene glycol, 0.5 1.6 parts of dispersant, 4 10 parts of emulsifying agent, 15 22 parts of coalescents and water reducer.Matrix is formed using perlite, mica powder, zircon sand and polypropylene monofilament fiber in the present invention, again matrix is wrapped up with epoxy resin and under the cooperation of the components such as zircon sand, mica, the finished product of preparation has good thermal and insulating performance, meets the use demand of people, wide market.

Description

A kind of heat preservation energy-saving coating for building and preparation method thereof
Technical field
The present invention relates to building thermal-insulation energy-saving Material Field, specifically a kind of heat preservation energy-saving coating for building.
Background technology
According to statistics, more than 50% raw material of substance that the mankind obtain from nature is used for building all kinds of buildings, and these buildings exist Build the energy with consuming the whole world 50% or so during use again.After world oil crisis in 1973, many flourishing states Family recognizes the importance of building energy conservation, formulates in succession and implements the special law of energy-conservation, is directed to research and is built with carrying out Power-saving technology.Now, while comfortableness improves constantly, new building unit area energy consumption has been reduced these national buildings 1/1st to five/3rd before by more than 30 years.In addition, these developed countries also expand large-scale section to existing building It can transform, therefore alleviate the energy demand of country, avoid the impact once again of energy crisis.
Under construction, the thermal losses of peripheral structure is larger, and wall account for very big share again in peripheral structure.According to system
Meter, the wall thermal losses for not carrying out isothermal holding account for 50%.Therefore, it is to build to develop outer wall heat insulating energy saving technology and material The main implementation of energy-conservation is built, thermal insulation coatings are a kind of conventional INSULATION DESIGNs, but the insulation of existing thermal insulation coatings is imitated Fruit is bad, therefore a kind of coating of high insulating effect has broad application prospects.
The content of the invention
It is an object of the invention to provide a kind of heat preservation energy-saving coating for building, to solve what is proposed in above-mentioned background technology Problem.
To achieve the above object, the present invention provides following technical scheme:
A kind of heat preservation energy-saving coating for building, is made up of following raw material according to parts by weight:Perlite 20-30 parts, mica powder 12-16 Part, epoxy resin 12-26 parts, powdered whiting 5-10 parts, zircon sand 4-8 parts, polypropylene monofilament fiber 2-5 parts, flyash 8- 14 parts, plant ash 22-30 parts, sodium soil powder 3-5 parts, bauxite 6-15 parts, titanium dioxide 6-12 parts, ethylene glycol 8-13 parts, dispersant 0.5-1.6 parts, emulsifying agent 4-10 parts, coalescents 15-22 parts and water reducer 4-6 parts.
As the further scheme of the present invention:The length of polypropylene monofilament fiber is 4-8mm, and epoxy resin uses phenolic aldehyde ring At least one of oxygen tree fat, glycidyl amine epoxy resin and alicyclic based epoxy resin.
As the further scheme of the present invention:Perlite uses spherical closed pore expanded perlite, and coalescents use propylene It is resin emulsion, emulsifying agent uses one or several kinds of mixing in OP-10 emulsifying agents, T80 emulsifying agents and S60 emulsifying agents Thing.
The preparation method of the heat preservation energy-saving coating for building, is comprised the following steps that:
Step 1, perlite, mica powder, zircon sand and polypropylene monofilament fiber are dried in drying box, after then drying Product be crushed to 210-280 mesh, obtain the first mixture;
Step 2, epoxy resin, dispersant and coalescents are mixed with 60-90rpm rotating speed, divide 3-5 while stirring Secondary equivalent adds powdered whiting, sodium soil powder, bauxite, titanium dioxide and ethylene glycol, with 180-270rpm after being added completely into Rotating speed stir to being uniformly dispersed, obtain the second mixture;
Step 3, flyash, plant ash, emulsifying agent and 60-80 degrees Celsius of water are added in the second mixture with 240- 360rpm rotating speed stirring, stands after emulsification, obtains the 3rd mixture completely;
Step 4, the first mixture and the 3rd mixture are mixed and be sufficiently stirred, you can obtains finished product.
As the further scheme of the present invention:A kind of drying temperature of drying box of step is 80-120 degrees Celsius.
Compared with prior art, the beneficial effects of the invention are as follows:Raw material sources of the present invention are extensive, and preparation technology is simple, fit For large-scale industrial production;Base is formed using perlite, mica powder, zircon sand and polypropylene monofilament fiber in the present invention Body, then wrap up matrix and under the cooperation of the components such as zircon sand, mica with epoxy resin, the finished product of preparation has good guarantor Warm heat-proof quality, meet the use demand of people, wide market.
Embodiment
The technical scheme of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of heat preservation energy-saving coating for building, is made up of following raw material according to parts by weight:20 parts of perlite, 12 parts of mica powder, ring 12 parts of oxygen tree fat, 5 parts of powdered whiting, 4 parts of zircon sand, 2 parts of polypropylene monofilament fiber, 8 parts of flyash, 22 parts of plant ash, sodium Native 3 parts of powder, 6 parts of bauxite, 6 parts of titanium dioxide, 8 parts of ethylene glycol, 0.5 part of dispersant, 4 parts of emulsifying agent, 15 parts of coalescents and subtract 4 parts of aqua.The length of polypropylene monofilament fiber is 6mm, and epoxy resin uses alicyclic based epoxy resin.
The preparation method of the heat preservation energy-saving coating for building, is comprised the following steps that:
Step 1, perlite, mica powder, zircon sand and polypropylene monofilament fiber are dried in drying box, after then drying Product be crushed to 240 mesh, obtain the first mixture;
Step 2, epoxy resin, dispersant and coalescents are mixed with 60rpm rotating speed, divide 4 equivalent while stirring Powdered whiting, sodium soil powder, bauxite, titanium dioxide and ethylene glycol are added, is stirred after being added completely into 210rpm rotating speed To being uniformly dispersed, the second mixture is obtained;
Step 3, flyash, plant ash, emulsifying agent and 66 degrees Celsius of water are added in the second mixture with 270rpm rotating speed Stood after stirring, completely emulsification, obtain the 3rd mixture;
Step 4, the first mixture and the 3rd mixture are mixed and be sufficiently stirred, you can obtains finished product.
Embodiment 2
A kind of heat preservation energy-saving coating for building, is made up of following raw material according to parts by weight:24 parts of spherical closed pore expanded perlite, cloud 14 parts of female powder, 18 parts of epoxy resin, 8 parts of powdered whiting, 6 parts of zircon sand, 3 parts of polypropylene monofilament fiber, 10 parts of flyash, grass 25 parts of wood ash, 4 parts of sodium soil powder, 9 parts of bauxite, 9 parts of titanium dioxide, 10 parts of ethylene glycol, 1 part of dispersant, 6 parts of emulsifying agent, propylene 5 parts of 18 parts of resin emulsion and water reducer.Emulsifying agent is using OP-10 emulsifying agents and the mixture of S60 emulsifying agents.
The preparation method of the heat preservation energy-saving coating for building, is comprised the following steps that:
Step 1, by the drying of spherical closed pore expanded perlite, mica powder, zircon sand and polypropylene monofilament fiber at 90 degrees Celsius Dried in case, the product after drying is then crushed to 260 mesh, obtain the first mixture;
Step 2, epoxy resin, dispersant and propylene resin latex are mixed with 75rpm rotating speed, divide 5 while stirring Secondary equivalent adds powdered whiting, sodium soil powder, bauxite, titanium dioxide and ethylene glycol, is turned after being added completely into 240rpm Speed stirring obtains the second mixture to being uniformly dispersed;
Step 3, flyash, plant ash, emulsifying agent and 75 degrees Celsius of water are added in the second mixture with 300rpm rotating speed Stood after stirring, completely emulsification, obtain the 3rd mixture;
Step 4, the first mixture and the 3rd mixture are mixed and be sufficiently stirred, you can obtains finished product.
Embodiment 3
A kind of heat preservation energy-saving coating for building, is made up of following raw material according to parts by weight:28 parts of perlite, 15 parts of mica powder, ring 23 parts of oxygen tree fat, 8 parts of powdered whiting, 7 parts of zircon sand, 4 parts of polypropylene monofilament fiber, 12 parts of flyash, 27 parts of plant ash, sodium Native 4.5 parts of powder, 13 parts of bauxite, 11 parts of titanium dioxide, 12 parts of ethylene glycol, 1.4 parts of dispersant, 8 parts of emulsifying agent, 20 parts of coalescents With 5.5 parts of water reducer.The length of polypropylene monofilament fiber is 6mm, and epoxy resin uses glycidyl amine epoxy resin and fat The mixture of ring same clan epoxy resin.Perlite uses spherical closed pore expanded perlite, and coalescents are using propylene resin breast Glue, emulsifying agent use T80 emulsifying agents.
The preparation method of the heat preservation energy-saving coating for building, is comprised the following steps that:
Step 1, spherical closed pore expanded perlite, mica powder, zircon sand and polypropylene monofilament fiber are dried in drying box, Then the product after drying is crushed to 240 mesh, obtains the first mixture;
Step 2, epoxy resin, dispersant and propylene resin latex are mixed with 80rpm rotating speed, divide 5 while stirring Secondary equivalent adds powdered whiting, sodium soil powder, bauxite, titanium dioxide and ethylene glycol, is turned after being added completely into 260rpm Speed stirring obtains the second mixture to being uniformly dispersed;
Step 3, flyash, plant ash, T80 emulsifying agents and 80 degrees Celsius of water are added in the second mixture with 330rpm's Rotating speed stirs, and is stood completely after emulsification, obtains the 3rd mixture;
Step 4, the first mixture and the 3rd mixture are mixed and be sufficiently stirred, you can obtains finished product.
Embodiment 4
A kind of heat preservation energy-saving coating for building, is made up of following raw material according to parts by weight:30 parts of perlite, 16 parts of mica powder, ring 26 parts of oxygen tree fat, 10 parts of powdered whiting, 8 parts of zircon sand, 5 parts of polypropylene monofilament fiber, 14 parts of flyash, 30 parts of plant ash, 5 parts of sodium soil powder, 15 parts of bauxite, 12 parts of titanium dioxide, 13 parts of ethylene glycol, 1.6 parts of dispersant, 10 parts of emulsifying agent, coalescents 22 6 parts of part and water reducer.The length of polypropylene monofilament fiber is 6mm, and epoxy resin is using novolac epoxy resin, glycidol amine The mixture of epoxy resin and alicyclic based epoxy resin.Perlite uses spherical closed pore expanded perlite, and coalescents use Propylene resin latex, emulsifying agent use the mixture of OP-10 emulsifying agents, T80 emulsifying agents and S60 emulsifying agents.
The preparation method of the heat preservation energy-saving coating for building, is comprised the following steps that:
Step 1, perlite, mica powder, zircon sand and polypropylene monofilament fiber are dried in 105 degrees Celsius of drying box, so The product after drying is crushed to 280 mesh afterwards, obtains the first mixture;
Step 2, epoxy resin, dispersant and coalescents are mixed with 80rpm rotating speed, divide 3 equivalent while stirring Powdered whiting, sodium soil powder, bauxite, titanium dioxide and ethylene glycol are added, is stirred after being added completely into 270rpm rotating speed To being uniformly dispersed, the second mixture is obtained;
Step 3, flyash, plant ash, emulsifying agent and 80 degrees Celsius of water are added in the second mixture with 360rpm rotating speed Stood after stirring, completely emulsification, obtain the 3rd mixture;
Step 4, the first mixture and the 3rd mixture are mixed and be sufficiently stirred, you can obtains finished product.
Powdered whiting can increase small product size, reduce cost, and improve binding ability.Spherical closed pore expanded perlite Its particle shell is continuous whole vitreous surface, has some strength, and the resistant to breakage ability of particle is excellent, hydrone be not easy into Enter, water absorption rate is very low, and its slurry workability is good, and final finished has excellent heat preservation and energy conservation effects.Polypropylene monofilament is fine Dimension has the characteristics that alkali resistance, acid-resisting, not absorbed water, completely not by corrosion, is a kind of high reinforcing material of durability.Use In the slurry, its cracking resistance, impervious, shock resistance, freeze proof, abrasive resistance can be improved, while improves its toughness and ductility, so as to protect The durability of card system.Mica has good insulating properties, heat resistance, antiacid, alkali resistance, resistance to compression and stripping point property, can strengthen The heat-insulating property of product.The resistance to elevated temperatures and corrosion resistance and good of zircon sand, the stability of finished product can be strengthened.Titanium dioxide was both As colouring agent, there is reinforcement, anti-aging and filling again, add the adhesive force between various components.By asphalt mixtures modified by epoxy resin Fat parcel perlite, mica powder, zircon sand and the fibroplastic matrix of polypropylene monofilament, are emulsified under emulsifying agent effect, The coating associativity of formation is good, and each component collaboration plays a role, and has good energy-saving heat preserving effect, meets the use need of people Ask.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.

Claims (5)

1. a kind of heat preservation energy-saving coating for building, it is characterised in that be made up of following raw material according to parts by weight:Perlite 20-30 Part, mica powder 12-16 parts, epoxy resin 12-26 parts, powdered whiting 5-10 parts, zircon sand 4-8 parts, polypropylene monofilament fiber 2-5 parts, flyash 8-14 parts, plant ash 22-30 parts, sodium soil powder 3-5 parts, bauxite 6-15 parts, titanium dioxide 6-12 parts, ethylene glycol 8-13 parts, dispersant 0.5-1.6 parts, emulsifying agent 4-10 parts, coalescents 15-22 parts and water reducer 4-6 parts.
2. heat preservation energy-saving coating for building according to claim 1, it is characterised in that the length of the polypropylene monofilament fiber Spend and used for 4-8mm, epoxy resin in novolac epoxy resin, glycidyl amine epoxy resin and alicyclic based epoxy resin It is at least one.
3. heat preservation energy-saving coating for building according to claim 1 or 2, it is characterised in that the perlite uses ball-type Closed-cell expanded perlite, coalescents use propylene resin latex, emulsifying agent using OP-10 emulsifying agents, T80 emulsifying agents and One or several kinds of mixtures in S60 emulsifying agents.
4. the preparation method of a kind of heat preservation energy-saving coating for building as described in claim 1-3 is any, it is characterised in that specific Step is as follows:
Step 1, perlite, mica powder, zircon sand and polypropylene monofilament fiber are dried in drying box, after then drying Product be crushed to 210-280 mesh, obtain the first mixture;
Step 2, epoxy resin, dispersant and coalescents are mixed with 60-90rpm rotating speed, divide 3-5 while stirring Secondary equivalent adds powdered whiting, sodium soil powder, bauxite, titanium dioxide and ethylene glycol, with 180-270rpm after being added completely into Rotating speed stir to being uniformly dispersed, obtain the second mixture;
Step 3, flyash, plant ash, emulsifying agent and 60-80 degrees Celsius of water are added in the second mixture with 240- 360rpm rotating speed stirring, stands after emulsification, obtains the 3rd mixture completely;
Step 4, the first mixture and the 3rd mixture are mixed and be sufficiently stirred, you can obtains finished product.
5. the preparation method of heat preservation energy-saving coating for building according to claim 4, it is characterised in that the step is a kind of The drying temperature of drying box is 80-120 degrees Celsius.
CN201710807023.7A 2017-09-08 2017-09-08 A kind of heat preservation energy-saving coating for building and preparation method thereof Pending CN107474695A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112876992A (en) * 2021-01-22 2021-06-01 涂晶 Anti-aging coating for building exterior wall and preparation method thereof

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CN102173680A (en) * 2011-01-26 2011-09-07 公安部四川消防研究所 Heat-insulating energy-saving flame-retardant material for external wall
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Publication number Priority date Publication date Assignee Title
CN102173680A (en) * 2011-01-26 2011-09-07 公安部四川消防研究所 Heat-insulating energy-saving flame-retardant material for external wall
CN103265865A (en) * 2013-04-24 2013-08-28 瑞安市德仕节能材料科技有限公司 Production technology of water-soluble volcanic ash paint

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112876992A (en) * 2021-01-22 2021-06-01 涂晶 Anti-aging coating for building exterior wall and preparation method thereof

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Application publication date: 20171215