CN107474540A - A kind of modified, high temperature resistant air filter silica gel air induction hose - Google Patents
A kind of modified, high temperature resistant air filter silica gel air induction hose Download PDFInfo
- Publication number
- CN107474540A CN107474540A CN201710707194.2A CN201710707194A CN107474540A CN 107474540 A CN107474540 A CN 107474540A CN 201710707194 A CN201710707194 A CN 201710707194A CN 107474540 A CN107474540 A CN 107474540A
- Authority
- CN
- China
- Prior art keywords
- parts
- modified
- silica gel
- air filter
- high temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of modified, high temperature resistant air filter silica gel air induction hose, it is extruded by silicon rubber composite material and formed, and the raw material of the silicon rubber composite material includes following components by weight:50 65 parts of silicon rubber, 40 55 parts of SGA, 20 30 parts of polyborosiloxane, 0.5 3 parts of stearic acid, 0.8 2.5 parts of sulphur, 28 parts of nano zine oxide, 45 60 parts of paraffin wax, 10 25 parts of atoleine, 0.5 2.5 parts of high wear-resistant carbon black, 0.5 2 parts of calcium carbonate, 0.8 2.5 parts of softening agent, 0.5 2 parts of alkaline soap, 0.5 2 parts of age resistor, 0.5 2 parts of accelerator, 15 parts of polyethylene polyamine.Present invention process is simple, high yield rate, and product resistance to elevated temperatures is good, and mechanical property is good.
Description
Technical field
The present invention relates to a kind of silastic product, more particularly, to a kind of modified, high temperature resistant air filter silica gel air induction hose.
Background technology
Automobile engine is very accurate parts, and minimum impurity can all damage engine.Therefore, air is into gas
Before cylinder, it is necessary to first pass through air cleaner(Air filter)Fine and closely woven filtering, cylinder could be entered.If make in running car
Used dirty air filter, engine charge can be made insufficient, make fuel oil incomplete combustion, cause engine job insecurity, power
Decline, the increased phenomenon of fuel consumption occurs.Therefore, automobile must keep the cleaning of air filter, and air filter is guarding for engine
God, the quality of air filter state are related to the life-span length of engine.Wherein with air filter performance it is closely bound up be air filter
Air induction hose, because air filter needs to work under the high temperature conditions for a long time in the process of running, therefore air induction hose also needs
Will can high temperature resistant, in order to avoid influence the overall operating efficiency of air filter.Organic silicon rubber is that output is maximum in organosilicon industry
A kind of product, thus as a mostly important branch in field of organic silicon.Due to the Si-O-Si keys in organic silicon rubber
Exist in the form of cross-linked network, therefore organic silicon rubber has a good high and low temperature resistance, weatherability, warm radiation hardness and absolutely
The special natures such as edge, there is its extensively and unique use in fields such as daily life life, electric, industry and Aero-Space
On the way.
Such as a kind of a kind of automobile-used rubber tube of high temperature resistant announced in Chinese patent document, its application publication number are CN
104592606 A, it is mainly made up of hydrogenated nitrile-butadiene rubber, nitrile rubber, ethylene propylene diene rubber and other auxiliary agents.It is this resistance to
Hot car rubber tube, not only oil resistance raising, is provided simultaneously with good resistance to elevated temperatures, is not easy out in 120 DEG C of high temperature
Existing aging, be hardened, embrittlement, fracture the problem of, service life increases significantly.But this high-temperature resistant rubber pipe still has many not
The place of foot, such as its main component are hydrogenated nitrile-butadiene rubber, nitrile rubber, although these rubber have certain heat-resisting quantity
Can, but its resistant to elevated temperatures upper limit is relatively low, often can only at 150 DEG C steady operation, therefore when temperature in use is more than 150 DEG C just
It can not work on.
The content of the invention
The present invention is to overcome prior art resistance to elevated temperatures poor, long-term use of under the high temperature conditions can not be asked
Topic, there is provided one kind has preferable resistance to elevated temperatures, a kind of modified, high temperature resistant air filter silicon that can be used under the high temperature conditions for a long time
Glue air induction hose.
To achieve these goals, the present invention uses following technical scheme:
A kind of modified, high temperature resistant air filter silica gel air induction hose, it is extruded by silicon rubber composite material and formed, and the silicon rubber is answered
The raw material of condensation material includes following components by weight:Silicon rubber 50-65 parts, SGA 40-55 parts, polyborosiloxane
20-30 parts, stearic acid 0.5-3 parts, sulphur 0.8-2.5 parts, nano zine oxide 2-8 parts, paraffin wax 45-60 parts, atoleine
10-25 parts, high wear-resistant carbon black 0.5-2.5 parts, calcium carbonate 0.5-2 parts, softening agent 0.8-2.5 parts, alkaline soap 0.5-2 parts, prevent
Old agent 0.5-2 parts, accelerator 0.5-2 parts, polyethylene polyamine 1-5 parts.
Silicon rubber has fabulous high and low temperature resistance, and its high temperature resistant maximum temperature is up to 250-300 DEG C, and acrylate
Glue at present can also be long-term use of at 175 DEG C, therefore the main material using both materials as air filter silica gel air induction hose
Material enables to air filter silica gel air induction hose to be used steadily in the long term under high temperature under the conditions of 200 DEG C, and its instantaneous highest is resistance to
Temperature is even up to 330 DEG C.Polyborosiloxane (PBS) refers to that some silicon atoms in the silica skeleton of polysiloxanes are former by boron
Polymer obtained from son substitution, B-O keys and Si-O keys in polyborosiloxane molecule are high bond energy chemical bond, key
Can be respectively 537.6kJ/mo1,422.5kJ/mol, it is pi-conjugated p- π, d- in structure to be again present, causes poly- borosilicate oxygen
The more common organopolysiloxane of alkane has more excellent heat-resisting quantity, and polyborosiloxane is added in silicon rubber, can be significantly
Lift the resistance to elevated temperatures and mechanical property at high temperature of silicon rubber.By adding paraffin wax, atoleine, more ethene
Polyamines, alkaline soap, softening agent and age resistor etc. can lift the compatibility between rubber component, add rubber
Plasticity, improves the ageing-resistant performance of rubber, and makes the flat appearance of rubber indefectible, improves the outward appearance of final products.Firmly
Resin acid, zinc oxide, sulphur and the addition of accelerator enable the sulfidation of rubber effectively to carry out, so that being plasticity
Rubber is converted into elastic caoutchouc, the rubber with practical value shaped.And high wear-resistant carbon black and calcium carbonate can be with
The overall rubber of reinforcement so that final air filter air induction hose has higher mechanical strength.
Preferably, in the raw material of the silicon rubber composite material, the weight of silicon rubber, SGA and polyborosiloxane
It is 50-60 to measure ratio:40-60:20-30.
Preferably, the synthesis step of described polyborosiloxane is as follows:The synthesis step of described polyborosiloxane is such as
Under:By 3-8 part boric acid, 2-6 part phenyl triethoxysilanes, 10-15 part dimethyldiethoxysilanes, 6-10 part ethylene methacrylics
Base dimethoxysilane, 50-70 part absolute ethyl alcohols, 10-15 part deionized waters, 3-6 parts 5mol/L hydrochloric acid, it is added sequentially to anti-
Answer in kettle, stir, back flow reaction 2-3 hours, steam solvent, be washed to neutrality, 80 DEG C are dried in vacuo 5 hours, obtain poly- borosilicate
Oxygen alkane.Polyborosiloxane is synthesized by hydrolysis of the boric acid with alkoxy silane under hydrochloric acid catalysis, and synthetic method is simple, after
Processing is simple, easy to implement.
Preferably, in the raw material of the silicon rubber composite material, in addition to organosilicon MQ resin 5-15 parts, the silicon rubber
In the raw material of glue composite, in addition to organosilicon MQ resin 5-15 parts, the synthesis step of described MQ resins are as follows:By 50-
60 parts of tetraethoxysilanes, 4-8 part HMDOs, 3-6 parts 1,3- divinyl 1,1,3,3 ,-tetramethyl disiloxane
Add in reactor and stir, then add 10-15 part water, the concentrated hydrochloric acid of 3-5 parts 37%, be warming up to 60 DEG C, react 3 hours,
Ethanol is steamed, 100 parts of toluene extractions is added, is washed to neutrality, then steam toluene, 80 DEG C are dried in vacuo 8 hours, obtain MQ trees
Fat.MQ resins due to its molecular backbone be Si-O keys it is identical with silicon rubber therefore very good with the compatibility of silicon rubber, while by
In its branched structure, therefore network structure can be formed with silicon rubber main chain, play a part of reinforcement.
Preferably, described high wear-resistant carbon black, by being modified, its step is as follows:A certain amount of silane coupler is taken to be dissolved in
Water-ethanol 1:In 1 solution, high wear-resistant carbon black is added at room temperature, ultrasonic disperse 5 minutes is heated to 50 DEG C, stirring reaction 1 hour,
Filtering, obtained filter cake is washed with absolute ethyl alcohol and is dried in vacuo 3 hours at 3 times, 70 DEG C, is obtained through silane coupler modified
High wear-resistant carbon black.
Because high wear-resistant carbon black surface is there is also more hydroxyl, therefore in order to improve the phase of high wear-resistant carbon black and rubber
Capacitive, while lift the reinforcing property of nanometer high wear-resistant carbon black, it is also desirable to by surface treatment.
Preferably, described silane coupler be silane resin acceptor kh-550, it is silane coupler KH-560, silane coupled
One or more mixtures in agent KH-580 or silane coupler KH-792, described silane coupler and water-ethanol 1:1
The mass ratio of solution is 1:5, its dosage of described silane coupler is the 10% of high wear-resistant carbon black.
Silane coupler effectively can be reacted with the hydroxyl on high wear-resistant carbon black surface, so that hydroxyl quantity subtracts
It is few, simultaneously as the material of main part of this air filter silica gel air induction hose is silica gel, can also be increased using silane coupler and high
Compatibility between abrasion resistant carbon black and silica gel.
Preferably, described softening agent is that dioctyl phthalate, dibutyl phthalate or decanedioic acid two are pungent
One or more mixtures in ester.These softening agent itselfs can have good compatible sexual compatibility with rubber, change
During kind rubber processing, the consumption for being kneaded power can be reduced, promotes the dispersed of various auxiliary materials, improves stretching for vulcanizate
The processing performances such as long rate resilience.
Preferably, described age resistor is in antioxidant 4010NA, age resistor 1010, age resistor 1076 or phosphite ester
One or more.Some age resistor are incorporated in rubber, so as to extend the storage period of rubber and its product and service life.
Preferably, described accelerator is N tert butyl benzothiazole 2 sulfenamide (NS), 2-mercaptobenzothiazole
(Captax)Or dibenzothiazyl disulfide(DM)In one or more.Cure time can be shortened by adding accelerator, reduce sulphur
Change temperature, reduce vulcanizing agent dosage and improve physical and mechanical properties of rubber etc..
Preferably, the preparation method of high temperature resistant air filter silica gel air induction hose comprises the following specific steps that:
(a)One section of mixing is carried out first, and mill is warming up to 50 DEG C, first addition silicon rubber, acrylate are fully plasticated,
Stearic acid, paraffin wax, atoleine glue are added, then by two-stage mixing, it is mixed that mill is warming up to 80 DEG C of one section of additions
Refine obtained sizing material, sequentially add calcium carbonate, alkaline soap, age resistor, high wear-resistant carbon black, softening agent, zinc oxide, sulphur,
Accelerator, is eventually adding polyethylene polyamine, and after being kneaded uniformly, regulating roller is thin logical 4 times away from for 0.5-1mm, obtains elastomeric compound;
(b)By step(a)In obtained elastomeric compound pipe embryo is obtained by extruder for shaping, head temperature is 35-45 DEG C, mouth
Type temperature is 75-85 DEG C;
(c)The pipe embryo of forming is sleeved on core rod, is put into steam vulcanization tank and is vulcanized, sulfuration steam pressure is 0.3-
0.6MPa, cure time are 1 hour, obtain sebific duct;
(d)The above-mentioned sebific duct through over cure is taken off from core rod, after cutting cleaning treatment, is put into baking oven and carries out drying temperature
For 175 DEG C, cure time is 6 hours, obtains finished product.
Step(a)Middle to be kneaded methods using two sections, mixing time is grown during avoiding one section of mixing method, and sizing material temperature is low
Shortcoming, two-stage mixing method have that each refining glue time is short, and melting temperature is low, and compounding ingredient is scattered evenly, the high spy of sizing material quality
Point.Step(b)It is middle to use extruding-out process, sizing material is reached the purpose of extruding and preliminary moulding.
Therefore, the present invention has the advantages that:(1)Resistance to elevated temperatures is good;(2)The simple production process of product, it is raw
Produce efficiency high.
Embodiment
Technical scheme is made to further describe explanation below by specific embodiment.
If without specified otherwise, the raw material that use is said in embodiments of the invention is raw material commonly used in the art, is implemented
Method employed in example, it is the conventional method of this area.
Embodiment 1
The present embodiment provides a kind of modified, high temperature resistant air filter silica gel air induction hose, and it is extruded by silicon rubber composite material and formed,
The raw material of the silicon rubber composite material includes following components by weight:50 parts of silicon rubber, 40 parts of SGA, poly- borosilicate
20 parts of oxygen alkane, 0.5 part of stearic acid, 0.8 part of sulphur, 2 parts of nano zine oxide, 45 parts of paraffin wax, 10 parts of atoleine, high abrasion
0.5 part of carbon black, 0.5 part of calcium carbonate, 0.8 part of softening agent dioctyl phthalate, 0.5 part of alkaline soap, antioxidant 4010NA
0.5 part, accelerator N-tertiary butyl -0.5 part of 2-[4-morpholinodithio sulfenamide, 1 part of polyethylene polyamine, 5 parts of MQ resins.
The synthesis step of polyborosiloxane is as follows:By 3 parts of boric acid, 2 parts of phenyl triethoxysilanes, 10 parts of dimethyl diethyls
TMOS, 6 parts of methylvinyldimethoxysilanes, 50 parts of absolute ethyl alcohols, 10 parts of deionized waters, 3 parts of 5mol/L hydrochloric acid,
It is added sequentially in reactor, stirs, back flow reaction 3 hours, steam solvent, is washed to neutrality, 80 DEG C are dried in vacuo 5 hours,
Obtain polyborosiloxane.
The synthesis step of MQ resins is as follows:By 50 parts of tetraethoxysilanes, 4 parts of HMDOs, 3 parts of 1,3- diethyls
Alkenyl 1,1,3,3 ,-tetramethyl disiloxane is added in reactor and stirred, and then adds 10 parts of water, 3 part of 37% dense salt
Acid, is warming up to 60 DEG C, reacts 3 hours, steams ethanol, adds 100 parts of toluene extractions, is washed to neutrality, then steams toluene, and 80
DEG C vacuum drying 8 hours, obtain MQ resins.
The modification method of high wear-resistant carbon black is as follows:10g silane coupler KH-560 is taken to be dissolved in water-ethanol 1:1 is molten
In liquid 50g, high wear-resistant carbon black 100g is added at room temperature, ultrasonic disperse 5 minutes, 50 DEG C is heated to, stirring reaction 1 hour, filters,
Obtained filter cake is washed with absolute ethyl alcohol and is dried in vacuo 3 hours at 3 times, 70 DEG C, obtains being modified through silane coupler KH-560
High wear-resistant carbon black.
A kind of preparation method of modified, high temperature resistant air filter silica gel air induction hose comprises the following specific steps that:
(a)One section of mixing is carried out first, mill is warming up to 50 DEG C, is first added silicon rubber, acrylate, polyborosiloxane and is entered
Row is fully plasticated, and adds stearic acid, paraffin wax, atoleine glue, then by two-stage mixing, mill is warming up into 80
DEG C adding one section is kneaded obtained sizing material, sequentially add calcium carbonate, alkaline soap, age resistor, high wear-resistant carbon black, MQ resins,
Softening agent, zinc oxide, sulphur, accelerator, are eventually adding polyethylene polyamine, and after being kneaded uniformly, regulating roller is thin by logical 4 away from for 0.5mm
It is secondary, obtain elastomeric compound;
(b)By step(a)In obtained elastomeric compound pipe embryo is obtained by extruder for shaping, head temperature is 35 DEG C, the shape of the mouth as one speaks
Temperature is 75 DEG C;
(c)The pipe embryo of forming is sleeved on core rod, is put into steam vulcanization tank and is vulcanized, sulfuration steam pressure is
0.3MPa, cure time are 1 hour, obtain sebific duct;
(d)The above-mentioned sebific duct through over cure is taken off from core rod, after cutting cleaning treatment, is put into baking oven and carries out drying temperature
For 175 DEG C, cure time is 6 hours, obtains finished product.
Described finished product passes through Mechanics Performance Testing, and its shore hardness is 79, tensile strength 12.6MPa, extension at break
Rate is 400%;Finished product is tested through exertin TGA, and its condition is as follows, 50-800 DEG C of temperature range, 10 DEG C/min of heating rate, nitrogen
Under the conditions of, temperature is 313 DEG C when thermally decomposing 5%, and temperature when thermally decomposing 50% is 506 DEG C, and thermal decomposition outlet temperature is 600 DEG C,
Remaining carbon is 35%.
Embodiment 2
The present embodiment provides a kind of modified, high temperature resistant air filter silica gel air induction hose, and it is extruded by silicon rubber composite material and formed,
The raw material of the silicon rubber composite material includes following components by weight:55 parts of silicon rubber, 45 parts of SGA, poly- boron
30 parts of siloxanes, 1 part of stearic acid, 1.25 parts of sulphur, 5 parts of nano zine oxide, 55 parts of paraffin wax, 20 parts of atoleine are high resistance to
Grind 1.75 parts of carbon black, 1 part of calcium carbonate, 1.5 parts of softening agent dibutyl phthalate, 1 part of alkaline soap, age resistor 1,010 1
Part, 1 part of accelerator 2-mercaptobenzothiazole, 2.5 parts of polyethylene polyamine, 15 parts of MQ resins.
The synthesis step of polyborosiloxane is as follows:By 8 parts of boric acid, 6 parts of phenyl triethoxysilanes, 15 parts of dimethyl two
Ethoxysilane, 6-10 part methylvinyldimethoxysilanes, 50-70 part absolute ethyl alcohols, 10-15 part deionized waters, 6 parts
5mol/L hydrochloric acid, is added sequentially in reactor, stirring, back flow reaction 2 hours, steams solvent, is washed to neutrality, and 80 DEG C true
Sky is dried 5 hours, obtains polyborosiloxane.
The synthesis step of MQ resins is as follows:By 50-60 part tetraethoxysilanes, 8 parts of HMDOs, 6 part 1,
3- divinyl 1,1,3,3 ,-tetramethyl disiloxane is added in reactor and stirred, and then adds 15 parts of water, 5 parts
37% concentrated hydrochloric acid, 60 DEG C are warming up to, reacted 3 hours, steam ethanol, added 100 parts of toluene extractions, be washed to neutrality, then steam
Toluene, 80 DEG C are dried in vacuo 8 hours, obtain MQ resins.
The modification method of high wear-resistant carbon black is as follows:20g silane resin acceptor kh-550 is taken to be dissolved in water-ethanol 1:1 is molten
In liquid 100g, high wear-resistant carbon black 200g is added at room temperature, and ultrasonic disperse 5 minutes is heated to 50 DEG C, stirring reaction 1 hour, mistake
Filter, obtained filter cake is washed with absolute ethyl alcohol and is dried in vacuo 3 hours at 3 times, 70 DEG C, obtains changing through silane resin acceptor kh-550
The high wear-resistant carbon black of property.
A kind of preparation method of modified, high temperature resistant air filter silica gel air induction hose comprises the following specific steps that:
(a)One section of mixing is carried out first, mill is warming up to 50 DEG C, is first added silicon rubber, acrylate, polyborosiloxane and is entered
Row is fully plasticated, and adds stearic acid, paraffin wax, atoleine glue, then by two-stage mixing, mill is warming up into 80
DEG C adding one section is kneaded obtained sizing material, sequentially add calcium carbonate, alkaline soap, age resistor, high wear-resistant carbon black, MQ resins,
Softening agent, zinc oxide, sulphur, accelerator, are eventually adding polyethylene polyamine, and after being kneaded uniformly, regulating roller is thin by logical 4 away from for 1 mm
It is secondary, obtain elastomeric compound;
(b)By step(a)In obtained elastomeric compound pipe embryo is obtained by extruder for shaping, head temperature is 45 DEG C, the shape of the mouth as one speaks
Temperature is 85 DEG C;
(c)The pipe embryo of forming is sleeved on core rod, is put into steam vulcanization tank and is vulcanized, sulfuration steam pressure is
0.49MPa, cure time are 1 hour, obtain sebific duct;
(d)The above-mentioned sebific duct through over cure is taken off from core rod, after cutting cleaning treatment, is put into baking oven and carries out drying temperature
For 175 DEG C, cure time is 6 hours, obtains finished product.
Described finished product passes through Mechanics Performance Testing, and its shore hardness is 78, tensile strength 13.2MPa, extension at break
Rate is 345%;Finished product is tested through exertin TGA, and its condition is as follows, 50-800 DEG C of temperature range, 10 DEG C/min of heating rate, nitrogen
Under the conditions of, temperature is 305 DEG C when thermally decomposing 5%, and temperature when thermally decomposing 50% is 469 DEG C, and thermal decomposition outlet temperature is 595 DEG C,
Remaining carbon is 33%.
Embodiment 3
The present embodiment provides a kind of modified, high temperature resistant air filter silica gel air induction hose, and it is extruded by silicon rubber composite material and formed,
The raw material of the silicon rubber composite material includes following components by weight:65 parts of silicon rubber, 55 parts of SGA, poly- boron
23 parts of siloxanes, 3 parts of stearic acid, 2.5 parts of sulphur, 8 parts of nano zine oxide, 60 parts of paraffin wax, 25 parts of atoleine, high abrasion
2.5 parts of carbon black, 2 parts of calcium carbonate, 2.5 parts of softening agent di-n-octyl sebacate, 2 parts of alkaline soap, 1,076 2 parts of age resistor, accelerator
1 part of 2-mercaptobenzothiazole, 1 part of accelerator dibenzothiazyl disulfide, 2.5 parts of polyethylene polyamine, 10 parts of MQ resins.
The synthesis step of polyborosiloxane is as follows:By 5 parts of boric acid, 4 parts of phenyl triethoxysilanes, 12 parts of dimethyl diethyls
TMOS, 8 parts of methylvinyldimethoxysilanes, 60 parts of absolute ethyl alcohols, 13 parts of deionized waters, 5 parts of 5mol/L hydrochloric acid,
It is added sequentially in reactor, stirs, back flow reaction 2.5 hours, steam solvent, be washed to neutrality, 80 DEG C of vacuum drying 5 is small
When, obtain polyborosiloxane.
The synthesis step of MQ resins is as follows:By 50-60 part tetraethoxysilanes, 5 parts of HMDOs, 5 part 1,3-
Divinyl 1,1,3,3 ,-tetramethyl disiloxane is added in reactor and stirred, and then adds 12 parts of water, 4 part 37% is dense
Hydrochloric acid, 60 DEG C are warming up to, reacted 3 hours, steam ethanol, added 100 parts of toluene extractions, be washed to neutrality, then steam toluene,
80 DEG C are dried in vacuo 8 hours, obtain MQ resins.
The modification method of high wear-resistant carbon black is as follows:20g silane coupler KH-580 is taken to be dissolved in water-ethanol 1:1 is molten
In liquid 100g, high wear-resistant carbon black 200g is added at room temperature, and ultrasonic disperse 5 minutes is heated to 50 DEG C, stirring reaction 1 hour, mistake
Filter, obtained filter cake is washed with absolute ethyl alcohol and is dried in vacuo 3 hours at 3 times, 70 DEG C, obtains changing through silane coupler KH-580
The high wear-resistant carbon black of property.
A kind of preparation method of modified, high temperature resistant air filter silica gel air induction hose comprises the following specific steps that:
(a)One section of mixing is carried out first, mill is warming up to 50 DEG C, is first added silicon rubber, acrylate, polyborosiloxane and is entered
Row is fully plasticated, and adds stearic acid, paraffin wax, atoleine glue, then by two-stage mixing, mill is warming up into 80
DEG C adding one section is kneaded obtained sizing material, sequentially add calcium carbonate, alkaline soap, age resistor, high wear-resistant carbon black, MQ resins,
Softening agent, zinc oxide, sulphur, accelerator, are eventually adding polyethylene polyamine, and after being kneaded uniformly, regulating roller is thin by logical 4 away from for 1 mm
It is secondary, obtain elastomeric compound;
(b)By step(a)In obtained elastomeric compound pipe embryo is obtained by extruder for shaping, head temperature is 45 DEG C, the shape of the mouth as one speaks
Temperature is 85 DEG C;
(c)The pipe embryo of forming is sleeved on core rod, is put into steam vulcanization tank and is vulcanized, sulfuration steam pressure is
0.4MPa, cure time are 1 hour, obtain sebific duct;
(d)The above-mentioned sebific duct through over cure is taken off from core rod, after cutting cleaning treatment, is put into baking oven and carries out drying temperature
For 175 DEG C, cure time is 6 hours, obtains finished product.
Described finished product passes through Mechanics Performance Testing, and its shore hardness is 81, tensile strength 13.6MPa, extension at break
Rate is 365%;Finished product is tested through exertin TGA, and its condition is as follows, 50-800 DEG C of temperature range, 10 DEG C/min of heating rate, nitrogen
Under the conditions of, temperature is 315 DEG C when thermally decomposing 5%, and temperature when thermally decomposing 50% is 499 DEG C, and thermal decomposition outlet temperature is 609 DEG C,
Remaining carbon is 48%.
Embodiment 4
The present embodiment provides a kind of modified, high temperature resistant air filter silica gel air induction hose, and it is extruded by silicon rubber composite material and formed,
The raw material of the silicon rubber composite material includes following components by weight:50 parts of silicon rubber, 40 parts of SGA, poly- borosilicate
28 parts of oxygen alkane, 3 parts of stearic acid, 2.5 parts of sulphur, 8 parts of nano zine oxide, 60 parts of paraffin wax, 25 parts of atoleine, high abrasion charcoal
Black 2.5 parts, 2 parts of calcium carbonate, 2.5 parts of softening agent di-n-octyl sebacate, 2 parts of alkaline soap, 1,076 1 parts of age resistor, age resistor
1076 1 parts, 2 parts of dibenzothiazyl disulfide, 5 parts of polyethylene polyamine, 15 parts of MQ resins.
The synthesis step of polyborosiloxane is as follows:By 12 parts of boric acid, 4 parts of phenyl triethoxysilanes, 14 parts of dimethyl two
Ethoxysilane, 8 parts of methylvinyldimethoxysilanes, 70 parts of absolute ethyl alcohols, 15 parts of deionized waters, 5 parts of 5mol/L's
Hydrochloric acid, it is added sequentially in reactor, stirs, back flow reaction 2 hours, steam solvent, is washed to neutrality, 80 DEG C of vacuum drying 5
Hour, obtain polyborosiloxane.
The synthesis step of MQ resins is as follows:By 55 parts of tetraethoxysilanes, 5 parts of HMDOs, 4 parts of 1,3- diethyls
Alkenyl 1,1,3,3 ,-tetramethyl disiloxane is added in reactor and stirred, and then adds 13 parts of water, 6 part of 37% dense salt
Acid, is warming up to 60 DEG C, reacts 3 hours, steams ethanol, adds 100 parts of toluene extractions, is washed to neutrality, then steams toluene, and 80
DEG C vacuum drying 8 hours, obtain MQ resins.
The modification method of high wear-resistant carbon black is as follows:20g KH-792 is taken to be dissolved in water-ethanol 1:In 1 solution 100g, room
Temperature is lower to add high wear-resistant carbon black 200g, ultrasonic disperse 5 minutes, is heated to 50 DEG C, stirring reaction 1 hour, filters, the filter that will be obtained
Cake is washed with absolute ethyl alcohol and is dried in vacuo 3 hours at 3 times, 70 DEG C, obtains the high abrasion charcoal being modified through silane coupler KH-792
It is black.
A kind of preparation method of modified, high temperature resistant air filter silica gel air induction hose comprises the following specific steps that:
(a)One section of mixing is carried out first, mill is warming up to 50 DEG C, is first added silicon rubber, acrylate, polyborosiloxane and is entered
Row is fully plasticated, and adds stearic acid, paraffin wax, atoleine glue, then by two-stage mixing, mill is warming up into 80
DEG C adding one section is kneaded obtained sizing material, sequentially add calcium carbonate, alkaline soap, age resistor, high wear-resistant carbon black, MQ resins,
Softening agent, zinc oxide, sulphur, accelerator, are eventually adding polyethylene polyamine, and after being kneaded uniformly, regulating roller is away from for 0.5 mm, Bao Tong
4 times, obtain elastomeric compound;
(b)By step(a)In obtained elastomeric compound pipe embryo is obtained by extruder for shaping, head temperature is 45 DEG C, the shape of the mouth as one speaks
Temperature is 85 DEG C;
(c)The pipe embryo of forming is sleeved on core rod, is put into steam vulcanization tank and is vulcanized, sulfuration steam pressure is
0.6MPa, cure time are 1 hour, obtain sebific duct;
(d)The above-mentioned sebific duct through over cure is taken off from core rod, after cutting cleaning treatment, is put into baking oven and carries out drying temperature
For 175 DEG C, cure time is 6 hours, obtains finished product.
Described finished product passes through Mechanics Performance Testing, and its shore hardness is 84, tensile strength 13.2MPa, extension at break
Rate is 330%;Finished product is tested through exertin TGA, and its condition is as follows, 50-800 DEG C of temperature range, 10 DEG C/min of heating rate, nitrogen
Under the conditions of, temperature is 319 DEG C when thermally decomposing 5%, and temperature when thermally decomposing 50% is 488 DEG C, and thermal decomposition outlet temperature is 603 DEG C,
Remaining carbon is 39%.
Embodiment 5
The present embodiment provides a kind of modified, high temperature resistant air filter silica gel air induction hose, and it is extruded by silicon rubber composite material and formed,
The raw material of the silicon rubber composite material includes following components by weight:60 parts of silicon rubber, 60 parts of SGA, poly- borosilicate
26 parts of oxygen alkane, 2 parts of stearic acid, 1 part of sulphur, 8 parts of nano zine oxide, 60 parts of paraffin wax, 25 parts of atoleine, high wear-resistant carbon black
2.5 parts, 2 parts of calcium carbonate, 1.2 parts of softening agent dioctyl phthalate, 0.6 part of softening agent diformazan dioctyl phthalate, alkaline soap 2
Part, 1,076 2 parts of age resistor, 0.5 part of accelerator 2-mercaptobenzothiazole, 1 part of accelerator dibenzothiazyl disulfide, more ethene
2.5 parts of polyamines, 11 parts of MQ resins.
The synthesis step of polyborosiloxane is as follows:By 8 parts of boric acid, 5 parts of phenyl triethoxysilanes, 12 parts of dimethyl diethyls
TMOS, 9 parts of methylvinyldimethoxysilanes, 66 parts of absolute ethyl alcohols, 12 parts of deionized waters, 4 parts of 5mol/L hydrochloric acid,
It is added sequentially in reactor, stirs, back flow reaction 3 hours, steam solvent, is washed to neutrality, 80 DEG C are dried in vacuo 5 hours,
Obtain polyborosiloxane.
The synthesis step of MQ resins is as follows:By 60 parts of tetraethoxysilanes, 5 parts of HMDOs, 5 parts of 1,3- diethyls
Alkenyl 1,1,3,3 ,-tetramethyl disiloxane is added in reactor and stirred, and then adds 10 parts of water, 4 part of 37% dense salt
Acid, is warming up to 60 DEG C, reacts 3 hours, steams ethanol, adds 100 parts of toluene extractions, is washed to neutrality, then steams toluene, and 80
DEG C vacuum drying 8 hours, obtain MQ resins.
The modification method of high wear-resistant carbon black is as follows:Take 10g silane coupler KH-792 and 10g silane coupler
KH-580 is dissolved in water-ethanol 1:In 1 solution 100g, high wear-resistant carbon black 200g is added at room temperature, ultrasonic disperse 5 minutes, is heated to
50 DEG C, stirring reaction 1 hour, filtering, obtained filter cake is washed with absolute ethyl alcohol and is dried in vacuo 3 hours at 3 times, 70 DEG C, is obtained
To through silane coupler modified high wear-resistant carbon black.
A kind of preparation method of modified, high temperature resistant air filter silica gel air induction hose comprises the following specific steps that:
(a)One section of mixing is carried out first, mill is warming up to 50 DEG C, is first added silicon rubber, acrylate, polyborosiloxane and is entered
Row is fully plasticated, and adds stearic acid, paraffin wax, atoleine glue, then by two-stage mixing, mill is warming up into 80
DEG C adding one section is kneaded obtained sizing material, sequentially add calcium carbonate, alkaline soap, age resistor, high wear-resistant carbon black, MQ resins,
Softening agent, zinc oxide, sulphur, accelerator, are eventually adding polyethylene polyamine, and after being kneaded uniformly, regulating roller is thin by logical 4 away from for 1 mm
It is secondary, obtain elastomeric compound;
(b)By step(a)In obtained elastomeric compound pipe embryo is obtained by extruder for shaping, head temperature is 45 DEG C, the shape of the mouth as one speaks
Temperature is 85 DEG C;
(c)The pipe embryo of forming is sleeved on core rod, is put into steam vulcanization tank and is vulcanized, sulfuration steam pressure is
0.3MPa, cure time are 1 hour, obtain sebific duct;
(d)The above-mentioned sebific duct through over cure is taken off from core rod, after cutting cleaning treatment, is put into baking oven and carries out drying temperature
For 175 DEG C, cure time is 6 hours, obtains finished product.
Described finished product passes through Mechanics Performance Testing, and its shore hardness is 84, tensile strength 13.2MPa, extension at break
Rate is 330%;Finished product is tested through exertin TGA, and its condition is as follows, 50-800 DEG C of temperature range, 10 DEG C/min of heating rate, nitrogen
Under the conditions of, temperature is 319 DEG C when thermally decomposing 5%, and temperature when thermally decomposing 50% is 488 DEG C, and thermal decomposition outlet temperature is 603 DEG C,
Remaining carbon is 39%.
Claims (10)
1. a kind of modified, high temperature resistant air filter silica gel air induction hose, it is characterized in that, it is extruded by silicon rubber composite material and formed, institute
State the raw material of silicon rubber composite material includes following components by weight:Silicon rubber 50-65 parts, SGA 40-55 parts, gather
Borosiloxane 20-30 parts, stearic acid 0.5-3 parts, sulphur 0.8-2.5 parts, nano zine oxide 2-8 parts, paraffin wax 45-60 parts,
Atoleine 10-25 parts, high wear-resistant carbon black 0.5-2.5 parts, calcium carbonate 0.5-2 parts, softening agent 0.8-2.5 parts, alkaline soap
0.5-2 parts, age resistor 0.5-2 parts, accelerator 0.5-2 parts, polyethylene polyamine 1-5 parts.
2. a kind of modified, high temperature resistant air filter silica gel air induction hose according to claim 1, it is characterized in that, the silicon rubber
In the raw material of composite, the weight ratio of silicon rubber, SGA and polyborosiloxane is 50-60:40-60:20-30.
3. a kind of modified, high temperature resistant air filter silica gel air induction hose according to claim 1 or 2, it is characterized in that, it is described
The synthesis step of polyborosiloxane is as follows:By 3-8 part boric acid, 2-6 part phenyl triethoxysilanes, 10-15 part dimethyl diethyls
TMOS, 6-10 part methylvinyldimethoxysilanes, 50-70 part absolute ethyl alcohols, 10-15 part deionized waters, 3-6 parts
5mol/L hydrochloric acid, is added sequentially in reactor, stirring, back flow reaction 2-3 hours, steams solvent, is washed to neutrality, 80 DEG C
Vacuum drying 5 hours, obtains polyborosiloxane.
4. a kind of modified, high temperature resistant air filter silica gel air induction hose according to claim 1, it is characterized in that, the silicon rubber
In the raw material of composite, in addition to organosilicon MQ resin 5-15 parts, the synthesis step of described MQ resins are as follows:By 50-60
Part tetraethoxysilane, 4-8 part HMDOs, 3-6 parts 1,3- divinyl 1,1,3,3 ,-tetramethyl disiloxane adds
Enter in reactor and stir, then add 10-15 part water, the concentrated hydrochloric acid of 3-5 parts 37%, be warming up to 60 DEG C, react 3 hours, steam
Go out ethanol, add 100 parts of toluene extractions, be washed to neutrality, then steam toluene, 80 DEG C are dried in vacuo 8 hours, obtain MQ trees
Fat.
5. a kind of modified, high temperature resistant air filter silica gel air induction hose according to claim 1, it is characterized in that, described is high resistance to
Carbon black is ground by being modified, its step is as follows:Silane coupler is taken to be dissolved in water-ethanol 1:In 1 solution, high abrasion charcoal is added at room temperature
It is black, ultrasonic disperse 5 minutes, 50 DEG C are heated to, stirring reaction 1 hour, filtering, obtained filter cake is washed 3 times with absolute ethyl alcohol,
It is dried in vacuo 3 hours, is obtained through silane coupler modified high wear-resistant carbon black at 70 DEG C.
6. a kind of modified, high temperature resistant air filter silica gel air induction hose according to claim 5, it is characterized in that, described silane
Coupling agent is silane resin acceptor kh-550, silane coupler KH-560, silane coupler KH-580 or silane coupler KH-792
In one or more mixtures, described silane coupler and water-ethanol 1:The mass ratio of 1 solution is 1:5, described silicon
Its dosage of alkane coupling agent is the 10% of high wear-resistant carbon black.
7. a kind of modified, high temperature resistant air filter silica gel air induction hose according to claim 1, it is characterized in that, described softening
Agent is one or more mixtures in dioctyl phthalate, dibutyl phthalate or di-n-octyl sebacate.
8. a kind of modified, high temperature resistant air filter silica gel air induction hose according to claim 1, it is characterized in that, described is anti-old
Agent is the one or more in antioxidant 4010NA, age resistor 1010, age resistor 1076 or phosphite ester.
9. a kind of modified, high temperature resistant air filter silica gel air induction hose according to claim 1, it is characterized in that, described promotion
Agent is one kind or more in N tert butyl benzothiazole 2 sulfenamide, 2-mercaptobenzothiazole or dibenzothiazyl disulfide
Kind.
10. a kind of modified, high temperature resistant air filter silica gel air induction hose according to claim 1, it is characterized in that, preparation method
Comprise the following specific steps that:
(a)One section of mixing is carried out first, mill is warming up to 50 DEG C, is first added silicon rubber, acrylate, polyborosiloxane and is entered
Row is fully plasticated, and adds stearic acid, paraffin wax, atoleine glue, then by two-stage mixing, mill is warming up into 80
DEG C adding one section is kneaded obtained sizing material, sequentially add calcium carbonate, alkaline soap, age resistor, high wear-resistant carbon black, MQ resins,
Softening agent, zinc oxide, sulphur, accelerator, are eventually adding polyethylene polyamine, and after being kneaded uniformly, regulating roller is thin away from for 0.5-1mm
It is logical 4 times, obtain elastomeric compound;
(b)By step(a)In obtained elastomeric compound pipe embryo is obtained by extruder for shaping, head temperature is 35-45 DEG C, mouth
Type temperature is 75-85 DEG C;
(c)The pipe embryo of forming is sleeved on core rod, is put into steam vulcanization tank and is vulcanized, sulfuration steam pressure is 0.3-
0.6MPa, cure time are 1 hour, obtain sebific duct;
(d)The above-mentioned sebific duct through over cure is taken off from core rod, after cutting cleaning treatment, is put into baking oven and carries out drying temperature
For 175 DEG C, cure time is 6 hours, obtains finished product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710707194.2A CN107474540A (en) | 2017-08-17 | 2017-08-17 | A kind of modified, high temperature resistant air filter silica gel air induction hose |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710707194.2A CN107474540A (en) | 2017-08-17 | 2017-08-17 | A kind of modified, high temperature resistant air filter silica gel air induction hose |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107474540A true CN107474540A (en) | 2017-12-15 |
Family
ID=60600941
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710707194.2A Pending CN107474540A (en) | 2017-08-17 | 2017-08-17 | A kind of modified, high temperature resistant air filter silica gel air induction hose |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107474540A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108410180A (en) * | 2018-04-24 | 2018-08-17 | 山东东都新材料科技有限公司 | A kind of environment-friendly type silica gel sebific duct and preparation method thereof |
CN110818966A (en) * | 2019-11-26 | 2020-02-21 | 西安匹克玄铠新材料有限公司 | Preparation method of polyborosiloxane modified rubber |
CN114790342A (en) * | 2022-05-25 | 2022-07-26 | 德欣精细化工(深圳)有限公司 | Silane modified carbon black composite filler and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101323667A (en) * | 2008-06-24 | 2008-12-17 | 杭州师范大学 | Preparation of methyl vinyl MQ resin for LED encapsulated strengthening |
CN103275325A (en) * | 2013-06-09 | 2013-09-04 | 上海爱世博有机硅材料有限公司 | Borosiloxane and preparation method thereof |
WO2013129709A2 (en) * | 2012-10-31 | 2013-09-06 | 三菱レイヨン株式会社 | Polyorganosiloxane-containing graft copolymer, resin composition, and molded article |
CN105419337A (en) * | 2015-11-24 | 2016-03-23 | 安徽都邦电器有限公司 | High-temperature-resistant anti-aging silicone tube |
-
2017
- 2017-08-17 CN CN201710707194.2A patent/CN107474540A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101323667A (en) * | 2008-06-24 | 2008-12-17 | 杭州师范大学 | Preparation of methyl vinyl MQ resin for LED encapsulated strengthening |
WO2013129709A2 (en) * | 2012-10-31 | 2013-09-06 | 三菱レイヨン株式会社 | Polyorganosiloxane-containing graft copolymer, resin composition, and molded article |
CN103275325A (en) * | 2013-06-09 | 2013-09-04 | 上海爱世博有机硅材料有限公司 | Borosiloxane and preparation method thereof |
CN105419337A (en) * | 2015-11-24 | 2016-03-23 | 安徽都邦电器有限公司 | High-temperature-resistant anti-aging silicone tube |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108410180A (en) * | 2018-04-24 | 2018-08-17 | 山东东都新材料科技有限公司 | A kind of environment-friendly type silica gel sebific duct and preparation method thereof |
CN110818966A (en) * | 2019-11-26 | 2020-02-21 | 西安匹克玄铠新材料有限公司 | Preparation method of polyborosiloxane modified rubber |
CN114790342A (en) * | 2022-05-25 | 2022-07-26 | 德欣精细化工(深圳)有限公司 | Silane modified carbon black composite filler and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106751889A (en) | A kind of high temperature resistance and high strength rubber composition and preparation method thereof | |
CN107474540A (en) | A kind of modified, high temperature resistant air filter silica gel air induction hose | |
CN109251375A (en) | Radial-ply tyre tread rubber composition containing isopthalic dihydrazide and preparation method thereof | |
CN1781991A (en) | Crosslinkable silicone compositions having long pot life and storage stability | |
CN109867965A (en) | A kind of high-temperature-resisting silicon rubber material and the preparation method and application thereof | |
CN111117257A (en) | Silicon rubber for automobile turbocharger tube and preparation method thereof | |
CN106366374A (en) | Oil-resistant sealing ring for motor of range hood | |
CN110372941A (en) | A kind of high density polyethylene pipe and preparation method thereof | |
CN111040167A (en) | Polymer for cross-linking and curing silicone rubber and preparation method thereof | |
CN1876719A (en) | Silicon rubber mixings composition and method for making same | |
CN110408218A (en) | A kind of high-temperature-resisting silicon rubber and preparation method thereof | |
CN114133661A (en) | Soft touch polypropylene material and preparation method thereof | |
CN106084495A (en) | A kind of automobile refrigeration system EPT rubber packing pad and preparation method thereof | |
CN107057071A (en) | The preparation method of polycarbosilane precusor | |
CN110183787A (en) | A kind of V-shaped rubber belt curing bag and its production method | |
CN114316272B (en) | Preparation process of structure control agent | |
CN115383924A (en) | Production method of shock pad | |
CN1296027A (en) | Method and making reinforced elastomer, elastomer compound material and tyre having same | |
CN109608706A (en) | A kind of preparation method of graphene rubber composite material | |
CN110092801A (en) | A kind of novel promotion silane coupling agent and preparation method thereof | |
CN113621239B (en) | Wear-resistant long-life organic silicon material and preparation method and application thereof | |
CN105837615B (en) | A kind of low pressure, two-component solvent, dual catalyst synthesizing silane coupler Si-75 method | |
CN105175903B (en) | A kind of modified rubber addition auxiliary agent and preparation method thereof | |
CN111073057B (en) | Heat-resistant additive, silicone rubber material and preparation method of silicone rubber material | |
KR101174389B1 (en) | Rubber composition for cure bladder with improved release effect and method for preparation thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171215 |