CN107474337A - A kind of anti-aging wear resisting films material and preparation method thereof - Google Patents

A kind of anti-aging wear resisting films material and preparation method thereof Download PDF

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Publication number
CN107474337A
CN107474337A CN201710734900.2A CN201710734900A CN107474337A CN 107474337 A CN107474337 A CN 107474337A CN 201710734900 A CN201710734900 A CN 201710734900A CN 107474337 A CN107474337 A CN 107474337A
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parts
wear resisting
magnesia
aging wear
microwax
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焦国平
齐继业
方兴旺
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Anhui Songtai Packing Material Co Ltd
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Anhui Songtai Packing Material Co Ltd
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Priority to CN201710734900.2A priority Critical patent/CN107474337A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The invention discloses a kind of anti-aging wear resisting films material and preparation method thereof, the anti-aging wear resisting films material is made up of the raw material of following parts by weight:20 40 parts of triallylamine, 15 25 parts of polyisoprene, 10 20 parts of diethylene glycol dibenzoate, 5 13 parts of butyl acrylate, 3 12 parts of triethanolamine borate, 8 16 parts of haloflex, 29 parts of zinc methacrylate, 38 parts of diphenyl silanediol, 37 parts of silica flour, 28 parts of vulcanizing agent, 19 parts of microwax, 3 10 parts of calcium carbonate, 28 parts of magnesium hydroxide, 16 parts of antimony oxide, 15 parts of lead oxide, 15 parts of vinyltrimethoxy silane, 0.8 3 parts of hydroxy silicon oil, 3 11 parts of m-xylene diamine, 5 10 parts of diacetyl peroxide, 48 parts of nylon fiber, 15 parts of magnesia.Thin-film material in the present invention has excellent ageing resistance and wearability, substantially increases the service life of thin-film material.

Description

A kind of anti-aging wear resisting films material and preparation method thereof
Technical field
The invention belongs to thin-film material technical field, more particularly to a kind of anti-aging wear resisting films material and its preparation side Method.
Background technology
Film is typically made of polyvinyl chloride, polyethylene, polypropylene, polystyrene and other resins, for pack or As coating layer.Commercially shared share is increasing for plastics package and plastic packet product, and particularly composite plastic is soft Packaging, has been widely used for the fields such as food, medicine, chemical industry, wherein it is maximum with packaging for foodstuff proportion, such as beverage Packaging, quick-frozen food packaging, cooking food packaging, fast food packaging etc.;However, the ageing resistance of existing thin-film material and resistance to Abrasiveness is poor, it is difficult to meets requirement.
The content of the invention
It is an object of the invention to provide a kind of anti-aging wear resisting films material and preparation method thereof, the thin-film material has Excellent ageing resistance and wearability.
To achieve the above object, the present invention provides following technical scheme:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:Triallylamine 20-40 parts, gather different Pentadiene 15-25 parts, diethylene glycol dibenzoate 10-20 parts, butyl acrylate 5-13 parts, triethanolamine borate 3-12 parts, Haloflex 8-16 parts, zinc methacrylate 2-9 parts, diphenyl silanediol 3-8 parts, silica flour 3-7 parts, vulcanizing agent 2-8 parts, Microwax 1-9 parts, calcium carbonate 3-10 parts, magnesium hydroxide 2-8 parts, antimony oxide 1-6 parts, lead oxide 1-5 parts, vinyl front three TMOS 1-5 parts, hydroxy silicon oil 0.8-3 parts, m-xylene diamine 3-11 parts, diacetyl peroxide 5-10 parts, nylon fiber 4-8 Part, magnesia 1-5 parts.
Preferably, described anti-aging wear resisting films material is made up of the raw material of following parts by weight:Triallylamine 26 Part, 22 parts of polyisoprene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, 8 parts of triethanolamine borate, chlorination gathers 10 parts of ethene, 3 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 3 parts of silica flour, 3 parts of vulcanizing agent, 5 parts of microwax, calcium carbonate 8 parts, 6 parts of magnesium hydroxide, 3 parts of antimony oxide, 2 parts of lead oxide, 5 parts of vinyltrimethoxy silane, 1 part of hydroxy silicon oil, 7 parts of benzene dimethylamine, 6 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
Preferably, described anti-aging wear resisting films material includes the raw material of following parts by weight:Triallylamine 30 Part, 20 parts of polyisoprene, 12 parts of diethylene glycol dibenzoate, 9 parts of butyl acrylate, 8 parts of triethanolamine borate, chlorination gathers 13 parts of ethene, 5 parts of zinc methacrylate, 8 parts of diphenyl silanediol, 6 parts of silica flour, 4 parts of vulcanizing agent, 4 parts of microwax, calcium carbonate 7 parts, 6 parts of magnesium hydroxide, 2 parts of antimony oxide, 2 parts of lead oxide, 3 parts of vinyltrimethoxy silane, 1.5 parts of hydroxy silicon oil, 7 parts of m-xylene diamine, 5 parts of diacetyl peroxide, 5 parts of nylon fiber, 2 parts of magnesia.
Preferably, described anti-aging wear resisting films material includes the raw material of following parts by weight:Triallylamine 24 Part, 18 parts of polyisoprene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, 6 parts of triethanolamine borate, chlorination gathers 9 parts of ethene, 6 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 5 parts of silica flour, 3 parts of vulcanizing agent, 6 parts of microwax, calcium carbonate 6 Part, 4 parts of magnesium hydroxide, 3 parts of antimony oxide, 2 parts of lead oxide, 4 parts of vinyltrimethoxy silane, 2 parts of hydroxy silicon oil, isophthalic 9 parts of dimethylamine, 8 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by triallylamine, polyisoprene, diethylene glycol dibenzoate, butyl acrylate, triethanolamine boric acid Ester, haloflex, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber, which add, to be kneaded Machine, 15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining pre-add labor and materials;
(4) the pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and vulcanized Processing, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Compared with prior art, the beneficial effects of the invention are as follows:
Thin-film material in the present invention has been especially added with zinc methacrylate, quartz, microwax, antimony oxide, ethene The raw materials such as base trimethoxy silane, m-xylene diamine and nylon fiber, thus excellent ageing resistance and wearability are made it have, Substantially increase the performance of thin-film material.
Embodiment
Technical scheme is described in detail with reference to embodiment, but protection domain is not limited thereto.
Embodiment one:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:25 parts of triallylamine, poly- isoamyl 23 parts of diene, 14 parts of diethylene glycol dibenzoate, 13 parts of butyl acrylate, 4 parts of triethanolamine borate, 9 parts of haloflex, 5 parts of zinc methacrylate, 7 parts of diphenyl silanediol, 4 parts of silica flour, 4 parts of vulcanizing agent, 6 parts of microwax, 6 parts of calcium carbonate, hydrogen-oxygen Change 5 parts of magnesium, 3 parts of antimony oxide, 2 parts of lead oxide, 3 parts of vinyltrimethoxy silane, 1.5 parts of hydroxy silicon oil, isophthalic diformazan 8 parts of amine, 8 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine, 15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Embodiment two:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:36 parts of triallylamine, poly- isoamyl 18 parts of diene, 16 parts of diethylene glycol dibenzoate, 12 parts of butyl acrylate, 11 parts of triethanolamine borate, haloflex 8 Part, 4 parts of zinc methacrylate, 4 parts of diphenyl silanediol, 5 parts of silica flour, 5 parts of vulcanizing agent, 6 parts of microwax, 7 parts of calcium carbonate, hydrogen 3 parts of magnesia, 3 parts of antimony oxide, 5 parts of lead oxide, 5 parts of vinyltrimethoxy silane, 3 parts of hydroxy silicon oil, isophthalic diformazan 11 parts of amine, 7 parts of diacetyl peroxide, 7 parts of nylon fiber, 4 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine, 15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Embodiment three:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:40 parts of triallylamine, poly- isoamyl 16 parts of diene, 17 parts of diethylene glycol dibenzoate, 10 parts of butyl acrylate, 9 parts of triethanolamine borate, haloflex 11 Part, 3 parts of zinc methacrylate, 6 parts of diphenyl silanediol, 3 parts of silica flour, 4 parts of vulcanizing agent, 9 parts of microwax, 4 parts of calcium carbonate, hydrogen 6 parts of magnesia, 5 parts of antimony oxide, 2 parts of lead oxide, 2 parts of vinyltrimethoxy silane, 1.2 parts of hydroxy silicon oil, isophthalic two 7 parts of methylamine, 10 parts of diacetyl peroxide, 5 parts of nylon fiber, 3 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine, 15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Example IV:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:26 parts of triallylamine, poly- isoamyl 22 parts of diene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, 8 parts of triethanolamine borate, 10 parts of haloflex, 3 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 3 parts of silica flour, 3 parts of vulcanizing agent, 5 parts of microwax, 8 parts of calcium carbonate, hydrogen-oxygen Change 6 parts of magnesium, 3 parts of antimony oxide, 2 parts of lead oxide, 5 parts of vinyltrimethoxy silane, 1 part of hydroxy silicon oil, m-xylene diamine 7 Part, 6 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine, 15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Embodiment five:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:30 parts of triallylamine, poly- isoamyl 20 parts of diene, 12 parts of diethylene glycol dibenzoate, 9 parts of butyl acrylate, 8 parts of triethanolamine borate, 13 parts of haloflex, 5 parts of zinc methacrylate, 8 parts of diphenyl silanediol, 6 parts of silica flour, 4 parts of vulcanizing agent, 4 parts of microwax, 7 parts of calcium carbonate, hydrogen-oxygen Change 6 parts of magnesium, 2 parts of antimony oxide, 2 parts of lead oxide, 3 parts of vinyltrimethoxy silane, 1.5 parts of hydroxy silicon oil, isophthalic diformazan 7 parts of amine, 5 parts of diacetyl peroxide, 5 parts of nylon fiber, 2 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine, 15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Embodiment six:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:24 parts of triallylamine, poly- isoamyl 18 parts of diene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, 6 parts of triethanolamine borate, 9 parts of haloflex, 6 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 5 parts of silica flour, 3 parts of vulcanizing agent, 6 parts of microwax, 6 parts of calcium carbonate, hydrogen-oxygen Change 4 parts of magnesium, 3 parts of antimony oxide, 2 parts of lead oxide, 4 parts of vinyltrimethoxy silane, 2 parts of hydroxy silicon oil, m-xylene diamine 9 Part, 8 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine, 15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention Art scheme is modified or equivalent substitution, and without departing from the objective and scope of the technical program, it all should cover in the present invention Right among.

Claims (5)

1. a kind of anti-aging wear resisting films material, it is characterised in that be made up of the raw material of following parts by weight:Triallylamine 20-40 parts, polyisoprene 15-25 parts, diethylene glycol dibenzoate 10-20 parts, butyl acrylate 5-13 parts, triethanolamine boron Acid esters 3-12 parts, haloflex 8-16 parts, zinc methacrylate 2-9 parts, diphenyl silanediol 3-8 parts, silica flour 3-7 parts, Vulcanizing agent 2-8 parts, microwax 1-9 parts, calcium carbonate 3-10 parts, magnesium hydroxide 2-8 parts, antimony oxide 1-6 parts, lead oxide 1-5 Part, vinyltrimethoxy silane 1-5 parts, hydroxy silicon oil 0.8-3 parts, m-xylene diamine 3-11 parts, diacetyl peroxide 5-10 Part, nylon fiber 4-8 parts, magnesia 1-5 parts.
2. anti-aging wear resisting films material according to claim 1, it is characterised in that by the raw material system of following parts by weight Into:26 parts of triallylamine, 22 parts of polyisoprene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, triethanolamine 8 parts of borate, 10 parts of haloflex, 3 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 3 parts of silica flour, 3 parts of vulcanizing agent, 5 parts of microwax, 8 parts of calcium carbonate, 6 parts of magnesium hydroxide, 3 parts of antimony oxide, 2 parts of lead oxide, vinyltrimethoxy silane 5 Part, 1 part of hydroxy silicon oil, 7 parts of m-xylene diamine, 6 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
3. anti-aging wear resisting films material according to claim 1, it is characterised in that include the original of following parts by weight Material:30 parts of triallylamine, 20 parts of polyisoprene, 12 parts of diethylene glycol dibenzoate, 9 parts of butyl acrylate, triethanolamine 8 parts of borate, 13 parts of haloflex, 5 parts of zinc methacrylate, 8 parts of diphenyl silanediol, 6 parts of silica flour, 4 parts of vulcanizing agent, 4 parts of microwax, 7 parts of calcium carbonate, 6 parts of magnesium hydroxide, 2 parts of antimony oxide, 2 parts of lead oxide, vinyltrimethoxy silane 3 Part, 1.5 parts of hydroxy silicon oil, 7 parts of m-xylene diamine, 5 parts of diacetyl peroxide, 5 parts of nylon fiber, 2 parts of magnesia.
4. anti-aging wear resisting films material according to claim 1, it is characterised in that include the original of following parts by weight Material:24 parts of triallylamine, 18 parts of polyisoprene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, triethanolamine 6 parts of borate, 9 parts of haloflex, 6 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 5 parts of silica flour, 3 parts of vulcanizing agent, 6 parts of microwax, 6 parts of calcium carbonate, 4 parts of magnesium hydroxide, 3 parts of antimony oxide, 2 parts of lead oxide, vinyltrimethoxy silane 4 Part, 2 parts of hydroxy silicon oil, 9 parts of m-xylene diamine, 8 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
5. the preparation method of the anti-aging wear resisting films material according to any one of claim 1-4, it is characterised in that Comprise the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by triallylamine, polyisoprene, diethylene glycol dibenzoate, butyl acrylate, triethanolamine borate, chlorine Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine, 15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxidation are sequentially added Lead, vinyltrimethoxy silane and magnesia, it is kneaded, is compressing, obtaining pre-add labor and materials;
(4) the pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out at vulcanization Reason, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
CN201710734900.2A 2017-08-24 2017-08-24 A kind of anti-aging wear resisting films material and preparation method thereof Pending CN107474337A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106349591A (en) * 2016-08-24 2017-01-25 安徽顺彤包装材料有限公司 Flame-retardant packaging material and preparation method thereof
CN106432838A (en) * 2016-11-24 2017-02-22 安徽省天乐塑业有限公司 Anti-ageing and anti-corrosion rubber material and preparation method thereof
CN106496669A (en) * 2016-11-25 2017-03-15 安徽美翔塑业有限公司 A kind of rubber tube material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106349591A (en) * 2016-08-24 2017-01-25 安徽顺彤包装材料有限公司 Flame-retardant packaging material and preparation method thereof
CN106432838A (en) * 2016-11-24 2017-02-22 安徽省天乐塑业有限公司 Anti-ageing and anti-corrosion rubber material and preparation method thereof
CN106496669A (en) * 2016-11-25 2017-03-15 安徽美翔塑业有限公司 A kind of rubber tube material and preparation method thereof

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