CN107474337A - A kind of anti-aging wear resisting films material and preparation method thereof - Google Patents
A kind of anti-aging wear resisting films material and preparation method thereof Download PDFInfo
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- CN107474337A CN107474337A CN201710734900.2A CN201710734900A CN107474337A CN 107474337 A CN107474337 A CN 107474337A CN 201710734900 A CN201710734900 A CN 201710734900A CN 107474337 A CN107474337 A CN 107474337A
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- wear resisting
- magnesia
- aging wear
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The invention discloses a kind of anti-aging wear resisting films material and preparation method thereof, the anti-aging wear resisting films material is made up of the raw material of following parts by weight:20 40 parts of triallylamine, 15 25 parts of polyisoprene, 10 20 parts of diethylene glycol dibenzoate, 5 13 parts of butyl acrylate, 3 12 parts of triethanolamine borate, 8 16 parts of haloflex, 29 parts of zinc methacrylate, 38 parts of diphenyl silanediol, 37 parts of silica flour, 28 parts of vulcanizing agent, 19 parts of microwax, 3 10 parts of calcium carbonate, 28 parts of magnesium hydroxide, 16 parts of antimony oxide, 15 parts of lead oxide, 15 parts of vinyltrimethoxy silane, 0.8 3 parts of hydroxy silicon oil, 3 11 parts of m-xylene diamine, 5 10 parts of diacetyl peroxide, 48 parts of nylon fiber, 15 parts of magnesia.Thin-film material in the present invention has excellent ageing resistance and wearability, substantially increases the service life of thin-film material.
Description
Technical field
The invention belongs to thin-film material technical field, more particularly to a kind of anti-aging wear resisting films material and its preparation side
Method.
Background technology
Film is typically made of polyvinyl chloride, polyethylene, polypropylene, polystyrene and other resins, for pack or
As coating layer.Commercially shared share is increasing for plastics package and plastic packet product, and particularly composite plastic is soft
Packaging, has been widely used for the fields such as food, medicine, chemical industry, wherein it is maximum with packaging for foodstuff proportion, such as beverage
Packaging, quick-frozen food packaging, cooking food packaging, fast food packaging etc.;However, the ageing resistance of existing thin-film material and resistance to
Abrasiveness is poor, it is difficult to meets requirement.
The content of the invention
It is an object of the invention to provide a kind of anti-aging wear resisting films material and preparation method thereof, the thin-film material has
Excellent ageing resistance and wearability.
To achieve the above object, the present invention provides following technical scheme:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:Triallylamine 20-40 parts, gather different
Pentadiene 15-25 parts, diethylene glycol dibenzoate 10-20 parts, butyl acrylate 5-13 parts, triethanolamine borate 3-12 parts,
Haloflex 8-16 parts, zinc methacrylate 2-9 parts, diphenyl silanediol 3-8 parts, silica flour 3-7 parts, vulcanizing agent 2-8 parts,
Microwax 1-9 parts, calcium carbonate 3-10 parts, magnesium hydroxide 2-8 parts, antimony oxide 1-6 parts, lead oxide 1-5 parts, vinyl front three
TMOS 1-5 parts, hydroxy silicon oil 0.8-3 parts, m-xylene diamine 3-11 parts, diacetyl peroxide 5-10 parts, nylon fiber 4-8
Part, magnesia 1-5 parts.
Preferably, described anti-aging wear resisting films material is made up of the raw material of following parts by weight:Triallylamine 26
Part, 22 parts of polyisoprene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, 8 parts of triethanolamine borate, chlorination gathers
10 parts of ethene, 3 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 3 parts of silica flour, 3 parts of vulcanizing agent, 5 parts of microwax, calcium carbonate
8 parts, 6 parts of magnesium hydroxide, 3 parts of antimony oxide, 2 parts of lead oxide, 5 parts of vinyltrimethoxy silane, 1 part of hydroxy silicon oil,
7 parts of benzene dimethylamine, 6 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
Preferably, described anti-aging wear resisting films material includes the raw material of following parts by weight:Triallylamine 30
Part, 20 parts of polyisoprene, 12 parts of diethylene glycol dibenzoate, 9 parts of butyl acrylate, 8 parts of triethanolamine borate, chlorination gathers
13 parts of ethene, 5 parts of zinc methacrylate, 8 parts of diphenyl silanediol, 6 parts of silica flour, 4 parts of vulcanizing agent, 4 parts of microwax, calcium carbonate
7 parts, 6 parts of magnesium hydroxide, 2 parts of antimony oxide, 2 parts of lead oxide, 3 parts of vinyltrimethoxy silane, 1.5 parts of hydroxy silicon oil,
7 parts of m-xylene diamine, 5 parts of diacetyl peroxide, 5 parts of nylon fiber, 2 parts of magnesia.
Preferably, described anti-aging wear resisting films material includes the raw material of following parts by weight:Triallylamine 24
Part, 18 parts of polyisoprene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, 6 parts of triethanolamine borate, chlorination gathers
9 parts of ethene, 6 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 5 parts of silica flour, 3 parts of vulcanizing agent, 6 parts of microwax, calcium carbonate 6
Part, 4 parts of magnesium hydroxide, 3 parts of antimony oxide, 2 parts of lead oxide, 4 parts of vinyltrimethoxy silane, 2 parts of hydroxy silicon oil, isophthalic
9 parts of dimethylamine, 8 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by triallylamine, polyisoprene, diethylene glycol dibenzoate, butyl acrylate, triethanolamine boric acid
Ester, haloflex, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber, which add, to be kneaded
Machine, 15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added
Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining pre-add labor and materials;
(4) the pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and vulcanized
Processing, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Compared with prior art, the beneficial effects of the invention are as follows:
Thin-film material in the present invention has been especially added with zinc methacrylate, quartz, microwax, antimony oxide, ethene
The raw materials such as base trimethoxy silane, m-xylene diamine and nylon fiber, thus excellent ageing resistance and wearability are made it have,
Substantially increase the performance of thin-film material.
Embodiment
Technical scheme is described in detail with reference to embodiment, but protection domain is not limited thereto.
Embodiment one:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:25 parts of triallylamine, poly- isoamyl
23 parts of diene, 14 parts of diethylene glycol dibenzoate, 13 parts of butyl acrylate, 4 parts of triethanolamine borate, 9 parts of haloflex,
5 parts of zinc methacrylate, 7 parts of diphenyl silanediol, 4 parts of silica flour, 4 parts of vulcanizing agent, 6 parts of microwax, 6 parts of calcium carbonate, hydrogen-oxygen
Change 5 parts of magnesium, 3 parts of antimony oxide, 2 parts of lead oxide, 3 parts of vinyltrimethoxy silane, 1.5 parts of hydroxy silicon oil, isophthalic diformazan
8 parts of amine, 8 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine
Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine,
15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added
Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out
Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Embodiment two:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:36 parts of triallylamine, poly- isoamyl
18 parts of diene, 16 parts of diethylene glycol dibenzoate, 12 parts of butyl acrylate, 11 parts of triethanolamine borate, haloflex 8
Part, 4 parts of zinc methacrylate, 4 parts of diphenyl silanediol, 5 parts of silica flour, 5 parts of vulcanizing agent, 6 parts of microwax, 7 parts of calcium carbonate, hydrogen
3 parts of magnesia, 3 parts of antimony oxide, 5 parts of lead oxide, 5 parts of vinyltrimethoxy silane, 3 parts of hydroxy silicon oil, isophthalic diformazan
11 parts of amine, 7 parts of diacetyl peroxide, 7 parts of nylon fiber, 4 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine
Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine,
15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added
Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out
Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Embodiment three:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:40 parts of triallylamine, poly- isoamyl
16 parts of diene, 17 parts of diethylene glycol dibenzoate, 10 parts of butyl acrylate, 9 parts of triethanolamine borate, haloflex 11
Part, 3 parts of zinc methacrylate, 6 parts of diphenyl silanediol, 3 parts of silica flour, 4 parts of vulcanizing agent, 9 parts of microwax, 4 parts of calcium carbonate, hydrogen
6 parts of magnesia, 5 parts of antimony oxide, 2 parts of lead oxide, 2 parts of vinyltrimethoxy silane, 1.2 parts of hydroxy silicon oil, isophthalic two
7 parts of methylamine, 10 parts of diacetyl peroxide, 5 parts of nylon fiber, 3 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine
Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine,
15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added
Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out
Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Example IV:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:26 parts of triallylamine, poly- isoamyl
22 parts of diene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, 8 parts of triethanolamine borate, 10 parts of haloflex,
3 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 3 parts of silica flour, 3 parts of vulcanizing agent, 5 parts of microwax, 8 parts of calcium carbonate, hydrogen-oxygen
Change 6 parts of magnesium, 3 parts of antimony oxide, 2 parts of lead oxide, 5 parts of vinyltrimethoxy silane, 1 part of hydroxy silicon oil, m-xylene diamine 7
Part, 6 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine
Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine,
15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added
Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out
Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Embodiment five:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:30 parts of triallylamine, poly- isoamyl
20 parts of diene, 12 parts of diethylene glycol dibenzoate, 9 parts of butyl acrylate, 8 parts of triethanolamine borate, 13 parts of haloflex,
5 parts of zinc methacrylate, 8 parts of diphenyl silanediol, 6 parts of silica flour, 4 parts of vulcanizing agent, 4 parts of microwax, 7 parts of calcium carbonate, hydrogen-oxygen
Change 6 parts of magnesium, 2 parts of antimony oxide, 2 parts of lead oxide, 3 parts of vinyltrimethoxy silane, 1.5 parts of hydroxy silicon oil, isophthalic diformazan
7 parts of amine, 5 parts of diacetyl peroxide, 5 parts of nylon fiber, 2 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine
Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine,
15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added
Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out
Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Embodiment six:
A kind of anti-aging wear resisting films material is made up of the raw material of following parts by weight:24 parts of triallylamine, poly- isoamyl
18 parts of diene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, 6 parts of triethanolamine borate, 9 parts of haloflex,
6 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 5 parts of silica flour, 3 parts of vulcanizing agent, 6 parts of microwax, 6 parts of calcium carbonate, hydrogen-oxygen
Change 4 parts of magnesium, 3 parts of antimony oxide, 2 parts of lead oxide, 4 parts of vinyltrimethoxy silane, 2 parts of hydroxy silicon oil, m-xylene diamine 9
Part, 8 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
The preparation method of described anti-aging wear resisting films material, it comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by brombutyl, polyvinylidene fluoride resin, butadiene-styrene rubber, butyl acrylate, triethanolamine borate, chlorine
Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine,
15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxygen are sequentially added
Change lead, vinyltrimethoxy silane and magnesia, be kneaded, be compressing, obtaining rubber pre-add labor and materials;
(4) the rubber pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out
Vulcanizing treatment, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of the technical program, it all should cover in the present invention
Right among.
Claims (5)
1. a kind of anti-aging wear resisting films material, it is characterised in that be made up of the raw material of following parts by weight:Triallylamine
20-40 parts, polyisoprene 15-25 parts, diethylene glycol dibenzoate 10-20 parts, butyl acrylate 5-13 parts, triethanolamine boron
Acid esters 3-12 parts, haloflex 8-16 parts, zinc methacrylate 2-9 parts, diphenyl silanediol 3-8 parts, silica flour 3-7 parts,
Vulcanizing agent 2-8 parts, microwax 1-9 parts, calcium carbonate 3-10 parts, magnesium hydroxide 2-8 parts, antimony oxide 1-6 parts, lead oxide 1-5
Part, vinyltrimethoxy silane 1-5 parts, hydroxy silicon oil 0.8-3 parts, m-xylene diamine 3-11 parts, diacetyl peroxide 5-10
Part, nylon fiber 4-8 parts, magnesia 1-5 parts.
2. anti-aging wear resisting films material according to claim 1, it is characterised in that by the raw material system of following parts by weight
Into:26 parts of triallylamine, 22 parts of polyisoprene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, triethanolamine
8 parts of borate, 10 parts of haloflex, 3 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 3 parts of silica flour, 3 parts of vulcanizing agent,
5 parts of microwax, 8 parts of calcium carbonate, 6 parts of magnesium hydroxide, 3 parts of antimony oxide, 2 parts of lead oxide, vinyltrimethoxy silane 5
Part, 1 part of hydroxy silicon oil, 7 parts of m-xylene diamine, 6 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
3. anti-aging wear resisting films material according to claim 1, it is characterised in that include the original of following parts by weight
Material:30 parts of triallylamine, 20 parts of polyisoprene, 12 parts of diethylene glycol dibenzoate, 9 parts of butyl acrylate, triethanolamine
8 parts of borate, 13 parts of haloflex, 5 parts of zinc methacrylate, 8 parts of diphenyl silanediol, 6 parts of silica flour, 4 parts of vulcanizing agent,
4 parts of microwax, 7 parts of calcium carbonate, 6 parts of magnesium hydroxide, 2 parts of antimony oxide, 2 parts of lead oxide, vinyltrimethoxy silane 3
Part, 1.5 parts of hydroxy silicon oil, 7 parts of m-xylene diamine, 5 parts of diacetyl peroxide, 5 parts of nylon fiber, 2 parts of magnesia.
4. anti-aging wear resisting films material according to claim 1, it is characterised in that include the original of following parts by weight
Material:24 parts of triallylamine, 18 parts of polyisoprene, 14 parts of diethylene glycol dibenzoate, 7 parts of butyl acrylate, triethanolamine
6 parts of borate, 9 parts of haloflex, 6 parts of zinc methacrylate, 5 parts of diphenyl silanediol, 5 parts of silica flour, 3 parts of vulcanizing agent,
6 parts of microwax, 6 parts of calcium carbonate, 4 parts of magnesium hydroxide, 3 parts of antimony oxide, 2 parts of lead oxide, vinyltrimethoxy silane 4
Part, 2 parts of hydroxy silicon oil, 9 parts of m-xylene diamine, 8 parts of diacetyl peroxide, 6 parts of nylon fiber, 3 parts of magnesia.
5. the preparation method of the anti-aging wear resisting films material according to any one of claim 1-4, it is characterised in that
Comprise the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) by triallylamine, polyisoprene, diethylene glycol dibenzoate, butyl acrylate, triethanolamine borate, chlorine
Change polyethylene, diphenyl silanediol, hydroxy silicon oil, m-xylene diamine, diacetyl peroxide and nylon fiber and add kneading machine,
15-20 minutes are kneaded at 136-145 DEG C;
(3) zinc methacrylate, silica flour, microwax, calcium carbonate, magnesium hydroxide, antimony oxide, oxidation are sequentially added
Lead, vinyltrimethoxy silane and magnesia, it is kneaded, is compressing, obtaining pre-add labor and materials;
(4) the pre-add labor and materials in step (3) are added in the mould in vulcanizing equipment, add vulcanizing agent and carry out at vulcanization
Reason, temperature are 172-178 DEG C, and cure time is 17-23 minutes, sulfide stress 11-13Mpa;
(5) deburring, the anti-aging wear resisting films material in the present invention is obtained.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106349591A (en) * | 2016-08-24 | 2017-01-25 | 安徽顺彤包装材料有限公司 | Flame-retardant packaging material and preparation method thereof |
CN106432838A (en) * | 2016-11-24 | 2017-02-22 | 安徽省天乐塑业有限公司 | Anti-ageing and anti-corrosion rubber material and preparation method thereof |
CN106496669A (en) * | 2016-11-25 | 2017-03-15 | 安徽美翔塑业有限公司 | A kind of rubber tube material and preparation method thereof |
-
2017
- 2017-08-24 CN CN201710734900.2A patent/CN107474337A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106349591A (en) * | 2016-08-24 | 2017-01-25 | 安徽顺彤包装材料有限公司 | Flame-retardant packaging material and preparation method thereof |
CN106432838A (en) * | 2016-11-24 | 2017-02-22 | 安徽省天乐塑业有限公司 | Anti-ageing and anti-corrosion rubber material and preparation method thereof |
CN106496669A (en) * | 2016-11-25 | 2017-03-15 | 安徽美翔塑业有限公司 | A kind of rubber tube material and preparation method thereof |
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