CN107474321A - A kind of degradable decoration material and preparation method thereof - Google Patents
A kind of degradable decoration material and preparation method thereof Download PDFInfo
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- CN107474321A CN107474321A CN201710968546.XA CN201710968546A CN107474321A CN 107474321 A CN107474321 A CN 107474321A CN 201710968546 A CN201710968546 A CN 201710968546A CN 107474321 A CN107474321 A CN 107474321A
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- degradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of degradable decoration material and preparation method thereof, the degradable decoration material is made up of the raw material components of following parts by weight：20 35 parts of starch, 20 40 parts of wood powder, 5 15 parts of licorice powder, 20 30 parts of polyurethane resin, 36 parts of calcium bicarbonate, 36 parts of diatomite, 25 parts of maleic anhydride, 13 parts of aluminate coupling agent, 13 parts of stannous chloride, 24 parts of activated carbon, 12 parts of tin dilaurate dimethyl ethyl tin, 35 parts of zinc stearate, 26 parts of phosphoric acid propane diamine, 13 parts of heat stabilizer, 38 parts of polyaminoacid, 6 12 parts of nano silicon, 5 10 parts of magnesium hypophosphite.Degradable decoration material in the present invention both can with recycling, while can also natural degradation, the influence to ecological environment is small.
Description
Technical field
The invention belongs to construction and decoration technical field, more particularly to a kind of degradable decoration material and its preparation side
Method.
Background technology
With the high speed development of petrochemical industry, for construction industry and the various new material species of daily life increasingly
Increase, particularly some temporay buildings or the increase of disposable consumptive material demand, these materials discard shape after being previously used
Into a large amount of production and living rubbish, environmental pollution and energy waste are caused, therefore, decoration material realizes degradable be treated as
Hot research problem.
The content of the invention
Both can be with recycling, while can also oneself it is an object of the invention to provide a kind of degradable decoration material
So degraded, the influence to ecological environment are small.
To achieve the above object, the present invention provides following technical scheme：
A kind of degradable decoration material, it is made up of the raw material components of following parts by weight：Starch 20-35 parts, wood
Powder 20-40 parts, licorice powder 5-15 parts, polyurethane resin 20-30 parts, calcium bicarbonate 3-6 parts, diatomite 3-6 parts, maleic anhydride 2-
5 parts, aluminate coupling agent 1-3 parts, stannous chloride 1-3 parts, activated carbon 2-4 parts, tin dilaurate dimethyl ethyl tin 1-2 parts, firmly
Resin acid zinc 3-5 parts, phosphoric acid propane diamine 2-6 parts, heat stabilizer 1-3 parts, polyaminoacid 3-8 parts, nano silicon 6-12 parts are secondary
Magnesium phosphate 5-10 parts.
Preferably, described degradable decoration material is made up of the raw material components of following parts by weight：28 parts of starch,
30 parts of wood powder, 12 parts of licorice powder, 22 parts of polyurethane resin, 5 parts of calcium bicarbonate, 6 parts of diatomite, 3 parts of maleic anhydride, Aluminate are even
Join 1 part of agent, 1.5 parts of stannous chloride, 3 parts of activated carbon, 1 part of tin dilaurate dimethyl ethyl tin, 4 parts of zinc stearate, phosphoric acid the third two
4 parts of amine, 1 part of heat stabilizer, 5 parts of polyaminoacid, 10 parts of nano silicon, 8 parts of magnesium hypophosphite.
Preferably, described degradable decoration material is made up of the raw material components of following parts by weight：32 parts of starch,
25 parts of wood powder, 11 parts of licorice powder, 24 parts of polyurethane resin, 3 parts of calcium bicarbonate, 5 parts of diatomite, 2 parts of maleic anhydride, Aluminate are even
Join 1.5 parts of agent, 1 part of stannous chloride, 2.5 parts of activated carbon, 2 parts of tin dilaurate dimethyl ethyl tin, 5 parts of zinc stearate, phosphoric acid third
5 parts of diamines, 1.5 parts of heat stabilizer, 6 parts of polyaminoacid, 12 parts of nano silicon, 6 parts of magnesium hypophosphite.
The preparation method of described degradable decoration material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) above-mentioned each raw material components are mixed to fusion under 230-250 DEG C of temperature conditionss, 22-28 minutes is stirred, is cooled to
Mixed resin；
(3) mixed resin in step (2) is placed in Granulation Equipments and be granulated, obtain powdery or granular polymerization
Thing；
(4) powdery in step (3) or powder shaped polymer are directly entered calender or extruding machine, form sheet material, plate
Material or section bar.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention makes each advantages of reasonable raw material components proportioning, cooperated by choosing suitable feedstock component, so that should
Decoration material both can with recycling, while can also natural degradation, the influence to ecological environment is small, limited to avoid
Material is discarded after being previously used and forms a large amount of production and living rubbish and cause environmental pollution and energy waste.
Embodiment
Technical scheme is described in detail with reference to embodiment, but protection domain is not limited thereto.
Embodiment one：
A kind of degradable decoration material, it is made up of the raw material components of following parts by weight：23 parts of starch, wood powder 36
Part, 15 parts of licorice powder, 27 parts of polyurethane resin, 5 parts of calcium bicarbonate, 6 parts of diatomite, 3 parts of maleic anhydride, aluminate coupling agent
1.8 parts, 1.6 parts of stannous chloride, 4 parts of activated carbon, 2 parts of tin dilaurate dimethyl ethyl tin, 5 parts of zinc stearate, phosphoric acid propane diamine 5
Part, 3 parts of heat stabilizer, 6 parts of polyaminoacid, 10 parts of nano silicon, 6 parts of magnesium hypophosphite.
The preparation method of described degradable decoration material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) above-mentioned each raw material components are mixed to fusion under 230-250 DEG C of temperature conditionss, 22-28 minutes is stirred, is cooled to
Mixed resin；
(3) mixed resin in step (2) is placed in Granulation Equipments and be granulated, obtain powdery or granular polymerization
Thing；
(4) powdery in step (3) or powder shaped polymer are directly entered calender or extruding machine, form sheet material, plate
Material or section bar.
Embodiment two：
A kind of degradable decoration material, it is made up of the raw material components of following parts by weight：28 parts of starch, wood powder 30
Part, 12 parts of licorice powder, 22 parts of polyurethane resin, 5 parts of calcium bicarbonate, 6 parts of diatomite, 3 parts of maleic anhydride, aluminate coupling agent 1
Part, 1.5 parts of stannous chloride, 3 parts of activated carbon, 1 part of tin dilaurate dimethyl ethyl tin, 4 parts of zinc stearate, 4 parts of phosphoric acid propane diamine,
1 part of heat stabilizer, 5 parts of polyaminoacid, 10 parts of nano silicon, 8 parts of magnesium hypophosphite.
The preparation method of described degradable decoration material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) above-mentioned each raw material components are mixed to fusion under 230-250 DEG C of temperature conditionss, 22-28 minutes is stirred, is cooled to
Mixed resin；
(3) mixed resin in step (2) is placed in Granulation Equipments and be granulated, obtain powdery or granular polymerization
Thing；
(4) powdery in step (3) or powder shaped polymer are directly entered calender or extruding machine, form sheet material, plate
Material or section bar.
Embodiment three：
A kind of degradable decoration material, it is made up of the raw material components of following parts by weight：32 parts of starch, wood powder 25
Part, 11 parts of licorice powder, 24 parts of polyurethane resin, 3 parts of calcium bicarbonate, 5 parts of diatomite, 2 parts of maleic anhydride, aluminate coupling agent
1.5 parts, 1 part of stannous chloride, 2.5 parts of activated carbon, 2 parts of tin dilaurate dimethyl ethyl tin, 5 parts of zinc stearate, phosphoric acid propane diamine 5
Part, 1.5 parts of heat stabilizer, 6 parts of polyaminoacid, 12 parts of nano silicon, 6 parts of magnesium hypophosphite.
The preparation method of described degradable decoration material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) above-mentioned each raw material components are mixed to fusion under 230-250 DEG C of temperature conditionss, 22-28 minutes is stirred, is cooled to
Mixed resin；
(3) mixed resin in step (2) is placed in Granulation Equipments and be granulated, obtain powdery or granular polymerization
Thing；
(4) powdery in step (3) or powder shaped polymer are directly entered calender or extruding machine, form sheet material, plate
Material or section bar.
Example IV：
A kind of degradable decoration material, it is made up of the raw material components of following parts by weight：20 parts of starch, wood powder 20
Part, 5 parts of licorice powder, 20 parts of polyurethane resin, 3 parts of calcium bicarbonate, 3 parts of diatomite, 2 parts of maleic anhydride, aluminate coupling agent 1
Part, 1 part of stannous chloride, 2 parts of activated carbon, 1 part of tin dilaurate dimethyl ethyl tin, 3 parts of zinc stearate, 2 parts of phosphoric acid propane diamine, heat
1 part of stabilizer, 3 parts of polyaminoacid, 6 parts of nano silicon, 5 parts of magnesium hypophosphite.
The preparation method of described degradable decoration material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) above-mentioned each raw material components are mixed to fusion under 230-250 DEG C of temperature conditionss, 22-28 minutes is stirred, is cooled to
Mixed resin；
(3) mixed resin in step (2) is placed in Granulation Equipments and be granulated, obtain powdery or granular polymerization
Thing；
(4) powdery in step (3) or powder shaped polymer are directly entered calender or extruding machine, form sheet material, plate
Material or section bar.
Embodiment five：
A kind of degradable decoration material, it is made up of the raw material components of following parts by weight：35 parts of starch, wood powder 40
Part, 15 parts of licorice powder, 30 parts of polyurethane resin, 6 parts of calcium bicarbonate, 6 parts of diatomite, 5 parts of maleic anhydride, aluminate coupling agent 3
Part, 3 parts of stannous chloride, 4 parts of activated carbon, 2 parts of tin dilaurate dimethyl ethyl tin, 5 parts of zinc stearate, 6 parts of phosphoric acid propane diamine, heat
3 parts of stabilizer, 8 parts of polyaminoacid, 12 parts of nano silicon, 10 parts of magnesium hypophosphite.
The preparation method of described degradable decoration material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) above-mentioned each raw material components are mixed to fusion under 230-250 DEG C of temperature conditionss, 22-28 minutes is stirred, is cooled to
Mixed resin；
(3) mixed resin in step (2) is placed in Granulation Equipments and be granulated, obtain powdery or granular polymerization
Thing；
(4) powdery in step (3) or powder shaped polymer are directly entered calender or extruding machine, form sheet material, plate
Material or section bar.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of the technical program, it all should cover in the present invention
Right among.
Claims (4)
1. a kind of degradable decoration material, it is characterised in that be made up of the raw material components of following parts by weight：Starch 20-
35 parts, wood powder 20-40 parts, licorice powder 5-15 parts, polyurethane resin 20-30 parts, calcium bicarbonate 3-6 parts, diatomite 3-6 parts, horse
Come acid anhydrides 2-5 parts, aluminate coupling agent 1-3 parts, stannous chloride 1-3 parts, activated carbon 2-4 parts, tin dilaurate dimethyl ethyl tin
1-2 parts, zinc stearate 3-5 parts, phosphoric acid propane diamine 2-6 parts, heat stabilizer 1-3 parts, polyaminoacid 3-8 parts, nano silicon
6-12 parts, magnesium hypophosphite 5-10 parts.
2. degradable decoration material according to claim 1, it is characterised in that by the raw material group of following parts by weight
Divide and be made：28 parts of starch, 30 parts of wood powder, 12 parts of licorice powder, 22 parts of polyurethane resin, 5 parts of calcium bicarbonate, 6 parts of diatomite, Malaysia
3 parts of acid anhydrides, 1 part of aluminate coupling agent, 1.5 parts of stannous chloride, 3 parts of activated carbon, 1 part of tin dilaurate dimethyl ethyl tin are stearic
Sour 4 parts of zinc, 4 parts of phosphoric acid propane diamine, 1 part of heat stabilizer, 5 parts of polyaminoacid, 10 parts of nano silicon, 8 parts of magnesium hypophosphite.
3. degradable decoration material according to claim 1, it is characterised in that by the raw material group of following parts by weight
Divide and be made：32 parts of starch, 25 parts of wood powder, 11 parts of licorice powder, 24 parts of polyurethane resin, 3 parts of calcium bicarbonate, 5 parts of diatomite, Malaysia
2 parts of acid anhydrides, 1.5 parts of aluminate coupling agent, 1 part of stannous chloride, 2.5 parts of activated carbon, 2 parts of tin dilaurate dimethyl ethyl tin, firmly
5 parts of resin acid zinc, 5 parts of phosphoric acid propane diamine, 1.5 parts of heat stabilizer, 6 parts of polyaminoacid, 12 parts of nano silicon, magnesium hypophosphite 6
Part.
4. the preparation method of the degradable decoration material according to any one of claim 1-3, it is characterised in that bag
Include following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) above-mentioned each raw material components are mixed to fusion under 230-250 DEG C of temperature conditionss, 22-28 minutes is stirred, is cooled to mixing
Base-material；
(3) mixed resin in step (2) is placed in Granulation Equipments and be granulated, obtain powdery or powder shaped polymer；
(4) powdery in step (3) or powder shaped polymer are directly entered calender or extruding machine, formed sheet material, sheet material or
Section bar.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710968546.XA CN107474321A (en) | 2017-10-18 | 2017-10-18 | A kind of degradable decoration material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710968546.XA CN107474321A (en) | 2017-10-18 | 2017-10-18 | A kind of degradable decoration material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107474321A true CN107474321A (en) | 2017-12-15 |
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| CN201710968546.XA Pending CN107474321A (en) | 2017-10-18 | 2017-10-18 | A kind of degradable decoration material and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999610A (en) * | 2006-01-12 | 2007-07-18 | 中国林业科学研究院木材工业研究所 | Wood plastic composite material composection and formed board thereof and their preparation process |
| CN103819801A (en) * | 2014-03-13 | 2014-05-28 | 福建师范大学 | Polyolefin wood-plastic composite and preparation method thereof |
| CN104231331A (en) * | 2014-09-18 | 2014-12-24 | 孙彦升 | Degradable decoration material and preparation method thereof |
-
2017
- 2017-10-18 CN CN201710968546.XA patent/CN107474321A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999610A (en) * | 2006-01-12 | 2007-07-18 | 中国林业科学研究院木材工业研究所 | Wood plastic composite material composection and formed board thereof and their preparation process |
| CN103819801A (en) * | 2014-03-13 | 2014-05-28 | 福建师范大学 | Polyolefin wood-plastic composite and preparation method thereof |
| CN104231331A (en) * | 2014-09-18 | 2014-12-24 | 孙彦升 | Degradable decoration material and preparation method thereof |
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Application publication date: 20171215 |