CN107473707A - A kind of crowded mud method luminescent ceramic pug composition and preparation method thereof - Google Patents
A kind of crowded mud method luminescent ceramic pug composition and preparation method thereof Download PDFInfo
- Publication number
- CN107473707A CN107473707A CN201710823301.8A CN201710823301A CN107473707A CN 107473707 A CN107473707 A CN 107473707A CN 201710823301 A CN201710823301 A CN 201710823301A CN 107473707 A CN107473707 A CN 107473707A
- Authority
- CN
- China
- Prior art keywords
- agent
- luminescent ceramic
- pug
- composition
- ceramic pug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
- C04B2235/3222—Aluminates other than alumino-silicates, e.g. spinel (MgAl2O4)
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3229—Cerium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3251—Niobium oxides, niobates, tantalum oxides, tantalates, or oxide-forming salts thereof
- C04B2235/3255—Niobates or tantalates, e.g. silver niobate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3296—Lead oxides, plumbates or oxide forming salts thereof, e.g. silver plumbate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3436—Alkaline earth metal silicates, e.g. barium silicate
- C04B2235/3445—Magnesium silicates, e.g. forsterite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3826—Silicon carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3839—Refractory metal carbides
- C04B2235/3843—Titanium carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
- C04B2235/445—Fluoride containing anions, e.g. fluosilicate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention relates to ceramic material field, more particularly to a kind of crowded mud method luminescent ceramic pug composition.By weight, including:Kaolin, bentonite, potassium feldspar, albite, anorthite, quartz, pyrochlore, fluorite, talcum powder, mullite, useless porcelain powder, Jiepai clay, plasticizer, liquefacient, flocculant, brightening agent, high temperature protection agent, crack resistence agent, wetting agent, tackifier, rare-earth trichromatic fluorescent powder, sintering aid, water.The luminescent ceramic pug composition obtained by the formula and preparation method of the present invention, has magnificent fluorescent characteristic and light transmission.And luminescent ceramic pug is better than the mobility of common pug, shower nozzle is not easily blocked in forming process, while plasticity is also than common pug more preferably, the base substrate in forming process is unlikely to deform.
Description
Technical field
The present invention relates to ceramic material field, more particularly to a kind of crowded mud method luminescent ceramic pug composition and its preparation
Method.
Background technology
Nowadays, individual character ceramics are dabbled extensively.But the ceramics formed by rapid shaping technique printing lack individuality, so
Its value is not high, and in the market without the ceramics with fluorescent characteristic and light transmission.
The content of the invention
The invention provides a kind of crowded mud method luminescent ceramic pug composition and preparation method thereof, to solve above-mentioned technology
Problem.
In order to achieve the above object, the technical proposal of the invention is realized in this way:
A kind of crowded mud method luminescent ceramic pug composition, by weight, including:
Kaolin 16.8-18.5%
Bentonite 1.1-1.6%
Potassium feldspar 5.1-5.6%
Albite 3.3-3.9%
Anorthite 3.7-4.3%
Quartzy 3.2-3.5%
Pyrochlore 2.2-2.8%
Fluorite 3.0-3.5%
Talcum powder 0.4-0.7%
Mullite 2.7-3.0%
Useless porcelain powder 2.3-2.5%
Jiepai clay 1.2-1.5%
Plasticizer 2.1-2.4%
Liquefacient 1.1-1.3%
Flocculant 0.9-1.1%
Brightening agent 0.6-0.8%
High temperature protection agent 1.0-1.3%
Crack resistence agent 2.0-2.2%
Wetting agent 1.9-2.2%
Tackifier 1.8-2.1%
Rare-earth trichromatic fluorescent powder 4.0-5.5%
Sintering aid 2.1-3.3%
Water 28.3-31.5%;
Wherein, the Jiepai clay includes SiO2、Al2O3And metal oxide;
The plasticizer includes sodium humate (C9H8Na2O4), soluble starch (C6H10O5) n, polyvinyl alcohol [C2H4O] n and
Carboxymethyl cellulose [C6H7O2(OH)2CH2COONa]n;
The liquefacient includes sodium metasilicate (Na2SiO3·9H2) and/or sodium carbonate (Na O2CO3) and/or tannic acid
(C76H52O46);
The flocculant includes magnesium silicate (MgSiO3) and/or calcium chloride (CaCl2);
The brightening agent includes titanium dioxide (TiO2) and/or pure zirconia lead (PbO);
The high temperature protection agent includes carborundum (SiC) and titanium carbide (TiC);
The crack resistence agent includes polyurethanes (C3H8N2O);
The wetting agent is anion surfactant, cationic surfactant, amphoteric surfactant and nonionic
One or more of mixtures of surfactant;
The constituent of the tackifier is 46% xanthans, 23% gelatin and 31% sodium carboxymethylcellulose
(C8H16NaO8)。
Preferably, sodium humate, soluble starch, polyvinyl alcohol and carboxymethyl cellulose be by weight ratio in the plasticizer
36%, 20%, 15% and the 29% of plasticizer gross weight is accounted for respectively.
Preferably, sodium metasilicate, sodium carbonate and tannic acid account for liquefacient gross weight respectively by weight ratio in the liquefacient
27%, 25% and 48%.
Preferably, magnesium silicate and calcium chloride account for 43% He of flocculant gross weight by weight ratio in the flocculant
57%.
Preferably, the sintering aid particle diameter is 100-400nm;The sintering aid contains fluoride.
Preferably, the fluoride includes CaF2、MgF2、ScF3、AlF3、YF3、ZrF4、HfF4、TiF3And/or lanthanide series
Fluoride.
Preferably, the composition of the useless porcelain powder is Fe2O3、SiO2, CaO and MgO.
A kind of above-mentioned crowded mud method preparation method of luminescent ceramic pug composition, comprises the following steps:
Step 1:Weight as described in claim 1 grows kaolin, bentonite, albite, anorthite, potassium
Stone, quartz, pyrochlore, fluorite, talcum powder, mullite, useless porcelain powder, Jiepai clay, sintering aid and rare-earth trichromatic fluorescent powder enter
Row mixing.
Step 2:Mixture after will be well mixed is mixed with water according to the weight proportion of claim 1;Stir
Plasticizer is added during mixing while stirring.
Step 3:Into muddy after stirring five minutes, then add liquefacient.
Step 4:The mud prepared is eluriated, adds flocculant during elutriation into mud.
Step 5:Pug after step 4 is sequentially added into brightening agent, high temperature protection agent, crack resistence agent, wetting agent and increasing
Stick.
Kaolin preferably uses the kaolin in kaolinite village of Jindezhen City of Jiangxi Province.Kaolinic main component is Al2
(Si2O5)(OH)4、Al2O3、SiO2And other micro metal oxides.
Bentonitic composition is (Al2Mg3)[Si4O10][OH]2And other micro metal oxides, bentonite property
Extensively, it has bloating tendency, caking property, adsorptivity, catalytic, thixotropy, suspension and cation exchange etc., these
Property plays the role of important to the plasticity, caking property and the curability that improve ceramic material.
The composition of potassium feldspar is KAlSi3O8、SiO2、Al2O3And other micro metal oxides.The composition of albite
For NaAlSi3O8、SiO2、Al2O3And other micro metal oxides.Anorthite is a kind of aluminosilicate of calcic, composition
For CaOAl2O3·2SiO2、SiO2、Al2O3And other micro metal oxides.The main component of quartz is SiO2, SiO2
Composition constitute about 98% or so, other are then some metal oxide impurities.The chemical composition of pyrochlore is 8.52%
Na2O, 15.21% CaO, 71.05% Nb2O5, 5.22% F.The main composition of fluorite is calcirm-fluoride (CaF2), additionally
Contain a small amount of Fe2O3, SiO2With micro Cl, He etc..
The main component of talcum powder derives from talcum, is a kind of britesorb, has lubricity, anti-stick, helps stream, fire resisting
Property, acid-resisting, insulating properties, fusing point are high, chemically torpescence, covering power good, softness, good luster, strong adsorption force etc. is excellent
Wuli-Shili-Renli system approach, its molecular formula are Mg3[Si4O10](OH)2。
Mullite is the mineral that aluminosilicate generates at high temperature, and the chemical formula of main component is 3Al2O3·2SiO2, not
The amount of liquid phase of pug can be adjusted well by carrying out stone, and mullite is more, and amount of liquid phase is fewer.The composition of useless porcelain powder is Fe2O3、SiO2、
CaO and MgO.About containing 59% SiO in Jiepai clay2, 30% Al2O3And 11% metal oxide impurities.
Plasticizer is by sodium humate (C9H8Na2O4), soluble starch (C6H10O5) n, polyvinyl alcohol [C2H4O] n and carboxylic first
Base cellulose [C6H7O2(OH)2CH2COONa] n mixes.Liquefacient can use sodium metasilicate (Na2SiO3·9H2) and sodium carbonate O
(Na2CO3), it is also possible to novel surface active material tannic acid (C76H52O46).Flocculant can use magnesium silicate (MgSiO3) and chlorine
Change calcium (CaCl2) in one kind or mixture.Brightening agent can use titanium dioxide (TiO2) or use pure zirconia lead (PbO).Ceramics
High temperature protection agent use SiC and TiC.SiC and TiC is very superior ceramic high-temperature resistant material.
Crack resistence agent composition is polyurethanes (C3H8N2O).Described wetting agent is anion surfactant, sun
One or more of mixtures of ionic surface active agent, amphoteric surfactant and nonionic surfactant.Tackifier can
With xanthans, gelatin and sodium carboxymethylcellulose (C8H16NaO8) in mixture.Fluorescent material mainly has europkium-activated yittrium oxide,
Green powder is cerium, the aluminate of terbium activation, and blue powder is europkium-activated barium magnesium aluminate at a low price.Three kinds of powder mix by a certain percentage, can be with
Obtain different colour temperature (2700~6500k).Needed in sintering aid containing fluoride, because the good agglutinating property of fluoride
It can strengthen the translucency of ceramics with excellent optical property, strengthen the ability to function of fluorescent material.
Compared with prior art, the advantage of the invention is that:
(1) ceramics printed using crowded mud method with luminescent ceramic pug have magnificent fluorescent characteristic.
(2) pyrochlore with crystal structure is used to allow ceramics with well saturating as a part for raw material with fluorite
Optical property, it can greatly improve the activity ratio of fluorescent material.
(3) squeeze mud method and be molded smoothness in Rapid Prototyping Process with luminescent ceramic pug, pug is not allow easily broken also will not
Collapse.
(4) mud method luminescent ceramic pug good fluidity is squeezed, impurity is few, and shower nozzle is not easily blocked in forming process.
(5) crowded mud method is good with the plasticity of luminescent ceramic pug, and the base substrate after shaping is unlikely to deform.
(6) under the collective effect of crack resistence agent and wetting agent, the smooth good integrity in surface, surface will not after blank forming
It is cracked.
(7) novel whitening agents added after the completion of pug sedimentation cause the ceramic whiteness after shaping more preferably.
(8) high-temperature firing for living 1300 DEG C that the base substrate after being molded can be subjected to is not easily damaged in sintering procedure into porcelain.
Embodiment
Clear, complete description will be carried out to the technical scheme of various embodiments of the present invention below, it is clear that described implementation
Example is only the part of the embodiment of the present invention, rather than whole embodiments.It is general based on the embodiment in the present invention, this area
Logical technical staff all other embodiment resulting on the premise of creative work is not made, belongs to the present invention and is protected
The scope of shield.
Embodiment 1
Take kaolin 360g, bentonite 30g, potassium feldspar 110g, albite 70g, anorthite 80g, quartzy 70g, pyrochlore
60g, fluorite 70g, talcum powder 10g, mullite 60g, give up porcelain powder 50g, Jiepai clay 30g, sintering aid 55g and fluorescent material
100g。
Above-mentioned raw materials are put into agitator, are sufficiently mixed raw material uniformly using mixer, are about stirred five minutes.
600g water is added in the well mixed backward raw material stirred, water is slowly added into while stirring, pug raw material can be increased
Mixture homogeneity.Stirring is completed to add plasticizer sodium humate 14g, soluble starch 8g, polyvinyl alcohol 6g and carboxymethyl cellulose
Plain 12g, continue stirring 3 minutes, after the completion of pug water content be about 26%.Added after the completion of stirring liquefacient sodium metasilicate 7g,
Sodium carbonate 6g and tannic acid 12g, it is about 25% to continue stirring to water content.It is eventually adding flocculant magnesium silicate 4.5g and calcium chloride
5.5g, stir 3 minutes.
After the completion of, pug taking-up is settled and is come out walk impurity sedimentation, the sedimentation time is about 5 hours.It is small to settle 5
When after the completion of sequentially add brightening agent pure zirconia lead 5g, high-white aluminum hydroxide 6g and calcined alumina 4g;High temperature protection agent carbon
SiClx 12g, titanium carbide 8g;Crack resistence agent polyurethanes 40g;Wetting agent naphthalene sulphonate formaldehyde polymer 5g, Sorbitan
Alcohol APEO 15g, sodium lignin sulfonate 7g, calcium lignosulfonate 8g and tackifier xanthans 15g, gelatin 12g and carboxylic first
Base sodium cellulosate 13g, continues to be slowly stirred after the completion of addition, until water content is 21% or so, pug just prepares completion.
Pug after the completion of preparation is put into a height of 10 centimetres of bowl-shape base substrate is printed in Quick ceramic forming machine, be put into
Fire in kiln, first preheated at 100 DEG C, preheat 90 minutes, after room temperature, be put into 1220 DEG C
Kiln in fire, ceramic is made.Through surveying, after abundant illumination, ceramic luminous intensity is 8mcd, sustainable 9
Hour, it is weak to the offline 0.32mcd of eye-observation by 55 hours.Ceramic surface is smooth, uniform color, flawless, no stain,
Body of making pottery is undeformed.
Embodiment 2:Kaolin 360g, bentonite 30g, potassium feldspar 110g, albite 70g, anorthite 80g are taken, quartz
70g, pyrochlore 60g, fluorite 70g, talcum powder 10g, mullite 60g, give up porcelain powder 50g, Jiepai clay 30g, sintering aid 55g and
Fluorescent material 125g.Above-mentioned raw materials are put into agitator, are sufficiently mixed raw material uniformly using mixer, about stir five minutes i.e.
Can.600g water is added in the well mixed backward raw material stirred, to be slowly added into water while stirring, pug original can be increased
The mixture homogeneity of material.Stirring is completed to add plasticizer sodium humate 14g, soluble starch 8g, polyvinyl alcohol 6g and carboxymethyl fibre
Tie up plain 12g, continue stirring 5 minutes, after the completion of water content be about 25%.Added after the completion of stirring liquefacient sodium metasilicate 7g,
Sodium carbonate 6g and tannic acid 12g, continue stirring 5 minutes.Flocculant magnesium silicate 4.5g and calcium chloride 5.5g are eventually adding, stirring is extremely
Water content is that 24% right and left can complete.After the completion of, pug taking-up is settled and is come out walk impurity sedimentation, the sedimentation time
For 6 hours.Sedimentation sequentially adds brightening agent pure zirconia lead 5g, high-white aluminum hydroxide 6g and calcined alumina after the completion of 6 hours
4g;High temperature protection agent carborundum 12g, titanium carbide 8g;Crack resistence agent polyurethanes 40g;Wetting agent naphthalene sulphonate formaldehyde gathers
Compound 5g, anhydrous sorbitol APEO 15g, sodium lignin sulfonate 7g, calcium lignosulfonate 8g and tackifier xanthans
12g, gelatin 15g and sodium carboxymethylcellulose 13g.It is slowly stirred after the completion of addition until water content is about 20%, pug is just made
It is standby to complete.Pug after the completion of preparation is put into a height of 10 centimetres of bowl-shape base substrate is printed in Quick ceramic forming machine, be put into
Fire in kiln, first preheated at 150 DEG C, preheat 75 minutes, after room temperature, be put into 1250 DEG C
Kiln in fire, ceramic is made.Through surveying, after abundant illumination, ceramic luminous intensity is 8.5mcd, sustainable
It is 9 hours, weak to the offline 0.32mcd of eye-observation by 60 hours.Ceramic surface is smooth, uniform color, flawless, without black
Point, pottery body are undeformed.
Embodiment 3:Kaolin 360g, bentonite 30g, potassium feldspar 110g, albite 70g, anorthite 80g are taken, quartz
70g, pyrochlore 60g, fluorite 70g, talcum powder 10g, mullite 60g, give up porcelain powder 50g, Jiepai clay 30g, sintering aid 55g and
Fluorescent material 150g.Above-mentioned raw materials are put into agitator, are sufficiently mixed raw material uniformly using mixer, about stir five minutes i.e.
Can.600g water is added in the well mixed backward raw material stirred, to be slowly added into water while stirring, pug original can be increased
The mixture homogeneity of material.Stirring is completed to add plasticizer sodium humate 14g, soluble starch 8g, polyvinyl alcohol 6g and carboxymethyl fibre
Tie up plain 12g, continue stirring 3 minutes, after the completion of water content be about 26%.Added after the completion of stirring liquefacient sodium metasilicate 7g,
Sodium carbonate 6g and tannic acid 12g, continue stirring 7 minutes.Flocculant magnesium silicate 4.5g and calcium chloride 5.5g are eventually adding, is stirred always
It is about that 23% side can complete to mix to water content.After the completion of, pug is taken out and is settled and comes out walk impurity sedimentation, during sedimentation
Between about 8 hours.Sedimentation sequentially adds brightening agent pure zirconia lead 5g, high-white aluminum hydroxide 6g and calcining oxygen after the completion of 8 hours
Change aluminium 4g;High temperature protection agent carborundum 12g, titanium carbide 8g;Crack resistence agent polyurethanes 40g;Wetting agent naphthalene sulfonate first
Aldehyde polymer 5g, anhydrous sorbitol APEO 15g, sodium lignin sulfonate 7g, calcium lignosulfonate 8g and tackifier xanthan
Glue 15g, gelatin 12g and sodium carboxymethylcellulose 13g, it is slowly stirred after addition to water content untill 19% or so, pug is just
Prepare and complete.Pug after the completion of preparation is put into a height of 10 centimetres of bowl-shape base substrate is printed in Quick ceramic forming machine, put
Enter in kiln and fire, first preheated at 200 DEG C, preheat 60 minutes, after room temperature, be put into 1225
DEG C kiln in fire, ceramic is made.Through surveying, after abundant illumination, ceramic luminous intensity top is 9mcd,
It is sustainable 9 hours, weak to the offline 0.32mcd of eye-observation by 70 hours.Ceramic surface is smooth, uniform color, flawless,
It is undeformed without stain, pottery body.
Embodiment 4:Kaolin 360g, bentonite 30g, potassium feldspar 110g, albite 70g, anorthite 80g are taken, quartz
70g, pyrochlore 60g, fluorite 70g, talcum powder 10g, mullite 60g, give up porcelain powder 50g, Jiepai clay 30g, sintering aid 55g and
Fluorescent material 150g.Above-mentioned raw materials are put into agitator, are sufficiently mixed raw material uniformly using mixer, about stir five minutes i.e.
Can.400g water is added in the well mixed backward raw material stirred, to be slowly added into water while stirring, pug original can be increased
The mixture homogeneity of material.Stirring is completed to add plasticizer sodium humate 14g, soluble starch 8g, polyvinyl alcohol 6g and carboxymethyl fibre
Tie up plain 12g, continue stirring 3 minutes, after the completion of water content be about 17.3%.Liquefacient sodium metasilicate is added after the completion of stirring
7g, sodium carbonate 6g and tannic acid 12g, continue stirring 4 minutes.It is eventually adding flocculant magnesium silicate 4.5g and calcium chloride 5.5g, one
It is about that 15.5% side can complete directly to stir to water content.After the completion of, pug taking-up is settled and is come out walk impurity sedimentation,
Sedimentation time is about 8 hours.Sedimentation is completed to add 200g water in backward pug for 8 hours, stirs.Just sequentially add afterwards
Brightening agent pure zirconia lead 5g, high-white aluminum hydroxide 6g and calcined alumina 4g;High temperature protection agent carborundum 12g, titanium carbide 8g;
Crack resistence agent polyurethanes 40g;Wetting agent naphthalene sulphonate formaldehyde polymer 5g, anhydrous sorbitol APEO 15g, wood
Quality sodium sulfonate 7g, calcium lignosulfonate 8g and tackifier xanthans 15g, gelatin 12g and sodium carboxymethylcellulose 13g, addition
After be slowly stirred to water content untill 21% or so, pug just prepares completion.Pug after the completion of preparation is put into ceramic fast
A height of 10 centimetres of bowl-shape base substrate is printed in fast forming machine, is put into kiln and fires, is first preheated at 175 DEG C, is preheated
60 minutes, after room temperature, it is put into 1210 DEG C of kiln and fires, ceramic is made.Through surveying, by abundant
After illumination, ceramic luminous intensity top is 9mcd, sustainable 9 hours, weak offline to eye-observation by 72 hours
0.32mcd.Ceramic surface is smooth, uniform color, flawless, no stain, and pottery body is undeformed.
Embodiment 5:Kaolin 360g, bentonite 30g, potassium feldspar 110g, albite 70g, anorthite 80g are taken, quartz
70g, pyrochlore 60g, fluorite 70g, talcum powder 10g, mullite 60g, give up porcelain powder 50g, Jiepai clay 30g, sintering aid 60g and
Fluorescent material 175g.Above-mentioned raw materials are put into agitator, are sufficiently mixed raw material uniformly using mixer, about stir five minutes i.e.
Can.300g water is added in the well mixed backward raw material stirred, to be slowly added into water while stirring, pug original can be increased
The mixture homogeneity of material.Stirring is completed to add plasticizer sodium humate 14g, soluble starch 8g, polyvinyl alcohol 6g and carboxymethyl fibre
Tie up plain 12g, continue stirring 3 minutes, after the completion of water content be about 14.5%.Liquefacient sodium metasilicate is added after the completion of stirring
7g, sodium carbonate 6g and tannic acid 12g, continue stirring 6 minutes.It is eventually adding flocculant magnesium silicate 4.5g and calcium chloride 5.5g, one
It is about that 13% side can complete directly to stir to water content.After the completion of, pug taking-up is settled and is come out walk impurity sedimentation, is sunk
It is about 8 hours to drop the time.Sedimentation is completed to add 300g water in backward pug for 8 hours, stirs.Increasing is just sequentially added afterwards
White agent pure zirconia lead 5g, high-white aluminum hydroxide 6g and calcined alumina 4g;High temperature protection agent carborundum 12g, titanium carbide 8g;It is anti-
Ftracture agent polyurethanes 40g;Wetting agent naphthalene sulphonate formaldehyde polymer 5g, anhydrous sorbitol APEO 15g, it is wooden
Plain sodium sulfonate 7g, calcium lignosulfonate 8g and tackifier xanthans 15g, gelatin 12g and sodium carboxymethylcellulose 13g, after addition
It is slowly stirred to water content untill 22% or so, pug just prepares completion.Pug after the completion of preparation is put into ceramic quick
A height of 10 centimetres of bowl-shape base substrate is printed in forming machine, is put into kiln and fires, is first preheated at 150 DEG C, preheating 65
Minute, after room temperature, it is put into 1230 DEG C of kiln and fires, ceramic is made.Through surveying, by abundant light
According to afterwards, ceramic luminous intensity top is 9.5mcd, sustainable 8.5 hours, weak under eye-observation by 65 hours
Line 0.32mcd.Ceramic surface is smooth, uniform color, flawless, no stain, and pottery body is undeformed.
The above described is only a preferred embodiment of the present invention, not making any formal limitation to the present invention, appoint
What those skilled in the art, without departing from the scope of the present invention, when in the technology using the disclosure above
Hold the equivalent embodiment made a little change or be modified to equivalent variations, as long as being the content without departing from technical solution of the present invention,
Any simple modification, equivalent change and modification that technical spirit according to the present invention is made to above example, still fall within this
In the range of inventive technique scheme.
Claims (8)
- A kind of 1. crowded mud method luminescent ceramic pug composition, it is characterised in that by weight, including:Kaolin 16.8-18.5%Bentonite 1.1-1.6%Potassium feldspar 5.1-5.6%Albite 3.3-3.9%Anorthite 3.7-4.3%Quartzy 3.2-3.5%Pyrochlore 2.2-2.8%Fluorite 3.0-3.5%Talcum powder 0.4-0.7%Mullite 2.7-3.0%Useless porcelain powder 2.3-2.5%Jiepai clay 1.2-1.5%Plasticizer 2.1-2.4%Liquefacient 1.1-1.3%Flocculant 0.9-1.1%Brightening agent 0.6-0.8%High temperature protection agent 1.0-1.3%Crack resistence agent 2.0-2.2%Wetting agent 1.9-2.2%Tackifier 1.8-2.1%Rare-earth trichromatic fluorescent powder 4.0-5.5%Sintering aid 2.1-3.3%Water 28.3-31.5%;Wherein, the Jiepai clay includes SiO2、Al2O3And metal oxide;The plasticizer includes sodium humate (C9H8Na2O4), soluble starch (C6H10O5) n, polyvinyl alcohol [C2H4O] n and carboxymethyl Cellulose [C6H7O2(OH)2CH2COONa]n;The liquefacient includes sodium metasilicate (Na2SiO3·9H2) and/or sodium carbonate (Na O2CO3) and/or tannic acid (C76H52O46);The flocculant includes magnesium silicate (MgSiO3) and/or calcium chloride (CaCl2);The brightening agent includes titanium dioxide (TiO2) and/or pure zirconia lead (PbO);The high temperature protection agent includes carborundum (SiC) and titanium carbide (TiC);The crack resistence agent includes polyurethanes (C3H8N2O);The wetting agent is anion surfactant, cationic surfactant, amphoteric surfactant and non-ionic surface One or more of mixtures of activating agent;The tackifier are xanthans, gelatin and sodium carboxymethylcellulose (C8H16NaO8) in one or more of mixtures.
- 2. crowded mud method luminescent ceramic pug composition as claimed in claim 1, it is characterised in that rotten in the plasticizer to plant Sour sodium, soluble starch, polyvinyl alcohol and carboxymethyl cellulose account for respectively by weight ratio plasticizer gross weight 36%, 20%, 15% and 29%.
- 3. crowded mud method luminescent ceramic pug composition as claimed in claim 1, it is characterised in that silicic acid in the liquefacient Sodium, sodium carbonate and tannic acid account for 27%, 25% and the 48% of liquefacient gross weight respectively by weight ratio.
- 4. crowded mud method luminescent ceramic pug composition as claimed in claim 1, it is characterised in that silicic acid in the flocculant Magnesium and calcium chloride account for the 43% and 57% of flocculant gross weight by weight ratio.
- 5. crowded mud method luminescent ceramic pug composition as claimed in claim 1, it is characterised in that the sintering aid particle A diameter of 100-400nm;The sintering aid contains fluoride.
- 6. crowded mud method luminescent ceramic pug composition as claimed in claim 5, it is characterised in that the fluoride includes CaF2、MgF2、ScF3、AlF3、YF3、ZrF4、HfF4、TiF3And/or the fluoride of lanthanide series.
- 7. crowded mud method luminescent ceramic pug composition as claimed in claim 1, it is characterised in that the composition of the useless porcelain powder For Fe2O3、SiO2, CaO and MgO.
- A kind of 8. preparation method of crowded mud method luminescent ceramic pug composition as claimed in claim 1, it is characterised in that bag Include following steps:Step 1:Weight as described in claim 1 is by kaolin, bentonite, albite, anorthite, potassium feldspar, stone English, pyrochlore, fluorite, talcum powder, mullite, useless porcelain powder, Jiepai clay, sintering aid and rare-earth trichromatic fluorescent powder are mixed Close.Step 2:Mixture after will be well mixed is mixed with water according to the weight proportion of claim 1;It is stirred Plasticizer is added in journey while stirring.Step 3:Into muddy after stirring five minutes, then add liquefacient.Step 4:The mud prepared is eluriated, adds flocculant during elutriation into mud.Step 5:Pug after step 4 is sequentially added into brightening agent, high temperature protection agent, crack resistence agent, wetting agent and tackifier.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710823301.8A CN107473707A (en) | 2017-09-13 | 2017-09-13 | A kind of crowded mud method luminescent ceramic pug composition and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710823301.8A CN107473707A (en) | 2017-09-13 | 2017-09-13 | A kind of crowded mud method luminescent ceramic pug composition and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107473707A true CN107473707A (en) | 2017-12-15 |
Family
ID=60584864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710823301.8A Pending CN107473707A (en) | 2017-09-13 | 2017-09-13 | A kind of crowded mud method luminescent ceramic pug composition and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107473707A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108373334A (en) * | 2018-03-23 | 2018-08-07 | 武汉理工大学 | The preparation method of the 3D printing slurry and its adhesive special that are recycled based on useless porcelain |
CN108550416A (en) * | 2018-05-18 | 2018-09-18 | 苏州天鸿电子有限公司 | A kind of chip resistor resistance slurry |
CN108751933A (en) * | 2018-06-11 | 2018-11-06 | 武汉理工大学 | It is a kind of to utilize the 3D printing ceramic paste and its preparation method and application prepared by porcelain that gives up |
CN109592965A (en) * | 2018-12-29 | 2019-04-09 | 钦州学院 | A kind of preparation process of luminous Nixing pottery pug and its moulded products |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1587196A (en) * | 2004-08-04 | 2005-03-02 | 中国科学院上海硅酸盐研究所 | High light output quick attenuation flash ceramic and its preparing method |
CN1903535A (en) * | 2006-08-11 | 2007-01-31 | 北京创导奥福精细陶瓷有限公司 | Method for extrusion-formation of ceramic mud material |
CN101973060A (en) * | 2010-07-30 | 2011-02-16 | 许庆华 | Production method of fluorescent colour attapulgite clay |
CN104591634A (en) * | 2015-01-21 | 2015-05-06 | 中铁大桥局集团第二工程有限公司 | Micro-expansion fiber reinforced concrete and preparation method thereof |
CN104961469A (en) * | 2015-07-03 | 2015-10-07 | 江苏脒诺甫纳米材料有限公司 | Whitening agent for ceramic blank body and preparation method thereof |
-
2017
- 2017-09-13 CN CN201710823301.8A patent/CN107473707A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1587196A (en) * | 2004-08-04 | 2005-03-02 | 中国科学院上海硅酸盐研究所 | High light output quick attenuation flash ceramic and its preparing method |
CN1903535A (en) * | 2006-08-11 | 2007-01-31 | 北京创导奥福精细陶瓷有限公司 | Method for extrusion-formation of ceramic mud material |
CN101973060A (en) * | 2010-07-30 | 2011-02-16 | 许庆华 | Production method of fluorescent colour attapulgite clay |
CN104591634A (en) * | 2015-01-21 | 2015-05-06 | 中铁大桥局集团第二工程有限公司 | Micro-expansion fiber reinforced concrete and preparation method thereof |
CN104961469A (en) * | 2015-07-03 | 2015-10-07 | 江苏脒诺甫纳米材料有限公司 | Whitening agent for ceramic blank body and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
徐利华: "《陶瓷坯釉料制备技术》", 31 October 2012, 中国轻工业出版社 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108373334A (en) * | 2018-03-23 | 2018-08-07 | 武汉理工大学 | The preparation method of the 3D printing slurry and its adhesive special that are recycled based on useless porcelain |
CN108373334B (en) * | 2018-03-23 | 2021-07-02 | 武汉理工大学 | 3D printing slurry based on waste ceramic recycling and preparation method of special binder thereof |
CN108550416A (en) * | 2018-05-18 | 2018-09-18 | 苏州天鸿电子有限公司 | A kind of chip resistor resistance slurry |
CN108751933A (en) * | 2018-06-11 | 2018-11-06 | 武汉理工大学 | It is a kind of to utilize the 3D printing ceramic paste and its preparation method and application prepared by porcelain that gives up |
CN109592965A (en) * | 2018-12-29 | 2019-04-09 | 钦州学院 | A kind of preparation process of luminous Nixing pottery pug and its moulded products |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI359798B (en) | Glaze compositions | |
CN107473707A (en) | A kind of crowded mud method luminescent ceramic pug composition and preparation method thereof | |
CN106082671B (en) | Longquan celadon blueness glaze, Longquan celadon and preparation method thereof | |
CN104926281B (en) | A kind of preparation method of inexpensive ultrawhite ceramic tile | |
CN103044082B (en) | Enamel ceramics luminescent glaze and glaze slip preparation method and application thereof | |
CN102020460B (en) | High-whiteness strengthened low-temperature fired daily fine porcelain and manufacturing method thereof | |
CN109384476A (en) | A kind of anti-skid wearable negative ion ceramic ceramic tile and preparation method thereof | |
CN102134167A (en) | Low-temperature melting block finished glaze and preparation method thereof | |
WO2015054805A1 (en) | High whiteness underglaze multicolored low-temperature porcelain and preparation method | |
CN105254282B (en) | A kind of preparation method of building ceramics | |
CN114507014A (en) | Snowflake crystal particle, preparation method thereof and preparation method of positioning crystal flower polished glazed brick | |
CN105198496A (en) | Praseodymium zirconium yellow ceramic pigment and preparation method thereof | |
CN106007381A (en) | Single-layer fambe pigmented glaze and preparation method thereof | |
CN115974411B (en) | Ceramic tile base glaze, ceramic tile and preparation method thereof | |
CN108484114A (en) | A kind of glaze Imitation Rock Porcelain Tiles of high additive polished waste material and preparation method thereof | |
CN109650848A (en) | It is a kind of from raw glaze enamel porcelain pug and use its technique for preparing enamel porcelain | |
CN114702298B (en) | Deep color whole-body landscape thick brick and preparation method thereof | |
CN114180841A (en) | Soft super-wear-resistant diamond glaze, ceramic tile and preparation method thereof | |
CN109835929B (en) | Method for preparing flaky alpha-alumina powder by sagger calcination | |
CN113402169B (en) | Easy-to-clean polished glaze and preparation method thereof | |
CN114573233A (en) | Preparation method of wear-resistant color-assisting frit for wear-resistant glaze, super wear-resistant glaze and ceramic tile | |
CN106746649A (en) | The light yellow glaze of high temperature light and its ceramic and preparation method | |
CN106082661A (en) | A kind of high abrasion pottery is with brightening glaze slip and preparation method thereof | |
CN106829984B (en) | A kind of wet process technique of waterglass | |
CN105948505A (en) | Preparation method for lead-zinc-silver tailing low-temperature-sintered encaustic brick glaze |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171215 |
|
RJ01 | Rejection of invention patent application after publication |