CN107469788A - A kind of dye wastewater treatment is composite porous and preparation method thereof with polyvinyl formal activated carbon - Google Patents
A kind of dye wastewater treatment is composite porous and preparation method thereof with polyvinyl formal activated carbon Download PDFInfo
- Publication number
- CN107469788A CN107469788A CN201710566301.4A CN201710566301A CN107469788A CN 107469788 A CN107469788 A CN 107469788A CN 201710566301 A CN201710566301 A CN 201710566301A CN 107469788 A CN107469788 A CN 107469788A
- Authority
- CN
- China
- Prior art keywords
- weight
- activated carbon
- polyvinyl alcohol
- parts
- polyvinyl formal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/265—Synthetic macromolecular compounds modified or post-treated polymers
- B01J20/267—Cross-linked polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
Abstract
It is composite porous and preparation method thereof with polyvinyl formal activated carbon the invention discloses a kind of dye wastewater treatment, it is characterised in that into polyvinyl alcohol plus distilled water, heating water bath stirring, to obtain the polyvinyl alcohol water solution of clarification；By a poly-vinyl alcohol solution heating water bath, after adding borax soln to react, with urea, hydrogen peroxide, ferrous sulfate hybrid reaction, add tributyl phosphate, stir to obtain hydrophobically modified polyvinyl alcohol glue；Into another polyvinyl alcohol water solution, dilute sulfuric acid, formaldehyde and expanded graphite, stirring reaction, fabricated in situ polyvinyl formal compound are added；Into polyvinyl formal compound, add starch, glycerine, heating stirring dissolves, obtain thick liquid, add activated carbon, OP 10, pentane and hydrophobically modified polyvinyl alcohol glue, be quickly uniformly mixed, thick liquid is poured into evaporating dish, it is put into baking oven and heats, it is composite porous obtains polyvinyl formal activated carbon.
Description
Technical field
The present invention relates to composite porous field, and in particular to a kind of dye wastewater treatment with polyvinyl formal-
Activated carbon is composite porous and preparation method thereof.
Background technology
Substantial amounts of organic pollution and inorganic pollution in waste water from dyestuff be present, unprocessed discharge can destroy water ecology
Balance, influences the existence of aquatile and microorganism, can not carry out biodegradation, make environmental degradation, can pass through drinking water and food
Thing chain passes to the mankind, eventually seriously endangers the health of the mankind.So handle the very urgent and necessary of waste water from dyestuff.
The content of the invention
The present invention solves the technical problem of provide a kind of dye wastewater treatment polyvinyl formal-activated carbon
Composite porous and preparation method thereof, composite porous according to technique preparation has good absorption property and waterproof
Performance.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of dye wastewater treatment composite porous preparation method of polyvinyl formal-activated carbon, it is characterised in that
Carry out according to the following steps：
A. into 30-40 weight account polyethylene alcohol 1:10-15 adds distilled water, is warming up to 90-100 DEG C of heating water bath stirring 1-
2h, the polyvinyl alcohol water solution clarified is divided into two parts, stand-by；
B. by a poly-vinyl alcohol solution heating water bath of gained in a to 70-80 DEG C, it is molten that lower addition 2-3 parts by weight boraxs are stirred
Liquid, after constant temperature stirring reaction 1-2h, mixed with 1-2 parts by weight of urea, 0.1-0.3 parts by weight hydrogen peroxide, stir, use 1-
It is 5-6 that 2mol/L HCl, which adjusts pH, adds 0.1-0.2 parts by weight of ferrous sulfate, is incubated 50-60 DEG C of stirring reaction 30-50min, is added dropwise
0.1-0.2 parts by weight of phosphoric acid tributyls, stir, and are cooled to room temperature, adjust pH to obtain hydrophobically modified polyvinyl alcohol glue for neutrality
Liquid；
C. into a in another polyvinyl alcohol water solution of gained, add 5-10 parts by weight dilute sulfuric acids, 10-15 parts by weight of formaldehyde and
2-4 parts by weight expanded graphites, controlling reaction temperature are 60-70 DEG C, stir 20-40min, fabricated in situ polyvinyl formal is answered
Compound；
D. 4-6 weight starch, 2-3 parts by weight of glycerin are added, in 70- in gained polyvinyl formal compound into c
80 DEG C of heating stirring dissolvings, obtain thick liquid, add 5-8 parts by weight of activated carbon, 1-2 parts by weight O P-10,2-4 weight
Resulting material in part pentane and b, is quickly uniformly mixed, thick liquid is poured into evaporating dish, be put into 60-80 DEG C of baking oven
Interior heating 5-6h, it is composite porous to obtain polyvinyl formal-activated carbon.
Wherein, borax soln concentration described in step b is 3-5%；Dilute sulfuric acid concentration described in step c is 40-50%.
The present invention reaction mechanism and have the beneficial effect that：
Under the catalytic action of dilute sulfuric acid, using polyvinyl alcohol, formaldehyde and expanded graphite as raw material, poly- second is obtained by fabricated in situ
Enol formal compound, then using glycerine and starch as pore-foaming agent, pentane be foaming agent, make polyvinyl alcohol contracting first by heating
Aldehyde compound, glycerine, starch and pentane mixture foam to obtain polyvinyl formal compound porous material, have processing
The adsorption capacity of waste water from dyestuff, by adding expanded graphite, the specific surface area of porous material is added, improves its adsorption capacity；
With polyvinyl alcohol (PVA) for adhesive, nonhazardous, but its poor water resistance is first modified with borax to polyvinyl alcohol, borax with
Reaction is crosslinked between polyvinyl alcohol, improves the water resistance of polyvinyl alcohol；It is sub- with oxidant hydrogen peroxide, catalyst sulfuric acid again
Iron, urea carry out oxidative degradation and hydrophobically modified to it, to reduce the viscosity of glue, improve its solid content and water resistance, are dredged
Water-based energy is got well and the PVA glues of good combination property, good to the hydrophobically modified effect of porous material.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment
A kind of dye wastewater treatment composite porous preparation method of polyvinyl formal-activated carbon, its feature
It is, carries out according to the following steps：
A. into 40kg polyvinyl alcohol 1:15 add distilled water, are warming up to 90-100 DEG C of heating water bath stirring 2h, are clarified
Polyvinyl alcohol water solution, is divided into two parts, stand-by；
B. by a poly-vinyl alcohol solution heating water bath of gained in a to 70-80 DEG C, lower addition 3kg borax solns, constant temperature are stirred
After stirring reaction 1h, mix, stir with 2kg urea, 0.3kg hydrogen peroxide, it is 5-6 to adjust pH with 1mol/L HCl, is added
0.2kg ferrous sulfate, 50-60 DEG C of stirring reaction 40min is incubated, 0.2kg tributyl phosphates are added dropwise, stirs, is cooled to room
Temperature, pH is adjusted to obtain hydrophobically modified polyvinyl alcohol glue for neutrality；
C. into a in another polyvinyl alcohol water solution of gained, 5kg dilute sulfuric acids, 10kg formaldehyde and 2kg expanded graphites, control are added
Reaction temperature processed is 60-70 DEG C, stirs 40min, fabricated in situ polyvinyl formal compound；
D. 4kg starch, 2kg glycerine are added, in 70-80 DEG C of heating stirring in gained polyvinyl formal compound into c
Dissolving, obtains thick liquid, adds resulting material in 6kg activated carbons, 1kg OP-10,2kg pentanes and b, quick stirring
It is well mixed, thick liquid is poured into evaporating dish, heating 5h in 70-80 DEG C of baking oven is put into, obtains polyvinyl formal-work
Property charcoal is composite porous.
Wherein, borax soln concentration described in step b is 4%；Dilute sulfuric acid concentration described in step c is 45%.
Claims (4)
1. a kind of dye wastewater treatment composite porous preparation method of polyvinyl formal-activated carbon, its feature exist
In：
Into polyvinyl alcohol plus distilled water, heating water bath stir, and obtain the polyvinyl alcohol water solution of clarification；A polyvinyl alcohol is molten
Liquid heating water bath, after adding borax soln to react, with urea, hydrogen peroxide, ferrous sulfate hybrid reaction, add tributyl phosphate, stir
Obtain hydrophobically modified polyvinyl alcohol glue；Into another polyvinyl alcohol water solution, dilute sulfuric acid, formaldehyde and expanded graphite are added, is stirred
Mix reaction, fabricated in situ polyvinyl formal compound；Into polyvinyl formal compound, add starch, glycerine, heat
Stirring and dissolving, thick liquid is obtained, add activated carbon, OP-10, pentane and hydrophobically modified polyvinyl alcohol glue, quickly stir
Mix uniformly, thick liquid is poured into evaporating dish, be put into baking oven and heat, it is porous multiple to obtain polyvinyl formal-activated carbon
Condensation material.
2. a kind of dye wastewater treatment composite porous preparation method of polyvinyl formal-activated carbon,
It is characterized in that：
A. into 30-40 weight account polyethylene alcohol 1:10-15 adds distilled water, is warming up to 90-100 DEG C of heating water bath stirring 1-
2h, the polyvinyl alcohol water solution clarified is divided into two parts, stand-by；
B. by a poly-vinyl alcohol solution heating water bath of gained in a to 70-80 DEG C, it is molten that lower addition 2-3 parts by weight boraxs are stirred
Liquid, after constant temperature stirring reaction 1-2h, mixed with 1-2 parts by weight of urea, 0.1-0.3 parts by weight hydrogen peroxide, stir, use 1-
It is 5-6 that 2mol/L HCl, which adjusts pH, adds 0.1-0.2 parts by weight of ferrous sulfate, is incubated 50-60 DEG C of stirring reaction 30-50min, is added dropwise
0.1-0.2 parts by weight of phosphoric acid tributyls, stir, and are cooled to room temperature, adjust pH to obtain hydrophobically modified polyvinyl alcohol glue for neutrality
Liquid；
C. into a in another polyvinyl alcohol water solution of gained, add 5-10 parts by weight dilute sulfuric acids, 10-15 parts by weight of formaldehyde and
2-4 parts by weight expanded graphites, controlling reaction temperature are 60-70 DEG C, stir 20-40min, fabricated in situ polyvinyl formal is answered
Compound；
D. 4-6 weight starch, 2-3 parts by weight of glycerin are added, in 70- in gained polyvinyl formal compound into c
80 DEG C of heating stirring dissolvings, obtain thick liquid, add 5-8 parts by weight of activated carbon, 1-2 parts by weight O P-10,2-4 weight
Resulting material in part pentane and b, is quickly uniformly mixed, thick liquid is poured into evaporating dish, be put into 60-80 DEG C of baking oven
Interior heating 5-6h, it is composite porous to obtain polyvinyl formal-activated carbon.
3. a kind of dye wastewater treatment according to claim 2 is composite porous with polyvinyl formal-activated carbon
Preparation method, it is characterised in that borax soln concentration described in step b is 3-5%.
4. a kind of dye wastewater treatment according to claim 2 is composite porous with polyvinyl formal-activated carbon
Preparation method, it is characterised in that dilute sulfuric acid concentration described in step c is 40-50%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710566301.4A CN107469788A (en) | 2017-07-12 | 2017-07-12 | A kind of dye wastewater treatment is composite porous and preparation method thereof with polyvinyl formal activated carbon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710566301.4A CN107469788A (en) | 2017-07-12 | 2017-07-12 | A kind of dye wastewater treatment is composite porous and preparation method thereof with polyvinyl formal activated carbon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107469788A true CN107469788A (en) | 2017-12-15 |
Family
ID=60596730
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710566301.4A Pending CN107469788A (en) | 2017-07-12 | 2017-07-12 | A kind of dye wastewater treatment is composite porous and preparation method thereof with polyvinyl formal activated carbon |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107469788A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113198417A (en) * | 2021-04-16 | 2021-08-03 | 云南省烟草公司玉溪市公司 | Iron-based biochar sponge composite material and preparation method and application thereof |
| CN110270161B (en) * | 2019-05-29 | 2021-11-23 | 陈明曦 | Air compressor oil-gas separation core material and preparation process thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5921514A (en) * | 1982-07-27 | 1984-02-03 | Kanebo Ltd | Manufacture of activated carbon composition |
| CN103736456A (en) * | 2013-12-17 | 2014-04-23 | 明光市国星凹土有限公司 | Composite decolouring adsorbent |
-
2017
- 2017-07-12 CN CN201710566301.4A patent/CN107469788A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5921514A (en) * | 1982-07-27 | 1984-02-03 | Kanebo Ltd | Manufacture of activated carbon composition |
| CN103736456A (en) * | 2013-12-17 | 2014-04-23 | 明光市国星凹土有限公司 | Composite decolouring adsorbent |
Non-Patent Citations (3)
| Title |
|---|
| 戴捷等: "聚乙烯醇-壳聚糖/活性碳多孔材料的制备及性能研究", 《长江大学学报（自然科学版）》 * |
| 樊晓东等: "复合改性聚乙烯醇胶黏剂的研制", 《沈阳化工学院学报》 * |
| 袁常在: "基于PVA及木薯淀粉改性的木材胶粘剂的制备", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110270161B (en) * | 2019-05-29 | 2021-11-23 | 陈明曦 | Air compressor oil-gas separation core material and preparation process thereof |
| CN113198417A (en) * | 2021-04-16 | 2021-08-03 | 云南省烟草公司玉溪市公司 | Iron-based biochar sponge composite material and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105110427B (en) | A kind of compound micro-electrolysis stuffing and preparation method and application | |
| CN107321350B (en) | Sludge-based Co/Fe bimetal composite Fenton-like catalyst and preparation method and application thereof | |
| CN107469788A (en) | A kind of dye wastewater treatment is composite porous and preparation method thereof with polyvinyl formal activated carbon | |
| CN103588935B (en) | Take acrylic acid wastewater as the method that modified lignosulfonate water reducing agent prepared by raw material | |
| CN102659377A (en) | Thermal preservation energy saving composite phase change energy storage gypsum board prepared by using phosphorous gypsum and preparation method thereof | |
| CN103466771B (en) | Method for preparing oxidized form polysilicic acid ferro-aluminum coagulant | |
| CN105858637A (en) | Macro-porous foam carbon Rasching ring packing for packed tower, and preparation method thereof | |
| CN106430887A (en) | Method for producing methane through anaerobic digestion of high-solid content sludge | |
| CN104098238A (en) | Deep treatment method of excess sludge | |
| CN104549273A (en) | Metal oxide loading active carbon catalyst and preparation method thereof | |
| CN106634301A (en) | High-toughness coating of aluminum charger case | |
| CN107055892A (en) | The method that various metals compounding micro ware auxiliary catalysis aoxidizes brewing wastewater biochemical tail water | |
| CN102051054B (en) | Method for preparing high polymer waterproof sheet | |
| CN105542092B (en) | The method that normal temperature synthesizes spacetabs type high-slump-retentionpolycarboxylate polycarboxylate water reducer | |
| CN107778766A (en) | A kind of phenolic aldehyde foam thermal insulation material for flat-plate solar collector | |
| CN101704911A (en) | Method for producing highly-chlorinated polyethylene | |
| CN104628605B (en) | A kind of naphthalene continuous catalysis method of sulfonating and device thereof | |
| CN106311270B (en) | A kind of preparation method of ozone oxidation catalyst | |
| CN107353513A (en) | A kind of rubber-plastic foamed insulation material of antimicrobial form and preparation method thereof | |
| CN107266121A (en) | A kind of cement insulation board and preparation method thereof | |
| CN102584258A (en) | Coating capable of reducing heating oxidation burning loss of steel billets | |
| CN107902857A (en) | A kind of sludge stabilization agent for handling heavy metal and its preparation method and application | |
| CN102976658B (en) | Special additive for water-permeable concrete and preparation method of special additive | |
| CN201730234U (en) | Foamed plastic and electrolytic manganese slag composite thermal-insulating block | |
| CN101805533B (en) | Heat-resistance energy-saving environment-protection epoxy solvent-free paint and production method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171215 |