CN107469778A - Nano material cleanser with fresh air and preparation method - Google Patents
Nano material cleanser with fresh air and preparation method Download PDFInfo
- Publication number
- CN107469778A CN107469778A CN201710786318.0A CN201710786318A CN107469778A CN 107469778 A CN107469778 A CN 107469778A CN 201710786318 A CN201710786318 A CN 201710786318A CN 107469778 A CN107469778 A CN 107469778A
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- nano
- nanometer
- tpa
- terephthalic acid
- fresh air
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- 239000002086 nanomaterial Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title description 13
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 108
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 29
- 239000011707 mineral Substances 0.000 claims abstract description 28
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 239000003463 adsorbent Substances 0.000 claims abstract description 15
- 125000002524 organometallic group Chemical group 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011575 calcium Substances 0.000 claims abstract description 11
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011777 magnesium Substances 0.000 claims abstract description 10
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011701 zinc Substances 0.000 claims abstract description 8
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 8
- 230000003213 activating effect Effects 0.000 claims abstract description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 235000010755 mineral Nutrition 0.000 claims description 25
- 238000001354 calcination Methods 0.000 claims description 21
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 17
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 17
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- 238000003801 milling Methods 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 238000005119 centrifugation Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000003502 gasoline Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 238000006053 organic reaction Methods 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 3
- 238000002525 ultrasonication Methods 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- OJFQIOACFWBKBN-UHFFFAOYSA-N dioctyl benzene-1,2-dicarboxylate;zinc Chemical group [Zn].CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC OJFQIOACFWBKBN-UHFFFAOYSA-N 0.000 claims description 2
- 239000002594 sorbent Substances 0.000 claims 2
- 238000003756 stirring Methods 0.000 claims 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract description 7
- 239000000292 calcium oxide Substances 0.000 abstract description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract description 7
- 230000000505 pernicious effect Effects 0.000 abstract description 5
- 231100000331 toxic Toxicity 0.000 abstract description 5
- 230000002588 toxic effect Effects 0.000 abstract description 5
- 238000006555 catalytic reaction Methods 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 230000008929 regeneration Effects 0.000 abstract description 3
- 238000011069 regeneration method Methods 0.000 abstract description 3
- 239000003570 air Substances 0.000 description 37
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 15
- 239000007789 gas Substances 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- 241000790917 Dioxys <bee> Species 0.000 description 2
- 238000004887 air purification Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- JIAARYAFYJHUJI-UHFFFAOYSA-L Zinc chloride Inorganic materials [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- ASLMJVVWFAQOQS-UHFFFAOYSA-N calcium;terephthalic acid Chemical compound [Ca].OC(=O)C1=CC=C(C(O)=O)C=C1 ASLMJVVWFAQOQS-UHFFFAOYSA-N 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- -1 formaldehyde, benzene class Chemical class 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004630 mental health Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- AOFLRIJGLJZIDW-UHFFFAOYSA-N phthalic acid;zinc Chemical compound [Zn].OC(=O)C1=CC=CC=C1C(O)=O AOFLRIJGLJZIDW-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/14—Diatomaceous earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- B01J35/39—
Abstract
The present invention discloses a kind of nano material cleanser with fresh air, the raw material based on natural mineral matter, is formed it is characterized in that being counted with mass parts including following component：Nano titanium oxide 58, nanometer organometallic skeletal adsorbent 15 25, nanometer natural mineral matter 75 95, and appropriate activating agent；The nanometer organometallic skeletal adsorbent forms for the mixing of terephthalic acid (TPA) calcium, terephthalic acid (TPA) magnesium and/terephthalic acid (TPA) zinc；The nanometer natural mineral matter forms including following mass component：Nano diatomite 40 55, nano imvite 20 30, nano zine oxide and/or nano calcium oxide 5 10, nano material cleanser with fresh air product prepared by the present invention can have regeneration function after toxic and harmful gas is adsorbed, effective catalysis oxidation can be carried out to the pernicious gas in air, constantly moved in circles.
Description
Technical field
The present invention relates to a kind of air purifying preparation and its preparation method, particularly a kind of nano material cleanser with fresh air and
Its preparation method.
Background technology
With the continuous development of industrialization technology, auto industry is popularized energetically, and automobile has come into huge numbers of families, China's automobile
The continuous improvement of owning amount, the pollution as caused by motor vehicle exhaust emission and the quickening of process of industrialization to air, which improves, also gets over
Come more serious.Thus occur Wu Mist weather in some big and medium-sized cities, the physical and mental health of people is caused serious harm.And room
Room, market, hotels and other places finishing when, a large amount of uses of decorating and renovating material are how many all containing certain in these materials
Volatile harmful gas, such as hydro carbons, aldehydes, benzene class, lipid, such people are long-term indoors and atmosphere pollution
Environmental condition under work, and easily because environmental pollution cause a disease cause evil caused by personnel premature death, according to the incomplete of World Health Organization
Statistics, the whole world reach as many as hundreds of thousands of them, thus air in air every year because of reason death tolls such as atmospheric ambient air pollutions
Quality and indoor environmental quality pollution, be public's health damaged also into maximum influence environmental factor it
One.
Thus air cleaner or pure and fresh cleanser product arise at the historic moment, if Chinese patent notification number is CN103447004《One
Strong absorbent-type air purifying preparation of kind and preparation method thereof》, it mainly includes following mass component and formed, activated carbon 15-30, swelling
Native 5-15, light magnesium oxide 8-20, tea oil 5-15, sodium hydrogensulfite 0.3-2, alkyl amine oxide 0.2-1, absolute ethyl alcohol and acid
Property potassium permanganate etc., it contains volatile component, and the germ in air can be killed.But it is laid particular emphasis on to sky relatively
The absorption cleaning effect of carbon dioxide in gas, and the killing effect to such as formaldehyde of the pernicious gas in air etc. is not very good.
It is CN102989308 also just like Chinese patent notification number《A kind of multifunctional air cleaning agent》, it include diatomite,
Nano titanium oxide, dispersant, calgon, rare earth activators, and inorganic mineral powder land plaster or sepiolite clay powder etc., but
It is that this kind of air purifying preparation addition rare earth composition product cost is higher, is commercially to be difficult to push away application, while purification of air is imitated
Fruit is also undesirable with respect to rate of exchange benefit.
Therefore, it is how a kind of cost-effective to provide, can be to such as dioxy of the toxic and harmful gas in air or room air
After change carbon, nitrogen, aldehydes such as formaldehyde, benzene class etc. carry out Adsorption, while cleanser product and can adsorption-decomposition function obtains regeneration,
Adsoption catalysis organic harmful poisonous gas can be aoxidized again again, constantly move in circles reuse, and air purification effect is high
Cleanser with fresh air product.
The content of the invention：The present invention seeks to provide nano material cleanser with fresh air, former based on natural mineral matter
Material；It uses the raw material such as nano titanium oxide and nanometer organometallic skeletal adsorbent, is received with bigger serface, macroporosity
Organometallic skeletal made of rice material is carrier, the toxic and harmful gas in energy efficient catalytic absorption air or room air,
And it is good to remove peculiar smell, the air purification effects such as the gasoline of in-car, cigarette；With preferable social and economic benefit.
The present invention provides a kind of nano material cleanser with fresh air, and the raw material based on natural mineral matter, it is with matter
Amount part meter includes following component composition：Nano titanium oxide 5-8, nanometer organometallic skeletal adsorbent 15-25, the natural ore deposit of nanometer
Material 75-95, and appropriate activating agent；The nanometer organometallic skeletal adsorbent is terephthalic acid (TPA) calcium, terephthalic acid (TPA) magnesium
With the mixing composition of/terephthalic acid (TPA) zinc.The activating agent is preferably to control the amount that it is added in 0.5-2 using activating activities carbon
Mass parts.
A kind of described nano material cleanser with fresh air, its described nanometer organometallic skeletal adsorbent are following matter
Measure components terephthalic acid calcium 5-10, terephthalic acid (TPA) magnesium 3-8 and terephthalic acid (TPA) zinc 5-15 mixing composition.
A kind of described nano material cleanser with fresh air, its described nanometer natural mineral matter include following mass component
Composition：Nano diatomite 40-55, nano imvite 20-30, nano zine oxide and/or nano calcium oxide 5-10.
A kind of described nano material cleanser with fresh air, it is preferably the nanometer organometallic skeletal adsorbent
Terephthalic acid (TPA) calcium, terephthalic acid (TPA) magnesium or terephthalic acid (TPA) zinc be by para-phthalic sodium respectively and corresponding magnesium sulfate or sulphur
Sour zinc and calcium chloride carry out organic reaction and are prepared.
A kind of nano material cleanser with fresh air of the present invention, it is it is further preferred that be that the nanometer is natural
Mineral matter is prepared through secondary clacining, is by corresponding natural mineral matter raw material, additive is added after broken, milling,
It is placed in after being uniformly mixed in calciner plant, it is 300-650 DEG C to control a calcining heat, calcination time 5-20 minutes,
It is 100 to control the mass ratio of natural mineral matter raw material and additive：0.2-1.2, cooling, obtains a calcining materials accordingly；Two
It is secondary calcining be by a black calcining materials after milling, be re-fed into calciner plant carry out it is secondary just finished product calcining, control it is secondary
First finished product calcining heat is 200-250 DEG C, calcination time 20-30 minutes, is milled after cooling, it is natural to produce corresponding nanometer
Mineral matter.
Preferably, it is that the additive is sodium hydrate solid or solution.
Still more preferably, it is a kind of described nano material cleanser with fresh air, its described nano imvite bag
Purifying montmorillonite miberal powder raw material is included, is that montmorillonite is dispersed in water or organic solvent with ultrasonic wave, controls its solid-to-liquid ratio
Example is from 1:1 to 1:10, obtain mixed liquor, by mixed liquor through staticly settling, rotary filter press removal of impurities, filtration drying must purify montmorillonite；
Purifying montmorillonite mixed liquor is made in purifying montmorillonite again, is warmed to 40-95 DEG C, and divided simultaneously with ultrasonication 5-20
Clock, obtains modified montmorillonoid mixed liquor, filtered, centrifugation, and re-dry produces nano imvite；
Described is that organic solvent is any one or a few in water, ethanol, methanol, toluene, benzene, acetone, ether, gasoline.
The nano material cleanser with fresh air of the present invention, including above-mentioned each nanometer natural minerals component form, in use
State preparation technology to be prepared, as nanometer natural mineral raw can be prepared using existing production technology, such as nanometer diatom
Soil is to carry out preparation using following preparation method and will prepare diatomaceous raw material being prepared using secondary clacining technique, this
The performance for the nano diatomite that sample is prepared is more excellent, and adsorptivity is stronger.And nanometer organometallic skeletal adsorbent nano material is empty
The preparation of the pure and fresh cleanser of gas, para-phthalic sodium and zinc sulfate can be used to carry out reaction for raw material and prepare terephthalic acid (TPA) zinc
Product.Key reaction equation：
Na2C8H4O4+ZnSO4 H2O→ZnC8H4O4+ Na2SO4 +H2O 。
The raw material of above-mentioned each mass component is obtained into raw material after preparing respectively, mixed → be granulated by quality proportioning → some
Finished product is prepared in secondary drying and granulation → roasting → cooling → packaging.
It is of the invention to be using the beneficial effect of above-mentioned technical proposal：
The present invention is preferably produced using the nanometer titanium dioxide titanium material with photochemical catalyst using nanometer anatase titania
Product, its performance is more excellent, at the same using nanometer organic metal bone adsorbent be terephthalic acid (TPA) calcium, terephthalic acid (TPA) magnesium and/to benzene
The raw material of the compound of dioctyl phthalate zinc, and nanometer natural mineral matter nano imvite and diatomite, the nano material prepared are empty
The pure and fresh cleanser product of gas is nontoxic, tasteless, in air after pernicious gas absorption, under active catalytic and light action, and it is empty
Oxidation chemistry reaction occurs for the oxygen in gas, generates dioxy carbon and water etc..Its adsorptivity is stronger, more existing active carbon silica gel
Deng and existing cleanser product it is more excellent.It adsorbs the absorption affinity of polar molecule and is followed successively by, the positive alkene ＞ fat ＞ of water ＞ alcohol ＞ aldehyde ＞
Aromatic hydrocarbons ＞ alkane etc., the pernicious gas composition that it can greatly in absorption air.Second, nano material air prepared by the present invention
Pure and fresh cleanser product can have regeneration function after toxic and harmful gas is adsorbed.Can have to the pernicious gas in air
Catalysis oxidation is imitated, is constantly moved in circles.The nano material cleanser with fresh air product utilization nanometer natural mineral matter of the present invention
Nano diatomite and its pore diameter range of the porous of nano imvite in 20-60nm, harmful poisonous gas can just be caught
Collection, recycle the titanium dioxide of photochemical catalyst to carry out catalytic degradation, be purified air.
Embodiment:
Technical scheme is further described in detail with reference to embodiment bright.
A kind of nano material cleanser with fresh air of the present invention, the raw material based on natural mineral matter, it is in terms of mass parts
Formed including following component：Nano titanium oxide 5-8, nanometer organometallic skeletal adsorbent 15-25, nanometer natural mineral matter
75-95, and appropriate activating agent；The nanometer organometallic skeletal adsorbent be terephthalic acid (TPA) calcium, terephthalic acid (TPA) magnesium and/it is right
The compound of phthalic acid zinc.
The nanometer organometallic skeletal adsorbent is following mass component terephthalic acid (TPA) calcium 5-10, terephthalic acid (TPA) magnesium
3-8 and terephthalic acid (TPA) zinc 5-15 compound.
The nanometer natural mineral matter forms including following mass component：Nano diatomite 40-55, nano imvite 20-
30, nano zine oxide and/or nano calcium oxide 5-10.
The nanometer organometallic skeletal adsorbent is by para-phthalic sodium and corresponding magnesium sulfate or zinc sulfate and chlorine
Change calcium progress organic reaction to be prepared.
The nanometer natural mineral matter, which is preferably nano diatomite and nano calcium oxide, to be prepared through secondary clacining, is
By corresponding natural mineral matter diatomite and calcium oxide raw ore raw material, additive is added after broken, milling, is uniformly mixed
After be placed in calciner plant, it is 300-650 DEG C to control calcining heat, calcination time 5-20 minutes, controls natural minerals
The mass ratio of matter raw material diatomite and calcium oxide and additive sodium hydroxide is 100：0.2-1.2, cooling, obtains and once forges accordingly
Burn material；Secondary clacining be by a black calcining materials after milling, be re-fed into calciner plant carry out it is secondary just finished product calcining,
It is 200-250 DEG C to control secondary just finished product calcining heat, calcination time 20-30 minutes, is milled after cooling, is produced corresponding
Nanometer natural mineral matter nano diatomite and nano calcium oxide raw produce.Described additive uses sodium hydrate solid group
Point.
The nano imvite is prepared using following technique, and the nano imvite includes purifying montmorillonite miberal powder raw material,
It is that montmorillonite is dispersed in water or organic solvent with ultrasonic wave, controls its solid-liquid ratio from 1:1 to 1:10, it must mix
Liquid, by mixed liquor through staticly settling, rotary filter press removal of impurities, filtration drying must purify montmorillonite；
Purifying montmorillonite mixed liquor is made in purifying montmorillonite again, is warmed to 40-95 DEG C, and divided simultaneously with ultrasonication 5-20
Clock, obtains modified montmorillonoid mixed liquor, filtered, centrifugation, and re-dry produces nano imvite；
Described is that organic solvent is any one or a few in water, ethanol, methanol, toluene, benzene, acetone, ether, gasoline.
The preparation method of nano imvite：Take montmorillonite 200g to be put into the container in consersion unit, be then placed in water
800g, ultrasonic power is opened, control and regulation output frequency is 20kc, power 200W processing, is kept for 15 minutes, can obtain
Montmorillonite dispersed solution in water, static 20 minutes, clean, filter, being dried to obtain purifying montmorillonite powder.Most afterwards through upper
Processing filtering, centrifugation are stated, re-dry produces nano imvite.
Embodiment, mass parts or mass ratio.Table 1 below, represent each constituent of each embodiment and to the impurity in air
And the percentage of the degree of purification of aqueous vapor etc..Table 1
Explanation：Cleanser with fresh air of the present invention is higher to the impurity in air and the degree of being cleaned into of aqueous vapor, and the impurity refers to
Such as carbon dioxide, nitrogen, the aldehydes such as synthesis of toxic and harmful gas such as formaldehyde, the Adsorption of benzene class progress.
Measure such as the adsorption cleaning rate of formaldehyde is that it is close that nano material cleanser with fresh air product of the present invention is placed in into one
In the higher space of the content of formaldehyde that closes, the content of formaldehyde in the confined space is detected within the defined time, it is neter to crossing
Change front and rear content of formaldehyde numerical value, present invention detection rear impurity content value is as listed in Table 1.And the purifying rate of similar product
The above-mentioned technical value requirement of the present invention is not reached.
Claims (7)
1. a kind of nano material cleanser with fresh air, the raw material based on natural mineral matter, it is characterized in that being wrapped in terms of mass parts
Include following component composition：Nano titanium oxide 5-8, nanometer organometallic skeletal adsorbent 15-25, nanometer natural mineral matter 75-
95, and appropriate activating agent；The nanometer organometallic skeletal adsorbent be terephthalic acid (TPA) calcium, terephthalic acid (TPA) magnesium and/to benzene
The mixing composition of dioctyl phthalate zinc.
A kind of 2. nano material cleanser with fresh air according to claim 1, it is characterized in that the nanometer organic metal
Framework sorbent is following mass component terephthalic acid (TPA) calcium 5-10's, terephthalic acid (TPA) magnesium 3-8 and terephthalic acid (TPA) zinc 5-15
Mixing composition.
A kind of 3. nano material cleanser with fresh air according to claim 1, it is characterized in that the nanometer natural minerals
Matter forms including following mass component：Nano diatomite 40-55, nano imvite 20-30, nano zine oxide and/or nano oxygen
Change calcium 5-10.
A kind of 4. nano material cleanser with fresh air according to claim 1, it is characterized in that the nanometer organic metal
Framework sorbent terephthalic acid (TPA) calcium, terephthalic acid (TPA) magnesium or terephthalic acid (TPA) zinc be by para-phthalic sodium respectively and accordingly
Magnesium sulfate or zinc sulfate and calcium chloride carry out organic reaction and are prepared.
A kind of 5. nano material cleanser with fresh air according to claim 1, it is characterized in that the nanometer natural minerals
Matter is prepared through secondary clacining, is by corresponding natural mineral matter raw material, additive is added after broken, milling, stirring is mixed
It is placed in after closing uniformly in calciner plant, it is 300-650 DEG C to control a calcining heat, calcination time 5-20 minutes, controls day
The mass ratio of right mineral raw material and additive is 100：0.2-1.2, cooling, obtains a calcining materials accordingly；Secondary clacining
Be by a black calcining materials after milling, be re-fed into calciner plant carry out it is secondary just finished product calcining, control it is secondary just finished product
Calcining heat is 200-250 DEG C, calcination time 20-30 minutes, is milled after cooling, produces corresponding nanometer natural minerals
Matter.
A kind of 6. nano material cleanser with fresh air according to claim 5, it is characterized in that the additive is hydrogen-oxygen
Change sodium solid or solution.
7. a kind of nano material cleanser with fresh air according to claim 3, taken off it is characterized in that the nanometer is covered
Soil includes purifying montmorillonite miberal powder raw material, is that montmorillonite is dispersed in water or organic solvent with ultrasonic wave, controls it solid
Liquid proportional is from 1:1 to 1:10, obtain mixed liquor, by mixed liquor through staticly settling, rotary filter press removal of impurities, it is de- that filtration drying must purify illiteracy
Soil；
Purifying montmorillonite mixed liquor is made in purifying montmorillonite again, is warmed to 40-95 DEG C, and divided simultaneously with ultrasonication 5-20
Clock, obtains modified montmorillonoid mixed liquor, filtered, centrifugation, and re-dry produces nano imvite；
Described is that organic solvent is any one or a few in water, ethanol, methanol, toluene, benzene, acetone, ether, gasoline.
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