CN107460779B - Glass fiber synthetic resin modified decorative plate and preparation method thereof - Google Patents
Glass fiber synthetic resin modified decorative plate and preparation method thereof Download PDFInfo
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- CN107460779B CN107460779B CN201710768860.3A CN201710768860A CN107460779B CN 107460779 B CN107460779 B CN 107460779B CN 201710768860 A CN201710768860 A CN 201710768860A CN 107460779 B CN107460779 B CN 107460779B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/001—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/47—Condensation polymers of aldehydes or ketones
- D21H17/48—Condensation polymers of aldehydes or ketones with phenols
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a glass fiber synthetic resin modified decorative plate and a preparation method thereof, wherein the decorative plate comprises the following components in parts by weight: 30-55 parts of kraft paper base paper, 19-40 parts of phenolic resin, 19-35 parts of glass fiber, 12-25 parts of graphene, 12-28 parts of silane coupling agent, 18-35 parts of ethyl acetate, 8-19 parts of sodium carbonate, 5-22 parts of calcium carbonate, 15-28 parts of aluminum oxide, 2-11 parts of kaolin and 1-5 parts of montmorillonite. The decorative plate modified by the glass fiber synthetic resin has good viscosity, and is not easy to absorb moisture and debond; the decorative plate modified by the glass fiber synthetic resin has high peel strength and good mechanical property.
Description
Technical Field
The invention belongs to the field of material chemistry, and relates to a decorative material, in particular to a glass fiber synthetic resin modified decorative plate and a preparation method thereof.
Background
The molten glass is drawn at an extremely high speed into fine filaments, i.e., glass fibers. Because of its soft texture, it can be woven into fabrics of glass cloth, glass band, etc. Glass fibers and glass, although different in appearance, are the same in combination. Glass fiber is characterized by low cost, wide source, high tensile strength and impact strength, good chemical corrosion resistance, small elongation at break, density similar to aluminum and about one third of that of steel, and is a material with high strength, high elastic modulus and higher specific strength, therefore, glass fiber and products thereof are widely used as reinforcing materials to be made into composite materials.
In 1950, the glass fiber industry in China started and only can be produced at that time. After 1955, the glass fiber industry in China is developed rapidly only when the glass fiber industry in China is developed. The product is widely used in industrial departments of petroleum, chemical industry, smelting, traffic, electric industry, electronics, communication, aerospace and the like, and various fields of military engineering and articles for daily use of people due to the special performance. Glass fibers are commonly used in the wood industry as reinforcement for fiber boards and particle boards, and are also a fire resistant material.
The coupling agent is a substance capable of improving the interfacial characteristics between the filler and the high polymer material. The molecular structure of the polymer has two functional groups, wherein one functional group can chemically react with a polymer matrix or has at least good compatibility; another functional group may form a chemical bond with the inorganic filler. The coupling agent can improve the interface performance between the high molecular material and the filler, improve the adhesion of the interface and improve the performance of the filled or reinforced high molecular material.
The decorative board in the prior art is placed in moisture for a long time, and the resin and the glass fiber are debonded.
Disclosure of Invention
The purpose of the invention is: the invention provides a decorative plate modified by glass fiber synthetic resin and a preparation method thereof, aiming at overcoming the defects of the prior art and obtaining the decorative plate which has good viscosity and is difficult to absorb moisture and debond or expand.
The technical scheme is as follows: the glass fiber synthetic resin modified decorative plate comprises the following components in parts by weight: 30-55 parts of kraft paper base paper, 19-40 parts of phenolic resin, 19-35 parts of glass fiber, 12-25 parts of graphene, 12-28 parts of silane coupling agent, 18-35 parts of ethyl acetate, 8-19 parts of sodium carbonate, 5-22 parts of calcium carbonate, 15-28 parts of aluminum oxide, 2-11 parts of kaolin and 1-5 parts of montmorillonite.
Preferably, the decorative sheet includes, by weight: 48 parts of kraft base paper, 34 parts of phenolic resin, 29 parts of glass fiber, 22 parts of graphene, 23 parts of silane coupling agent, 32 parts of ethyl acetate, 15 parts of sodium carbonate, 17 parts of calcium carbonate, 23 parts of aluminum oxide, 8 parts of kaolin and 4 parts of montmorillonite.
A preparation method of a glass fiber synthetic resin modified decorative plate comprises the following steps:
(1) dispersing graphene in a sulfuric acid solution, adding glass fiber, and magnetically stirring for 1-4 hours at the stirring temperature of 30-45 ℃ to obtain a modified solution;
(2) dispersing a silane coupling agent in ethyl acetate, adding the product prepared in the step (1), stirring while adding until the product is uniformly dispersed, placing the product in an environment with the temperature of 55-65 ℃ for dehydration and drying, and passing through a 0.1mm square-hole sieve to prepare modified glass fiber powder;
(3) mixing sodium carbonate, calcium carbonate, aluminum oxide, kaolin, montmorillonite and the modified glass fiber powder obtained in the step (2), and adding deionized water according to the mass ratio of 1: 1-1.2 to adjust the mixture into a paste body, so as to obtain glass fiber gel;
(4) cutting kraft paper into test pieces of 10cm multiplied by 10cm, drying at 55-65 ℃ until the water content is 1% -5%, immersing the kraft paper into phenolic resin, discharging bubbles on the paper surface, soaking for 1-5 hours, taking out and drying;
(5) coating the surface of the kraft paper base paper treated in the step (4) with the glass fiber gel prepared in the step (3), airing at room temperature, and then drying in an environment at 55-65 ℃;
(6) and (3) immersing the kraft paper base paper treated in the step (5) in phenolic resin, discharging paper surface bubbles, soaking for 2-10 hours, and then drying, assembling and hot-pressing to obtain the decorative plate.
Preferably, in the step (1), the graphene is dispersed in a sulfuric acid solution, then the glass fiber is added, and magnetic stirring is carried out for 2.5 hours at the stirring temperature of 40 ℃ to obtain the modified solution.
Preferably, the silane coupling agent is dispersed in ethyl acetate in the step (2), then the product obtained in the step (1) is added and stirred until the dispersion is uniform, and the mixture is placed in an environment with 60 ℃ for dehydration and drying and passes through a 0.1mm square-hole sieve to obtain the modified glass fiber powder.
Preferably, in the step (3), sodium carbonate, calcium carbonate, aluminum oxide, kaolin, montmorillonite and the modified glass fiber powder obtained in the step (2) are mixed, and deionized water is added according to the mass ratio of 1:1 to adjust the mixture into a paste, so that glass fiber gel is obtained.
Preferably, in the step (4), the kraft paper base paper is cut into 10cm × 10cm test pieces, dried at 62 ℃ until the water content is 4%, immersed in the phenolic resin, bubbles on the paper surface are discharged, and the paper is taken out and dried after being immersed for 4 hours.
Preferably, in the step (5), the surface of the kraft paper base paper treated in the step (4) is coated with the glass fiber gel prepared in the step (3), and the glass fiber gel is dried at room temperature and then dried in an environment at 62 ℃.
Preferably, in the step (6), the kraft paper base paper treated in the step (5) is immersed in phenolic resin, bubbles on the paper surface are discharged, the paper surface is soaked for 7 hours, and then the decorative plate can be prepared through drying, assembling and hot pressing.
Has the advantages that: (1) the decorative plate modified by the glass fiber synthetic resin has good viscosity, and is not easy to absorb moisture and debond; (2) the decorative plate modified by the glass fiber synthetic resin has high peel strength and good mechanical property.
Detailed Description
Example 1
The glass fiber synthetic resin modified decorative plate comprises the following components in parts by weight: 30 parts of kraft base paper, 19 parts of phenolic resin, 19 parts of glass fiber, 12 parts of graphene, 12 parts of silane coupling agent, 18 parts of ethyl acetate, 8 parts of sodium carbonate, 5 parts of calcium carbonate, 15 parts of aluminum oxide, 2 parts of kaolin and 1 part of montmorillonite.
A preparation method of a glass fiber synthetic resin modified decorative plate comprises the following steps:
(1) dispersing graphene in a sulfuric acid solution, adding glass fiber, and magnetically stirring for 1 hour at the stirring temperature of 30 ℃ to obtain a modified solution;
(2) dispersing a silane coupling agent in ethyl acetate, adding the product prepared in the step (1), stirring while adding until the product is uniformly dispersed, placing the product in an environment with the temperature of 55 ℃ for dehydration and drying, and passing the product through a 0.1mm square-hole sieve to prepare modified glass fiber powder;
(3) mixing sodium carbonate, calcium carbonate, aluminum oxide, kaolin, montmorillonite and the modified glass fiber powder obtained in the step (2), and adding deionized water according to the mass ratio of 1:1 to adjust the mixture into a paste, so as to obtain glass fiber gel;
(4) cutting kraft paper into test pieces of 10cm × 10cm, drying at 55 deg.C until the water content is 1%, immersing kraft paper in phenolic resin, discharging bubbles on the paper surface, soaking for 1 hr, taking out, and drying;
(5) coating the surface of the kraft paper base paper treated in the step (4) with the glass fiber gel prepared in the step (3), airing at room temperature, and then drying in an environment at 55 ℃;
(6) and (4) immersing the kraft paper base paper treated in the step (5) in phenolic resin, discharging paper surface bubbles, soaking for 2 hours, and then drying, assembling and hot-pressing to obtain the decorative plate.
Example 2
The glass fiber synthetic resin modified decorative plate comprises the following components in parts by weight: 48 parts of kraft base paper, 34 parts of phenolic resin, 29 parts of glass fiber, 22 parts of graphene, 23 parts of silane coupling agent, 32 parts of ethyl acetate, 15 parts of sodium carbonate, 17 parts of calcium carbonate, 23 parts of aluminum oxide, 8 parts of kaolin and 4 parts of montmorillonite.
A preparation method of a glass fiber synthetic resin modified decorative plate comprises the following steps:
(1) dispersing graphene in a sulfuric acid solution, adding glass fiber, and magnetically stirring for 2.5 hours at the stirring temperature of 40 ℃ to obtain a modified solution;
(2) dispersing a silane coupling agent in ethyl acetate, adding the product prepared in the step (1), stirring while adding until the product is uniformly dispersed, placing the product in an environment at 60 ℃ for dehydration and drying, and passing the product through a 0.1mm square-hole sieve to prepare modified glass fiber powder;
(3) mixing sodium carbonate, calcium carbonate, aluminum oxide, kaolin, montmorillonite and the modified glass fiber powder obtained in the step (2), and adding deionized water according to the mass ratio of 1:1 to adjust the mixture into a paste, so as to obtain glass fiber gel;
(4) cutting kraft paper into test pieces of 10cm × 10cm, drying at 62 ℃ until the water content is 4%, immersing the kraft paper in phenolic resin, discharging bubbles on the paper surface, soaking for 4 hours, taking out and drying;
(5) coating the surface of the kraft paper base paper treated in the step (4) with the glass fiber gel prepared in the step (3), airing at room temperature, and then drying in an environment of 62 ℃;
(6) and (4) immersing the kraft paper base paper treated in the step (5) in phenolic resin, discharging paper surface bubbles, soaking for 7 hours, and then drying, assembling and hot-pressing to obtain the decorative plate.
Example 3
The glass fiber synthetic resin modified decorative plate comprises the following components in parts by weight: 55 parts of kraft paper base paper, 40 parts of phenolic resin, 35 parts of glass fiber, 25 parts of graphene, 28 parts of silane coupling agent, 35 parts of ethyl acetate, 19 parts of sodium carbonate, 22 parts of calcium carbonate, 28 parts of aluminum oxide, 11 parts of kaolin and 5 parts of montmorillonite.
A preparation method of a glass fiber synthetic resin modified decorative plate comprises the following steps:
(1) dispersing graphene in a sulfuric acid solution, adding glass fiber, and magnetically stirring for 4 hours at the stirring temperature of 45 ℃ to obtain a modified solution;
(2) dispersing a silane coupling agent in ethyl acetate, adding the product prepared in the step (1), stirring while adding until the product is uniformly dispersed, placing the product in an environment of 65 ℃ for dehydration and drying, and passing the product through a 0.1mm square-hole sieve to prepare modified glass fiber powder;
(3) mixing sodium carbonate, calcium carbonate, aluminum oxide, kaolin, montmorillonite and the modified glass fiber powder obtained in the step (2), and adding deionized water according to the mass ratio of 1:1.2 to adjust into a paste body, so as to obtain glass fiber gel;
(4) cutting kraft paper into test pieces of 10cm × 10cm, drying at 65 ℃ until the water content is 5%, immersing the kraft paper in phenolic resin, discharging bubbles on the paper surface, soaking for 5 hours, taking out and drying;
(5) coating the surface of the kraft paper base paper treated in the step (4) with the glass fiber gel prepared in the step (3), airing at room temperature, and then drying in a 65 ℃ environment;
(6) and (4) immersing the kraft paper base paper treated in the step (5) in phenolic resin, discharging paper surface bubbles, soaking for 10 hours, and then drying, assembling and hot-pressing to obtain the decorative plate.
The decorative plate modified by the glass fiber synthetic resin prepared in the examples 1 to 3 was subjected to performance tests, and the results are shown in the following table:
Claims (8)
1. the glass fiber synthetic resin modified decorative plate is characterized by comprising the following components in parts by weight: 30-55 parts of kraft paper base paper, 19-40 parts of phenolic resin, 19-35 parts of glass fiber, 12-25 parts of graphene, 12-28 parts of silane coupling agent, 18-35 parts of ethyl acetate, 8-19 parts of sodium carbonate, 5-22 parts of calcium carbonate, 15-28 parts of aluminum oxide, 2-11 parts of kaolin and 1-5 parts of montmorillonite; the decorative board is prepared by the following method: (1) dispersing graphene in a sulfuric acid solution, adding glass fiber, and magnetically stirring for 1-4 hours at the stirring temperature of 30-45 ℃ to obtain a modified solution; (2) dispersing a silane coupling agent in ethyl acetate, adding the product prepared in the step (1), stirring while adding until the product is uniformly dispersed, placing the product in an environment with the temperature of 55-65 ℃ for dehydration and drying, and passing through a 0.1mm square-hole sieve to prepare modified glass fiber powder; (3) mixing sodium carbonate, calcium carbonate, aluminum oxide, kaolin, montmorillonite and the modified glass fiber powder obtained in the step (2), and adding deionized water according to the mass ratio of 1: 1-1.2 to adjust the mixture into a paste body, so as to obtain glass fiber gel; (4) cutting kraft paper into test pieces of 10cm multiplied by 10cm, drying at 55-65 ℃ until the water content is 1% -5%, immersing the kraft paper into phenolic resin, discharging bubbles on the paper surface, soaking for 1-5 hours, taking out and drying; (5) coating the surface of the kraft paper base paper treated in the step (4) with the glass fiber gel prepared in the step (3), airing at room temperature, and then drying in an environment at 55-65 ℃; (6) and (3) immersing the kraft paper base paper treated in the step (5) in phenolic resin, discharging paper surface bubbles, soaking for 2-10 hours, and then drying, assembling and hot-pressing to obtain the decorative plate.
2. The glass fiber synthetic resin modified decorative sheet according to claim 1, wherein the decorative sheet comprises, in parts by weight: 48 parts of kraft base paper, 34 parts of phenolic resin, 29 parts of glass fiber, 22 parts of graphene, 23 parts of silane coupling agent, 32 parts of ethyl acetate, 15 parts of sodium carbonate, 17 parts of calcium carbonate, 23 parts of aluminum oxide, 8 parts of kaolin and 4 parts of montmorillonite.
3. The glass fiber synthetic resin modified decorative sheet according to claim 1, wherein the graphene is dispersed in a sulfuric acid solution in the step (1), and then the glass fiber is added, and the mixture is magnetically stirred for 2.5 hours at 40 ℃ to obtain the modified solution.
4. The decorative plate modified by synthetic resin of glass fiber as claimed in claim 1, wherein the silane coupling agent is dispersed in ethyl acetate in step (2), the product obtained in step (1) is added and stirred until the dispersion is uniform, the mixture is dehydrated and dried in an environment of 60 ℃, and the dried mixture passes through a 0.1mm square-hole sieve to obtain the modified glass fiber powder.
5. The glass fiber synthetic resin modified decorative sheet according to claim 1, wherein in the step (3), sodium carbonate, calcium carbonate, aluminum oxide, kaolin, montmorillonite and the modified glass fiber powder obtained in the step (2) are mixed, and deionized water is added according to a mass ratio of 1:1 to adjust the mixture into a paste, so that glass fiber gel is obtained.
6. The decorative sheet modified by synthetic resin of glass fiber according to claim 1, wherein in step (4), kraft paper is cut into 10cm × 10cm pieces, dried at 62 ℃ until the water content is 4%, immersed in phenolic resin, and then the paper is soaked for 4 hours, and then dried.
7. The glass fiber synthetic resin modified decorative sheet according to claim 1, wherein in the step (5), the surface of the kraft paper base paper treated in the step (4) is coated with the glass fiber gel prepared in the step (3), and the glass fiber gel is dried at room temperature and then dried in an environment of 62 ℃.
8. The glass fiber synthetic resin modified decorative sheet according to claim 1, wherein in the step (6), the kraft paper base paper treated in the step (5) is immersed in phenolic resin, bubbles on the paper surface are discharged, the paper surface is immersed for 7 hours, and then the decorative sheet is prepared by drying, assembling and hot pressing.
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| CN201710768860.3A CN107460779B (en) | 2017-08-31 | 2017-08-31 | Glass fiber synthetic resin modified decorative plate and preparation method thereof |
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| CN201710768860.3A CN107460779B (en) | 2017-08-31 | 2017-08-31 | Glass fiber synthetic resin modified decorative plate and preparation method thereof |
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| CN107460779B true CN107460779B (en) | 2020-04-21 |
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| CN112094092A (en) * | 2019-06-17 | 2020-12-18 | 南京倍立达欧陆装饰艺术工程有限公司 | Chopped strand mat reinforcing plate and preparation method thereof |
| CN113619245B (en) * | 2021-07-21 | 2023-06-09 | 今创集团股份有限公司 | High-strength composite decoration panel |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1251334A (en) * | 1998-10-16 | 2000-04-26 | 普雷马克Rwp控股公司 | Clouring lining film and mfg. method thereof |
| CN1809454A (en) * | 2003-05-23 | 2006-07-26 | 特里斯帕国际公司 | Decorative panel for outdoor use and method for manufacturing the same |
| CN103570255A (en) * | 2012-08-07 | 2014-02-12 | 重庆国际复合材料有限公司 | Glass fiber infiltrating agent composition as well as preparation method and application thereof |
| CN104262953A (en) * | 2014-08-21 | 2015-01-07 | 巨石集团有限公司 | Graphene-coated glass fiber reinforced resin-based composite material and preparation method thereof |
| CN106397690A (en) * | 2015-08-01 | 2017-02-15 | 魏忠 | Gel substrate material |
-
2017
- 2017-08-31 CN CN201710768860.3A patent/CN107460779B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1251334A (en) * | 1998-10-16 | 2000-04-26 | 普雷马克Rwp控股公司 | Clouring lining film and mfg. method thereof |
| CN1809454A (en) * | 2003-05-23 | 2006-07-26 | 特里斯帕国际公司 | Decorative panel for outdoor use and method for manufacturing the same |
| CN103570255A (en) * | 2012-08-07 | 2014-02-12 | 重庆国际复合材料有限公司 | Glass fiber infiltrating agent composition as well as preparation method and application thereof |
| CN104262953A (en) * | 2014-08-21 | 2015-01-07 | 巨石集团有限公司 | Graphene-coated glass fiber reinforced resin-based composite material and preparation method thereof |
| CN106397690A (en) * | 2015-08-01 | 2017-02-15 | 魏忠 | Gel substrate material |
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