CN107459265A - A kind of reflective surface treatment method and application with glass microballoon - Google Patents
A kind of reflective surface treatment method and application with glass microballoon Download PDFInfo
- Publication number
- CN107459265A CN107459265A CN201710554226.XA CN201710554226A CN107459265A CN 107459265 A CN107459265 A CN 107459265A CN 201710554226 A CN201710554226 A CN 201710554226A CN 107459265 A CN107459265 A CN 107459265A
- Authority
- CN
- China
- Prior art keywords
- glass microballoon
- reflective
- treatment method
- surface treatment
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
Abstract
The present invention relates to technical field of surface, to solve the problems, such as the rolling during pearl is planted due to pearl and the easy generation electrostatic of high polymer original film friction, the present invention proposes a kind of reflective surface treatment method with glass microballoon, using cationic surface active agent as antistatic additive, add the free-flowing that nano silica fume improves powder, it is surface-treated mixed surfactant and nano silica fume by dispersion solvent simultaneously after, glass microballoon after processing has good antistatic behaviour and mobility, suitable for silver lustre reflective fabric and reflective membrane.
Description
Technical field
The present invention relates to technical field of surface, and in particular to a kind of reflective surface treatment method with glass microballoon with
Using.
Background technology
Reflective fabric is exactly that the glass microballoon of high index of refraction is made in into cloth primary surface with the technique of coating or overlay film so that common
Cloth can reflection light under the irradiation of light.Reflective fabric can be divided into according to the difference of glistening intensity：General bright reflective fabric, highlight
Reflective fabric, silver lustre reflective fabric, metal light reflective fabric etc..
At present, the glass microballoon of reflective fabric is all first handled surface through coupling agent, to reach certain mobility
And washing fastness, but for silver lustre reflective fabric, the rolling and the friction of high polymer original film during pearl is planted due to pearl are easy
Generation electrostatic, and the surface treatment of traditional glass microballoon, do not reach good antistatic and free mobility, easily exist
Occur the quality problems for being unfavorable for product with pearl, folded pearl, floating pearl etc. during plant pearl.
The content of the invention
To solve the problems, such as the rolling during pearl is planted due to pearl and the easy generation electrostatic of high polymer original film friction, this
Invention proposes a kind of reflective surface treatment method and application with glass microballoon, and the glass microballoon after processing has good resist
Static behaviour and mobility, suitable for silver lustre reflective fabric and reflective membrane.
The present invention is achieved by the following technical solutions：A kind of reflective surface treatment method with glass microballoon is following
Step：First glass microballoon is put into agitator, cationic surface active agent, nano silica fume, dispersion solvent is then added and exists
Mixed treatment fluid at 25-100 DEG C, speed of agitator 600-1000rps, mixing time 0.5-5min, carry out fully mixed
Close and reach uniformly, then bakee, temperature is 50-200 DEG C, time 10-90min, is a kind of reflective micro- with glass after cooling
Pearl.
Preferably, treatment fluid in mixed process by water-bath realize temperature at 25-100 DEG C to ensure to be uniformly dispersed,
Mixed in homogenizer, baked and banked up with earth by baking oven.
Described cationic surface active agent is selected from alkyl quaternary ammonium salts, preferably, selected from dodecyl quaternary ammonium salt, ten
It is one or more of in eight alkyl quaternary ammonium salts.Its molecule of alkyl quaternary ammonium salts is dissolved in after water ionizes, and structural formula is such as shown in (I), just
Ionic adsorption is in glass microballoon surface, one adsorbed film oriented of formation on glass microballoon surface, in plant production process Central Plains
The high polymers such as film easily produce negative electrical charge by friction, and the adsorbed film on the glass microballoon surface has been neutralized because of negative electricity caused by friction
Lotus, so as to reach antistatic property.
Described dispersion solvent is the mixed liquor of deionized water and isopropanol.
Nano silica fume is selected from aerosil, and nano silica fume has purity high, and particle diameter is small, the features such as being evenly distributed.Than
Surface area is big, and high surface, apparent density is low, and nano silica fume prevents from, because luming in surface treatment process, increasing after adding
Add the mobility of powder.
Above-mentioned treatment fluid cationic surfactant, nano silica fume, the parts by weight of solvent are respectively cationic table
Face activating agent 1-100 parts, nano silica fume 1-100 parts, deionized water 1-200 parts, isopropanol 0-100 parts.
Preferably, the mass ratio of glass microballoon and treatment fluid is 50-500: 1.
Present specification adds cationic surface active agent and improves oneself of powder as antistatic additive, addition nano silica fume
By flowing, while it is surface-treated after being mixed surfactant and nano silica fume by solvent, the glass after processing is micro-
Pearl is applied on silver lustre reflective fabric and reflective membrane.
Compared with prior art, the beneficial effects of the invention are as follows：Reflective after processing has good anti-with glass microballoon
Static behaviour and mobility.
Embodiment
The present invention is described in further detail below by embodiment, raw materials used commercially available in embodiment or use
Conventional method is prepared, and weight is represented with parts by weight in embodiment.
Wherein, a kind of nano silica fume specific surface area purchased in market is 200m2/ g, primary particle diameter 12nm hydrophily gas phase titanium dioxide
Silicon.
Embodiment 1
By 100 parts of OTAC, 100 parts of aerosil, 200 parts of deionized water, isopropanol 100
Stirred after part mixing with electric blender and treatment fluid is made, the temperature for the treatment of fluid is 100 DEG C under water bath processing, by treatment fluid
Pour into homogenizer in 50000 parts of glass microballoons, be uniformly mixed, speed of agitator 1000rps, mixing time is
5min, be sufficiently mixed arrival uniformly, then bakee in an oven, temperature is 200 DEG C, time 90min, is after cooling
A kind of reflective glass microballoon 1.
Embodiment 2
By 100 parts of DTAC, 50 parts of aerosil, 100 parts of deionized water, 50 parts of isopropanol
Stirred after mixing with electric blender and treatment fluid is made, the temperature for the treatment of fluid is 60 DEG C under water bath processing, and treatment fluid is fallen
Enter in homogenizer in 30000 parts of glass microballoons, be uniformly mixed, speed of agitator 800rps, mixing time 3min,
Be sufficiently mixed arrival uniformly, then bakee in an oven, temperature is 150 DEG C, time 50min, is one kind after cooling
Reflective glass microballoon 2.
Embodiment 3
By N, N, 100 parts of N- trimethyl -1- Tetra-n-decylammonium bromides, 1 part of aerosil, 1 part of deionized water, mixing
Stirred afterwards with electric blender and treatment fluid is made, the temperature for the treatment of fluid is 25 DEG C under water bath processing, and treatment fluid is poured into height
In fast mixer in 10000 parts of glass microballoons, it is uniformly mixed, speed of agitator 600rps, mixing time 1min, carries out
It is uniform to be sufficiently mixed arrival, then bakees in an oven, temperature is 50 DEG C, time 10min, is a kind of reflective use after cooling
Glass microballoon 3.
After tested, the glass microballoon that embodiment 1~3 obtains and the glass purchased in market being surface-treated using conventional method
Microballon performance comparision is as shown in table 1, and sheet resistance value is measured by surface resistivity tester, from BENETECH instruments,
Model GM3110.
Table 1：
Claims (7)
1. a kind of reflective surface treatment method with glass microballoon, it is characterised in that shown processing method is following steps：First
Glass microballoon is put into agitator, then adds cationic surface active agent, nano silica fume, dispersion solvent at 25-100 DEG C
Under mixed treatment fluid, speed of agitator 600-1000rps, mixing time 0.5-5min, then bakee, temperature 50-
200 DEG C, time 10-90min, which are that one kind is reflective after cooling, uses glass microballoon.
A kind of 2. reflective surface treatment method with glass microballoon according to claim 1, it is characterised in that described sun
Ionic surfactant is selected from alkyl quaternary ammonium salts.
A kind of 3. reflective surface treatment method with glass microballoon according to claim 1, it is characterised in that described point
Dissipate the mixed liquor that solvent is deionized water and isopropanol.
A kind of 4. reflective surface treatment method with glass microballoon according to claim 1, it is characterised in that nano silica fume
Selected from aerosil.
5. the reflective surface treatment method with glass microballoon according to any one of claim 1-4, it is characterised in that sun
Ionic surfactant, nano silica fume, the parts by weight of dispersion solvent are respectively cationic surface active agent 1-100 parts, are received
Rice silica flour 1-100 parts, deionized water 1-200 parts, isopropanol 0-100 parts.
A kind of 6. reflective surface treatment method with glass microballoon according to claim 1, it is characterised in that glass microballoon
Mass ratio with treatment fluid is 50-500：1.
7. a kind of reflective glass microballoon obtained with the surface treatment method of glass microballoon using described in claim 1 is in silver lustre
Application on reflective fabric, reflective membrane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710554226.XA CN107459265B (en) | 2017-07-07 | 2017-07-07 | Surface treatment method and application of glass beads for light reflection |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710554226.XA CN107459265B (en) | 2017-07-07 | 2017-07-07 | Surface treatment method and application of glass beads for light reflection |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107459265A true CN107459265A (en) | 2017-12-12 |
| CN107459265B CN107459265B (en) | 2020-11-03 |
Family
ID=60546711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710554226.XA Active CN107459265B (en) | 2017-07-07 | 2017-07-07 | Surface treatment method and application of glass beads for light reflection |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107459265B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115260930A (en) * | 2022-07-21 | 2022-11-01 | 泉州森润煜辉反光材料有限公司 | Production process of super-soft reflective fabric |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962268A (en) * | 2010-08-13 | 2011-02-02 | 上海安杰反光材料有限公司 | Antistatic finish technique for high-refractivity glass microballoons |
| CN103380094A (en) * | 2010-12-29 | 2013-10-30 | 巴斯夫欧洲公司 | Colored composite pavement structure |
| CN103589254A (en) * | 2012-08-15 | 2014-02-19 | 贵州柯维建材开发有限公司 | Environment-friendly reflective insulation heat-preserving coating |
-
2017
- 2017-07-07 CN CN201710554226.XA patent/CN107459265B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962268A (en) * | 2010-08-13 | 2011-02-02 | 上海安杰反光材料有限公司 | Antistatic finish technique for high-refractivity glass microballoons |
| CN103380094A (en) * | 2010-12-29 | 2013-10-30 | 巴斯夫欧洲公司 | Colored composite pavement structure |
| CN103589254A (en) * | 2012-08-15 | 2014-02-19 | 贵州柯维建材开发有限公司 | Environment-friendly reflective insulation heat-preserving coating |
Non-Patent Citations (2)
| Title |
|---|
| GEORGE WYPYCH 编著: "《填料手册（第二版）》", 31 October 2002, 中国石化出版社 * |
| 崔淑玲: "《高技术纤维》", 30 September 2016, 中国纺织出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115260930A (en) * | 2022-07-21 | 2022-11-01 | 泉州森润煜辉反光材料有限公司 | Production process of super-soft reflective fabric |
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| Publication number | Publication date |
|---|---|
| CN107459265B (en) | 2020-11-03 |
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| CB03 | Change of inventor or designer information |
Inventor after: Wang Shijie Inventor after: Zha Weiqiang Inventor before: Qiu Shanghuang Inventor before: Zhan Pintao Inventor before: Zha Weiqiang Inventor before: Wang Shijie |
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