One kind sending drill tools drilling fluid
This case is divisional application
The title of female case are as follows: one kind send drill tools
Female case application No. is: 2016103882953
The applying date of female case are as follows: on May 31st, 2016
Technical field
The present invention relates to a kind of tool, especially one kind to send drill tools drilling fluid.
Background technique
Since 1985, the investment with first depth of water in 300m or more deepwater petroleum exploration exploration project is built,
International deepwater petroleum exploration exploitation gradually increases.The average annual growth rate of initial 10a is 65%, northwest Europe, Brazil, Mexico
The exploration and development in gulf is fastest, and the yield of Gulf of Mexico profundal zone has been more than phytal zone from 2001.According to statistics, by 2000
Year, the deep water hydrocarbon field of depth of water 500m has 162, each sea area all over the world, wherein especially with the Gulf of Mexico sea area in America, Latin
The Brazil's sea area and West Africa sea area in America are most, and it is 22.6 × 10 that oil and gas reserves is verified in deep water hydrocarbon field8T oil equivalent, accounts for sea
Oil gas field verifies the 12% of gross reserves.
Compared with shallow water area, the main problem that deepwater drilling faces has: the stability of seabed shale is poor, drilling fluid dosage
Greatly, wellbore cleaning is difficult, the gas hydrate of shallow layer gas and formation, the rheological characteristic of drilling fluid, formation fracture pressure under low temperature
Window narrows etc..These problems bring many difficulties to drilling well work.During deepwater drilling, the generation of gas hydrate
The safety for having seriously affected deep water hydrocarbon probing with blocking carries out.At present mainly by the way that salt and alcohols etc. are added in drilling fluid
Thermodynamic inhibitor prevents and treats hydrate problems, and the inhibitor of high concentration increases drilling cost, and is unfavorable for property of drilling fluid
Maintenance.
Summary of the invention
Goal of the invention of the invention is: in view of the above problems, one kind is provided during deepwater drilling, to sea
Bottom shale causes impact smaller, reduces the avalanche of seabed shale, cooperates during sending and boring and sends out drilling fluid, reduces gas hydrate
Object generates, and improves to drilling fluid, improves property of drilling fluid, and effectively inhibit hydrate generation send drill tools.
The technical solution adopted by the invention is as follows:
One kind of the present invention send drill tools, the drilling well sap cavity being connected including sleeve inner is arranged in upper shell, the drilling well
Sap cavity is connected with piston chamber, and the piston chamber is connected with drive chamber, and drive rod, the drive rod and rotation are equipped in the middle part of the drive chamber
Turn part to be connected, the revolving part is connected with lower contact.
By adopting the above-described technical solution, increase drilling well sap cavity inside drill tools sending, and it is intracavitary that drilling fluid is housed, it is boring
During well, i.e., drilling fluid is cooperated and sent out, to preferably inhibit the generation of hydrate.It is done work by piston chamber, so that
Drilling fluid can preferably reach bit head, increase drilling well drop and spray rate.Cooperate drill bit to seabed shale by revolving part
Drilling well work is carried out, vertical strike can be reduced to the impact force of seabed shale, cooperate vertical strike to reduce by rotary drilling
Seabed shale avalanche, further ensures the safety of deepwater drilling.
One kind of the invention send drill tools, and drilling fluid bottom of chamber portion is equipped with nozzle, and the nozzle is connected to piston chamber.
By adopting the above-described technical solution, by nozzle by drilling fluid injection into pistion room, enable drilling fluid with more
Good cooperates with piston head, guarantees that drilling fluid enters in piston chamber and is admitted in revolving part, reduces the loss of drilling fluid.
One kind of the invention send drill tools, and piston head is equipped in the piston chamber, is equipped with liquid flow hole in the middle part of the piston head;
The two sides of the piston chamber are equipped with several stripper loops, are equipped with deflector hole inside the stripper loop, the deflector hole is pierced by sleeve
Side wall is in communication with the outside;The stripper loop can limit piston head to bottom offset.
By adopting the above-described technical solution, piston head moves up and down acting, pressure is generated, and drilling fluid is sent into and is bored
Head, stripper loop can limit piston head to bottom offset, the pressure for avoiding piston head acting from generating is excessive, and makes with seabed shale
At biggish impact, meanwhile, stripper loop, deflector hole and piston head cooperate so that one pressure oscillation chamber of formation piston chamber in, from
And the pressure that piston is generated is just right, and only working drilling well generates gain effect, without bringing biggish impact force,
It, will not avalanche to guarantee to guarantee the stabilization of seabed shale structure while preferably carrying out drilling well work.
One kind of the invention send drill tools, and through-hole is provided in the middle part of the drive rod, and the piston chamber bottom is equipped with pressure transmission hole,
The through-hole is connected to pressure transmission hole, and the pressure transmission hole is connected to liquid flow hole.
One kind of the invention send drill tools, and the revolving part outer surface is evenly equipped with several helical blades, in the revolving part
Portion is provided with blind hole, and the blind hole is connected to through-hole, and the helical blade surface is equipped with several fluid holes, the fluid hole and blind hole
Connection.
By adopting the above-described technical solution, revolving part in the course of rotation takes drilling fluid out of.
One kind of the invention send drill tools, and the drilling fluid is intracavitary to be equipped with drilling fluid, and the drilling fluid includes mass parts 12
~25 parts of terpenyl polyester, the fragrant alkene polymer of 18~26 parts of matrix types two, 8~15 parts of nanometer Na2SiO3, 3~8 parts of polyoxygenateds third
Enediol, 5~13 parts of double decyl trimethyl ammonium chlorides, 30~45 parts of polyethylene glycol, 30~45 parts of ethyl alcohol and 40~80 parts it is swollen
Moisten local soil type at the structural formula of the fragrant alkene polymer of the matrix type two is
By adopting the above-described technical solution, drilling fluid has good filtration reduction and rheology in deep-water low-temperature environment
Property, there is apparent inhibiting effect to the generation of hydrate.
Wherein, terpenyl polyester can be the arbitrary value in 12~25 parts, such as 13,15,17,19,20,23,24 etc., bone
The fragrant alkene polymer of frame type two can be the arbitrary value in 18~26 parts, such as 20,21,24,25 etc., nanometer Na2SiO3It can be 8
Arbitrary value in~15 parts, such as 9,10,13,14 etc., polyoxypropyleneglycol can be the arbitrary value in 3~8 parts, such as 4,
5,6,7 etc., double decyl trimethyl ammonium chlorides can be the arbitrary value in 5~13 parts, such as 6,7,8,9,10 etc., polyethylene glycol
It can be the arbitrary value in 30~45 parts, such as 32,35,36,38,40,42 etc., ethyl alcohol can be any in 30~45 parts
Value, such as 32,34,36,38,39,40,43 etc., bentonite can be the arbitrary value in 40~80 parts, such as 42,43,47,49,
50,56,59,60,67,69,73,76,78 etc..
Preferably, when drilling fluid includes 18 parts of terpenyl polyester of mass parts, the fragrant alkene polymer of 23 parts of matrix types two, 15 parts are received
Rice Na2SiO3, 8 parts of polyoxypropyleneglycols, 8 parts of double decyl trimethyl ammonium chlorides, 42 parts of polyethylene glycol, 35 parts of ethyl alcohol and 76
It is optimum value, the density (gL at 15 DEG C, 0 DEG C, -4 DEG C, -8 DEG C when part bentonite composition-1) it is 1.03,1.05,1.06,
1.06, gel strength (Pa) is 2.3/2.6,2.5/3.2,2.5/3.2,2.5/3.2, and plastic viscosity (mPas) is 18,21,23,
25, yield value (Pa) is that 9.4,10.2,10.5,10.9, API leak-offs (mL) are 5.3,5.3,5.5,5.5,2.47h (3.4 DEG C,
Just start largely to generate hydrate when 10.93mPa), in system, can Drilling Fluid Viscosity it is larger, delayed gas molecule to enter water
Close object cagelike structure cavity.
One kind of the invention send drill tools, and the degree of polymerization of the fragrant alkene polymer of the matrix type two is greater than 6.
One kind of the invention send drill tools, the nanometer Na2SiO3Partial size be 20nm~80nm, it is described bentonitic thin
Degree is 200 mesh.
One kind of the invention send drill tools, and the intracavitary portion of drilling fluid is equipped with temperature regulating device, and the temperature regulating device keeps boring
Well liquid chamber internal temperature is constant at 12~20 DEG C.
One kind of the invention send drill tools, and the maximum pressure that the piston head acting generates is 4 atmospheric pressure, the rotation
Part slewing rate is 370r/min.
By adopting the above-described technical solution, above-mentioned is optimum range value, can guarantee during drilling well works most
Good performance.
In conclusion by adopting the above-described technical solution, the beneficial effects of the present invention are:
1, it during deepwater drilling, causes impact smaller in seabed shale, reduces the avalanche of seabed shale, sending drill-through journey
In i.e. cooperation send out drilling fluid, reduce gas hydrate generate.
2, drilling fluid is improved, has good filtration reduction and rheological characteristic in deep-water low-temperature environment, to hydration
The safety that the generation of object has apparent inhibiting effect to improve deepwater drilling operation.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram for sending drill tools.
Marked in the figure: 1 is upper shell, 2 be drilling well sap cavity, and 3 be piston chamber, and 4 be stripper loop, and 5 be deflector hole, and 7 be pressure transmission
Hole, 8 be drive rod, and 11 be lower contact, and 12 be revolving part.
Specific embodiment
With reference to the accompanying drawing, the present invention is described in detail.
In order to which the objects, technical solutions and advantages of invention are more clearly understood, with reference to the accompanying drawings and embodiments, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Embodiment 1
As shown in Figure 1, one kind send drill tools, the drilling well sap cavity 2 being connected including sleeve inner is arranged in upper shell 1 is bored
Well liquid chamber 2 is connected with piston chamber 3, and piston chamber 3 is connected with drive chamber, and drive rod 8, drive rod 8 and revolving part are equipped in the middle part of drive chamber
12 are connected, and the revolving part 12 is connected with lower contact 11.2 bottom of drilling well sap cavity is equipped with nozzle 14, and nozzle 14 is connected to piston chamber.
It is equipped with piston head in piston chamber 3, is equipped with liquid flow hole in the middle part of piston head;The two sides of piston chamber are equipped with several stripper loops 4, stripper loop
4 inside are equipped with deflector hole 5, and deflector hole 5 is pierced by sleeve lateral wall and is in communication with the outside;Stripper loop 4 can limit piston head to bottom offset,
Stripper loop 4, deflector hole 5 and piston head mating reaction form a pressure oscillation chamber in piston chamber 3.It is provided in the middle part of drive rod 8
Through-hole, 3 bottom of piston chamber are equipped with pressure transmission hole 7, and through-hole is connected to pressure transmission hole 7, and pressure transmission hole 7 is connected to liquid flow hole.Outside revolving part 12
Surface is evenly equipped with several helical blades, and blind hole is provided in the middle part of revolving part 12, and blind hole is connected to through-hole, if helical blade surface is equipped with
Fluid apertures is done, fluid hole is connected to blind hole.Temperature regulating device is equipped with inside drilling well sap cavity 2, temperature regulating device is kept inside drilling well sap cavity 2
Temperature is constant at 12~20 DEG C.The maximum pressure that piston head acting generates is 4 atmospheric pressure, and 12 slewing rate of revolving part is
370r/min。
Embodiment 2
Drilling well sap cavity 2 is provided with drilling fluid, and drilling fluid includes 12~25 parts of terpenyl polyester of mass parts, 18~26 parts of skeletons
The fragrant alkene polymer of type two, 8~15 parts of nanometer Na2SiO3, 3~8 parts of polyoxypropyleneglycols, 5~13 parts of double ten alkyl trimethyl chlorine
Change ammonium, 30~45 parts of polyethylene glycol, 30~45 parts of ethyl alcohol and 40~80 parts of bentonite compositions, the knot of the fragrant alkene polymer of matrix type two
Structure formula isThe degree of polymerization of the fragrant alkene polymer of matrix type two is greater than 6.
Nanometer Na2SiO3Partial size be 20nm~80nm, bentonitic fineness be 200 mesh.The present invention provides in 8 preferably
Combination matching, and test its density p (gL at 15 DEG C, 0 DEG C, -4 DEG C, -8 DEG C-1), gel strength k (Pa), plastic viscosity n
(mPas), yield value q (Pa) and API leak-off m (mL), and test hydrate and situation detailed data is inhibited to be shown in Table 1 to table 3.
1 preferred component of table (mass parts)
2 filtration reduction of table and rheological characteristic test
3 hydrate of table inhibits situation (system largely generates the time of hydrate, temperature, pressure)
Embodiment 3
The fragrant alkene polymer of matrix type twoSynthesis formula it is as follows,
Intermediate Cl-DTE synthesis: under the protection of argon gas, 16g (94mmol) glutaryl chlorine is dissolved in 200mLCH2Cl2
In, it is added anhydrous aluminum chloride 30g (225.6mmol), two of the 5- chloro-2-methyl thiophene containing 25g (188mmol) is slowly added dropwise
Chloroethanes solution 100mL, the reaction was continued 8h.50mL is added and terminates reaction, is recrystallized with 95% ethanol water.
Under the protection of argon gas, in the tetrahydrofuran 200mL that takes zinc powder 34.56g to be put into after overweight steaming, injection
TiCl417.16mL is heated to reflux 1h after mixing evenly.The THF solution 200mL containing cloth product on 11g is existed in the case of being protected from light
It is added drop-wise in flask in for 24 hours, the reaction was continued 12h, addition unsaturated carbonate aqueous solutions of potassium 50mL termination reaction.Reaction solution acetic acid second
Ester extraction, organic phase are dried overnight with sewage magnesium sulfate, and crude product is recrystallized with 95% ethanol water.
1H NMR (400MHz, CDCl3) δ=1.88 (s, 6H), 1.92~2.10 (m, 2H), 2.69 (t, J=7.5Hz,
4H), 6.58 (s, 2H);13C NMR (400MHz, CDCl3) δ=15.1,23.8,39.1,126.0,127.2,134.0,135.3,
135.7;MS:m/z=328 [M+];IR:2953cm-1,2916cm-1,2841cm-1,1640cm-1,1551cm-1,1455cm-1,
1437cm-1,1311cm-1,1197cm-1,1159cm-1,1140cm-1,991cm-1,830cm-1,822cm-1,746cm-1,666cm-1,481cm-1;C15H14Cl2S2: calcd.C 54.71, H 4.29;Found C 54.63, H 4.30.
The synthesis of intermediate FPOx: being solvent and catalyst with polyphosphoric acids, by the pentafluoro benzoic acid and sulphur of molar ratio 3:2
Sour hydrazine obtains brown-red solution in 200 DEG C of reaction 5h.It is cooled to room temperature, reaction solution is then poured into a large amount of deionized waters, is obtained
White precipitate.This white precipitate is recrystallized with isopropanol and toluene (volume ratio 1:3) mixed solution, obtains white needles crystalline substance
Body, yield 88%.
19F NMR: δ=- 135 (m, 4F, ortho to Ox);-146(m,2F,para to Ox);-159(m,4F,
meta to Ox).MS:m/z=402 [M+].IR:1653cm-1,1556cm-1,1526cm-1,1496cm-1,1422cm-1,
1366cm-1,1321cm-1,121cm-1,1092cm-1,1042cm-1,993cm-1,978cm-1,844cm-1,812cm-1,751cm-1。
Elemental analysis C:41.75;N:6.95;O:4.00 (theoretical value C:41.81;F:47.24;N:6.97;O:3.98).
The synthesis of target product: 0.2g (0.6mmol) Cl-DTE is dissolved in 20mLTHF, under nitrogen protection, stirs evenly,
It is slowly dropped into butyl lithium 0.5mL (2.4molL-1Hexane solution).The reaction was continued after being added dropwise to complete 3h, is added 5mL and contains
The tetrahydrofuran solution of 0.245gFPOx.The reaction was continued 5h, reaction solution is poured into 200mL deionized water, yellow mercury oxide is obtained,
It filters, for solid with methanol rinses three times, vacuum drying obtains target product 0.27g, yield 71%.
19F NMR: δ=- 130~-132, -135~-137;-148.49(s);- 152~-154;-155.67(s);-
156.44(s).GPC:Mn=184000, PDI=1.57, DP=6.
Embodiment 4
The synthesis of terpenyl polyester: by the phthalic anhydride of molar ratio 1:1:2.4:0.4, TMA, diethylene glycol (DEG) and trimethylolpropane,
Phosphoric acid (the 0.1% of gross mass), dibutyl hydroxy toluene (0.1%) and dimethylbenzene (3%) are added to logical nitrogen and with temperature controls, gather
In the four-hole bottle of tetrafluoroethene agitating paddle and water segregator, the polyester of hydroxyl value about 170mg/g is prepared, it is dilute with ethyl acetate after cooling
Releasing mass fraction of solids is 70%, obtains target product.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.