CN107446686A - A kind of lubricant - Google Patents

A kind of lubricant Download PDF

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Publication number
CN107446686A
CN107446686A CN201710630533.1A CN201710630533A CN107446686A CN 107446686 A CN107446686 A CN 107446686A CN 201710630533 A CN201710630533 A CN 201710630533A CN 107446686 A CN107446686 A CN 107446686A
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CN
China
Prior art keywords
lubricant
parts
silicone oil
isopropanol
water
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CN201710630533.1A
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Chinese (zh)
Inventor
周文信
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Beijing Olympic Sports Culture Jinmiao Co Ltd
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Beijing Olympic Sports Culture Jinmiao Co Ltd
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Priority to CN201710630533.1A priority Critical patent/CN107446686A/en
Publication of CN107446686A publication Critical patent/CN107446686A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants

Abstract

The present invention relates to a kind of lubricant, the lubricant contains the raw material of following parts by weight:28 parts of silicone oil;0.5 5 parts of lauryl alcohol APEO;18 parts of isopropanol;15 parts of ethylene glycol;85 94 parts of water.The lubricant properties of the present invention are stable, and lubricating capacity, wetability are good, and frost resistance is good, are especially suitable for low-temperature lubrication field, lubricant of the present invention also have it is nonpoisonous and tasteless, anti-oxidant, can natural degradation, the beneficial effect that preparing raw material is renewable, cheap.

Description

A kind of lubricant
Technical field
The present invention relates to chemical technical field, and in particular to a kind of lubricant.
Background technology
Lubricant is lubricating area through commonly used chemical products, and the lubricant of application in public places leads in the prior art It is commonly present following technical problem:1st, the lubricant in the prior art in application in public places is formulated complexity mostly, and raw material are not Easily obtain, selection is not plant renewable raw materials, there is potential injury to people and thing, meanwhile, also result in production cost compared with The problem of high;2nd, the lubricating capacity of product is not strong enough, and wetability is poor;3rd, the primary raw material of existing lubricant is not renewable money Source, enough complete biodegradables are tended not to, some lubricants are also containing the poisonous and harmful substances such as dioxin, VOC, inadequate safety collar Protect;Harm is produced to citizen's health either to pollute air;4th, existing lubricant corrodes bar in high temperature or soda acid etc. Oxidation resistance under part is poor, easily aoxidizes and reduces performance;5th, existing lubricant when in use, without rust-proofing effect.
Chinese patent Authorization Notice No. CN103060063A discloses a kind of lubricant, and the lubricant is in high temperature and room temperature Under lubricant effect it is preferable, but lubricant effect at low temperature is poor, is not suitable for the low-temperature lubrication such as rink field.
Therefore a kind of lubricant is researched and developed, to overcome above-mentioned at least one technological deficiency to turn into a kind of required.
The content of the invention
It is an object of the invention to provide a kind of lubricant, the lubricant has following technological merit.
The purpose of the present invention is to be achieved through the following technical solutions:
A kind of lubricant, the lubricant contain the raw material of following parts by weight:Silicone oil 2-8 parts;Lauryl alcohol polyoxy second Alkene ether 0.5-5 parts;Isopropanol 1-8 parts;Ethylene glycol 1-5 parts;Water 85-94 parts.
Further, the lubricant also includes the antioxidant of 2-6 parts.
Further, the antioxidant is phytic acid.
Further, the lubricant contains the raw material of following parts by weight:Silicone oil 3-6 parts;Lauryl alcohol polyoxyethylene Ether 1-3 parts;Isopropanol 3-6 parts;Ethylene glycol 2-4 parts;Phytic acid 3-5 parts;Water 88-92 parts.
Further, the lubricant contains the raw material of following parts by weight:5 parts of silicone oil;Lauryl alcohol APEO 2 Part;4 parts of isopropanol;3 parts of ethylene glycol;4 parts of phytic acid;90 parts of water.
A kind of lubricant compositions for being used to clean artificial ice face, the lubricant compositions contain in claim 1-4 Lubricant described in any one.
Silicone oil:Silicone oil is commonly referred to as keeping the linear polysiloxanes product of liquid condition at room temperature.It is generally divided into first Base silicone oil and the class of modified silicon oil two.The most frequently used silicone oil monomethyl silicone oil, also referred to as common silicone oil, all first of its organic group Base, methyl-silicone oil have good chemical stability, insulating properties and hydrophobic performance.It is to add water to hydrolyze by dimethyldichlorosilane First minification polycyclic body is made, low ring body is made through cracking, rectifying in ring body, and then ring body, closure agent, catalyst are put together telomerization The mixture of various different polymerization degrees is just can obtain, silicone oil can be made through being evaporated under reduced pressure removing low-boiling-point substance.Silicone oil is usually nothing Color (or faint yellow), tasteless, nontoxic, not volatile liquid.Silicone oil is not soluble in water, methanol, glycol and ethoxy ethanol, can be with Benzene, dimethyl ether, methyl ethyl ketone, carbon tetrachloride or kerosene dissolve each other, and are slightly dissolved in acetone, dioxanes, ethanol and butanol.Silicone oil has Remarkable heat resistance, electrical insulating property, weatherability, hydrophobicity, physiological inertia and less surface tension, additionally glued with low Warm coefficient, higher resistance to compression, the kind that has also have radiation-resistant performance.
Silicone oil has higher heat resistance, water resistance, electrical insulating property and less surface tension.It is commonly used for advanced lubrication Oily, shockproof oil, insulating oil, defoamer, releasing agent, polish, interleaving agent and diffusion in vacuum pump oil etc.;Emulsion can be used for automobile Tire glazing, instrument board glazing etc..
Lauryl alcohol APEO:White is to slightly yellow paste.10% aqueous solution clear at 25 DEG C, is dissolved in Water, ethanol, ethylene glycol etc..This product has the functions such as excellent washing, emulsification, scattered, wetting, solubilising, and foaming power is strong, easily drift Wash, detergency is excellent;It is one of kind minimum to skin irritation in surfactant.It can be answered with various surfactants Match somebody with somebody, reduce their excitant, improve the performance of product, it is mild washing, shampoo (such as shampoo for baby), body lotion, washed one's face The optimum feed stock of milk and cosmetics;Instead of AES, the excitant of product can be reduced and do not increase cost;It is also used as breast Agent, softening agent, wetting agent, foaming agent etc..
Isopropanol:A kind of organic compound, the isomer of normal propyl alcohol, alias dimethylcarbinol, 2- propyl alcohol, in industry Also IPA is made.Colourless transparent liquid, there is the smell like ethanol and acetone mixture.Water is dissolved in, also is soluble in alcohol, ether, benzene, chloroform etc. Most organic solvents.Isopropanol is important chemical products and raw material.It is mainly used in pharmacy, cosmetics, plastics, spices, coating Deng.
Phytic acid:Phytic acid be also known as creatine, inositol six it is complete-dihydrogen orthophosphate, it is primarily present in the seed of plant, root is done In stem, wherein with the seed of legume, cereal wheat bran and plumule in content highest.The application of phytic acid is very extensive. In food industry, phytic acid can be used as food additives, can be used as removing metal agent in brewing industry.It can be used in medical industry Treat the illnesss such as diabetes, kidney stone.Application in chemical industry, oil, metallurgy, daily chemical industry all very extensively, can be used as The antioxidant of grease, the antistaling agent of food and fruit, pvc polymerizer anti-fouling agent, antidipticum pharmaceutically, feed Additive, antirust, cleaning, antistatic and metal conditioner etc. are also acted as, especially can be as the important original of production inositol One of material.
Ethylene glycol:English name is Polypropylene glycol, Chinese nickname PPG;POLYPROPYLENE GLYCOL 400, No. CAS For 25322-69-4, molecular formula C6H14O3, it is a kind of chemical intermediate for defoamer.It is colourless to arrive flaxen sticky liquid Body, non-volatile, non-corrosiveness.Lower molecular weight polymer can be dissolved in water, and higher molecular weight polymer is only very slightly soluble in water, is dissolved in oil Class, many hydrocarbon and aliphatic alcohol, ketone, ester etc..The hydroxyl at molecule both ends can be esterified generation monoesters or dibasic acid esters.Its monoesters right and wrong from The surfactant of subtype, generation ether can be also acted on alcohol.It is the solvent of vegetable oil, resin and paraffin, is also used for preparing alkyd Resin, emulsifying agent, demulsifying agent, lubricating oil and plasticizer etc..Deposited by expoxy propane with propane diols in high pressure or acidic catalyst Obtained in lower condensation, can be used as daily use chemicals, medicine, the base-material of finish.
Beneficial effects of the present invention are:The present invention is used silicone oil, lauryl alcohol APEO, isopropanol, ethylene glycol And water is prepared by mixing into lubricant, the lauryl alcohol APEO can make isopropanol, water and silicone oil as emulsifying agent The emulsion being obtained by mixing is more uniform and stable, while the lauryl alcohol APEO also has the raising emulsion profit Moist function, the lauryl alcohol APEO, silicone oil, isopropanol, ethylene glycol preparation are simple and cheap, can pass through plant Prepared by thing recyclable materials, the lubricant of preparation can be biodegradable, overcome difficult degradation and lubricating capacity when silicone oil is used alone, The problem of wetability difference, the lubricant has no toxic side effect and peculiar smell, and the lubricant product of preparation is free of dioxin and volatility Organic matter, it is green safe, air will not be polluted;The lubricant lubricating capacity is strong, and wetability is good, is widely used in lathe, artificial The lubrication in the fields such as ice face.
Using phytic acid as antioxidant, it can effectively strengthen the oxidation resistance of the lubricant, the profit of preparation Lubrication prescription is applied to oxidizable lubricating area;The complete plant extract of phytic acid, has no toxic side effect, safety and environmental protection and can green drop Solution.
The ethylene glycol provides strong support, to ensure as antifreezing agent to the use in a low temperature of the lubricant Severe cold weather uses or can still reached when being lubricated for artificial ice rink the technique effect of high-efficiency lubricating to lubricant in the winter time.
Embodiment
Heretofore described lauryl alcohol APEO is mixed in isopropanol, water and silicon as emulsifying agent by a certain percentage After in the mixed solution of oil, the emulsion of preparation is uniform and stable and the wetability of silicone oil can be substantially improved, the isopropyl Alcohol is relatively inexpensive solvent, can be dissolved each other with water arbitrary proportion, the isopropanol has good dilution and peptizaiton, energy The lubricating capacity and wetability of the silicone oil is enough substantially improved, lubricant of the invention carries at double compared to silicone oil, its lubricating ability Rise.
The ethylene glycol provides strong support, to ensure as antifreezing agent to the use in a low temperature of the lubricant Severe cold weather uses or can still reached when being lubricated for artificial ice rink the technique effect of high-efficiency lubricating to lubricant in the winter time.
The silicone oil, lauryl alcohol APEO, ethylene glycol are easily dissolved in isopropanol and water, the lubricant of formation For emulsion, the lubricant lubricating capacity is strong, and wetability is good, can rapidly extend in ice face or plant equipment, especially exists Used in ice face, will more clean light using rear ice face, above-mentioned lubricant is long-term use of the skill for conserving artificial ice ice face Art effect, the trickle scuffing of artificial ice ice face can be repaired naturally.
Embodiment 1
Lubricant contains the raw material of following parts by weight described in embodiment 1:8 parts of silicone oil, lauryl alcohol APEO 5 Part, 8 parts of isopropanol, 1 part of ethylene glycol, 85 parts of water.Above-mentioned formula is sequentially added in reactor, normal pressure will mix in a kettle Solution stirs, and whipping temp is 20 DEG C, speed of agitator 100r/min, mixing time 2h, to obtain the profit Lubrication prescription.
Verified repeatedly through testing for many years, oiliness relatively low using manufactured lubricant viscosity and friction factor after said ratio Good, the viscosity, friction factor are lower, and the oiliness is better, show that the lubricating capacity of this lubricant and wetability are better, therefore this The lubricant of formula can obtain splendid lubricant effect, can be widely used for the profit in the fields such as mechanical, artificial ice face, human body Sliding, lubricant is gentle non-stimulated in itself, and tasteless nontoxic, value is cheap;The lubricant is applied in the low temperature such as artificial ice face field There is special efficacy, the lubricant is lasting in artificial ice face lubricating capacity, and the lubricant of said ratio is long-term use of maintenance artificial ice The technique effect of ice face, the trickle scuffing of artificial ice ice face can be repaired naturally.Specific greasy property test result is shown in Table one.
Embodiment 2
Lubricant contains the raw material of following parts by weight described in embodiment 2:2 parts of silicone oil, lauryl alcohol APEO 0.5 part, 1 part of isopropanol, 5 parts of ethylene glycol, 94 parts of water.Above-mentioned formula is sequentially added in reactor, normal pressure will in a kettle Mixed solution stirs, and whipping temp is 20 DEG C, speed of agitator 100r/min, mixing time 2h, to obtain State lubricant.
Verified repeatedly through testing for many years, oiliness relatively low using manufactured lubricant viscosity and friction factor after said ratio Good, the viscosity, friction factor are lower, and the oiliness is better, show that the lubricating capacity of this lubricant and wetability are better, therefore this The lubricant of formula can obtain splendid lubricant effect, can be widely used for the profit in the fields such as mechanical, artificial ice face, human body Sliding, lubricant is gentle non-stimulated in itself, and tasteless nontoxic, value is cheap;The lubricant is applied in the low temperature such as artificial ice face field There is special efficacy, the lubricant is lasting in artificial ice face lubricating capacity, and the lubricant of said ratio is long-term use of maintenance artificial ice The technique effect of ice face, the trickle scuffing of artificial ice ice face can be repaired naturally.Specific greasy property test result is shown in Table one.
Embodiment 3
Lubricant contains the raw material of following parts by weight described in embodiment 3:3 parts of silicone oil, lauryl alcohol APEO 1 Part, 3 parts of isopropanol, 4 parts of ethylene glycol, 2 parts of phytic acid, 92 parts of water.Above-mentioned formula is sequentially added in reactor, in a kettle often Pressure stirs mixed solution, and whipping temp is 20 DEG C, speed of agitator 100r/min, mixing time 2h, with To the lubricant.
Verified repeatedly through testing for many years, oiliness relatively low using manufactured lubricant viscosity and friction factor after said ratio Good, the viscosity, friction factor are lower, and the oiliness is better, show that the lubricating capacity of this lubricant and wetability are better, therefore this The lubricant of formula can obtain splendid lubricant effect, can be widely used for the profit in the fields such as mechanical, artificial ice face, human body Sliding, lubricant is gentle non-stimulated in itself, and tasteless nontoxic, value is cheap;The lubricant is applied in the low temperature such as artificial ice face field There is special efficacy, the lubricant is lasting in artificial ice face lubricating capacity, and the lubricant of said ratio is long-term use of maintenance artificial ice The technique effect of ice face, the trickle scuffing of artificial ice ice face can be repaired naturally.Specific greasy property test result is shown in Table one.
Meanwhile verified repeatedly through testing for many years, using above-mentioned lubricant, within 200 DEG C of high temperature range, the lubrication Agent has excellent inoxidizability.Specific antioxygenic property test result is shown in Table one.
Embodiment 4
Lubricant contains the raw material of following parts by weight described in embodiment 4:6 parts of silicone oil, lauryl alcohol APEO 3 Part, 6 parts of isopropanol, 2 parts of ethylene glycol, 6 parts of phytic acid, 88 parts of water.Above-mentioned formula is sequentially added in reactor, in a kettle often Pressure stirs mixed solution, and whipping temp is 20 DEG C, speed of agitator 100r/min, mixing time 2h, with To the lubricant.
Verified repeatedly through testing for many years, oiliness relatively low using manufactured lubricant viscosity and friction factor after said ratio Good, the viscosity, friction factor are lower, and the oiliness is better, show that the lubricating capacity of this lubricant and wetability are better, therefore this The lubricant of formula can obtain splendid lubricant effect, can be widely used for the profit in the fields such as mechanical, artificial ice face, human body Sliding, lubricant is gentle non-stimulated in itself, and tasteless nontoxic, value is cheap;The lubricant is applied in the low temperature such as artificial ice face field There is special efficacy, the lubricant is lasting in artificial ice face lubricating capacity, and the lubricant of said ratio is long-term use of maintenance artificial ice The technique effect of ice face, the trickle scuffing of artificial ice ice face can be repaired naturally.Specific greasy property test result is shown in Table one.
Meanwhile verified repeatedly through testing for many years, using above-mentioned lubricant, within 200 DEG C of high temperature range, the lubrication Agent has excellent inoxidizability.Specific anti-oxidant energy test result is shown in Table one.
Embodiment 5
Lubricant contains the raw material of following parts by weight described in embodiment 5:5 parts of silicone oil, lauryl alcohol APEO 2 Part, 4 parts of isopropanol, 3 parts of ethylene glycol, 4 parts of phytic acid, 90 parts of water.Above-mentioned formula is sequentially added in reactor, in a kettle often Pressure stirs mixed solution, and whipping temp is 20 DEG C, speed of agitator 100r/min, mixing time 2h, with To the lubricant.
Verified repeatedly through testing for many years, using manufactured lubricant after said ratio viscosity and rubbed in the embodiment of the present invention It is minimum to wipe factor, one group of best lubricant embodiment of oiliness, the fields such as mechanical, artificial ice face, human body can be widely used for Lubrication, lubricant is gentle non-stimulated in itself, and tasteless nontoxic, value is cheap.The lubricant is lasting in artificial ice face lubricating capacity, The lubricant of said ratio is long-term use of the technique effect for conserving artificial ice ice face, can repair artificial ice ice face naturally Trickle scuffing.Specific greasy property test result is shown in Table one.Specific greasy property test result is shown in Table one.
Meanwhile verified repeatedly through testing for many years, using above-mentioned lubricant, within 200 DEG C of high temperature range, the lubrication Agent has inoxidizability best in the embodiment of the present invention.Specific anti-oxidant energy test result is shown in Table one.
Embodiment 6:
The present invention additionally provides a kind of lubricant compositions for artificial ice face on the basis of above-described embodiment 1-5, The lubricant compositions contain foregoing lubricant.Due to lubricating capacity when the above-mentioned lubricant of the present invention uses at low temperature And wetability is preferable, there is special efficacy in terms of artificial ice face lubrication, the bright skill of artificial ice face cleaning can be reached after use Art effect, the trickle scuffing of artificial ice face can be repaired naturally, therefore can be used as the lubricant agent special of artificial ice face, energy The further efficient using effect of similar lubricant product in enough acquirements compared with prior art.
Table 1 be 1-5 of the embodiment of the present invention lubricant and reference examples 1-2 lubricity test result, the lubricity Test is tested using resistance to fretting wear, and the experiment condition of resistance to fretting wear is as follows:
Equipment:SRV friction wear testing machines.
Ball-disk:Steel-steel.
Frequency:50Hz.
Load:20N.
Amplitude:0.15m.
Temperature:180 DEG C and -20 DEG C.
Time:60min.
Sample coating thickness:0.1mm.
After experiment, the depth capacity (μm) of the sliding part of disk is determined using rough surface instrument.
Table 1 also have recorded the anti-oxidant of the inoxidizability of lubricant described in 3-5 of the embodiment of the present invention and reference examples 1-2 simultaneously The test result of property, the test of the inoxidizability use following device and method:Choose embodiment 3-5 lubricant, control The water in Castrol lubricating oil, reference examples 2 in example 1, above-mentioned 5 groups of solution is poured into be heated in 150 DEG C of container respectively, selected Take identical material and the tinplate by polishing of size, the tinplate to be divided into 5 groups, be respectively put into above-mentioned 5 containers, protect Warm 30min, tinplate is taken out, the color of 5 groups of tinplates is observed respectively and keeps a record.
Table 1
In industrial lubrication field, from table 1, the when disk that determines of the lubricant at 180 DEG C of the formula of embodiment 5 is used Friction depth capacity be respectively 1.1 μm, do lubricant compared to water, there is obvious superior lubricant effect, compared to normal For the lubricating oil of industrial lubricants Castrol, lubricant effect is more or less the same, but embodiments of the invention 1-5 lubricant Price to be far below Castrol lubricating oil, meanwhile, the lubricant effect of embodiment 3 and 4 is substantially better than embodiment 1 and 2, this table In the range of the bright lubricant formulations in embodiment 3 and 4 limit, the lubricant effect of the lubricant is better than embodiment 1 and 2 Lubricant in the range of lubricant formulations restriction.
Meanwhile from the data of table 1, at -20 DEG C, the friction of the disk determined using the lubricant of the formula of embodiment 5 Depth capacity is respectively 1.5 μm, and lubricant is done compared to water, has obvious superior lubricant effect, compared to conventional work For the lubricating oil of industry lubricant Castrol, lubricant effect is more or less the same, but the price of embodiments of the invention 1-5 lubricant Castrol lubricating oil is far below, this shows that the lubricant of embodiment 1 has excellent antifreezing effect at low temperature, it is ensured that Lubricant lubricant effect declines little.
The friction depth capacity for the disk that embodiment 1 and 4 determines is found simultaneously for 180 DEG C of detection data, point About 1.2 and 1.0 μm are not added, detection data of the friction depth capacity compared to 180 DEG C for the disk that embodiment 2 and 3 determines For, add about 0.7 μm, detection data of the friction depth capacity compared to 180 DEG C for the disk that embodiment 5 determines and Speech, adds about 0.4 μm, this antifreeze glycol for showing to add in above-described embodiment 1-5 lubricant achieves good Good antifreezing effect, while it can be found that the antifreeze glycol in embodiment 1-4 adds more, its lubricating ability decline It is fewer, but in embodiment 5 antifreeze glycol add be not most, but its lubricating ability decline it is minimum, this may It is relevant with the formula of embodiment 5.
In anti-oxidation field, from table 1, antioxidant phytic acid is added due to no in embodiment 1 and 2, it is found that horse The surface of mouth iron has obvious a small amount of iron rust, shows that the oxidation resistance of above-mentioned lubricant is limited, and embodiment 3-5 lubrication 2 parts, 6 parts and 4 parts of antioxidant phytic acid is separately added into agent, color corresponding to the tinplate is jaundice, slight hair respectively Yellow and true qualities, show that phytic acid is added in the formula of the present invention has excellent antioxidant effect, in addition, as phytic acid adds The increase of amount, antioxygenic property have the trend become better and better, but the lubricant inoxidizability of embodiment 5 preferably and phytic acid simultaneously It is not to add most embodiments, this shows that the antioxygenic property of phytic acid may be also relevant with the specific formula of embodiment.
It is worth mentioning that the lubricant antioxygenic property of the embodiment of the present invention 5 is even better than the Castrol in reference examples 1 Lubricating oil, the embodiment of the present invention 5 have obvious price advantage compared to industrial conventional lubricants Castrol lubricating oil, and this shows The lubricant of the embodiment of the present invention 5 has bright market prospects in anti-oxidant lubricating area.
The present invention is not limited to above-mentioned preferred forms, and anyone can show that other are various under the enlightenment of the present invention The product of form, however, make any change in its shape or structure, it is every that there is skill identical or similar to the present application Art scheme, is within the scope of the present invention.

Claims (6)

1. a kind of lubricant, it is characterised in that the lubricant contains the raw material of following parts by weight:Silicone oil 2-8 parts;Laruyl alcohol Ether APEO 0.5-5 parts;Isopropanol 1-8 parts;Ethylene glycol 1-5 parts;Water 85-94 parts.
2. lubricant according to claim 1, it is characterised in that:The lubricant also includes the antioxidant of 2-6 parts.
3. lubricant according to claim 2, it is characterised in that:The antioxidant is phytic acid.
4. lubricant according to claim 3, it is characterised in that:The lubricant contains the raw material of following parts by weight: Silicone oil 3-6 parts;Lauryl alcohol APEO 1-3 parts;Isopropanol 3-6 parts;Ethylene glycol 2-4 parts;Phytic acid 3-5 parts;Water 88-92 Part.
5. lubricant according to claim 4, it is characterised in that:The lubricant contains the raw material of following parts by weight: 5 parts of silicone oil;2 parts of lauryl alcohol APEO;4 parts of isopropanol;3 parts of ethylene glycol;4 parts of phytic acid;90 parts of water.
A kind of 6. lubricant compositions for being used to clean artificial ice face, it is characterised in that:The lubricant compositions, which contain, has the right It is required that the lubricant any one of 1-5.
CN201710630533.1A 2017-07-28 2017-07-28 A kind of lubricant Pending CN107446686A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1046548A (en) * 1990-05-30 1990-10-31 李洪耀 Efficiently brightening and cleaning liquid for glass
CN1844341A (en) * 2006-04-11 2006-10-11 王士奎 Anti-freezing waterless car-washing detergent
CN102978047A (en) * 2012-12-12 2013-03-20 上海皇宇科技发展有限公司 Multifunctional leather cleaner and preparation method thereof
CN103446630A (en) * 2013-08-23 2013-12-18 蔡智浙 Safe and easy-to-clean lubricating oil composition for condoms and preparation method thereof
CN105838511A (en) * 2016-04-11 2016-08-10 河南工程学院 A novel environmental-friendly automobile windshield washing concentrated liquid

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1046548A (en) * 1990-05-30 1990-10-31 李洪耀 Efficiently brightening and cleaning liquid for glass
CN1844341A (en) * 2006-04-11 2006-10-11 王士奎 Anti-freezing waterless car-washing detergent
CN102978047A (en) * 2012-12-12 2013-03-20 上海皇宇科技发展有限公司 Multifunctional leather cleaner and preparation method thereof
CN103446630A (en) * 2013-08-23 2013-12-18 蔡智浙 Safe and easy-to-clean lubricating oil composition for condoms and preparation method thereof
CN105838511A (en) * 2016-04-11 2016-08-10 河南工程学院 A novel environmental-friendly automobile windshield washing concentrated liquid

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Application publication date: 20171208