CN107442128A - A kind of Cu/Cu2O/CeO2It is prepared by one pot of hydro-thermal method of ternary nano compound - Google Patents
A kind of Cu/Cu2O/CeO2It is prepared by one pot of hydro-thermal method of ternary nano compound Download PDFInfo
- Publication number
- CN107442128A CN107442128A CN201710661480.XA CN201710661480A CN107442128A CN 107442128 A CN107442128 A CN 107442128A CN 201710661480 A CN201710661480 A CN 201710661480A CN 107442128 A CN107442128 A CN 107442128A
- Authority
- CN
- China
- Prior art keywords
- ceo
- hydro
- pot
- ternary nano
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 title claims abstract description 76
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 title claims abstract description 75
- 238000001027 hydrothermal synthesis Methods 0.000 title claims abstract description 19
- 238000005580 one pot reaction Methods 0.000 title claims abstract description 16
- 150000001875 compounds Chemical class 0.000 title description 33
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims abstract description 109
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000012153 distilled water Substances 0.000 claims abstract description 44
- 239000011259 mixed solution Substances 0.000 claims abstract description 32
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 238000002360 preparation method Methods 0.000 claims abstract description 23
- 238000005406 washing Methods 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000002114 nanocomposite Substances 0.000 claims abstract description 16
- 150000000703 Cerium Chemical class 0.000 claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 9
- 239000000376 reactant Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 5
- -1 template Substances 0.000 claims abstract description 4
- 239000007787 solid Substances 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 157
- 239000010949 copper Substances 0.000 claims description 120
- 239000000243 solution Substances 0.000 claims description 32
- 150000002500 ions Chemical class 0.000 claims description 29
- SXTLQDJHRPXDSB-UHFFFAOYSA-N copper;dinitrate;trihydrate Chemical group O.O.O.[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O SXTLQDJHRPXDSB-UHFFFAOYSA-N 0.000 claims description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 238000013019 agitation Methods 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 7
- MPTQRFCYZCXJFQ-UHFFFAOYSA-L copper(II) chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Cu+2] MPTQRFCYZCXJFQ-UHFFFAOYSA-L 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910002492 Ce(NO3)3·6H2O Inorganic materials 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 2
- 239000007800 oxidant agent Substances 0.000 abstract description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 45
- SKEYZPJKRDZMJG-UHFFFAOYSA-N cerium copper Chemical compound [Cu].[Ce] SKEYZPJKRDZMJG-UHFFFAOYSA-N 0.000 description 26
- 235000013339 cereals Nutrition 0.000 description 20
- 238000002441 X-ray diffraction Methods 0.000 description 19
- 150000004677 hydrates Chemical class 0.000 description 13
- 238000000034 method Methods 0.000 description 7
- 238000001228 spectrum Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- CQPFMGBJSMSXLP-ZAGWXBKKSA-M Acid orange 7 Chemical compound OC1=C(C2=CC=CC=C2C=C1)/N=N/C1=CC=C(C=C1)S(=O)(=O)[O-].[Na+] CQPFMGBJSMSXLP-ZAGWXBKKSA-M 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 238000005576 amination reaction Methods 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- PTVDYARBVCBHSL-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu] PTVDYARBVCBHSL-UHFFFAOYSA-N 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses a kind of Cu/Cu2O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, Solid raw materials mantoquita, cerium salt are added into dissolving in distilled water in molar ratio and form mixed solution, and aqueous slkali is added in backward mixed solution, form reactant mixture；Cool down after reactant mixture is heated into a period of time, taken out after cooling, centrifuged, dried after washing.Preparation process of the present invention is simple and convenient to operate；Avoid, using reductant-oxidant, template, product purity being improved, also comply with the requirement that material green is combined to, be also suitable for mass producing.
Description
Technical field
The present invention relates to a kind of Cu/Cu2O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, belongs to
Nano composite material preparing technical field.
Background technology
Cu2O/CeO2Composite is a kind of quite varied functional material of purposes, is had in fields such as catalysis, electrode materials
Important application.Wherein, Cu2O/CeO2Compound shows stronger visible absorption ability and light is urged as photochemical catalyst
Change activity, be a kind of outstanding visible-light photocatalysis material.
At present, Cu2O/CeO2The preparation method of composite is mainly liquid phase reactor method.
Such as：Using glucose as reducing agent, Cu is prepared by soaking and reducing method2O/CeO2Heterojunction photocatalyst
（Shichao Hu, et. al. Preparation of Cu2O/CeO2 heterojunction photocatalyst for
The degradation of Acid Orange 7 under visible light irradiation, Catalysis
Communications, 2011,12:794–797）；
With cube and octahedra Cu2O prepares Cu as template is sacrificed by template auxiliary law2O/CeO2Nano-complex
（Huizhi Bao, et. al. Compositions, structures, and catalytic activities of
CeO2@Cu2O nanocomposites prepared by the template-assisted method, Langmuir, 30
(22):6427–6436）；
Caught up with by Argon Bubble gas pre-treatment except the oxygen in reaction medium, with Ce (OH) in alkaline solution3For template, oxygen is utilized
Change the Cu that core shell structure is prepared in reduction assembling2O/CeO2Nanocube（Xiao Wang, et. al. Clean
synthesis of Cu2O@CeO2Core@shell nanocubes with highly active interface, NPG
Asia Materials, 2015,7 (1):7-19）；
With cube and octahedra Cu2O prepares Cu as template is sacrificed by template auxiliary law2O/CeO2Nano-complex,
Subsequent amination Cu2O/CeO2Obtain Cu2O/CeO2-NH2Compound, then pass through reduction of sodium citrate AuCl4 -Ion obtains Au and received
Rice corpuscles, pass through Au nano-particles and-NH2Between build stable chemical bond and obtain Cu2O@CeO2- Au nano-complexes
（Faying Li, et. al. Ultrasensitive amperometric immunosensor for PSA
detection based on Cu2O@CeO2-Au nanocomposites as integrated triple signal
Amplification strategy, Biosensors and Bioelectronics, 2017,87:630–637）.
Although a variety of preparation methods can prepare Cu disclosed in prior art2O/CeO2Composite, it can also use above-mentioned side
Method is produced such as Au/Cu2O/CeO2Ternary complex, but Shortcomings, a large amount of solvents are needed to use in liquid phase method preparation process,
In preparation process, before some needs to use reductant-oxidant, some to need to use template, some to need to use inert gas
Processing, meanwhile, the preparation process of compound is all that substep is carried out, and process is complicated, is unfavorable for large-scale production, it is necessary to continue deeper into
Research.
The content of the invention
For above-mentioned technical problem underlying, it is an object of the invention to provide one kind without using solvent, also without
Need to add reductant-oxidant or template, process be simple and convenient to operate, green Cu/Cu2O/CeO2Ternary nano is compound
One pot of hydro-thermal reaction preparation method of material.
To achieve the above object, the technological means taken of the present invention is：A kind of Cu/Cu2O/CeO2Ternary nano composite wood
Expect one pot of hydro-thermal reaction preparation method, it is molten that Solid raw materials mantoquita, cerium salt are added into dissolving formation mixing in distilled water in molar ratio
Liquid, and aqueous slkali is added in backward mixed solution, form reactant mixture；Cooled down after reactant mixture is heated into a period of time,
Take out, centrifuge after cooling, dried after washing.
Further, the mantoquita, the mol ratio of cerium salt are 0.8 ~ 0.95: 1.
Further, 0.16~0.19 molL is contained in the mixed solution-1Cu2+Ion and 0.2 molL-1Ce3+From
Son.
Further, the mantoquita is cupric salt.
Further, the cupric salt is Gerhardite, Salzburg vitriol, the one of Copper dichloride dihydrate
Kind.
Further, the cerium salt is Ce (NO3)3·6H2O。
Further, the aqueous slkali is 4 molL-1The mol ratio of sodium hydroxide solution, cerium salt and sodium hydroxide is 1:
8.0。
Further, the addition aqueous slkali refers to rapidly join sodium hydroxide solution molten just in the mixing of magnetic agitation
Liquid.
Further, cooling refers to reactant mixture being transferred to poly- after described reactant mixture heating a period of time
In the reactor of tetrafluoroethene liner, 1~4h of heated at constant temperature, then naturally cools to room temperature at 100~180 DEG C.
Further, take out, centrifuge after the cooling, dried after washing and refer to after cooling, take out in reactor
Solidliquid mixture, centrifuge, distilled water and absolute ethyl alcohol respectively washing 3 times, be dried in vacuo 2 hours at 60 DEG C.
The beneficial effects of the present invention are：Preparation process is simple and convenient to operate；Avoid using reductant-oxidant, template,
Product purity can be improved, also complies with the requirement that material green is combined to, is also suitable for mass producing.
Brief description of the drawings
The present invention is further elaborated with embodiment below in conjunction with the accompanying drawings.
Fig. 1 is Cu/Cu prepared by the embodiment of the present invention 1,2,3,4 and 52O/CeO2Ternary nano compound XRD spectrum；
Fig. 2 is Cu/Cu prepared by the embodiment of the present invention 6,2,7 and 82O/CeO2Ternary nano compound XRD spectrum；
Fig. 3 is Cu/Cu prepared by the embodiment of the present invention 9,10,2 and 112O/CeO2Ternary nano compound XRD spectrum.
Embodiment
Embodiment 1
It is accurate weigh 8.5 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 100 DEG C
After heating 2h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 49.3 nm and 23.1 nm.
Embodiment 2
It is accurate weigh 8.5 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 120 DEG C
After heating 2h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 57.9 nm and 27.5 nm.
Embodiment 3
It is accurate weigh 8.5 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 140 DEG C
After heating 2h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 65.1 nm and 30.1 nm.
Embodiment 4
It is accurate weigh 8.5 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 160 DEG C
After heating 2h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 71.4 nm and 32.7 nm.
Embodiment 5
It is accurate weigh 8.5 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 180 DEG C
After heating 2h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 89.6 nm and 35.2 nm.
Embodiment 6
It is accurate weigh 8.5 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 120 DEG C
After heating 1h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 56.3 nm and 27.3 nm.
Embodiment 7
It is accurate weigh 8.5 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 120 DEG C
After heating 3h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 58.8 nm and 27.8nm.
Embodiment 8
It is accurate weigh 8.5 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 120 DEG C
After heating 4h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 59.7 nm and 28.2 nm.
Embodiment 9
It is accurate weigh 9.5 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 120 DEG C
After heating 2h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 58.1 nm and 27.5 nm.
Embodiment 10
It is accurate weigh 9.0 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 120 DEG C
After heating 2h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 58.0 nm and 27.4 nm.
Embodiment 11
It is accurate weigh 8.0 mMs of analytically pure Gerhardites, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 120 DEG C
After heating 2h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 57.9 nm and 27.6 nm.
Embodiment 12
It is accurate weigh 8.5 mMs of analytically pure Salzburg vitriols, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 120 DEG C
After heating 2h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 57.3 nm and 27.3 nm..
Embodiment 13
It is accurate weigh 8.5 mMs of analytically pure Copper dichloride dihydrates, 10.0 mMs of analytically pure six nitric hydrates ceriums and
80.0 mMs of analytically pure sodium hydroxides, Gerhardite and six nitric hydrate ceriums are dissolved in 50 ml distilled water, obtained
0.17 molL must be contained-1Cu2+Ion and 0.2 molL-1Ce3+The copper cerium mixed solution of ion；Sodium hydroxide is dissolved in 20
In ml distilled water, acquisition contains 4.0 molL-1Sodium hydroxide solution.Sodium hydroxide solution is rapidly joined to the copper cerium of magnetic agitation
In mixed solution, after being well mixed, being transferred to 100 ml has in the reactor of polytetrafluoroethyllining lining, the constant temperature at 120 DEG C
After heating 2h, room temperature is naturally cooled to, takes out solidliquid mixture in reactor, is centrifuged, it is each with distilled water and absolute ethyl alcohol
Washing 3 times, is dried in vacuo 2 hours at 60 DEG C, obtains Cu/Cu2O/CeO2Ternary nano compound.
To Cu/Cu2O/CeO2Product carries out XRD analysis, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Three
Cu in first nano-complex2O and CeO2Average grain size is respectively 57.1 nm and 27.2 nm..
The X-ray diffraction analysis of above-described embodiment（XRD analysis）：Respectively by Cu/ made from embodiment 1,2,3,4 and 5
Cu2O/CeO2Ternary nano compound carries out XRD analysis, as a result sees Fig. 1.It is calculated by Scherrer formula：Reaction raw materials three
Nitric hydrate copper, six nitric hydrate ceriums and sodium hydroxide according to after 0.85: 1: 8 mixed in molar ratio respectively 100 DEG C, 120 DEG C,
Hydro-thermal reaction 2h, products therefrom Cu/Cu at 140 DEG C, 160 DEG C and 180 DEG C2O/CeO2Cu in ternary nano compound2O and CeO2
Average grain size be respectively 49.3 nm, 57.9 nm, 65.1 nm, 71.4 nm, 89.6 nm and 23.1 nm, 27.5 nm,
30.1 nm, 32.7 nm, 35.2 nm, show the change of hydrothermal temperature to Cu/Cu2O/CeO2In ternary nano compound
Cu2O and CeO2The size of average grain size has certain influence, with the rise of hydrothermal temperature, Cu/Cu2O/CeO2Ternary
Cu in nano-complex2O and CeO2Crystal grain is gradually being grown up, wherein Cu2O becomes apparent.
To Cu/Cu made from embodiment 6,2,7 and 82O/CeO2Ternary nano compound carries out XRD analysis, as a result sees Fig. 2.
It is calculated by Scherrer formula：Reaction raw materials Gerhardite, six nitric hydrate ceriums and sodium hydroxide are according to 0.85: 1:
Hydro-thermal reaction 1h, 2h, 3h, 4h, products therefrom Cu/Cu are distinguished after 8 mixed in molar ratio at 120 DEG C2O/CeO2Ternary nano is answered
Cu in compound2O and CeO2Average grain size be respectively 56.3 nm, 57.9 nm, 58.8 nm, 59.7 nm and 27.3 nm,
27.5 nm, 27.8nm, 28.2 nm, show the extension with the hydro-thermal reaction time, to Cu/Cu2O/CeO2Ternary nano compound
Middle Cu2O and CeO2Average crystal grain size all slowly increases.
To Cu/Cu made from embodiment 9,10,2 and 112O/CeO2Ternary nano compound carries out XRD analysis, as a result sees
Fig. 3.It is calculated by Scherrer formula：When Gerhardite, six nitric hydrate ceriums and sodium hydroxide mol ratio by
0.95: 1: 8 when being changed into 0.8: 1: 8, is calculated according to Scherrer formula, Cu/Cu2O/CeO2Cu in ternary nano compound2O and
CeO2Average grain size be respectively 58.1 nm, 58.0 nm, 57.9 nm, 57.9 nm and 27.5,27.5 nm, 27.4 nm,
27.6 nm, show that the dosage of Gerhardite changes in certain periphery, to Cu/Cu2O/CeO2In ternary nano compound
Cu2O and CeO2The influence of average crystal grain size is smaller.
To Cu/Cu made from embodiment 12 and 132O/CeO2Ternary nano compound has also carried out XRD analysis, by
Scherrer formula result of calculations show that cupric salt is changed into Salzburg vitriol or Copper dichloride dihydrate from Gerhardite
When, product Cu/Cu2O/CeO2Cu in ternary nano compound2O and CeO2Average crystal grain size is almost unchanged.
In addition, it is necessary to explanation, from Cu/Cu2O/CeO2It can be seen that simple substance in the XRD spectrum of ternary nano compound
Cu characteristic diffraction peak is present, and shows Cu/Cu2O/CeO2Crystalline phase simple substance Cu in ternary nano compound be present, from Cu/Cu2O/
CeO2In ternary nano compound XRD spectrum it can also be seen that with the increase of cupric salt dosage, its characteristic diffraction peak intensity
Increase, shows Cu/Cu2O/CeO2Simple substance Cu amount is increasing in ternary nano compound, but because Cu characteristic diffraction peak exists
Cu/Cu2O/CeO2It is relatively weak in ternary nano compound XRD spectrum, its average crystalline substance can not be accurately calculated with Scherrer formula
Grain size.
From the foregoing, in Cu/Cu2O/CeO2, can be by suitably changing water in the preparation process of ternary nano compound
The temperature and time of thermal response controls Cu in product2O and CeO2Average grain size, and by controlling cupric salt
Dosage controls simple substance Cu load capacity.
One of ordinary skill in the art will appreciate that：Various embodiments above is merely illustrative of the technical solution of the present invention, and
It is non-that it is limited；Although the present invention is described in detail with reference to foregoing embodiments, one of ordinary skill in the art
It should be understood that：It can still modify to the technical scheme described in foregoing embodiments, either to which part or
All technical characteristic carries out equivalent substitution；And these modifications or replacement, the essence of appropriate technical solution is departed from this hair
The scope of bright each embodiment technical scheme.
Claims (10)
- A kind of 1. Cu/Cu2O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, by Solid raw materials mantoquita, cerium salt Dissolving in distilled water is added in molar ratio and forms mixed solution, and aqueous slkali is added in backward mixed solution, forms reaction mixing Thing；Cool down after reactant mixture is heated into a period of time, taken out after cooling, centrifuged, dried after washing.
- 2. Cu/Cu according to claim 12O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, it is special Sign is：The mantoquita, the mol ratio of cerium salt are 0.8 ~ 0.95: 1.
- 3. Cu/Cu according to claim 12O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, it is special Sign is：Contain 0.16~0.19 molL in the mixed solution-1Cu2+Ion and 0.2 molL-1Ce3+Ion.
- 4. Cu/Cu according to claim 12O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, it is special Sign is：The aqueous slkali is 4 molL-1The mol ratio of sodium hydroxide solution, cerium salt and sodium hydroxide is 1:8.0.
- 5. Cu/Cu according to claim 12O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, it is special Sign is：The mantoquita is cupric salt.
- 6. Cu/Cu according to claim 52O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, it is special Sign is：The cupric salt is Gerhardite, Salzburg vitriol, one kind of Copper dichloride dihydrate.
- 7. Cu/Cu according to claim 12O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, it is special Sign is：The cerium salt is Ce (NO3)3·6H2O。
- 8. Cu/Cu according to claim 12O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, it is special Sign is：The addition aqueous slkali refers to rapidly join sodium hydroxide solution just in the mixed solution of magnetic agitation.
- 9. Cu/Cu according to claim 12O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, it is special Sign is：Cooling refers to reactant mixture being transferred to in polytetrafluoroethylene (PTFE) after described reactant mixture heating a period of time In the reactor of lining, 1~4h of heated at constant temperature, then naturally cools to room temperature at 100~180 DEG C.
- 10. Cu/Cu according to claim 12O/CeO2One pot of hydro-thermal reaction preparation method of ternary nano composite material, its It is characterised by：Take out, centrifuge after the cooling, dried after washing and refer to after cooling, take out solid-liquid in reactor and mix Thing, centrifuge, distilled water and absolute ethyl alcohol respectively washing 3 times, be dried in vacuo 2 hours at 60 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710661480.XA CN107442128B (en) | 2017-08-04 | 2017-08-04 | Cu/Cu 2O/CeO 2One-pot hydrothermal preparation method of ternary nano-composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710661480.XA CN107442128B (en) | 2017-08-04 | 2017-08-04 | Cu/Cu 2O/CeO 2One-pot hydrothermal preparation method of ternary nano-composite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107442128A true CN107442128A (en) | 2017-12-08 |
| CN107442128B CN107442128B (en) | 2020-02-11 |
Family
ID=60490814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710661480.XA Active CN107442128B (en) | 2017-08-04 | 2017-08-04 | Cu/Cu 2O/CeO 2One-pot hydrothermal preparation method of ternary nano-composite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107442128B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108080653A (en) * | 2018-01-04 | 2018-05-29 | 湖北大学 | A kind of Co of morphology controllable2The autoclave liquid-phase reduction the preparation method of FeAl nanostructureds |
| CN110841649A (en) * | 2019-10-17 | 2020-02-28 | 华南师范大学 | Preparation method of copper-cerium bimetal Fenton catalytic material, prepared catalytic material and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102489304A (en) * | 2011-12-01 | 2012-06-13 | 黑龙江大学 | Preparation method for spherical copper-cerium composite oxides |
| CN103657666A (en) * | 2013-11-29 | 2014-03-26 | 内蒙古大学 | Preparation method of catalyst using multi-walled carbon nanotube as carrier and for preferential oxidation of CO |
| CN103979597A (en) * | 2014-05-26 | 2014-08-13 | 黑龙江大学 | Preparation method of rod-like copper-cerium composite oxide |
-
2017
- 2017-08-04 CN CN201710661480.XA patent/CN107442128B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102489304A (en) * | 2011-12-01 | 2012-06-13 | 黑龙江大学 | Preparation method for spherical copper-cerium composite oxides |
| CN103657666A (en) * | 2013-11-29 | 2014-03-26 | 内蒙古大学 | Preparation method of catalyst using multi-walled carbon nanotube as carrier and for preferential oxidation of CO |
| CN103979597A (en) * | 2014-05-26 | 2014-08-13 | 黑龙江大学 | Preparation method of rod-like copper-cerium composite oxide |
Non-Patent Citations (2)
| Title |
|---|
| FAYING LI ET AL: ""Ultrasensitive amperometric immunosensor for PSA detection based on Cu2O@CeO2-Au nanocomposites as integrated triple signal amplification strategy"", 《BIOSENSORS AND BIOELECTRONICS》 * |
| 田俊杰: ""介孔氧化铈及其金属负载复合物的合成及性能研究"", 《中国优秀硕士学位论文全文数据库》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108080653A (en) * | 2018-01-04 | 2018-05-29 | 湖北大学 | A kind of Co of morphology controllable2The autoclave liquid-phase reduction the preparation method of FeAl nanostructureds |
| CN110841649A (en) * | 2019-10-17 | 2020-02-28 | 华南师范大学 | Preparation method of copper-cerium bimetal Fenton catalytic material, prepared catalytic material and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107442128B (en) | 2020-02-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108517038B (en) | Size regulation and control method of porphyrin metal organic framework material | |
| CN104028269B (en) | Graphene loaded metal nano composite material, and preparation method and application thereof | |
| CN103933972B (en) | A kind of preparation method of noble metal titanium dioxide core shell structure | |
| CN105800686B (en) | One kind prepares Bi5O7I method | |
| CN107952455A (en) | It is a kind of with the three-dimensional sheet BiOI catalysis materials of macroscopic frame and its preparation and application | |
| CN110180529B (en) | Preparation method for synthesizing photocatalytic material by using MOF as precursor | |
| CN107648606A (en) | Collect chemotherapy and the preparation method of thermotherapy integrated nuclear shell nanometer material and products thereof and application | |
| CN102773110A (en) | Method for preparing SnS2/SnO2 composite photocatalyst material of numismatics-shaped hollow structure | |
| CN106423161A (en) | Preparation method of hydrogenation catalyst and catalyst | |
| CN107442128A (en) | A kind of Cu/Cu2O/CeO2It is prepared by one pot of hydro-thermal method of ternary nano compound | |
| CN115041210A (en) | Preparation method of bimetallic monoatomic modified semiconductor photocatalyst for photolysis of water to produce hydrogen | |
| CN108722486A (en) | A kind of preparation method of narrowband carbonitride modification ferrous metals organic backbone composite photo-catalyst | |
| CN114192149A (en) | Catalyst for preparing methanol by carbon dioxide hydrogenation and preparation method thereof | |
| CN107720803A (en) | A kind of brilliant preparation method of cuprous nano | |
| CN107321356B (en) | A kind of Cu2O-2CeO2The solid phase reaction preparation method of nano-complex | |
| CN108940325A (en) | A kind of binary composite semiconductor light-catalyst materials A g2CrO4/ BiOI and its preparation and application | |
| CN106629815B (en) | A kind of semiconductor-based hetero-nanocrystals with hollow reaction microchamber structure and preparation method thereof | |
| CN107185573A (en) | A kind of Ni-based base metal photocatalysis co-catalyst and preparation method thereof | |
| CN105582926B (en) | Terephthalic acid (TPA) hydrogenation catalyst | |
| CN103933999B (en) | A kind of Heterogeneous Composite body Mo xw 1-Xo 3-CuCrO 2and its preparation method and application | |
| CN109518274A (en) | A kind of 12 tungstate crystal materials and preparation method thereof with two-dimensional nanopore cavity configuration | |
| CN107224983B (en) | A kind of Ag/Cu2O/CeO2One pot of solid phase reaction preparation method of ternary nano compound | |
| CN106179343B (en) | A kind of rapid synthesis square Ag4V2O7The method of photochemical catalyst | |
| CN104843792A (en) | Method for preparing nano needle-shaped purple tungsten powder | |
| CN106115764B (en) | The method that one pot of ball milling solid phase method prepares CuI nano-powders |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |