CN107434902A - A kind of environment-friendly type is without magnetic armouring charging pile fire-resisting cable material and preparation method thereof - Google Patents
A kind of environment-friendly type is without magnetic armouring charging pile fire-resisting cable material and preparation method thereof Download PDFInfo
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- CN107434902A CN107434902A CN201710770414.6A CN201710770414A CN107434902A CN 107434902 A CN107434902 A CN 107434902A CN 201710770414 A CN201710770414 A CN 201710770414A CN 107434902 A CN107434902 A CN 107434902A
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/36—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes condensation products of phenols with aldehydes or ketones
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
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- C08L2203/00—Applications
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- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
Include phenolic resin, polyvinyl chloride, silicon rubber, epoxy resin, sodium pyrophosphate, stearic acid, magnesia, calcium stearate, polyethylene glycol, mica powder, antioxidant A, triphenyl phosphite, nanometer alchlor, 3 aminopropyl trimethoxysilanes, altax, zinc stearate, PCDL, hydroxy terminated fluorosilicone oil, ATBC, bauxite powder, calcinated argil, agstone, hydroxyethyl cellulose and fire resisting modified filler without magnetic armouring charging pile fire-resisting cable material, its raw material the invention discloses a kind of environment-friendly type.The present invention also proposes a kind of preparation method of the above-mentioned environment-friendly type without magnetic armouring charging pile fire-resisting cable material.The CABLE MATERIALS that the present invention is prepared is used for environmental protection and used without magnetic armouring charging pile, has excellent fire resistance.
Description
Technical field
The present invention relates to the technical field of CABLE MATERIALS, more particularly to a kind of environment-friendly type is without magnetic armouring charging pile fire-resisting cable
Material and preparation method thereof.
Background technology
Wire cable insulating and sheath are commonly called as CABLE MATERIALS with plastics, and which includes a variety of product such as rubber, plastics, nylon
Kind.CABLE MATERIALS manufacturing enterprise is using cable manufacturing enterprise as user, as long as live wire cabling requirements just have the market of CABLE MATERIALS.Electricity
In line cable product insulating barrier mouth is almost required in addition to the bare wire product such as steel-cored aluminium strand, electromagnetic wire.China's live wire at present
Nearly 5000 of cable manufacturing enterprise, there are upgrading urban and rural power grids, development of the West Regions and communications facility large area upgrading again to electricity
The great demand of line cable product, thus from the point of view of for a period of time, CABLE MATERIALS has extensive market development prospect in China.Fill
The CABLE MATERIALS that electric stake is used with power cable, its fire resistance can not meet actual use when the needs of, so needing exploitation one badly
Kind environment-friendly type solves the problems of the prior art without magnetic armouring charging pile with fire-resisting cable material.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of environment-friendly type without magnetic armouring charging pile with resistance to
Fiery CABLE MATERIALS and preparation method thereof, the CABLE MATERIALS being prepared have excellent fire resistance.
A kind of environment-friendly type proposed by the present invention includes by weight without magnetic armouring charging pile fire-resisting cable material, its raw material：
Phenolic resin 80-120 parts, polyvinyl chloride 30-90 parts, silicon rubber 20-40 parts, epoxy resin 40-80 parts, sodium pyrophosphate 30-60
Part, stearic acid 10-30 parts, magnesia 5-15 parts, calcium stearate 2-8 parts, polyethylene glycol 3-9 parts, mica powder 2-8 parts, antioxidant A
1-5 parts, triphenyl phosphite 4-8 parts, nanometer alchlor 2-9 parts, 3- aminopropyl trimethoxysilane 2-5 parts, altax
2-4 parts, zinc stearate 3-6 parts, PCDL 1-8 parts, hydroxy terminated fluorosilicone oil 2-8 parts, ATBC 3-5 parts, aluminium alum
Native powder 4-8 parts, calcinated argil 1-5 parts, agstone 2-6 parts, hydroxyethyl cellulose 1-5 parts, fire resisting modified filler 4-8 parts.
Preferably, the raw material of fire resisting modified filler includes by weight：Magnesium hydroxide 5-15 parts, nano aluminum nitride 4-8 parts,
It is flake asbestos 3-5 parts, hydrazine hydrate 2-5 parts, carboxylic acrylonitrile butadiene rubber latex 1-5 parts, aluminum sulfate 3-6 parts, ethane-acetic acid ethyenyl ester 2-5 parts, poly-
Olefin elastomer 1-5 parts, cumyl peroxide 3-6 parts, cetyl trimethylammonium bromide 1-5 parts, silane coupler KH-
560 2-8 parts.
Preferably, fire resisting modified filler is prepared by following technique：By magnesium hydroxide, nano aluminum nitride, flake asbestos and
Hydrazine hydrate is well mixed, stirring, is then added carboxylic acrylonitrile butadiene rubber latex and is well mixed, stir, then heat up, is incubated, then adds
Condensed in aluminum sulfate, after then being cleaned with deionized water, filter, be placed in baking oven and dry, be cooled to room temperature and obtain material a；Will
Ethane-acetic acid ethyenyl ester, polyolefin elastomer, cumyl peroxide, cetyl trimethylammonium bromide and silane coupler
KH-560 is well mixed, and is heated, and insulation, is subsequently added into material a, is heated, and is filtered, and is dried, and is cooled to room temperature and is obtained fire resisting modification
Filler.
Preferably, fire resisting modified filler is prepared by following technique：By magnesium hydroxide, nano aluminum nitride, flake asbestos and
Hydrazine hydrate is well mixed, and 10-12h is stirred in 65-75 DEG C, is then added carboxylic acrylonitrile butadiene rubber latex and is well mixed, in 5500-6500r/
2-4h is stirred under min rotating speeds, then heats to 90-100 DEG C, is incubated 0.5-1.5h, then adds in aluminum sulfate and condenses, then use
After deionized water cleaning, filter, be placed in 45-55 DEG C of baking oven and dry 1-4h, be cooled to room temperature and obtain material a；By ethene-second
Vinyl acetate, polyolefin elastomer, cumyl peroxide, cetyl trimethylammonium bromide and silane coupler KH-560 are mixed
Close uniformly, be heated to 80-90 DEG C, be incubated 10-20min, be subsequently added into material a, be heated to 105-115 DEG C, filter, dry, it is cold
But fire resisting modified filler is obtained to room temperature.
A kind of preparation method of the environment-friendly type of the present invention without magnetic armouring charging pile with fire-resisting cable material, comprises the following steps：
S1, by phenolic resin, polyvinyl chloride, silicon rubber, epoxy resin, sodium pyrophosphate, stearic acid, magnesia, stearic acid
Calcium, polyethylene glycol, mica powder, antioxidant A, triphenyl phosphite, nanometer alchlor, 3- aminopropyl trimethoxysilanes, rush
Enter agent DM, zinc stearate, PCDL, hydroxy terminated fluorosilicone oil, ATBC, bauxite powder, calcinated argil, lime stone
Powder, hydroxyethyl cellulose and fire resisting modified filler are added in high-speed mixer, and double screw extruder extrusion is put into after being well mixed
It is granulated；
S2, it will be mixed in material input high-speed mixer made from S1；Double screw extruder is put into after well mixed
Extruding pelletization, pellet produce environment-friendly type without magnetic armouring charging pile fire-resisting cable material after drying, screening, packaging.
Preferably, in S, the temperature of the extruding pelletization of double screw extruder is 120-150 DEG C.
Preferably, in S2,140-160 DEG C of the temperature of the extruding pelletization of double screw extruder.
A kind of environment-friendly type of the present invention includes phenolic resin, polychlorostyrene without magnetic armouring charging pile fire-resisting cable material, its raw material
Ethene, silicon rubber, epoxy resin, sodium pyrophosphate, stearic acid, magnesia, calcium stearate, polyethylene glycol, mica powder, antioxidant A,
Triphenyl phosphite, nanometer alchlor, 3- aminopropyl trimethoxysilanes, altax, zinc stearate, makrolon two
Alcohol, hydroxy terminated fluorosilicone oil, ATBC, bauxite powder, calcinated argil, agstone, hydroxyethyl cellulose and fire resisting are modified
Filler, wherein using phenolic resin, polyvinyl chloride, silicon rubber and epoxy resin as major ingredient, with sodium pyrophosphate, stearic acid, magnesia,
Calcium stearate, polyethylene glycol, mica powder, antioxidant A, triphenyl phosphite, nanometer alchlor, 3- aminopropyl trimethoxy silicon
Alkane, altax, zinc stearate, PCDL, hydroxy terminated fluorosilicone oil, ATBC, bauxite powder, calcinated argil,
Agstone, hydroxyethyl cellulose and fire resisting modified filler are coordinated by major ingredient and reinforcing aids, imparted as reinforcing aids
The excellent fire resistance of CABLE MATERIALS of the invention, good combination property.Wherein, fire resisting modified filler is by by magnesium hydroxide, nanometer
Aluminium nitride, flake asbestos and hydrazine hydrate are well mixed, stirring, are then added carboxylic acrylonitrile butadiene rubber latex and are well mixed, stir, Ran Housheng
Temperature, insulation, then add in aluminum sulfate and condense, after then being cleaned with deionized water, filter, be placed in baking oven and dry, be cooled to
Room temperature obtains material a；By ethane-acetic acid ethyenyl ester, polyolefin elastomer, cumyl peroxide, cetyl trimethyl bromine
Change ammonium and silane coupler KH-560 is well mixed, heat, insulation, be subsequently added into material a, heat, filter, dry, be cooled to
Room temperature obtains fire resisting modified filler, applies in the CABLE MATERIALS of the present invention so that CABLE MATERIALS of the invention has excellent fire resisting
Performance.The CABLE MATERIALS that the present invention is prepared is used for environmental protection and used without magnetic armouring charging pile, has excellent fire resistance.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
Embodiment 1
A kind of environment-friendly type proposed by the present invention includes by weight without magnetic armouring charging pile fire-resisting cable material, its raw material：
100 parts of phenolic resin, 60 parts of polyvinyl chloride, 30 parts of silicon rubber, 60 parts of epoxy resin, 45 parts of sodium pyrophosphate, 20 parts of stearic acid, oxygen
Change 10 parts of magnesium, 5 parts of calcium stearate, 6 parts of polyethylene glycol, 5 parts of mica powder, 3 parts of antioxidant A, part, nanometer three of triphenyl phosphite 6
5.5 parts of aluminum oxide, 3.5 parts of 3- aminopropyl trimethoxysilanes, 3 parts of altax, 4.5 parts of zinc stearate, PCDL
4.5 parts, 5 parts of hydroxy terminated fluorosilicone oil, 4 parts of ATBC, 6 parts of bauxite powder, 3 parts of calcinated argil, 4 parts of agstone, hydroxyl second
3 parts of base cellulose, 6 parts of fire resisting modified filler.
Fire resisting modified filler is prepared by following technique：By weight by 10 parts of magnesium hydroxides, 6 parts of nano aluminum nitrides, 4
Part flake asbestos and 3.5 parts of hydrazine hydrates are well mixed, and 11h are stirred in 70 DEG C, are then added 3 parts of carboxylic acrylonitrile butadiene rubber latexs and are well mixed,
3h is stirred under 6000r/min rotating speeds, then heats to 95 DEG C, is incubated 1h, then adds in 4.5 parts of aluminum sulfate and condenses, then
After being cleaned with deionized water, filter, be placed in 50 DEG C of baking oven and dry 2.5h, be cooled to room temperature and obtain material a；By 3.5 parts of second
Alkene-vinyl acetate, 3 parts of polyolefin elastomers, 4.5 parts of cumyl peroxides, 3 parts of cetyl trimethylammonium bromides and 5
Part silane coupler KH-560 is well mixed, and is heated to 85 DEG C, is incubated 15min, is subsequently added into material a, is heated to 110 DEG C, takes out
Filter, dry, be cooled to room temperature and obtain fire resisting modified filler.
A kind of preparation method of the environment-friendly type of the present invention without magnetic armouring charging pile with fire-resisting cable material, comprises the following steps：
S1, by phenolic resin, polyvinyl chloride, silicon rubber, epoxy resin, sodium pyrophosphate, stearic acid, magnesia, stearic acid
Calcium, polyethylene glycol, mica powder, antioxidant A, triphenyl phosphite, nanometer alchlor, 3- aminopropyl trimethoxysilanes, rush
Enter agent DM, zinc stearate, PCDL, hydroxy terminated fluorosilicone oil, ATBC, bauxite powder, calcinated argil, lime stone
Powder, hydroxyethyl cellulose and fire resisting modified filler are added in high-speed mixer, and double screw extruder extrusion is put into after being well mixed
It is granulated, the temperature of extruding pelletization is 135 DEG C；
S2, it will be mixed in material input high-speed mixer made from S1；Double screw extruder is put into after well mixed
Extruding pelletization, 150 DEG C of the temperature of extruding pelletization, pellet produce environment-friendly type after drying, screening, packaging and used without magnetic armouring charging pile
Fire-resisting cable material.
Embodiment 2
A kind of environment-friendly type proposed by the present invention includes by weight without magnetic armouring charging pile fire-resisting cable material, its raw material：
80 parts of phenolic resin, 90 parts of polyvinyl chloride, 20 parts of silicon rubber, 80 parts of epoxy resin, 30 parts of sodium pyrophosphate, 30 parts of stearic acid, oxygen
Change 5 parts of magnesium, 8 parts of calcium stearate, 3 parts of polyethylene glycol, 8 parts of mica powder, 1 part of antioxidant A, part, nanometer three of triphenyl phosphite 8
2 parts of aluminum oxide, 5 parts of 3- aminopropyl trimethoxysilanes, 2 parts of altax, 6 parts of zinc stearate, 1 part of PCDL, hydroxyl
8 parts of base fluorosilicon oil, 3 parts of ATBC, 8 parts of bauxite powder, 1 part of calcinated argil, 6 parts of agstone, hydroxyethyl cellulose 1
Part, 8 parts of fire resisting modified filler.
Fire resisting modified filler is prepared by following technique：By weight by 5 parts of magnesium hydroxides, 8 parts of nano aluminum nitrides, 3
Part flake asbestos and 5 parts of hydrazine hydrates are well mixed, and 12h are stirred in 65 DEG C, are then added 1 part of carboxylic acrylonitrile butadiene rubber latex and are well mixed, in
2h is stirred under 6500r/min rotating speeds, then heats to 100 DEG C, is incubated 0.5h, then adds in 6 parts of aluminum sulfate and condenses, then use
After deionized water cleaning, filter, be placed in 45 DEG C of baking oven and dry 4h, be cooled to room temperature and obtain material a；By 2 parts of ethylene-acetates
Vinyl acetate, 5 parts of polyolefin elastomers, 3 parts of cumyl peroxides, 5 parts of cetyl trimethylammonium bromides and 2 parts are silane coupled
Agent KH-560 is well mixed, and is heated to 90 DEG C, is incubated 10min, is subsequently added into material a, is heated to 115 DEG C, is filtered, and is dried, cold
But fire resisting modified filler is obtained to room temperature.
A kind of preparation method of the environment-friendly type of the present invention without magnetic armouring charging pile with fire-resisting cable material, comprises the following steps：
S1, by phenolic resin, polyvinyl chloride, silicon rubber, epoxy resin, sodium pyrophosphate, stearic acid, magnesia, stearic acid
Calcium, polyethylene glycol, mica powder, antioxidant A, triphenyl phosphite, nanometer alchlor, 3- aminopropyl trimethoxysilanes, rush
Enter agent DM, zinc stearate, PCDL, hydroxy terminated fluorosilicone oil, ATBC, bauxite powder, calcinated argil, lime stone
Powder, hydroxyethyl cellulose and fire resisting modified filler are added in high-speed mixer, and double screw extruder extrusion is put into after being well mixed
It is granulated, the temperature of extruding pelletization is 120 DEG C；
S2, it will be mixed in material input high-speed mixer made from S1；Double screw extruder is put into after well mixed
Extruding pelletization, 160 DEG C of the temperature of extruding pelletization, pellet produce environment-friendly type after drying, screening, packaging and used without magnetic armouring charging pile
Fire-resisting cable material.
Embodiment 3
A kind of environment-friendly type proposed by the present invention includes by weight without magnetic armouring charging pile fire-resisting cable material, its raw material：
120 parts of phenolic resin, 30 parts of polyvinyl chloride, 40 parts of silicon rubber, 40 parts of epoxy resin, 60 parts of sodium pyrophosphate, 10 parts of stearic acid, oxygen
Change 15 parts of magnesium, 2 parts of calcium stearate, 9 parts of polyethylene glycol, 2 parts of mica powder, 5 parts of antioxidant A, part, nanometer three of triphenyl phosphite 4
9 parts of aluminum oxide, 2 parts of 3- aminopropyl trimethoxysilanes, 4 parts of altax, 3 parts of zinc stearate, 8 parts of PCDL, hydroxyl
2 parts of base fluorosilicon oil, 5 parts of ATBC, 4 parts of bauxite powder, 5 parts of calcinated argil, 2 parts of agstone, hydroxyethyl cellulose 5
Part, 4 parts of fire resisting modified filler.
Fire resisting modified filler is prepared by following technique：By weight by 15 parts of magnesium hydroxides, 4 parts of nano aluminum nitrides, 5
Part flake asbestos and 2 parts of hydrazine hydrates are well mixed, and 10h are stirred in 75 DEG C, are then added 5 parts of carboxylic acrylonitrile butadiene rubber latexs and are well mixed, in
4h is stirred under 5500r/min rotating speeds, then heats to 90 DEG C, is incubated 1.5h, then adds in 3 parts of aluminum sulfate and condenses, then use
After deionized water cleaning, filter, be placed in 55 DEG C of baking oven and dry 1h, be cooled to room temperature and obtain material a；By 5 parts of ethylene-acetates
Vinyl acetate, 1 part of polyolefin elastomer, 6 parts of cumyl peroxides, 1 part of cetyl trimethylammonium bromide and 8 parts are silane coupled
Agent KH-560 is well mixed, and is heated to 80 DEG C, is incubated 20min, is subsequently added into material a, is heated to 105 DEG C, is filtered, and is dried, cold
But fire resisting modified filler is obtained to room temperature.
A kind of preparation method of the environment-friendly type of the present invention without magnetic armouring charging pile with fire-resisting cable material, comprises the following steps：
S1, by phenolic resin, polyvinyl chloride, silicon rubber, epoxy resin, sodium pyrophosphate, stearic acid, magnesia, stearic acid
Calcium, polyethylene glycol, mica powder, antioxidant A, triphenyl phosphite, nanometer alchlor, 3- aminopropyl trimethoxysilanes, rush
Enter agent DM, zinc stearate, PCDL, hydroxy terminated fluorosilicone oil, ATBC, bauxite powder, calcinated argil, lime stone
Powder, hydroxyethyl cellulose and fire resisting modified filler are added in high-speed mixer, and double screw extruder extrusion is put into after being well mixed
It is granulated, the temperature of extruding pelletization is 150 DEG C；
S2, it will be mixed in material input high-speed mixer made from S1；Double screw extruder is put into after well mixed
Extruding pelletization, 140 DEG C of the temperature of extruding pelletization, pellet produce environment-friendly type after drying, screening, packaging and used without magnetic armouring charging pile
Fire-resisting cable material.
Embodiment 4
A kind of environment-friendly type proposed by the present invention includes by weight without magnetic armouring charging pile fire-resisting cable material, its raw material：
85 parts of phenolic resin, 85 parts of polyvinyl chloride, 25 parts of silicon rubber, 75 parts of epoxy resin, 35 parts of sodium pyrophosphate, 25 parts of stearic acid, oxygen
Change 8 parts of magnesium, 7 parts of calcium stearate, 4 parts of polyethylene glycol, 7 parts of mica powder, 2 parts of antioxidant A, part, nanometer three of triphenyl phosphite 7
3 parts of aluminum oxide, 4 parts of 3- aminopropyl trimethoxysilanes, 2.5 parts of altax, 5 parts of zinc stearate, 2 parts of PCDL,
7 parts of hydroxy terminated fluorosilicone oil, 3.5 parts of ATBC, 7 parts of bauxite powder, 2 parts of calcinated argil, 5 parts of agstone, ethoxy are fine
Dimension plain 2 parts, 7 parts of fire resisting modified filler.
Fire resisting modified filler is prepared by following technique：By weight by 8 parts of magnesium hydroxides, 7 parts of nano aluminum nitrides,
3.5 parts of flake asbestos and 4 parts of hydrazine hydrates are well mixed, and 11.5h is stirred in 68 DEG C, and it is equal then to add 2 parts of carboxylic acrylonitrile butadiene rubber latex mixing
It is even, 2.5h is stirred under 6200r/min rotating speeds, then heats to 98 DEG C, is incubated 0.8h, then adds in 5 parts of aluminum sulfate and condenses,
Then after being cleaned with deionized water, filter, be placed in 48 DEG C of baking oven and dry 3h, be cooled to room temperature and obtain material a；By 3 parts of second
Alkene-vinyl acetate, 4 parts of polyolefin elastomers, 4 parts of cumyl peroxides, 4 parts of cetyl trimethylammonium bromides and 3 parts
Silane coupler KH-560 is well mixed, and is heated to 88 DEG C, is incubated 12min, is subsequently added into material a, is heated to 112 DEG C, is filtered,
Dry, be cooled to room temperature and obtain fire resisting modified filler.
A kind of preparation method of the environment-friendly type of the present invention without magnetic armouring charging pile with fire-resisting cable material, comprises the following steps：
S1, by phenolic resin, polyvinyl chloride, silicon rubber, epoxy resin, sodium pyrophosphate, stearic acid, magnesia, stearic acid
Calcium, polyethylene glycol, mica powder, antioxidant A, triphenyl phosphite, nanometer alchlor, 3- aminopropyl trimethoxysilanes, rush
Enter agent DM, zinc stearate, PCDL, hydroxy terminated fluorosilicone oil, ATBC, bauxite powder, calcinated argil, lime stone
Powder, hydroxyethyl cellulose and fire resisting modified filler are added in high-speed mixer, and double screw extruder extrusion is put into after being well mixed
It is granulated, the temperature of extruding pelletization is 125 DEG C；
S2, it will be mixed in material input high-speed mixer made from S1；Double screw extruder is put into after well mixed
Extruding pelletization, the temperature of extruding pelletization is 155 DEG C, and pellet produces environment-friendly type without magnetic armouring charging pile after drying, screening, packaging
With fire-resisting cable material.
Embodiment 5
A kind of environment-friendly type proposed by the present invention includes by weight without magnetic armouring charging pile fire-resisting cable material, its raw material：
115 parts of phenolic resin, 35 parts of polyvinyl chloride, 35 parts of silicon rubber, 45 parts of epoxy resin, 55 parts of sodium pyrophosphate, 15 parts of stearic acid, oxygen
Change 12 parts of magnesium, 3 parts of calcium stearate, 8 parts of polyethylene glycol, 3 parts of mica powder, 4 parts of antioxidant A, part, nanometer three of triphenyl phosphite 5
8 parts of aluminum oxide, 3 parts of 3- aminopropyl trimethoxysilanes, 3.5 parts of altax, 4 parts of zinc stearate, 7 parts of PCDL,
3 parts of hydroxy terminated fluorosilicone oil, 4.5 parts of ATBC, 5 parts of bauxite powder, 4 parts of calcinated argil, 3 parts of agstone, ethoxy are fine
Dimension plain 4 parts, 5 parts of fire resisting modified filler.
Fire resisting modified filler is prepared by following technique：By weight by 12 parts of magnesium hydroxides, 5 parts of nano aluminum nitrides,
4.5 parts of flake asbestos and 3 parts of hydrazine hydrates are well mixed, and 10.5h is stirred in 72 DEG C, and it is equal then to add 4 parts of carboxylic acrylonitrile butadiene rubber latex mixing
It is even, 3.5h is stirred under 5800r/min rotating speeds, then heats to 92 DEG C, is incubated 1.2h, then adds in 4 parts of aluminum sulfate and condenses,
Then after being cleaned with deionized water, filter, be placed in 52 DEG C of baking oven and dry 2h, be cooled to room temperature and obtain material a；By 4 parts of second
Alkene-vinyl acetate, 2 parts of polyolefin elastomers, 5 parts of cumyl peroxides, 2 parts of cetyl trimethylammonium bromides and 7 parts
Silane coupler KH-560 is well mixed, and is heated to 82 DEG C, is incubated 18min, is subsequently added into material a, is heated to 108 DEG C, is filtered,
Dry, be cooled to room temperature and obtain fire resisting modified filler.
A kind of preparation method of the environment-friendly type of the present invention without magnetic armouring charging pile with fire-resisting cable material, comprises the following steps：
S1, by phenolic resin, polyvinyl chloride, silicon rubber, epoxy resin, sodium pyrophosphate, stearic acid, magnesia, stearic acid
Calcium, polyethylene glycol, mica powder, antioxidant A, triphenyl phosphite, nanometer alchlor, 3- aminopropyl trimethoxysilanes, rush
Enter agent DM, zinc stearate, PCDL, hydroxy terminated fluorosilicone oil, ATBC, bauxite powder, calcinated argil, lime stone
Powder, hydroxyethyl cellulose and fire resisting modified filler are added in high-speed mixer, and double screw extruder extrusion is put into after being well mixed
It is granulated, the temperature of extruding pelletization is 145 DEG C；
S2, it will be mixed in material input high-speed mixer made from S1；Double screw extruder is put into after well mixed
Extruding pelletization, 145 DEG C of the temperature of extruding pelletization, pellet produce environment-friendly type after drying, screening, packaging and used without magnetic armouring charging pile
Fire-resisting cable material.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of environment-friendly type is without magnetic armouring charging pile fire-resisting cable material, it is characterised in that its raw material includes by weight：Phenolic aldehyde
It is resin 80-120 parts, polyvinyl chloride 30-90 parts, silicon rubber 20-40 parts, epoxy resin 40-80 parts, sodium pyrophosphate 30-60 parts, hard
Resin acid 10-30 parts, magnesia 5-15 parts, calcium stearate 2-8 parts, polyethylene glycol 3-9 parts, mica powder 2-8 parts, antioxidant A 1-5
Part, triphenyl phosphite 4-8 parts, nanometer alchlor 2-9 parts, 3- aminopropyl trimethoxysilane 2-5 parts, altax 2-4
Part, zinc stearate 3-6 parts, PCDL 1-8 parts, hydroxy terminated fluorosilicone oil 2-8 parts, ATBC 3-5 parts, bauxite powder
4-8 parts, calcinated argil 1-5 parts, agstone 2-6 parts, hydroxyethyl cellulose 1-5 parts, fire resisting modified filler 4-8 parts.
2. environment-friendly type according to claim 1 is without magnetic armouring charging pile fire-resisting cable material, it is characterised in that fire resisting is modified
The raw material of filler includes by weight：Magnesium hydroxide 5-15 parts, nano aluminum nitride 4-8 parts, flake asbestos 3-5 parts, hydrazine hydrate 2-5
Part, carboxylic acrylonitrile butadiene rubber latex 1-5 parts, aluminum sulfate 3-6 parts, ethane-acetic acid ethyenyl ester 2-5 parts, polyolefin elastomer 1-5 parts, peroxide
Change diisopropylbenzene (DIPB) 3-6 parts, cetyl trimethylammonium bromide 1-5 parts, silane coupler KH-560 2-8 parts.
3. environment-friendly type according to claim 1 or 2 is without magnetic armouring charging pile fire-resisting cable material, it is characterised in that fire resisting
Modified filler is prepared by following technique：Magnesium hydroxide, nano aluminum nitride, flake asbestos and hydrazine hydrate are well mixed, stirred,
Then add carboxylic acrylonitrile butadiene rubber latex to be well mixed, stir, then heat up, be incubated, then add in aluminum sulfate and condense, then spend
After ionized water cleaning, filter, be placed in baking oven and dry, be cooled to room temperature and obtain material a；By ethane-acetic acid ethyenyl ester, polyolefin
Elastomer, cumyl peroxide, cetyl trimethylammonium bromide and silane coupler KH-560 are well mixed, and are heated, and are protected
Temperature, material a is subsequently added into, heated, filtered, dried, be cooled to room temperature and obtain fire resisting modified filler.
4. the environment-friendly type according to claim any one of 1-3 is without magnetic armouring charging pile fire-resisting cable material, it is characterised in that
Fire resisting modified filler is prepared by following technique：Magnesium hydroxide, nano aluminum nitride, flake asbestos and hydrazine hydrate are well mixed,
10-12h is stirred in 65-75 DEG C, carboxylic acrylonitrile butadiene rubber latex is then added and is well mixed, 2- is stirred under 5500-6500r/min rotating speeds
4h, 90-100 DEG C is then heated to, be incubated 0.5-1.5h, then added in aluminum sulfate and condense, after then being cleaned with deionized water,
Filter, be placed in 45-55 DEG C of baking oven and dry 1-4h, be cooled to room temperature and obtain material a；By ethane-acetic acid ethyenyl ester, polyolefin
Elastomer, cumyl peroxide, cetyl trimethylammonium bromide and silane coupler KH-560 are well mixed, and are heated to
80-90 DEG C, be incubated 10-20min, be subsequently added into material a, be heated to 105-115 DEG C, filter, dry, be cooled to room temperature obtain it is resistance to
Fiery modified filler.
A kind of 5. preparation side of environment-friendly type according to claim any one of 1-4 without magnetic armouring charging pile fire-resisting cable material
Method, it is characterised in that comprise the following steps：
S1, by phenolic resin, polyvinyl chloride, silicon rubber, epoxy resin, sodium pyrophosphate, stearic acid, magnesia, calcium stearate, poly-
Ethylene glycol, mica powder, antioxidant A, triphenyl phosphite, nanometer alchlor, 3- aminopropyl trimethoxysilanes, accelerator
DM, zinc stearate, PCDL, hydroxy terminated fluorosilicone oil, ATBC, bauxite powder, calcinated argil, agstone,
Hydroxyethyl cellulose and fire resisting modified filler are added in high-speed mixer, and double screw extruder extrusion is put into after well mixed and is made
Grain；
S2, it will be mixed in material input high-speed mixer made from S1；Double screw extruder extrusion is put into after well mixed
It is granulated, pellet produces environment-friendly type without magnetic armouring charging pile fire-resisting cable material after drying, screening, packaging.
6. preparation method of the environment-friendly type according to claim 5 without magnetic armouring charging pile with fire-resisting cable material, its feature exist
In in S, the temperature of the extruding pelletization of double screw extruder is 120-150 DEG C.
7. preparation method of the environment-friendly type according to claim 5 or 6 without magnetic armouring charging pile with fire-resisting cable material, its feature
It is, in S2,140-160 DEG C of the temperature of the extruding pelletization of double screw extruder.
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Cited By (1)
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| CN110358248A (en) * | 2019-05-27 | 2019-10-22 | 扬州曙光电缆股份有限公司 | Rail traffic vehicles high-performance environment protection type DC traction cable |
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