CN107427180B - Floor cleaning articles having strips with differential bonding patterns - Google Patents
Floor cleaning articles having strips with differential bonding patterns Download PDFInfo
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- CN107427180B CN107427180B CN201680015721.7A CN201680015721A CN107427180B CN 107427180 B CN107427180 B CN 107427180B CN 201680015721 A CN201680015721 A CN 201680015721A CN 107427180 B CN107427180 B CN 107427180B
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/20—Mops
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Abstract
Description
技术领域technical field
本发明涉及清洁制品,更具体地讲涉及用于从目标表面吸收清洁流体的清洁制品。The present invention relates to cleaning articles, and more particularly to cleaning articles for absorbing cleaning fluids from a target surface.
背景技术Background technique
人们已创造出了各种清洁制品,用于除尘和轻微的清洁。例如,已在相对平坦的表面(诸如厨房的工作台面、浴室、水槽和地板)上使用了干燥的、或用抛光和清洁组合物润湿过的布质抹布和纸巾。但抹布和纸巾会由于如下方面的原因而产生问题:诸如卫生性(使用者的手在清洁期间可能接触到化学品、污垢或表面)、作用范围(使用者可能难以将拿有抹布或纸巾的手伸入到难以触及的位置)和不方便性(在间隙很小的制品之间进行清洁通常需要移动制品)。Various cleaning products have been created for dusting and light cleaning. For example, cloth rags and paper towels, dry or moistened with polishing and cleaning compositions, have been used on relatively flat surfaces such as kitchen countertops, bathrooms, sinks, and floors. But wipes and paper towels can be problematic for reasons such as hygiene (the user's hands may come into contact with chemicals, dirt or surfaces during cleaning), reach (the user may have difficulty removing the wipes or paper towels reaching into hard-to-reach places) and inconvenience (cleaning between articles with tight clearances often requires moving the articles).
为克服与使用抹布和纸巾相关联的问题,各种可重复使用的集尘装置已被利用了多于一个世纪,其使用毡和毛发,如由1906年授予Hayden的US 823,725所示的,和使用纱线,如4,145,787中所示的。为了解决可重复使用的集尘装置所具有的问题,已开发出了具有有限的可重复使用性的一次性清洁制品。这些一次性清洁制品可包括附接到片材上的由合成纤维束(被称为丝束纤维)制成的刷部分,如下列专利中所示:6,813,801、7,003,856、7,566,671、7,779,502、7,937,797、8,146,197、8,151,402、8,161,594、8,186,001、8,245,349、8,528,151、8,756,746和8,763,197。To overcome the problems associated with the use of wipes and paper towels, various reusable dust collection devices have been used for over a century using felt and hair, as shown by US 823,725 to Hayden in 1906, and Use yarn as shown in 4,145,787. To address the problems associated with reusable dust collection devices, disposable cleaning articles with limited reusability have been developed. These disposable cleaning articles may include a brush portion made of synthetic fiber bundles (referred to as tow fibers) attached to a sheet, as shown in the following patents: 6,813,801, 7,003,856, 7,566,671, 7,779,502, 7,937,797, 8,146,197 , 8,151,402, 8,161,594, 8,186,001, 8,245,349, 8,528,151, 8,756,746 and 8,763,197.
一次性除尘器可提供湿清洁,如7,566,671,和共同转让的7,803,726,以及共同转让的US 2008/0028560中所公开的。但丝束纤维可在湿润时变得缠结,并且不适用于清洁大的或者重度润湿的表面,诸如地板。Disposable dust collectors can provide wet cleaning as disclosed in 7,566,671, and commonly assigned 7,803,726, and commonly assigned US 2008/0028560. But tow fibers can become tangled when wet and are not suitable for cleaning large or heavily wet surfaces, such as floors.
为克服大的和/或重度润湿的表面的问题,已经开发了地板片材。所述地板片材可包含大量吸收性纤维素,如7,191,486和7,721,381中所公开的,并且可包括至少两个内部片材,如9,032,577中所公开的。地板片材可包含AGM以进一步辅助液体吸收和保留,如共同转让的5,960,508、6,003,191、6,048,123和6,766,552中所公开的。制备清洁垫的其它尝试结合了疏水性和亲水性特性两者,如7,694,379(共同转让的7,480,956)中所公开的。另一尝试包括自由漂浮的箍,如共同转让的7,028,364中所公开的。本领域的其它相关尝试包括US 2003/0300991、2011/0041274、6,245,413、6,681,434、6,701,567、7,458,128、7,624,468、8,341,797、8,707,505和8,863,347。To overcome the problem of large and/or heavily wetted surfaces, floor sheets have been developed. The floor sheet may contain substantial amounts of absorbent cellulose, as disclosed in 7,191,486 and 7,721,381, and may include at least two inner sheets, as disclosed in 9,032,577. Floor sheets may contain AGM to further aid in liquid absorption and retention, as disclosed in commonly assigned 5,960,508, 6,003,191, 6,048,123 and 6,766,552. Other attempts to make cleaning pads have combined both hydrophobic and hydrophilic properties, as disclosed in 7,694,379 (commonly assigned 7,480,956). Another attempt has included free-floating hoops, as disclosed in commonly assigned 7,028,364. Other related attempts in the field include US 2003/0300991, 2011/0041274, 6,245,413, 6,681,434, 6,701,567, 7,458,128, 7,624,468, 8,341,797, 8,707,505 and 8,863,347.
虽然这些尝试涉及从润湿的目标表面,具体地讲地板中吸收液体,但仍然具有问题。大致平坦的地板片材对整个清洁任务呈现相同表面。污垢可从饱和的地板片材重新沉积。并且大致平坦的地板片材可不充分清洁到地板裂缝或灌浆线中。While these attempts have involved absorbing liquid from a wet target surface, specifically a floor, problems remain. A substantially flat floor sheet presents the same surface for the entire cleaning task. Dirt can redeposit from saturated floor sheets. And generally flat floor sheets may not adequately clean into floor cracks or grout lines.
因此,需要清洁制品,其可用于润湿的表面并且在整个清洁任务中呈现动态变化的表面。Therefore, there is a need for cleaning articles that can be used on wetted surfaces and that exhibit dynamically changing surfaces throughout the cleaning task.
发明内容SUMMARY OF THE INVENTION
本发明包括清洁制品,该清洁制品具有层合构造。清洁制品包括片材和亲水性收集条元件,该亲水性收集条元件具有条并且在细长粘结部处接合到片材。收集条元件包括邻近片材的至少第一层和设置在其外侧的至少一个向外层。层中的每个层通过细长共同粘结部接合到片材。至少一个层还通过第二粘结部接合到片材,该第二粘结部不与共同粘结部一致并与该共同粘结部间隔开,并且至少一个层不通过第二粘结部接合到片材。The present invention includes cleaning articles having a laminated construction. The cleaning article includes a sheet and a hydrophilic collection strip element having a strip and joined to the sheet at an elongated bond. The collection bar element includes at least a first layer adjacent to the sheet material and at least one outward layer disposed on its outer side. Each of the layers is joined to the sheet by an elongated co-bond. At least one layer is also joined to the sheet by a second bond that is not coincident with and spaced from the common bond, and at least one layer is not joined by the second bond to the sheet.
附图说明Description of drawings
图1为根据本发明的清洁制品的分解透视图。Figure 1 is an exploded perspective view of a cleaning article according to the present invention.
图2A为按比例缩放的,并且为沿图1的线2-2截取的垂直截面图。FIG. 2A is to scale and is a vertical cross-sectional view taken along line 2-2 of FIG. 1 .
图2B为具有倒锥体几何形状的另选的实施方案的垂直截面图。2B is a vertical cross-sectional view of an alternate embodiment having an inverted pyramid geometry.
图3为具有非直线中间粘结线和倒锥体几何形状的另选实施方案的断开的底部平面视图,其中上部具有正弦形粘结部并且下部具有点状粘结部。Figure 3 is a broken-down bottom plan view of an alternative embodiment with a non-linear intermediate bond line and an inverted pyramid geometry, wherein the upper portion has a sinusoidal bond and the lower portion has a point bond.
图4A为具有两个中间粘结线的另选实施方案的底部平面视图。Figure 4A is a bottom plan view of an alternate embodiment with two intermediate bond lines.
图4B为沿图4A的线4B–4B截取的垂直截面图。4B is a vertical cross-sectional view taken along
图5A–5G为按比例缩放的,并且是收集条元件的另选实施方案的垂直截面图,所述收集条元件各自具有材料的两个片材。5A-5G are to scale and are vertical cross-sectional views of alternative embodiments of collector bar elements each having two sheets of material.
图6为可用于本发明的柄部的透视图。Figure 6 is a perspective view of a handle that can be used in the present invention.
图7为可用于本发明的地板清洁工具的透视图。Figure 7 is a perspective view of a floor cleaning tool that can be used with the present invention.
图8为根据本发明的地板片材和可商购获得的地板片材的性能的图示。Figure 8 is a graphical representation of the properties of a floor sheet according to the present invention and a commercially available floor sheet.
具体实施方式Detailed ways
参见图1,清洁制品10可以为大致细长的和矩形的,尽管其它形状是可设想的并且可行的。清洁制品10可包括两个或更多个部件,所述部件以层合体形式接合以提供适用于地板清洁的清洁制品10。清洁制品可具有片材12,所述片材形成用于将其它部件附接到其上的框架。清洁制品10还可具有收集条元件25,所述收集条元件具有堆叠的向外延伸的柔性条17的多个层27。吸收芯可设置在收集条元件25和片材12之间。Referring to Figure 1, the
清洁制品10可以为一次性的。所谓一次性的,是指清洁制品10用于一个清洁任务,或者一般不超过数平方米,然后丢弃。相比之下,可重复使用的清洁制品10在使用之后洗涤或以其它方式恢复。The
清洁制品10具有至少两个,更优选地至少三个,四个或更多个薄层,其以层合体形式接合/折叠清洁制品10。片材12还可提供对地板清洁工具的附接,如下文所述。如本文所用,除非另有说明,接合包括两个部件之间的直接接触关系以及两者间具有中间部件的关系。The cleaning
清洁制品10可具有纵向轴线LA和与其正交的横向轴线TA。清洁制品10及其相应的部件可具有平行于纵向轴线LA的两个纵向边缘20以及平行于横向轴线TA的两个横向边缘22。The
如下文所述,条17可有利地基本上,或优选地完全容纳在片材12的占有面积内。具体地讲,条17的远端可容纳在占有面积内并由所述占有面积限定,所述占有面积由片材12的两个纵向边缘20和两个横向边缘22限定。据信该布置促进条17在使用时的移动性,并且在使用时对目标表面呈现清洁制品10的动态表面积,这是由于当使用者将清洁工具压向地板时条17所遭遇的直接压力。The
清洁制品10的长度在纵向上获取。清洁制品10的宽度对应于垂直于长度方向且设置在片材12的平面内的横向。厚度被定义为z方向上的尺度。XY平面被定义为由清洁制品10限定的平面。清洁制品10的Z方向为垂直于片材平面的方向。清洁制品10可具有20至50cm的长度和10至20cm的宽度。清洁制品可具体地为30+/-2cm长乘以14+/-2cm宽,如在最大尺寸处所测量的,以便贴合典型的清洁工具70的头部,如下文所讨论的。任选的芯可具体地具有6.5+/-2cm的宽度和26+/-2cm的长度。当然,本领域技术人员将认识到其它形状是可行的并在本发明的范围内。The length of the cleaning
清洁制品10可具有面向外的清洁侧面和与其相对的附接位点。清洁制品10的附接位点可具有用于附接到工具的头部的一个或多个附接条30,例如如图所示的两个平行条30。所述条30可包括环材料,所述环材料适用于互补附接到具有钩的清洁工具的头部。The cleaning
清洁制品10可以被看作具有一个薄层或具有以面对面关系接合的两个、三个或更多个薄层。薄层可以蛇形方式重新折叠以在Z方向提供多个薄层。The cleaning
更具体地讲,清洁制品可包括至少一个片材12和至少一个收集条元件25的构造。片材12和收集条元件25利用至少一个永久性粘结部以面对面关系接合以形成层合体。More specifically, the cleaning article may include a configuration of at least one
片材12可用作用于将收集条元件25附接到其上的基础结构。其它薄层和特征结构可插入片材12和收集条元件25之间,但不背离本发明。The
具体地讲,片材12可包括合成非织造片材12。具有合成纤维的片材12提供了收集条元件25对其的便利的接合。非织造物包括纺粘、梳理成网和气流成网材料,如本领域中已知的并由合成纤维制成。合适的非织造片材可根据共同转让的6,797,357进行制造。Specifically,
优选地,片材12包括纤维素,以提供吸收容量。纤维素片材12可具有添加于其上的永久性湿强度树脂,如本领域中已知的。或者片材12可优选地包括纤维素和合成纤维的混合物,以提供吸收性和阻隔特性,并且提供收集条元件25的方便接合。所谓纤维素,是指组分占纤维素纤维的主要重量百分比。Preferably,
片材12和/或收集条元件25可以为亲水性的,以从被清洁表面有利地吸收水。所谓亲水性,一般是指组分将在使用时吸收水并在普通使用时保留此类水,但不施用过量压缩力。The
具体地讲,亲水性对疏水性特性可如下测量。将1克材料样品在约110℃下烘箱干燥12小时,然后在65%相对湿度/21℃下调理五天。然后将样品在110℃下重新干燥12小时。湿度增加量被测量为回潮率的百分比:Specifically, hydrophilic versus hydrophobic properties can be measured as follows. A 1 gram sample of material was oven dried at about 110°C for 12 hours and then conditioned for five days at 65% relative humidity/21°C. The samples were then re-dried at 110°C for 12 hours. Moisture gain is measured as a percentage of moisture regain:
回潮率=[(在65%RH下的调理样品总重量-干燥后的样品重量)÷干燥的样品重量]×100%。Moisture regain = [(total weight of conditioned sample at 65% RH - weight of sample after drying) ÷ weight of dried sample] x 100%.
如本文所用,亲水性材料具有在65%下,大于约2%、3%、4%、5%和优选地大于约6%的回潮率。下表1示出在65%RH中在平衡下,不同纤维类型的回潮率%的比较结果。As used herein, a hydrophilic material has a moisture regain at 65% greater than about 2%, 3%, 4%, 5%, and preferably greater than about 6%. Table 1 below shows the comparative results of the % moisture regain for different fiber types at equilibrium in 65% RH.
表1: Table 1 :
回潮率(百分比)Moisture regain (percentage)
虽然亲水性材料可用于本文所述的本发明,但此类材料可不具有用于甚至一次性清洁制品10中的足够的强度。因此,选择适当的材料是重要的。While hydrophilic materials may be used in the invention described herein, such materials may not have sufficient strength to be used even in
例如,如果收集条17为100%纤维素,则湿摩擦系数可太大使得使用者难以在特定目标表面上移动清洁制品10。通过混合不同材料,可保持用于污垢收集的表面积同时优化湿摩擦系数。同样,使用不同长度的收集条17,即使使用相同材料,也可增加清洁表面积但不过度增加湿摩擦系数,从而提供目标表面上的移动容易性。For example, if the
参见图2A和2B,片材12可包括两个、三个或更多个层片的层合体。具体地讲,层合体可包括三个层片,用于与清洁工具接触的面向外的层片12A,用于吸收的中间层片/芯12B,和用于接合到收集条元件25的面向内的层片12C。Referring to Figures 2A and 2B,
面向外的层片12A可包括具有20至80gsm的基重的水刺法纺粘非织造物。已经发现得自Avgol Nonwovens(Tel-Aviv,Israel)的45gsm非织造物是合适的。如本文所用,非织造物为具有不编织在一起的气流成网和/或湿法成网纤维的混合物的部件。The outward facing ply 12A may comprise a hydroentangled spunbond nonwoven having a basis weight of 20 to 80 gsm. A 45 gsm nonwoven from Avgol Nonwovens (Tel-Aviv, Israel) has been found to be suitable. As used herein, a nonwoven is a component having a mixture of air-laid and/or wet-laid fibers that are not woven together.
中间层片/芯12B可用作储存容器,以吸收并保留由收集条元件25从目标表面收集的液体。中间层片/芯12B可包括双组分纤维/合成气流成网。购自Suominen(Helsinki,Finland)的包含85:15纤维素:双组分纤维的135gsm气流成网是合适的。The interlayer sheet/
中间层片/芯12B还可包括吸收胶凝材料[AGM],如本领域中已知的。AGM可增加吸收的液体的保留,并且提供清洁制品10的增加的容量。清洁制品10可不含泡沫,以节约成本。The intermediate layer sheet/
面向内的层片12C可包括形成为组织的湿法成网纤维的混合物,所述组织使用诸如水刺或水刺法的方法粘结到合成非织造物上。面向内的层片12C可包括具有17gsm聚丙烯纺粘物的23gsm组织作为复合材料,其由Suominen(Helsinki,Finland)以商品名Genesis组织出售。如果需要,可将专用芯12B结合到清洁制品10中。专用芯12B可在片材12的层片12A,12C中的任一个之间或设置在片材12的向内取向的面或向外取向的面上。具体地讲,芯12B可包括中间层片。芯12B和/或附加/另选的中间层片可比面向外的层片12A和面向内的层片12C更窄。芯12B和/或中间层片可以为面向外的层片12A和面向内的层片12C的宽度的约一半,并且中心位于纵向轴线上。具体地讲,芯12B和/或中间层片的宽度可以小于或等于附接材料的条30之间的间距。The inward facing ply 12C may comprise a mixture of wet-laid fibers formed into a tissue that is bonded to a synthetic nonwoven using methods such as hydroentanglement or hydroentanglement. The inward facing ply 12C may comprise as a composite a 23 gsm tissue with 17 gsm polypropylene spunbond, sold under the trade name Genesis tissue by Suominen (Helsinki, Finland). A
芯12B和/或片材12和收集条元件25的宽度如下测量。清洁制品10设置在平坦的水平表面上。使皱纹和对一般平面性的其它破裂平滑。清洁制品通过指尖拉紧。通常购自L.S.Starrett Co.(Athol,MA)的钢尺、游标卡尺或工具制造商的坐标方格用于测量收集条17和芯12B的相对端之间的宽度。根据需要,可移除面向外的层片12A,12C和层27以提供测量的无阻碍通路。The widths of
在平行于横向轴线的横向上测量芯12B的宽度。如果芯12B具有可变宽度,则在最窄点处测量宽度。收集条元件25的宽度也在横向上测量。收集条元件25的宽度在相对设置在纵向轴线上并位于XY平面内的相对收集条17的远端之间测量。如果收集条元件25,并且具体地讲收集条17的相对端具有可变宽度,所述宽度在最宽点处测量。据信在纵向轴线上等分的至少4、6、8、10、12或14cm的宽度差适用于本文所述的实施方案。The width of the core 12B is measured in the transverse direction parallel to the transverse axis. If the
据信相对的收集条17和芯12B之间的宽度差促进芯12B和/或中间层片12B的稳定性,以保留从收集条元件25转移的液体。此外,据信这种几何形状辅助排干吸收液体的收集条17。另外,这种几何形状提供间隙,据信所述间隙促进收集条17的移动,从而在普通使用期间,响应于使用者移动清洁制品10,对目标表面呈现其不同的部分。It is believed that the difference in width between the opposing collection bars 17 and
三个层片12A,12B和12C可使用粘合剂和/或热粘结部永久性接合在一起,如本领域中所已知的,以形成片材12。环材料的任选附接条30可接合到外侧层片12A的面向外的表面以将清洁制品10可移除地接合到柄部60或工具。条30可以为连续的或不连续的。The three
参见图3,清洁制品10还可包括设置在收集条元件25中的亲水性收集条17。如本文所用,收集条17是指从近端向外延伸到对应远端的悬臂条。单独的收集条17可具有在制品10的纵向中心线处或偏离所述纵向中心线的近端,并且具有大于相应宽度(如在纵向上截取的)的长度(在横向上截取),以提供至少1并且任选地2至20,并且任选地5至15的纵横比。收集条17可具有从与粘结部38并置的相应近端到可与清洁制品的横向边缘并置的相应远端截取的,3至15cm、4至12cm或具体地讲5至8cm的长度,和3至20mm、4至15mm或具体地讲6至8mm的宽度。已经发现当使用清洁工具时,这些特定尺寸适用于地板清洁。Referring to FIG. 3 , the cleaning
所述收集条如制造所期望的那样位于XY平面内,尽管可由于在使用之前起毛的缘故和/或由于贴靠目标表面运动的缘故发生在使用期间的变形被变形出XY平面之外。收集条17可被结合到本文所述的片材12之一中或可被部署在单独的片材12上。收集条17可平行于制品的宽度方向延伸,或可以与其呈锐角的关系设置。收集条17可以为直的,如图所示,弯曲的、蛇形或具有任何期望的形状。The collection strip lies within the XY plane as desired for manufacture, although it may be deformed out of the XY plane due to fluff prior to use and/or deformation during use due to movement against the target surface. The
收集条元件25可包括与上文对于面向内的层片12C所述相同的材料,并且具体地讲为亲水性,并且更具体地讲为纤维。收集条元件25和/或片材12可另选地或还包括微纤维,如本领域所已知的。The
重新参见图2A和2B,收集条元件25可包括以蛇形方式折叠回本身的一个或多个层片。该布置提供至少双重、三重或更多重厚度。当层27被切割成大致横向取向的单独收集条时,双重厚度在相应条17的远端处提供环。据信所述环是有利的,因为其有助于将在Z方向上重叠的条17间隔开。Referring back to Figures 2A and 2B, the
折叠构造可由c形折叠完成,如整个图中所示。本领域技术人员将认识到,c形折叠可级联以提供z形折叠、w形折叠或其它多层折叠,如本领域已知的并且包括c形折叠。The folded configuration can be accomplished by a c-fold as shown throughout. Those skilled in the art will recognize that c-folds can be cascaded to provide z-folds, w-folds, or other multilayer folds, as known in the art and including c-folds.
取决于预期目标表面的期望的吸收容量和纹理,收集条元件25可包括2至25个、5至20个,并且另选地约10个层27的收集条17。设置于每个边缘上,具体地纵向边缘上的收集条17可有利地包括在远端处的环和在收集条17的远端处具有单一厚度的游离端,以在清洁期间提供不同响应并且在清洁期间预先达到并保留更多碎屑。Depending on the desired absorbent capacity and texture of the intended target surface, the
具体地讲,据信收集条的差异响应在正常使用条件下在清洁期间对目标表面呈现动态变化的表面积。通过改变表面积,可从目标表面清洁更多液体和相关联的碎屑。Specifically, it is believed that the differential response of the collection strip exhibits a dynamically changing surface area to the target surface during cleaning under normal use conditions. By changing the surface area, more liquid and associated debris can be cleaned from the target surface.
示出了具有三种独立的收集条材料的非限制性收集条元件25。更靠近片材12的上片材折叠到其本身上以提供四个收集条层27。两个下收集条17层27z形折叠到其本身上以各自提供三个收集条层27。A non-limiting
片材12和收集条元件25可通过多个粘结部38接合,如下文所示。粘结部38可以是热粘结部、粘合剂粘结部或超声粘结部等,如本领域所已知的。The
中间粘结部38可接合清洁制品10的全部层27/薄层,以确保整体构造并防止使用时单独部件的损失。中间粘结部38可以对收集条元件25的全部层27是共同的,并且将收集条元件25的每个层27直接或间接地接合到所述片材12。The
可提供两个外侧粘结部38并且仅接合邻近片材12的收集条元件25的层27。就本文所述的实施方案而言,外侧粘结部38可以在中心上横向间隔开至少约7cm,使得外侧粘结部与芯12B向外间隔开并且不与芯12B重叠。如果此类粘结部仅将收集条元件25的层27的一部分直接或间接接合到片材12,则可认为外侧粘结部38或中间粘结部38是第二粘结部38。Two
通常,收集条元件25的所有层27通过至少一个粘结部38接合到片材12。可认为最接近片材12的层27是第一层27。认为后续层27相对邻近片材12,并且可被认为依次为第二层27、第三层27、第四层27等。认为远离片材12并最靠近或接触地板的层27是远侧层27。Typically, all
粘结部38可以与片材12纵向共延或略短于片材12。在稍不优选的实施方案中,外侧粘结部可仅接合远离并且不邻近片材12的收集条元件25的部分。
该布置提供目标表面上的相对较长的收集条17和其内部的较短的收集条。据信,具有不同长度的收集条通过使得收集条17彼此独立地移动并在两者间形成间隔来改善清洁功效。据信收集条17之间的此类间隔,并且具体地讲以重叠层的形式呈现收集条17,在对被清洁表面提供足够的面积方面是重要的,以由清洁制品10有效拾取并保留污垢。因此,所述层27可由单一折叠、多个折叠或通过不具有折叠部的简单叠加来制备。This arrangement provides a relatively
重新参见图3,收集条元件25可使用正弦形粘结部38、锯齿状粘结部38接合到片材,其全部统称为蛇形粘结部38或其它非直线粘结部38。该粘结部38图案提供相对较长和相对较短的单独的收集条17。另外,收集条17各自具有相应的近端,所述近端不平行于纵向轴线。该几何形状提供了近侧端,据信所述近侧端促进收集条在清洁期间扭曲和破裂。Referring back to FIG. 3 , the
另选地,中间粘结部38可包括离散粘结部38的阵列,如共同转让的EP申请序列号15162895.5,P&G案件号13742F中所公开的。预期据信,离散粘结部38促进普通使用期间收集条元件25对目标表面的动态变化呈现。Alternatively, the
据信不同长度的收集条17在使用时对目标表面呈现不同的条17和/或其部分。还据信收集条17的不规则近端在使用时对目标表面呈现不同的条17,或其部分。It is believed that collection strips 17 of different lengths present
一般来讲,通过在使用时对目标表面呈现不同的收集条17和/或收集条17的不同部分,据信清洁制品10的饱和部分与目标表面不保持接触。在使用时呈现收集条元件25的不同部分,使再沉积最小化并使得收集条元件25的不饱和部分接触、吸收并保留来自目标表面的液体。据信通过动态改变接触目标表面的收集条元件25的有效部分,发生改善的清洁。重要的是,除了作为正常清洁的部分的正常前后行程之外,动态改变收集条元件25的有效部分自动发生并且不需要使用者干预。In general, by presenting different collection bars 17 and/or different portions of collection bars 17 to the target surface in use, it is believed that saturated portions of cleaning
优选地,清洁制品不具有丝束纤维。丝束纤维趋于在润湿时缠结并结块,从而降低清洁功效。但是在较不优选的实施方案中,清洁制品还可包括丝束纤维的一个或多个薄层。丝束纤维薄层可以面对面关系接合到片材12或收集条元件25。丝束纤维薄层可适合于并被设置用于在清洁期间直接接触目标表面。另选地,丝束纤维薄层可设置在片材12和收集条元件25之间。Preferably, the cleaning article has no tow fibers. Tow fibers tend to tangle and clump when wet, reducing cleaning efficacy. In less preferred embodiments, however, the cleaning article may also include one or more thin layers of tow fibers. The sheets of tow fibers may be joined to the
丝束纤维可以是合成的。如本文所用,“束纤维”和/或“丝束”是指纤维,所述纤维包含合成聚合物,所述合成聚合物包括聚酯、聚丙烯、聚乙烯,生物衍生的聚合物,诸如聚乳酸、生物聚乙烯、生物聚酯等。丝束纤维还包括来自天然源的纤维,诸如纤维素、乙酸纤维素、亚麻、大麻、黄麻及其制造的混合物,其中单独的纤维是以束形式制成的相对长的股线。束纤维可被定义为具有明显的终点且长度为至少约1cm的任何纤维。丝束纤维可在制品10的横向边缘之间,连续地并在基本上横向上延伸。Tow fibers can be synthetic. As used herein, "tow fibers" and/or "tows" refer to fibers comprising synthetic polymers including polyester, polypropylene, polyethylene, biologically derived polymers such as poly Lactic acid, bio-polyethylene, bio-polyester, etc. Tow fibers also include fibers from natural sources, such as cellulose, cellulose acetate, flax, hemp, jute, and manufactured mixtures thereof, where the individual fibers are relatively long strands made in tow form. A bundle of fibers can be defined as any fiber with a distinct endpoint and a length of at least about 1 cm. The tow fibers may extend continuously and substantially in the transverse direction between the transverse edges of the
一个或多个片材12、收集条元件25、和任选的一个或多个丝束纤维层可通过多个永久性粘结部38接合。粘结部38旨在最小化或防止杂散或脱落的丝束纤维变稀松。一个或多个此类片材12、收集条元件25和一个或多个丝束纤维层可通常在两者间具有或不具有干预构件或部件的情况下直接彼此重叠。One or
一个或多个粘结部38可通过粘合剂粘结、热粘结、超声粘结等形成。在热粘结和超声粘结时,将能量和压缩压力施加到局部粘结38位点。合成片材12和合成丝束纤维在此类局部位点处熔融。在重新冻结时,片材12和丝束纤维的局部材料在此类局部位点处重新冻结在一起,从而形成局部焊接部,其为粘结部38。The one or
如果需要,可由面向外的液体不可透过的阻隔件覆盖片材12。阻隔件防止吸收液体接触使用者的手部、工具等。合适的阻隔件包括LDPE膜,如本领域所已知的。If desired, the
参见图2B,收集条元件25可包括宽度随着接近收集条元件25的远侧边缘而减小的蛇形折叠构件。该几何形状在使用时提供倒椎体构造。此类收集条元件25的构造可提供具有多个宽度的收集条元件25的多个层27。宽度可从第一层27到远侧层27减小,并且具体地讲宽度可从第一层27到远侧层27单调减小。预期据信倒椎体构造有利地在清洁期间对目标表面呈现更多边缘。Referring to FIG. 2B , the
参见图4A-4B,清洁制品可不含将收集条元件25的所有层27接合到片材12的共同粘结部38。相反,第一粘结部38可将一个或多个近侧层27接合到片材12。第二粘结部38可将一个或多个远侧层27接合到近侧层27,但不将远侧层27直接接合到片材。这种布置预期提供以下有益效果:如果清洁制品10在z方向上特别厚,则避免了穿过其所有部件的粘结部38。Referring to FIGS. 4A-4B , the cleaning article may be free of the
片材12、收集条元件25和/或任选的丝束纤维层中的任一个均可任选地完全或部分地涂覆有粘合剂、蜡、牛顿油或非牛顿油或它们的组合,以便改善清洁性并增大所吸收碎屑的保持性。如果需要,清洁制品10任选地可与清洁溶液或可用于其他目的例如处理外观表面或消毒的其他溶液等一起使用。清洁溶液可被预先施用到清洁制品10,产生预先弄湿的清洁制品10,或者可被包含在单独的贮存器内用于给清洁制品10和/或目标表面定量给料。清洁溶液可包括大部分的水和至少约0.5、2、5或10重量%的固体,或者至少约30重量%或50重量%的水溶剂、非水溶剂或它们的混合物。Any of the
参见图5A-5G,示出了各种另选的收集条元件25。虽然示出各种收集条元件25具有两个层25,但本领域技术人员将认识到本发明不受如此限制。收集条元件25可具有一个、两个、三个或更多个层27,其具有如图所示的粘结部38,或具有不同的粘结部38。本领域技术人员还将认识到,根据需要,可将这些实施方案的各种组合和混合结合到单个清洁制品10中。Referring to Figures 5A-5G, various alternative
参见图5A,收集条元件25可包括材料的两个片材,每个片材具有开口的c形折叠。预期据信该布置有利地提供大致对称的相对几何形状,这有助于以常用前后运动清洁,并提供大致相等厚度的清洁制品10。Referring to Figure 5A, the
参见图5B,收集条元件25可包括材料的两个片材,每个片材具有带缩短的外腿部的z形折叠。预期据信该布置有利地提供大致对称的相对几何形状。清洁制品10的每个纵向边缘具有两个c形折叠,其提供环状收集条17和收集条17的两个自由端。据信提供收集条17的自由端和环端以及大致恒定的厚度的这种布置有助于以常见前后运动进行清洁。Referring to Figure 5B, the
参见图5C,收集条元件25可包括材料的两个片材,每个片材具有在相对方向上取向的c形折叠。预期据信该布置有利地提供大致对称的相对几何形状。清洁制品10的每个纵向边缘具有c形折叠,其提供环状收集条17和收集条17的两个自由端。据信提供收集条17的自由端和环端这种布置有助于以常用前后运动进行清洁。Referring to Figure 5C, the
参见图5D,收集条元件25可包括材料的两个片材,每个片材具有在相同方向上取向的c形折叠。预期据信这种布置有利地提供一个纵向边缘上的环状收集条17和其它纵向边缘上的收集条17的自由端。这种布置提供适用于不同清洁任务的不同类型的收集条17。Referring to Figure 5D, the
参见图5E,收集条元件25可包括材料的两个片材,每个片材具有带缩短的外腿部的z形折叠并被布置成提供W形折叠。预期据信该布置有利地提供在清洁制品10的每个纵向边缘上的两个面向外的环状收集条。Referring to Figure 5E, the
参见图5F,收集条元件25可包括交错折叠材料的两个片材。预期据信该布置有利地提供大致对称的相对几何形状。清洁制品10的每个纵向边缘具有c形折叠,所述c形折叠提供环状收集条17和带较厚中心区的收集条17的单个自由端。预期据信具有较厚中心区使得收集条17移动并在使用时对地板呈现不同的表面积。Referring to Figure 5F, the
参见图5G,收集条元件25可包括两个或更多个独立的蛇形层27。每个收集条元件25可通过专用粘结部38接合到片材12。继而,每个此类收集条元件25可具有收集条17的两个向外延伸的堤。所述布置提供了有益效果,即附加收集条17可用并且向内取向的收集条17可在使用期间缠绕。预期据信这使得不同收集条17具有不同功能并且增加使用时对地板呈现的动态表面积的量。Referring to FIG. 5G , the
当然,本领域技术人员将认识到前述另选的替代方案的组合和混合是可行的并且在本文中是可想到的。例如,清洁制品10可具有多于两条粘结线38。一条此类粘结线38可以是直的或者所有粘结线38可以是不直的。如果使用三条粘结线38,例如,粘结线38可以为对称相对和蛇形的,然而中心粘结线38是直的。或者可通过多个粘结线将单个收集条元件25接合到片材。Of course, those skilled in the art will recognize that combinations and mixtures of the foregoing alternative alternatives are possible and contemplated herein. For example, the cleaning
参见图6,清洁制品10可以可移除地附接到柄部60。具体地讲,附接系统可提供清洁制品10与合适的且任选的柄部60的可移除附接。清洁制品10附接系统和任选的互补的柄部60附接件可包括粘合剂接合、内聚接合、通过套管机械接合等。一种通用的附接系统包括柄部60的尖端可插进其中的套管。适宜的柄部60公开于共同转让的US 8,578,564和D674,949 S中。Referring to FIG. 6 , the cleaning
参见图7,清洁制品10可以可移除地附接到工具70。具体地讲,地板清洁工具70可允许在使用者站着时清洁地板,并且还可提供将清洁溶液或其它液体对地板的喷洒。典型的地板清洁工具70具有柄部72,所述柄部用于被使用者抓握并且头部74附接到其上,并且优选地枢转地附接到其上。头部74紧贴地板或其它目标表面移动。清洁工具70可以可移除地附接到头部的底部。优选地,条17由使用期间头部74的占有面积来限定,从而促进清洁期间条17的动态移动。Referring to FIG. 7 , cleaning
清洁制品10对工具70的可移除附接可使用粘合剂、钩-环系统和夹具来完成。夹具和适宜的清洁工具70公开于共同转让的6,484,356中。适宜的真空工具70公开于7,137,169中。适宜的喷洒工具70公开于共同转让的5,888,006、5,988,920、6,842,936、7,182,537、7,536,743、7,676,877和8,186,898中。Removable attachment of the
清洁制品10还可手动使用,而不具有柄部60或工具70。如果需要,则本文所述的各种清洁制品10可被包装并以套件形式出售。该布置提供了有益效果,即使用者具有对用于不同任务的不同清洁制品10的选择。例如,如果需要,多种尺寸的清洁制品10可以单一套件形式一起出售。该布置允许使用者选择最适用于即时任务的具体清洁制品10。The cleaning
据信本发明的清洁制品10解决对清洁现代木材/层合体的未满足的需要。具体清洁制品10由条17的10个层27构建。每个条17的宽度为约7mm。所有10个层27均在中间粘结部38处接合。邻近并最接近片材12的四个层27还利用附加的粘结部38与其附接,所述附加的粘结部设置在中间粘结部38的横向外侧。The cleaning
如上所述,测试根据本发明的清洁制品10,和两种可商购获得的对照样品。第一对照样品为由本受让人销售的WetJet地板片材。该样品包含AGM并且一般被认为是一次性的。第二对照样品为由Bona销售的微纤维地板片材并且一般被认为可重新用于多次清洁任务。据信这两种样品代表了广泛的一次性和可重复使用的地板片材。Cleaning
所述测试在设置于哑光黑卡纸上的6mm厚的透明聚碳酸酯树脂玻璃(plexi-glass)表面上进行。就测试的每个样品而言,使用BYK-Gardner光泽计测量该表面的光泽度。The test was carried out on a 6 mm thick transparent polycarbonate plexi-glass surface set on matte black cardboard. For each sample tested, the gloss of the surface was measured using a BYK-Gardner glossmeter.
BYK-GardnerTM“洗擦”磨耗试验洗擦机用于样品之间的一致性。在初始光泽度测量之后,利用2ml的常用清洁溶液处理表面,所述常用清洁溶液以Swiffer品牌作为WetJet液体销售,并且一般均匀喷洒在测试表面上。将200克砝码置于每个样品上。每个样品来回循环50次。然后使所述测试表面风干。测试所述表面的最终光泽度,并且减去相应读数。A BYK-Gardner ™ "Scrub" Abrasion Test Scrub was used for sample-to-sample consistency. After the initial gloss measurement, the surfaces were treated with 2 ml of a common cleaning solution, sold under the brand Swiffer as WetJet liquid, and generally sprayed evenly on the test surface. A 200 gram weight was placed on each sample. Each sample was cycled back and forth 50 times. The test surfaces were then allowed to air dry. The final gloss of the surface was tested and the corresponding reading was subtracted.
不将污垢用于该测试。因此,光泽度的变化代表由相应样品造成的表面损坏。Dirt was not used for this test. Therefore, the change in gloss represents the surface damage caused by the corresponding sample.
对每个样品进行四个平行测定。在测试表面的三个不同位置上进行每个重复测试,以确定对光泽度的影响。结果示于表2中。因此,光泽度的变化的每个条目代表12个数据点的平均值。还测定样品的相对表面积。Four replicates were performed for each sample. Each replicate was performed on three different locations on the test surface to determine the effect on gloss. The results are shown in Table 2. Thus, each entry for change in gloss represents the average of 12 data points. The relative surface area of the samples was also determined.
表2: Table 2 :
表2中的数据示出当如上所述测试时,Bona微纤维样品不利地导致光泽度的显著下降。WetJet样品导致比Bona微纤维样品的光泽度的较少损失。光泽度的损失指示通过在未污染测试表面上进行普通清洁可发生表面损坏。不受理论束缚,据信来自微纤维样品的较大表面损坏可能是由于包含相对磨损性材料,诸如尼龙。The data in Table 2 show that the Bona microfiber samples disadvantageously resulted in a significant drop in gloss when tested as described above. The WetJet samples resulted in less loss of gloss than the Bona microfiber samples. The loss of gloss indicates that surface damage can occur by ordinary cleaning on the uncontaminated test surface. Without being bound by theory, it is believed that the greater surface damage from the microfiber samples may be due to the inclusion of relatively abrasive materials, such as nylon.
令人惊奇地,本发明样品示出光泽度的最小损失,其具有的差异几乎在标准偏差内。不受理论束缚,据信微纤维样品的较少表面损坏可能是由于具有移动条17的有益效果,所述移动条在使用时对目标表面呈现动态表面积。Surprisingly, the inventive samples showed minimal loss of gloss with differences almost within standard deviation. Without being bound by theory, it is believed that the less surface damage of the microfiber samples may be due to the beneficial effect of having a moving
使用0.77平方米的RN 104577 Santos Mahogany工程化硬厚木板层压木地板(由Home Legend(Fontana,CA)分配的)重复上述测试。该地板掺有包含悬浮于水/纯溶液中的约2%超细尘的污垢(由PTI soils出售的粘土污垢)。使用涂料辊将约2ml的该溶液施用于测试表面并使其风干。然后用2ml的清洁溶液重新润湿污垢。然后,将每个样品在该地板上来回循环25次。所得的样本之间的光泽度差异示于下表3中。The above test was repeated using 0.77 square meters of RN 104577 Santos Mahogany engineered hard plank laminate wood flooring (assigned by Home Legend, Fontana, CA). The floor was spiked with a soil (clay soil sold by PTI soils) containing about 2% ultrafine dust suspended in a water/pure solution. About 2 ml of this solution was applied to the test surface using a paint roller and allowed to air dry. Then re-moisten the dirt with 2ml of cleaning solution. Then, cycle each sample back and forth on the
表3示出即使在利用粒状污垢在较新地板材料上的更严格测试的存在下,本发明的清洁制品10相对于对照样品也使对表面损坏的潜力最小化。Table 3 shows that cleaning
参见图8,各自在前述RN 104577 Santos Mahogany工程化硬厚木地板上,对Bona地板片材和根据本发明的地板片材10的10次循环进行测试。将地板分成两半,其中每个半部用于一个样品。清洁地板并记录初始光泽度。将污垢、油和异丙醇的溶液施用于地板并风干。将由本转让人出售的可商购获得的WetJet清洁液体喷洒在测试表面上。Referring to Figure 8, 10 cycles of Bona floor sheet and
每个样品在每个方向上用八个前后擦拭物测试以覆盖约2.8平方米,从而代表一个循环。在每个循环之后,测量测试表面的两次成膜,即,雾度的外观,并测试条纹。利用相同样品重复所述过程,直至完成10次循环。Each sample was tested with eight front and rear wipes in each direction to cover approximately 2.8 square meters, thus representing one cycle. After each cycle, the test surfaces were measured for the appearance of both film formation, ie, haze, and streaks were tested. The process was repeated with the same samples until 10 cycles were completed.
图8示出可商购获得的Bona微纤维样品表现出高于主观可见检测阈值的条纹和雾度两者。两种特性一般在测试中在不利的方向上增加。相比之下,根据本发明的清洁制品10有利地在全部10个循环中均表现出远低于可见检测阈值[1无量纲比例]的条纹和雾度。Figure 8 shows that a commercially available Bona microfiber sample exhibits both streak and haze above the subjectively visible detection threshold. Both characteristics generally increase in the unfavorable direction during testing. In contrast, the cleaning
本文所公开的量纲和值不应理解为严格限于所引用的精确数值。相反,除非另外指明,否则每个这样的量纲旨在表示所述值以及围绕该值功能上等同的范围。例如,公开为“40mm”的量纲旨在表示“约40mm”。Dimensions and values disclosed herein should not be construed as strictly limited to the precise numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as "40mm" is intended to mean "about 40mm".
除非明确排除或换句话讲有所限制,否则将本文引用的每篇文献,包括任何交叉引用或相关专利或申请,全文均以引用方式并入本文。任何文献的引用不是对其相对于任何本发明所公开的或本文受权利要求书保护的现有技术的认可,或不是对其单独地或以与任何其它参考文献或多个参考文献的组合提出、建议或公开了任何此类发明的认可。此外,如果此文献中术语的任何含义或定义与以引用方式并入本文的文献中相同术语的任何含义或定义相冲突,将以此文献中赋予该术语的含义或定义为准。Unless expressly excluded or otherwise limited, each document cited herein, including any cross-reference or related patents or applications, is hereby incorporated by reference in its entirety. The citation of any document is not an admission that it is relative to any prior art disclosed herein or claimed herein, or is not presented individually or in combination with any other reference or references , suggest or disclose any such invention. Furthermore, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
虽然已经举例说明和描述了本发明的具体实施方式,但是对于本领域技术人员而言显而易见的是,在不脱离本发明的实质和范围的情况下可作出多个其他改变和修改。因此,本文旨在于所附权利要求中涵盖属于本发明范围内的所有这些变化和修改。While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. Accordingly, it is intended to cover in the appended claims all such changes and modifications as fall within the scope of this invention.
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| US14/755,506 | 2015-06-30 | ||
| US14/755,506 US9833118B2 (en) | 2006-08-07 | 2015-06-30 | Floor cleaning article having strips with differential bond pattern |
| PCT/US2016/025473 WO2016161235A1 (en) | 2015-04-02 | 2016-04-01 | Floor cleaning article having strips with differential bond pattern |
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| CA2981656C (en) | 2019-12-03 |
| EP3277146A1 (en) | 2018-02-07 |
| KR102027667B1 (en) | 2019-10-01 |
| EP3277146B1 (en) | 2023-12-20 |
| KR20170122813A (en) | 2017-11-06 |
| CA2981656A1 (en) | 2016-10-06 |
| WO2016161235A1 (en) | 2016-10-06 |
| JP2018510030A (en) | 2018-04-12 |
| CN107427180A (en) | 2017-12-01 |
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