CN107418269A - A kind of epoxy casting transformer varnish and its preparation technology - Google Patents
A kind of epoxy casting transformer varnish and its preparation technology Download PDFInfo
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- CN107418269A CN107418269A CN201710805439.5A CN201710805439A CN107418269A CN 107418269 A CN107418269 A CN 107418269A CN 201710805439 A CN201710805439 A CN 201710805439A CN 107418269 A CN107418269 A CN 107418269A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of epoxy casting transformer varnish, the varnish is made up of following raw material:15 20 parts of methacrylate, 20 25 parts of lac, 25 30 parts of polyamide, 15 25 parts of septichen phenyl ester, 15 20 parts of propandiol butyl ether, 5 10 parts of lecithin, 10 15 parts of fluorocarbon resin, 13 parts of hydroxymethyl cellulose, 15 parts of polypropylene glycerol aether, 58 parts of Zinc oxide powder;Epoxy casting transformer varnish provided by the present invention is corrosion-resistant, light shine, cold-hot, and performance is more more stable than the common coating of in the market, is made and promotes.
Description
Technical field
The present invention relates to varnish field, and in particular to a kind of epoxy casting transformer varnish.
Background technology
Varnish is by the coating that resin is that main film forming substance adds that solvent forms, because coating and film are all transparent
, thus also referred to as clear dope.Body surface is coated in, smooth film is formed after drying, shows the original texture of object plane.With clear
The continuous aggravation of industry competition is painted, M&A integration and capital operation are increased between large-scale varnish enterprise, the outstanding varnish in the country
Manufacturing enterprise more and more payes attention to the research to industry market, the particularly depth to Business Development Environment and customer demand Long-term change trend
Enter research.Modern varnish progressively turns into a kind of multi-functional engineering material, is an important row in chemical industry
Industry.
For obtaining a kind of water varnish in patent application CN101358101B disclosed in China, using fluorine carbon surface
Activating agent, surface tension and surface free energy are significantly reduced, add wet performance.The patent application disclosed in China
For obtaining the water varnish of the good water-fast wiping of height of solubility in CN103642339B, using containing triethylamine, the invention in nertralizer
Obtained varnish solubility when being coated with use is good, not closure plate, has good water-fast wiping after film forming.
Currently available technology reduces surface tension to a certain extent, increases wet performance, gained varnish solubility and resistance to
It is water-based can all very well, but fluorocarbon surfactant is substantially pulpous state or powder, directly in-convenience in use, it is frequent in low temperature
Two-phase or precipitation can be separated into, needs to stir before use, also needs slightly to heat in the case of necessary, inconvenience is brought to construction.Three
Ethamine has toxicity, has excitant to skin and mucous membrane, can cause pulmonary edema even dead after suction.
The content of the invention
For above-mentioned problem, the present invention proposes a kind of epoxy casting transformer varnish.It is former used in the present invention
Material processing is convenient, nontoxic.Made varnish also has the advantages that corrosion-resistant, anti-light photograph, cold-hot.
In order to realize above-mentioned purpose, the present invention uses following technical scheme:
A kind of epoxy casting transformer varnish, is made up of following parts by weight raw material:Methyl methacrylate 15-20
Part, lac 10-15 parts, polyamide 15-20 parts, septichen phenyl ester 20-25 parts, propandiol butyl ether 5-10 parts, ovum
- 5 parts of phosphatidase 1, fluorocarbon resin 10-15 parts, hydroxymethyl cellulose 1-3 parts, defoamer 1-5 parts, Zinc oxide powder 5-8 parts.
Preferably, epoxy casting transformer varnish, is made up of following parts by weight raw material:Methyl methacrylate
16-20 parts, lac 11-15 parts, polyamide 16-20 parts, septichen phenyl ester 21-25 parts, propandiol butyl ether 6-10
Part, lecithin 2-5 parts, fluorocarbon resin 11-15 parts, hydroxymethyl cellulose 2-3 parts, defoamer 2-5 parts, Zinc oxide powder 6-8 parts.
Preferably, the defoamer is polypropylene glycerol aether.
Preferably, epoxy casting transformer protects the preparation technology of varnish, including the following steps with varnish:
(1) Zinc oxide powder is weighed, adds after appropriate liquid lecithin to be put into thermostat water bath and stirs 30-60min,
Then 1h is incubated under the conditions of 60 DEG C, is dried, be crushed 400-500 mesh sieves, obtain modified oxidized zinc powder, it is standby;
(2) by methyl methacrylate and septichen phenyl ester be impregnated into 60 DEG C mass concentration be 3-6g/l hydrogen
Oil processing is carried out in sodium hydroxide solution, then takes out and is dried for standby after being washed with deionized water totally;
(3) to the lac weighed, polyamide, fluorocarbon resin, add appropriate water and ethanol in hydroxymethyl cellulose,
10-20min is stirred by ultrasonic, is then cleaned repeatedly with deionized water, places into 80 DEG C of vacuum tank and dry, then put 300- into
Ground in 400r/min sand mill, cross 400-500 mesh sieves, it is standby;
(4) leftover materials and step (1), (2), (3) products therefrom are put into mixer, then add appropriate matter together
Amount is than being 1:2 ethanol and ether mixed liquor, epoxy casting transformer varnish shield coating can be obtained by stirring.
Preferably, water bath with thermostatic control kettle temperature is 80-100 DEG C in step (1).
Preferably, processing time of being deoiled in step (2) is 30min.
Preferably, sand mill temperature is 30-35 DEG C when being ground in step (3).
Using above-mentioned technical scheme, the beneficial effects of the invention are as follows:Propandiol butyl ether is preferable coupling agent, and it improves
Interface interaction between varnish raw material,, can in being manufactured for varnish so as to greatly improving the electrical property of composite and hot property
To improve the wearability of varnish and ageing-resistant performance, propandiol butyl ether can promote with the radical reaction on reinforcing material surface, and can
Enter matrix resin cross-linking reaction, a boundary layer is formed between reinforcing material and resin, boundary layer transmits induction force, so as to increase
Strong bonding strength between material and resin, improve the performance of composite.The zinc oxide that reaction modifying obtains is ground through crushing
After mill, surface atom quantity substantially exceeds conventional particle, and surface atom is due to lacking neighbouring coordination atom and with very high
Energy, the affinity of zinc oxide is enhanced, improves corrosion resistance.Lac is to UV stable, as waste varnish,
Improve anti-light capabilities.Polyamide, fluorocarbon resin cooperate in the presence of coupling agent propandiol butyl ether, improve
The performances such as weatherability, cold-resistant hot, low temperature flexibility, in the presence of hydroxymethyl cellulose, promote varnish in drying and forming-film
One smooth, smooth, uniform paint film of middle formation, reduces surface tension, improves levelability and uniformity.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described.Based on embodiments of the invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
Embodiment 1:
A kind of epoxy casting transformer varnish, is made up of following parts by weight raw material:15 parts of methyl methacrylate, purple
10 parts of glue, 15 parts of polyamide, 20 parts of septichen phenyl ester, 5 parts of propandiol butyl ether, 1 part of lecithin, fluorocarbon resin 10
Part, 1 part of hydroxymethyl cellulose, 1 part of defoamer, 5 parts of Zinc oxide powder.
A kind of preparation technology of epoxy casting transformer varnish, including the following steps:
(1) Zinc oxide powder is weighed, is put into after addition liquid lecithin in 80 DEG C of thermostat water bath and stirs 30min, so
1h is incubated under the conditions of 60 DEG C afterwards, is dried, be crushed 400 mesh sieves, obtain modified oxidized zinc powder, it is standby;
(2) by methyl methacrylate and septichen phenyl ester be impregnated into 60 DEG C mass concentration be 3g/l hydrogen-oxygen
Change in sodium solution and carry out oil processing 30min, then take out and be dried for standby after being washed with deionized water totally;
(3) to the lac weighed, polyamide, fluorocarbon resin, add appropriate water and ethanol in hydroxymethyl cellulose,
10min is stirred by ultrasonic, is then cleaned repeatedly with deionized water, places into 80 DEG C of vacuum tank and dry, then putting temperature into is
30 DEG C of rotating speed is to be ground in 300r/min sand mill, crosses 400 mesh sieves, standby;
(4) leftover materials and step (1), (2), (3) products therefrom are put into mixer, then add appropriate matter together
Amount is than being 1:2 ethanol and ether mixed liquor, epoxy casting transformer varnish shield coating can be obtained by stirring.
Embodiment 2:
A kind of epoxy casting transformer varnish, is made up of following parts by weight raw material:20 parts of methyl methacrylate, purple
15 parts of glue, 20 parts of polyamide, 25 parts of septichen phenyl ester, 10 parts of propandiol butyl ether, 5 parts of lecithin, fluorocarbon resin
15 parts, 3 parts of hydroxymethyl cellulose, 5 parts of defoamer, 8 parts of Zinc oxide powder.
A kind of preparation technology of epoxy casting transformer varnish, including the following steps:
(1) Zinc oxide powder is weighed, is put into after addition liquid lecithin in 100 DEG C of thermostat water bath and stirs 60min, so
1h is incubated under the conditions of 60 DEG C afterwards, is dried, be crushed 500 mesh sieves, obtain modified oxidized zinc powder, it is standby;
(2) by methyl methacrylate and septichen phenyl ester be impregnated into 60 DEG C mass concentration be 6g/l hydrogen-oxygen
Change in sodium solution and carry out oil processing 30min, then take out and be dried for standby after being washed with deionized water totally;
(3) to the lac weighed, polyamide, fluorocarbon resin, add appropriate water and ethanol in hydroxymethyl cellulose,
20min is stirred by ultrasonic, is then cleaned repeatedly with deionized water, places into 80 DEG C of vacuum tank and dry, then putting temperature into is
35 DEG C of rotating speed is to be ground in 400r/min sand mill, crosses 500 mesh sieves, standby;
(4) leftover materials and step (1), (2), (3) products therefrom are put into mixer, then add appropriate matter together
Amount is than being 1:2 ethanol and ether mixed liquor, epoxy casting transformer varnish shield coating can be obtained by stirring.
Embodiment 3:
A kind of epoxy casting transformer varnish, is made up of following parts by weight raw material:16 parts of methyl methacrylate, purple
11 parts of glue, 16 parts of polyamide, 21 parts of septichen phenyl ester, 6 parts of propandiol butyl ether, 2 parts of lecithin, fluorocarbon resin 11
Part, 2 parts of hydroxymethyl cellulose, 2 parts of defoamer, 6 parts of Zinc oxide powder.
A kind of preparation technology of epoxy casting transformer varnish, including the following steps:
(1) Zinc oxide powder is weighed, is put into after addition liquid lecithin in 90 DEG C of thermostat water bath and stirs 40min, so
1h is incubated under the conditions of 60 DEG C afterwards, is dried, be crushed 450 mesh sieves, obtain modified oxidized zinc powder, it is standby;
(2) by methyl methacrylate and septichen phenyl ester be impregnated into 60 DEG C mass concentration be 4g/l hydrogen-oxygen
Change in sodium solution and carry out oil processing 30min, then take out and be dried for standby after being washed with deionized water totally;
(3) to the lac weighed, polyamide, fluorocarbon resin, add appropriate water and ethanol in hydroxymethyl cellulose,
15min is stirred by ultrasonic, is then cleaned repeatedly with deionized water, places into 80 DEG C of vacuum tank and dry, then putting temperature into is
31 DEG C of rotating speed is to be ground in 350r/min sand mill, crosses 450 mesh sieves, standby;
(4) leftover materials and step (1), (2), (3) products therefrom are put into mixer, then add appropriate matter together
Amount is than being 1:2 ethanol and ether mixed liquor, epoxy casting transformer varnish shield coating can be obtained by stirring.
Embodiment 4:
A kind of epoxy casting transformer varnish, is made up of following parts by weight raw material:17 parts of methyl methacrylate, purple
12 parts of glue, 17 parts of polyamide, 22 parts of septichen phenyl ester, 7 parts of propandiol butyl ether, 3 parts of lecithin, fluorocarbon resin 12
Part, 3 parts of hydroxymethyl cellulose, 3 parts of defoamer, 7 parts of Zinc oxide powder.
A kind of preparation technology of epoxy casting transformer varnish, including the following steps:
(1) Zinc oxide powder is weighed, is put into after addition liquid lecithin in 85 DEG C of thermostat water bath and stirs 50min, so
1h is incubated under the conditions of 60 DEG C afterwards, is dried, be crushed 440 mesh sieves, obtain modified oxidized zinc powder, it is standby;
(2) by methyl methacrylate and septichen phenyl ester be impregnated into 60 DEG C mass concentration be 5g/l hydrogen-oxygen
Change in sodium solution and carry out oil processing 30min, then take out and be dried for standby after being washed with deionized water totally;
(3) to the lac weighed, polyamide, fluorocarbon resin, add appropriate water and ethanol in hydroxymethyl cellulose,
16min is stirred by ultrasonic, is then cleaned repeatedly with deionized water, places into 80 DEG C of vacuum tank and dry, then putting temperature into is
33 DEG C of rotating speed is to be ground in 360r/min sand mill, crosses 480 mesh sieves, standby;
(4) leftover materials and step (1), (2), (3) products therefrom are put into mixer, then add appropriate matter together
Amount is than being 1:2 ethanol and ether mixed liquor, epoxy casting transformer varnish shield coating can be obtained by stirring.
Embodiment 5:
A kind of epoxy casting transformer varnish, is made up of following parts by weight raw material:18 parts of methyl methacrylate, purple
13 parts of glue, 18 parts of polyamide, 23 parts of septichen phenyl ester, 8 parts of propandiol butyl ether, 4 parts of lecithin, fluorocarbon resin 13
Part, 3 parts of hydroxymethyl cellulose, 4 parts of defoamer, 8 parts of Zinc oxide powder.
A kind of preparation technology of epoxy casting transformer varnish, including the following steps:
(1) Zinc oxide powder is weighed, is put into after addition liquid lecithin in 95 DEG C of thermostat water bath and stirs 55min, so
1h is incubated under the conditions of 60 DEG C afterwards, is dried, be crushed 420 mesh sieves, obtain modified oxidized zinc powder, it is standby;
(2) by methyl methacrylate and septichen phenyl ester be impregnated into 60 DEG C mass concentration be 5g/l hydrogen-oxygen
Change in sodium solution and carry out oil processing 30min, then take out and be dried for standby after being washed with deionized water totally;
(3) to the lac weighed, polyamide, fluorocarbon resin, add appropriate water and ethanol in hydroxymethyl cellulose,
18min is stirred by ultrasonic, is then cleaned repeatedly with deionized water, places into 80 DEG C of vacuum tank and dry, then putting temperature into is
34 DEG C of rotating speed is to be ground in 390r/min sand mill, crosses 490 mesh sieves, standby;
(4) leftover materials and step (1), (2), (3) products therefrom are put into mixer, then add appropriate matter together
Amount is than being 1:2 ethanol and ether mixed liquor, epoxy casting transformer varnish shield coating can be obtained by stirring.
Epoxy casting transformer in the embodiment of the present invention is subjected to performance test with varnish common in varnish and market,
Its test result is as follows:
Rub resistance/time | Corrosion-resistant/h | Cold-resistant thermal cycle/h | Ageing-resistant/h | |
Embodiment 1 | 94 | 156 | 140 | 1420 |
Embodiment 2 | 98 | 169 | 148 | 1500 |
Embodiment 3 | 95 | 158 | 142 | 1460 |
Embodiment 4 | 97 | 162 | 147 | 1450 |
Embodiment 5 | 96 | 165 | 145 | 1460 |
Comparative example 1 | 53 | 72 | 60 | 500 |
Comparative example 2 | 55 | 69 | 75 | 600 |
Comparative example 3 | 54 | 74 | 69 | 450 |
Wherein rub resistance experiment is that trial target is fixed on fastness to rubbing instrument, pastes and throws on fastness to rubbing instrument probe
Machine-glazed paper, starts fastness to rubbing instrument, and observation varnish destroys situation and records Rubbing number when just there is slight crack.Decay resistance
Test is that the time corroded and record occurs in observation varnish as in concentrated sulfuric acid mist by trial target.Cold-resistant thermal cycle test be by
Trial target is put under heating frozen cycling condition, observes the time that varnish is cracked and comes off.Ageing-resistant test is to test
Under the conditions of product are as simulation Exposure to Sunlight, paint film color change, crackle time of occurrence and efflorescence time are observed and recorded.
Above example is only to illustrate the technical scheme of type of the present invention, rather than its limitations;Although with reference to foregoing implementation
Type of the present invention is described in detail example, it will be understood by those within the art that:It still can be to foregoing each
Technical scheme described in embodiment is modified, or carries out equivalent substitution to which part technical characteristic;And these are changed
Or replace, the essence of appropriate technical solution is departed from the spirit and scope of each embodiment technical scheme of type of the present invention.
Claims (7)
- The transformer varnish 1. a kind of epoxy is cast, it is characterised in that be made up of following parts by weight raw material:Methyl methacrylate Ester 15-20 parts, lac 10-15 parts, polyamide 15-20 parts, septichen phenyl ester 20-25 parts, propandiol butyl ether 5- 10 parts, lecithin 1-5 parts, fluorocarbon resin 10-15 parts, hydroxymethyl cellulose 1-3 parts, defoamer 1-5 parts, Zinc oxide powder 5-8 Part.
- The transformer varnish 2. epoxy according to claim 1 is cast, it is characterised in that by following parts by weight raw material system Into:Methyl methacrylate 16-20 parts, lac 11-15 parts, polyamide 16-20 parts, septichen phenyl ester 21-25 Part, propandiol butyl ether 6-10 parts, lecithin 2-5 parts, fluorocarbon resin 11-15 parts, hydroxymethyl cellulose 2-3 parts, defoamer 2-5 Part, Zinc oxide powder 6-8 parts.
- The transformer varnish 3. epoxy according to claim 1 is cast, it is characterised in that the defoamer is polyoxypropylene Glycerin ether.
- 4. epoxy casting transformer varnish according to claim 1 and its preparation technology, it is characterised in that including as follows Several steps:(1) Zinc oxide powder is weighed, is put into after addition liquid lecithin in thermostat water bath and stirs 30-60min, then at 60 DEG C Under the conditions of be incubated 1h, dry, crushed 400-500 mesh sieves, obtain modified oxidized zinc powder, it is standby;(2) by methyl methacrylate and septichen phenyl ester be impregnated into 60 DEG C mass concentration be 3-6g/l hydroxide Oil processing is carried out in sodium solution, then takes out and is dried for standby after being washed with deionized water totally;(3) to the lac weighed, polyamide, fluorocarbon resin, add appropriate water and ethanol in hydroxymethyl cellulose, ultrasound 10-20min is stirred, is then cleaned repeatedly with deionized water, is placed into 80 DEG C of vacuum tank and dry, then put 300- into Ground in 400r/min sand mill, cross 400-500 mesh sieves, it is standby;(4) leftover materials and step (1), (2), (3) products therefrom are put into mixer, then add appropriate mass ratio together For 1:2 ethanol and ether mixed liquor, epoxy casting transformer varnish shield coating can be obtained by stirring.
- 5. the preparation technology of epoxy casting transformer varnish according to claim 4, it is characterised in that in step (1) Water bath with thermostatic control kettle temperature is 80-100 DEG C.
- 6. the preparation technology of epoxy casting transformer varnish according to claim 4, it is characterised in that in step (2) Processing time of deoiling is 30min.
- 7. the preparation technology of epoxy casting transformer varnish according to claim 4, it is characterised in that in step (3) Sand mill temperature is 30-35 DEG C during grinding.
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Citations (4)
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CN102977700A (en) * | 2012-12-28 | 2013-03-20 | 上海电缆研究所 | Coating for improving performance of overhead conductor comprehensively |
CN104650666A (en) * | 2015-02-06 | 2015-05-27 | 天津普罗米化工有限公司 | Anti-pollution-flashover fluorocarbon coating |
CN106675385A (en) * | 2016-12-14 | 2017-05-17 | 池州市小康人家科技有限公司 | Scratch-resistant coating |
CN107099217A (en) * | 2017-04-28 | 2017-08-29 | 山东欧铂新材料有限公司 | A kind of resin anti-corrosive paint containing graphene/zinc powder composite and preparation method thereof |
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2017
- 2017-09-08 CN CN201710805439.5A patent/CN107418269A/en active Pending
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CN102977700A (en) * | 2012-12-28 | 2013-03-20 | 上海电缆研究所 | Coating for improving performance of overhead conductor comprehensively |
CN104650666A (en) * | 2015-02-06 | 2015-05-27 | 天津普罗米化工有限公司 | Anti-pollution-flashover fluorocarbon coating |
CN106675385A (en) * | 2016-12-14 | 2017-05-17 | 池州市小康人家科技有限公司 | Scratch-resistant coating |
CN107099217A (en) * | 2017-04-28 | 2017-08-29 | 山东欧铂新材料有限公司 | A kind of resin anti-corrosive paint containing graphene/zinc powder composite and preparation method thereof |
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