CN107417098A - A kind of glass formula for being used to prepare solid phase converter glass microsphere - Google Patents

A kind of glass formula for being used to prepare solid phase converter glass microsphere Download PDF

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Publication number
CN107417098A
CN107417098A CN201710797747.8A CN201710797747A CN107417098A CN 107417098 A CN107417098 A CN 107417098A CN 201710797747 A CN201710797747 A CN 201710797747A CN 107417098 A CN107417098 A CN 107417098A
Authority
CN
China
Prior art keywords
glass
solid phase
phase converter
formula
microsphere
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710797747.8A
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Chinese (zh)
Inventor
王芸
陈凯
马立云
彭程
彭小波
董为勇
王华文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Kasen Basic Mstar Technology Ltd
Original Assignee
Anhui Kasen Basic Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Kasen Basic Mstar Technology Ltd filed Critical Anhui Kasen Basic Mstar Technology Ltd
Priority to CN201710797747.8A priority Critical patent/CN107417098A/en
Publication of CN107417098A publication Critical patent/CN107417098A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C12/00Powdered glass; Bead compositions

Abstract

The present invention discloses a kind of glass formula for being used to prepare solid phase converter glass microsphere, including following components in percentage by weight:Silica 60%~65%, boric acid 0.5%~1.5%, lime stone 8%~12%, soda ash 18%~22%, aluminum oxide 1%~3%, potassium carbonate 0.5%~1.5%, magnesia 1%~1.5%.Reachable (80 ± 5) × 10 of the average line style coefficient of expansion in the range of 740 ± 20 DEG C, 0~300 DEG C can be reached using the softening point of the glass microsphere of the glass production of the present invention‑7, glass tube matched expansion coefficient that the solid phase converter of preparation can well with pendular ring.

Description

A kind of glass formula for being used to prepare solid phase converter glass microsphere
Technical field
It is specifically a kind of to be used to prepare solid phase converter glass microsphere the present invention relates to angular acceleration transducer field Glass formula.
Background technology
With the development of science and technology, in war industry, the control of most of moving object of aerospace field and prison In examining system, angular displacement, the information of angular speed are not only needed, with greater need for the relevant information of angular acceleration.With industrial automatic control Technology processed develops rapidly, and the application demand of angular acceleration transducer becomes more and more.
The structure of Pendular ring type angular acceleration transducer is mainly made up of datum plate, amplifying circuit and pendular ring, and wherein pendular ring is Core, it is made up of fluid chamber, liquid, electrode and solid phase converter.Wherein solid phase converter is porous network structure, when Pendular ring is in motion process, and a series of change can occur for " Gu-liquid " interface inside and outside switching device, the electricity formed Potential difference is accessed after amplifying circuit is amplified by the electrode of pendular ring terminal and exported, so solid phase converter is to influence whole angle to add An important factor for velocity sensor performance.
Converter needs strict softening point and the coefficient of expansion, and component requirements with glass microsphere in Pendular ring type sensor Compare strictly, the softening point and the coefficient of expansion of glass microsphere and the softening point and the coefficient of expansion of pendular ring need to be mutually matched, and otherwise can Cause pendular ring leakage or burst.Further, since frit in melting process caused gaseous product in glass system Solubility is different, and the clarifying effect of glass and its solubility directly affect the performance after glass balling-up, so as to influence The density of glass microsphere and solid rate, directly affect the performance of converter, and glass composition directly affects glass microsphere after sintering One of key of energy.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of glass for being used to prepare solid phase converter glass microsphere Formula, the average line style coefficient of expansion that the softening point of the glass of the formula can reach in the range of 740 ± 20 DEG C, 0~300 DEG C can Up to (80 ± 5) × 10-7, using the formula glass production glass microsphere prepare solid phase converter can well with pendular ring Glass tube matched expansion coefficient.
In order to solve the above technical problems, the invention provides a kind of glass for being used to prepare solid phase converter glass microsphere Formula, including following components in percentage by weight:Silica (SiO2) 60%~65%, boric acid (B2O3) 0.5%~1.5%, Lime stone (CaCO3) 8%~12%, soda ash (Na2CO3) 18%~22%, aluminum oxide (Al2O3) 1%~3%, potassium carbonate (K2CO3) 0.5%~1.5%, magnesia (MgO) 1%~1.5%;Preferably:Silica 65%, boric acid 0.8%, lime stone 10%th, soda ash 20%, aluminum oxide 2%, potassium carbonate 1.1% and magnesia 1.1%.
Softening point using the glass microsphere of the glass production of the present invention can reach 740 ± 20 DEG C, 0~300 DEG C of scope The interior average line style coefficient of expansion is up to (80 ± 5) × 10-7, glass tube that the solid phase converter of preparation can well with pendular ring Matched expansion coefficient.
Embodiment
The present invention can further be well understood below by way of example given below, but they are not to the present invention Restriction.
Embodiment 1
For preparing the glass formula of solid phase converter glass microsphere, including following components in percentage by weight:Dioxy SiClx (SiO2) 65%, boric acid (B2O3) 1.5%, lime stone (CaCO3) 10%, soda ash (Na2CO3) 20%, aluminum oxide (Al2O3) 2%th, potassium carbonate (K2CO3) 0.5%, magnesia (MgO) 1.5%.Using the formula prepare glass softening point for 723.35 DEG C, 0 The average line style coefficient of expansion in the range of~300 DEG C is 79.88 × 10-7
Embodiment 2
For preparing the glass formula of solid phase converter glass microsphere, including following components in percentage by weight:Dioxy SiClx (SiO2) 66%, boric acid (B2O3) 1%, lime stone (CaCO3) 10.5%, soda ash (Na2CO3) 18%, aluminum oxide (Al2O3) 2%th, potassium carbonate (K2CO3) 1%, magnesia (MgO) 1%.Using the formula prepare glass softening point for 743.55 DEG C, 0~ The average line style coefficient of expansion in the range of 300 DEG C is 81.66 × 10-7
Embodiment 3
For preparing the glass formula of solid phase converter glass microsphere, including following components in percentage by weight:Dioxy SiClx (SiO2) 65%, boric acid (B2O3) 0.8%, lime stone (CaCO3) 10%, soda ash (Na2CO3) 20%, aluminum oxide (Al2O3) 2%th, potassium carbonate (K2CO3) 1.1%, magnesia (MgO) 1.1%.Using the formula prepare glass softening point for 751.36 DEG C, 0 The average line style coefficient of expansion in the range of~300 DEG C is 82.55 × 10-7

Claims (2)

1. a kind of glass formula for being used to prepare solid phase converter glass microsphere, it is characterised in that including following weight percent The component of ratio:Silica 60%~65%, boric acid 0.5%~1.5%, lime stone 8%~12%, soda ash 18%~22%, Aluminum oxide 1%~3%, potassium carbonate 0.5%~1.5%, magnesia 1%~1.5%.
2. the glass formula according to claim 1 for being used to prepare solid phase converter glass microsphere, it is characterised in that:Bag Include following components in percentage by weight:Silica 65%, boric acid 0.8%, lime stone 10%, soda ash 20%, aluminum oxide 2%, Potassium carbonate 1.1% and magnesia 1.1%.
CN201710797747.8A 2017-09-06 2017-09-06 A kind of glass formula for being used to prepare solid phase converter glass microsphere Pending CN107417098A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710797747.8A CN107417098A (en) 2017-09-06 2017-09-06 A kind of glass formula for being used to prepare solid phase converter glass microsphere

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710797747.8A CN107417098A (en) 2017-09-06 2017-09-06 A kind of glass formula for being used to prepare solid phase converter glass microsphere

Publications (1)

Publication Number Publication Date
CN107417098A true CN107417098A (en) 2017-12-01

Family

ID=60432726

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710797747.8A Pending CN107417098A (en) 2017-09-06 2017-09-06 A kind of glass formula for being used to prepare solid phase converter glass microsphere

Country Status (1)

Country Link
CN (1) CN107417098A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101717191A (en) * 2009-11-13 2010-06-02 中国家用电器研究院 Opal glass suitable for full electrofusion forming and preparation process thereof
CN101857355A (en) * 2010-06-02 2010-10-13 天台精工西力玻璃珠有限公司 Method for producing glass beads used for curing high-level nuclear wastes
CN103241952A (en) * 2012-02-08 2013-08-14 訾然 Method for producing aluminosilicate water gauge surface glass
CN104968623A (en) * 2013-02-07 2015-10-07 日本板硝子株式会社 Glass composition, chemically-strengthened glass composition, glass composition, chemically-strengthened article, and cover glass for display
CN107108331A (en) * 2014-12-26 2017-08-29 旭硝子株式会社 Glass and chemically reinforced glass

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101717191A (en) * 2009-11-13 2010-06-02 中国家用电器研究院 Opal glass suitable for full electrofusion forming and preparation process thereof
CN101857355A (en) * 2010-06-02 2010-10-13 天台精工西力玻璃珠有限公司 Method for producing glass beads used for curing high-level nuclear wastes
CN103241952A (en) * 2012-02-08 2013-08-14 訾然 Method for producing aluminosilicate water gauge surface glass
CN104968623A (en) * 2013-02-07 2015-10-07 日本板硝子株式会社 Glass composition, chemically-strengthened glass composition, glass composition, chemically-strengthened article, and cover glass for display
CN107108331A (en) * 2014-12-26 2017-08-29 旭硝子株式会社 Glass and chemically reinforced glass

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
基泰戈罗德斯基等: "《玻璃工艺学 下册》", 30 June 1965, 建筑工程出版社 *

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Application publication date: 20171201