CN107417072A - A kind of device of liquid blast furnace production foam glass - Google Patents

A kind of device of liquid blast furnace production foam glass Download PDF

Info

Publication number
CN107417072A
CN107417072A CN201710468711.5A CN201710468711A CN107417072A CN 107417072 A CN107417072 A CN 107417072A CN 201710468711 A CN201710468711 A CN 201710468711A CN 107417072 A CN107417072 A CN 107417072A
Authority
CN
China
Prior art keywords
slag
blast furnace
furnace
electrode
cinder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710468711.5A
Other languages
Chinese (zh)
Other versions
CN107417072B (en
Inventor
许玉蕊
许征鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Luxin Guohe Energy Saving And Environmental Protection Technology Co ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710468711.5A priority Critical patent/CN107417072B/en
Publication of CN107417072A publication Critical patent/CN107417072A/en
Application granted granted Critical
Publication of CN107417072B publication Critical patent/CN107417072B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/08Other methods of shaping glass by foaming
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags

Abstract

The invention discloses a kind of liquid blast furnace production foam glass device, mainly by:Slag truck ladle(1), middle slag tank(2), ac arc furnace(3), cooler bin(4), mixer(5)And conticaster(6)Composition, the present invention are solved the problems, such as stockpiling of the blast furnace slag as solid waste, are effectively utilized the waste heat of molten blast furnace slag, realized the recycling recycling to molten blast furnace slag, improve resource utilization using blast furnace hot slag production foam glass;And its abundant mineral matter is excellent by high melt overall mechanical properties.Use furnace bottom overflow slag mode provide high temperature melt cinder ensure that it is continuous for production line provide regime flow, temperature, composition, viscosity slag raw material, ensure that production line output high standard, architecture of high quality ornament materials product lay the foundation, the resistance to material of electric arc furnaces is washed away when reducing charging simultaneously, ensure that the resistance to material continuous use life-span.

Description

A kind of device of liquid blast furnace production foam glass
Technical field
The invention belongs to utilization of waste as resource field, is related to one kind and utilizes liquid blast furnace comprehensive utilization technique, special It is not related to a kind of device of liquid blast furnace production foam glass.
Background technology
Foam glass be a kind of thermal insulation of superior performance (cold insulation), sound absorption, protection against the tide, fireproof light high-strength building material and Ornament materials, use temperature range are subzero 196 degree to 450 degree, and A levels are non-ignitable to be almost with building same life-span, moisture permeable coefficient 0.Although other novel heat insulation materials emerge in an endless stream, foam glass is so that it is permanent, security, high reliability are exhausted in low-heat The fields such as edge, tidal defense engineering, sound absorption are in occupation of increasingly consequence.
Liquid blast furnace temperature is good residual heat resources more than 1400 DEG C, the waste heat phase that blast furnace cinder per ton contains When in heat caused by 60Kg standard coal completely burneds.For the melting sensible heat of high-temperature liquid state blast-furnace slag, State of Blast Furnace is developed The height of slag adds value, directly uses liquid blast-furnace slag, studies and directly prepare foam by liquid blast-furnace slag Glass, economic benefit is substantially increased, while effectively prevent the oxysulfide that blast furnace cinder discharges during water quenching.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of liquid height for above-mentioned the shortcomings of the prior art Clinker produce ornament materials device, mainly by:Slag truck ladle(1), middle slag tank(2), ac arc furnace(3), cooler bin(4)、 Mixer(5)And conticaster(6)Composition, slag truck ladle(1)Liquid blast furnace is accessed by locomotive from tap cinder mouth to be transported to positioned at friendship Flow electric arc furnaces(3)The middle slag tank on top(2), middle slag tank(2)By liquid blast furnace through slag inlet(321)It is slowly added to exchange Electric arc furnaces(3), and by auxiliary material entrance(322)Add raw mineral materials well mixed according to a certain percentage, mine tailings, flyash Deng flowing cooler bin after being heated to 1400 DEG C ~ 1500 DEG C(4), and foamed dose of entrance(41)Stirring is flowed out to after adding foaming agent Machine(5)It has been stirred conticaster(6)Die casting and molding, the annealing temperature that carries out annealing after shaping is 550~600 DEG C, annealing Time is 2~3 hours;The ac arc furnace(3)Mainly by body of heater(31)And bell(32)Two parts form, bell(32)Position In body of heater(31)Top, provided with slag inlet(321)With auxiliary material entrance(322);Body of heater(31)For cylinder-like structure, its bottom is provided with Three-phase alternating current electrode(33), three-phase alternating current electrode(33)Surrounded for three sector structures it is one circular, by insulating between three-phase Refractory material(36)Carry out insulation gap, three-phase alternating current electrode(33)Each electrode respectively by metal electrode(331)And fire resisting Electrode(332)Two parts form, metal electrode(331)The diverging electrodes made using a plurality of copper rod are welded on group on fan-shaped copper coin Into the length of diverging electrodes is the 2/3 of furnace bottom thickness, and fan-shaped copper coin part is exposed at body of heater(31)It is outside;Positioning metal electrode (331)Use insulating refractories first afterwards(36)Layering is made firm by ramming to the 1/3 of furnace bottom part gross thickness, then in three-phase alternating current electrode (33)Position is continued layering using conduction refractory and made firm by ramming, and remainder continues to use insulating refractories(36)Layering has been made firm by ramming Into;Body of heater(31)Side is provided with the cinder notch that overflows(38), overflow cinder notch(38)Drawn by furnace bottom side and upward to the 1/5 of body of heater height Place's connection cooler bin (4);In excessive cinder notch(38)Inside top be provided with temperature measuring equipment(381).
Three-phase alternating current electrode(33)Connect respectively system power supply A B C three-phase furnace low pressure sides.
The fire resisting electrode(332)For the compound ramming material of magnesium carbonaceous of conduction, resistivity≤3 × 10 after carbonization-4 Ω m, bulk density >=2.8g/cm3, compressive resistance >=20Mpa;Pole piece insulate(35)And insulating refractories(36)For insulation The calcareous compound ramming material of magnesium.
Brief description of the drawings
The embodiment of the present invention is described in further detail below in conjunction with the accompanying drawings;
Accompanying drawing 1 show present system structural representation
Accompanying drawing 2 show arc furnace bottom of the present invention top partial view diagram
Explanation is marked in figure
1st, slag truck ladle, 2, middle slag tank, 3, electric arc furnaces, 4, cooler bin, 5, mixer, 6, conticaster, 31, body of heater, 32, bell, 33rd, three-phase alternating current electrode, 35, pole piece insulation, 36, insulating refractories, 37, refractory brick, 38, overflow cinder notch, 39, residue mouth, 321st, slag inlet, 322, auxiliary material entrance, 331, metal electrode, 332, fire resisting electrode, 381, temperature measuring equipment, 41, foaming agent inlet.
Embodiment
A kind of device of present invention liquid blast furnace production ornament materials, mainly by:Slag truck ladle(1), middle slag tank(2)、 Ac arc furnace(3), cooler bin(4), mixer(5)And conticaster(6)Composition, slag truck ladle(1)By locomotive from tap cinder mouth Liquid blast furnace is accessed to be transported to positioned at ac arc furnace(3)The middle slag tank on top(2), middle slag tank(2)By liquid blast furnace Through slag inlet(321)It is slowly added to ac arc furnace(3), and by auxiliary material entrance(322)Addition is well mixed according to a certain percentage Raw mineral materials, mine tailings, flyash etc., flow cooler bin after being heated to 1400 DEG C ~ 1500 DEG C(4), and foamed dose of entrance (41)Mixer is flowed out to after adding foaming agent(5)It has been stirred conticaster(6)Die casting and molding, annealed after shaping Annealing temperature is 550~600 DEG C, and annealing time is 2~3 hours;The ac arc furnace(3)Mainly by body of heater(31)And bell (32)Two parts form, bell(32)Positioned at body of heater(31)Top, provided with slag inlet(321)With auxiliary material entrance(322);Body of heater (31)For cylinder-like structure, its bottom is provided with three-phase alternating current electrode(33), three-phase alternating current electrode(33)Enclosed for three sector structures Into it is one circular, by insulating refractories between three-phase(36)Carry out insulation gap, three-phase alternating current electrode(33)Each electricity Pole is respectively by metal electrode(331)With fire resisting electrode(332)Two parts form, metal electrode(331)Made using a plurality of copper rod Diverging electrodes be welded on fan-shaped copper coin and form, the length of diverging electrodes is the 2/3 of furnace bottom thickness, and fan-shaped copper coin part is exposed In body of heater(31)It is outside;Positioning metal electrode(331)Use insulating refractories first afterwards(36)Layering is made firm by ramming total to furnace bottom part The 1/3 of thickness, then in three-phase alternating current electrode(33)Position is continued layering using conduction refractory and made firm by ramming, and remainder continues Use insulating refractories(36)Completion is made in layering firm by ramming;Body of heater(31)Side is provided with the cinder notch that overflows(38), overflow cinder notch(38)By furnace bottom side Draw and upward to connection cooler bin (4) at the 1/5 of body of heater height in face;In excessive cinder notch(38)Inside top provided with thermometric fill Put(381).
Three-phase alternating current electrode(33)Connect respectively electric furnace low pressure side power supply A B C three-phases, in furnace interior shape after energization Into the rotating excitation field of fixed-direction, play a part of simultaneously to electromagnetic agitation in stove in smelting process.
The fire resisting electrode(332)For the compound ramming material of magnesium carbonaceous of conduction, resistivity≤3 × 10 after carbonization-4 Ω m, bulk density >=2.8g/cm3, compressive resistance >=20Mpa;Pole piece insulate(35)And insulating refractories(36)For insulation The calcareous compound ramming material of magnesium.
Pass through temperature measuring equipment(381)The excessive cinder notch of monitoring electric arc furnaces in real time(38)Interior melt cinder temperature, reach 1400 DEG C in temperature Before, keep liquid level in arc furnace to be less than the cinder notch that overflows(38), and high current is smelted, when temperature reach 1400 DEG C ~ After 1500 DEG C, middle slag tank(2)Start to slag inlet(321)Blast furnace melt cinder is supplemented, high temperature melt cinder is passed through the cinder notch that overflows(38)Overflow Go out;And by auxiliary material entrance while blast furnace melt cinder is supplemented(322)Auxiliary material is added, by adjusting electric arc furnace smelting electric current, control The addition of the magnitude of recruitment and auxiliary material of blast furnace melt cinder, high temperature melt cinder is set endlessly to be flowed out from excessive cinder notch.When needing the long period Blowing out or when being overhauled to electric arc furnaces, it is necessary to open residue mouth(39)Furnace interior residue is excluded, to prevent cooled and solidified;Overhaul Into rear using fire clay closure residue mouth(39).
The present invention uses raw material to solve the problems, such as stockpiling of the blast furnace slag as solid waste, effectively for blast furnace hot slag The waste heat of molten blast furnace slag is make use of, the recycling recycling to molten blast furnace slag is realized, improves resource utilization;And Its abundant mineral matter is excellent by high melt overall mechanical properties.It high temperature melt cinder is provided ensure that using furnace bottom slag mode of overflowing It is continuous for production line provide regime flow, temperature, composition, viscosity slag raw material, it is ensured that production line output high standard, high-quality Building decorative materials product lays the foundation, while the resistance to material of electric arc furnaces is washed away when reducing charging, ensure that resistance to material continuous use Life-span.

Claims (5)

1. a kind of device of liquid blast furnace production ornament materials, mainly by:Slag truck ladle(1), middle slag tank(2), alternating current arc Stove(3), cooler bin(4), mixer(5)And conticaster(6)Composition, it is characterised in that:Slag truck ladle(1)By locomotive from tap cinder Mouth accesses liquid blast furnace and is transported to positioned at ac arc furnace(3)The middle slag tank on top(2), middle slag tank(2)By liquid blast furnace Slag is through slag inlet(321)It is slowly added to ac arc furnace(3), and by auxiliary material entrance(322)It is equal to add mixing according to a certain percentage Even raw mineral materials, mine tailings, flyash etc., flow cooler bin after being heated to 1400 DEG C ~ 1500 DEG C(4), and foamed dose enters Mouthful(41)Mixer is flowed out to after adding foaming agent(5)It has been stirred conticaster(6)Die casting and molding, moved back after shaping Fiery annealing temperature is 550~600 DEG C, and annealing time is 2~3 hours.
A kind of 2. according to claim 1, device of liquid blast furnace production ornament materials, it is characterised in that:The exchange Electric arc furnaces(3)Mainly by body of heater(31)And bell(32)Two parts form, bell(32)Positioned at body of heater(31)Top, provided with slag input Mouthful(321)With auxiliary material entrance(322);Body of heater(31)For cylinder-like structure, its bottom is provided with three-phase alternating current electrode(33), three is intersecting Flow electrode(33)Surrounded for three sector structures it is one circular, by insulating refractories between three-phase(36)Between being insulated Every three-phase alternating current electrode(33)Each electrode respectively by metal electrode(331)With fire resisting electrode(332)Two parts form, gold Belong to electrode(331)The diverging electrodes made using a plurality of copper rod are welded on fan-shaped copper coin and formed, and the length of diverging electrodes is stove The 2/3 of base thickness degree, fan-shaped copper coin part are exposed at body of heater(31)It is outside;Positioning metal electrode(331)Use insulated fireproof first afterwards Material(36)Layering is made firm by ramming to the 1/3 of furnace bottom part gross thickness, then in three-phase alternating current electrode(33)Position uses conductive fire resisting Material continues layering and made firm by ramming, and remainder continues to use insulating refractories(36)Completion is made in layering firm by ramming;Body of heater(31)Side is provided with Overflow cinder notch(38), overflow cinder notch(38)Drawn by furnace bottom side and upward to 1/5 connection cooler bin (4) of body of heater height; Overflow cinder notch(38)Inside top be provided with temperature measuring equipment(381).
A kind of 3. according to claim 2, device of liquid blast furnace production ornament materials, it is characterised in that:Three-phase alternating current Electrode(33)Connect respectively electric furnace low pressure side power supply A B C three-phases, the rotation of fixed-direction is formed after energization in furnace interior Magnetic field, play a part of simultaneously to electromagnetic agitation in stove in smelting process.
A kind of 4. according to claim 2, device of liquid blast furnace production ornament materials, it is characterised in that:The fire resisting Electrode(332)For the compound ramming material of magnesium carbonaceous of conduction, resistivity≤3 × 10 after carbonization-4Ω m, bulk density >= 2.8g/cm3, compressive resistance >=20Mpa;Pole piece insulate(35)And insulating refractories(36)For the calcareous compound ramming of magnesium of insulation Material.
A kind of 5. according to claim 2, device of liquid blast furnace production ornament materials, it is characterised in that:Warm device (381)The excessive cinder notch of monitoring electric arc furnaces in real time(38)Interior melt cinder temperature, before temperature reaches 1400 DEG C, keep liquid level in arc furnace Less than excessive cinder notch(38), and high current is smelted, and after reaching 1400 DEG C ~ 1500 DEG C in temperature, middle slag tank(2)Start To slag inlet(321)Blast furnace melt cinder is supplemented, high temperature melt cinder is passed through the cinder notch that overflows(38)Overflow;And while blast furnace melt cinder is supplemented By auxiliary material entrance(322)Auxiliary material is added, by adjusting electric arc furnace smelting electric current, controls the magnitude of recruitment of blast furnace melt cinder and adding for auxiliary material Add, high temperature melt cinder is endlessly flowed out from excessive cinder notch.
CN201710468711.5A 2017-06-20 2017-06-20 Device for producing foam glass by liquid blast furnace slag Active CN107417072B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710468711.5A CN107417072B (en) 2017-06-20 2017-06-20 Device for producing foam glass by liquid blast furnace slag

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710468711.5A CN107417072B (en) 2017-06-20 2017-06-20 Device for producing foam glass by liquid blast furnace slag

Publications (2)

Publication Number Publication Date
CN107417072A true CN107417072A (en) 2017-12-01
CN107417072B CN107417072B (en) 2019-12-24

Family

ID=60426028

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710468711.5A Active CN107417072B (en) 2017-06-20 2017-06-20 Device for producing foam glass by liquid blast furnace slag

Country Status (1)

Country Link
CN (1) CN107417072B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110282862A (en) * 2019-06-24 2019-09-27 鞍钢股份有限公司 A kind of device preparing foam glass and preparation method

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2123484C1 (en) * 1996-07-18 1998-12-20 Всероссийский федеральный научно-исследовательский и проектно-конструкторский технологический институт строительной индустрии "ВНИИжелезобетон" Slag-alkaline cellular concrete
CN101941802A (en) * 2010-09-07 2011-01-12 重庆大学 Method for directly utilizing liquid-state blast furnace slag to manufacture glass ceramics
CA2678169A1 (en) * 2009-09-03 2011-03-03 Yongqiang Guo Method and apparatus for preparing a slag melt in a medium frequency induction furnace for producing slag wool fiber materials
CN102815867A (en) * 2012-09-05 2012-12-12 北京盛康宁科技开发有限公司 Color glass-ceramic plate and preparation method thereof
CN104496184A (en) * 2014-09-03 2015-04-08 宝钢矿棉科技(宁波)有限公司 Blast furnace hot slag microcrystalline glass and preparation method thereof
CN105417957A (en) * 2016-01-27 2016-03-23 华北理工大学 Preparing method of energy-saving type high blast slag microcrystal glass
CN106587634A (en) * 2016-12-16 2017-04-26 武汉理工大学 Marbled glass ceramics directly employing fusion blast furnace slag and preparation method of marbled glass ceramics

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2123484C1 (en) * 1996-07-18 1998-12-20 Всероссийский федеральный научно-исследовательский и проектно-конструкторский технологический институт строительной индустрии "ВНИИжелезобетон" Slag-alkaline cellular concrete
CA2678169A1 (en) * 2009-09-03 2011-03-03 Yongqiang Guo Method and apparatus for preparing a slag melt in a medium frequency induction furnace for producing slag wool fiber materials
CN101941802A (en) * 2010-09-07 2011-01-12 重庆大学 Method for directly utilizing liquid-state blast furnace slag to manufacture glass ceramics
CN102815867A (en) * 2012-09-05 2012-12-12 北京盛康宁科技开发有限公司 Color glass-ceramic plate and preparation method thereof
CN104496184A (en) * 2014-09-03 2015-04-08 宝钢矿棉科技(宁波)有限公司 Blast furnace hot slag microcrystalline glass and preparation method thereof
CN105417957A (en) * 2016-01-27 2016-03-23 华北理工大学 Preparing method of energy-saving type high blast slag microcrystal glass
CN106587634A (en) * 2016-12-16 2017-04-26 武汉理工大学 Marbled glass ceramics directly employing fusion blast furnace slag and preparation method of marbled glass ceramics

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110282862A (en) * 2019-06-24 2019-09-27 鞍钢股份有限公司 A kind of device preparing foam glass and preparation method
CN110282862B (en) * 2019-06-24 2021-09-14 鞍钢股份有限公司 Device and method for preparing foam glass

Also Published As

Publication number Publication date
CN107417072B (en) 2019-12-24

Similar Documents

Publication Publication Date Title
CN106191344B (en) A kind of method for mixing the production of slag melting and reducing and modifier treatment
CN106045301B (en) A method of producing mineral wool using converter molten state early period slag
CN107021641B (en) Method for producing mineral wool from manganese-silicon alloy slag
CN102617164B (en) Acid lining material of medium-frequency induction furnace and furnace building method thereof
CN100489140C (en) Vertical grinding hollow abrading-resistant ball chemical composition control and thermal treatment process
CN103994663B (en) A kind of method extending medium-frequency induction furnace lining durability
CN103803793B (en) Method for preparing inorganic fibers by using direct blowing of blast furnace molten slag
CN104370455A (en) Method and device for producing mineral wool by matching molten-state blast furnace slag with mine tailings
CN103575103B (en) Mineral wool, rock wool, devitrified glass, the crucible of cast stone series products is produced for induction furnace
CN102161567A (en) Method for smelting nickel alloy by utilizing ore-smelting electric furnace and producing mineral wool fiber by melting waste residues and utilizing sensible heat
CN104891814A (en) Method for preparing high temperature resistance foam material by adopting molten blast furnace slag
CN102889789A (en) Furnace building method of intermediate-frequency induction furnace for copper alloy smelting
CN102242231B (en) Method for producing flat plate-shaped inorganic non-metallic material by molten slag
CN104357650A (en) Method for quickly creating molten bath for bath smelting
CN107062900B (en) A kind of alternating current arc smelting furnace
CN103588393A (en) Preparation technology for melt for production of mineral wool, rock wool and cast stone products
CN103643056B (en) The smelting process of low carbon ferromanganese
CN107602087A (en) A kind of fire resisting low carbon magnesia carbon brick
CN103063030B (en) A kind of modified compound stove of slag and operating procedure thereof
CN102992805A (en) High-thermal conductivity ultramicropore carbon brick and preparation method thereof
CN102399055A (en) Method for preparing super-fine inorganic fiber by using nickel-iron smelting waste residue
CN107056039B (en) Utilize the device of liquid blast furnace production mineral wool
CN107417072A (en) A kind of device of liquid blast furnace production foam glass
CN107162432B (en) A kind of device of liquid blast furnace production mineral wool
CN102051482A (en) Process for directly reducing ferrochrome powder ore by microwave and crucible special for same

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: 266061 Qingdao University, 93 Songling Road, Laoshan District, Qingdao City, Shandong Province

Applicant after: Xu Yurui

Address before: 266404 Electrical Engineering Department, Qingdao Bay College, No. 316, two road, science and education, West Coast New District, Qingdao, Shandong

Applicant before: Xu Yurui

CB02 Change of applicant information
CB02 Change of applicant information

Address after: Jiuyang group, No.8, Zhengtong South Road, Yangli Town, Laiwu District, Jinan City, Shandong Province

Applicant after: Xu Yurui

Address before: 266061 Qingdao University, 93 Songling Road, Laoshan District, Qingdao City, Shandong Province

Applicant before: Xu Yurui

CB02 Change of applicant information
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20240124

Address after: No. 29 Longtan East Street, Laiwu District, Jinan City, Shandong Province, 271199

Patentee after: Shandong Luxin Guohe energy saving and Environmental Protection Technology Co.,Ltd.

Country or region after: China

Address before: Jiuyang group, No.8 Zhengtong South Road, Yangli Town, Laiwu District, Jinan City, Shandong Province

Patentee before: Xu Yurui

Country or region before: China

TR01 Transfer of patent right