CN107407056A - Package paper - Google Patents
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- Publication number
- CN107407056A CN107407056A CN201680011852.8A CN201680011852A CN107407056A CN 107407056 A CN107407056 A CN 107407056A CN 201680011852 A CN201680011852 A CN 201680011852A CN 107407056 A CN107407056 A CN 107407056A
- Authority
- CN
- China
- Prior art keywords
- paper
- pulp
- package
- watermark portion
- watermark
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/12—Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/14—Polyalkenes, e.g. polystyrene polyethylene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/02—Patterned paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
Abstract
The present invention provides a kind of watermark portion when in face of light and non-watermark portion produces contrast, watermark portion is high-visible, design is excellent and resiliency also excellent package paper.The package paper of the present invention is package paper obtained from natural pulp is mixed into copy paper with olefin-based synthetic paper-pulp, and it has the light transmittance watermark portion higher than periphery, and paper pulp is not present in the watermark portion or paper pulp is fewer than periphery.The weight per unit area of the package paper of the present invention is preferably 30g/m2Below.The package paper of the present invention to form l Water Paper and then the process for drying l Water Paper manufacture by being ferreted out two paper pulp from the dispersion liquid of natural pulp and synthetic paper-pulp, formed with the absence of paper pulp or the paper pulp part fewer than periphery in the l Water Paper before it is dried.
Description
Technical field
The present invention relates to package paper, specifically, is related to the package paper formed by the bristol paper for applying white watermark.
Background technology
The bristol paper of watermarked pattern is widely used in being packed for, decorates the necks such as use, printing use according to its external appearance characteristic
Domain.Applying the watermark recovery on paper, to have pattern part to appear black and visible around visible " white watermark " and pattern part ratio
" Heisui River print ".L Water Paper formation stages (wire-cloths) of these watermark recoveries generally in copy paper process are by making the list of paper pulp
Change and formed plane product wt part.In wire-cloths, using the pattern for applying punch-pin copy paper net when, to wet
Corresponding with the pattern part of the punch-pin in paper partly to implement the thin pressing mold of thickness ratio periphery, the part through pressing mold turns into will
White watermark in paper obtained from the l Water Paper is dried.In addition, other forming methods as white watermark, it is also known that in paper machine
The l Water Paper (the homogeneous l Water Paper of pulp unit area weight) that wet end is formed is pressed against outer surface and applies pressure roller of pattern of punch-pin etc.
Outer surface of pressing means, so as to the method that the pattern is transferred into l Water Paper and figuration.
Patent Document 1 discloses the counterfeit prevention paper with white watermark.The counterfeit prevention paper with white watermark is by will be to natural
Paper obtained from paper pulp and polyolefin series fiber mixing copy paper carries out hot-pressing processing with processing outside the machine after copy paper and obtained, plain boiled water
Print by under the hot-pressing processing polyolefin series fiber softening melting and formed.
Patent document
Patent document 1:Japanese Unexamined Patent Publication 2005-330622 publications
The content of the invention
Invent problem to be solved
The present invention relates to producing contrast at non-watermark portion, watermark portion is high-visible, designs in watermark portion when in face of light
The excellent and resiliency of property also excellent package paper.
Means for solving the problems
The package paper of the present invention is package paper obtained from natural pulp is mixed into copy paper with olefin-based synthetic paper-pulp,
It has the light transmittance watermark portion higher than periphery, and paper pulp is not present in the watermark portion or paper pulp is fewer than periphery.
In addition, manufacture method of the manufacture method of the package paper of the present invention for the package paper of the invention described above, it has
Have and be ferreted out to form l Water Paper and then dry the l Water Paper by two paper pulp from the dispersion liquid of above-mentioned natural pulp and above-mentioned synthetic paper-pulp
Process, formed with the absence of paper pulp or the paper pulp part fewer than periphery in the l Water Paper before it is dried.
In the manufacture method of the package paper of the invention described above, " paper pulp is not present or paper pulp compares periphery in l Water Paper
In formation predetermined portions of the few part " preferably in the formation process of l Water Paper, by purposefully hindering above-mentioned watermark portion
The accumulation of paper pulp is formed.
Invention effect
According to the present invention, there is provided produced when in face of light at watermark portion and non-watermark portion contrast, watermark portion it is high-visible,
Design is excellent and resiliency also excellent package paper.
Brief description of the drawings
In Fig. 1, the photograph for the package paper that Fig. 1 (a) is the photo of the package paper of embodiment 1, Fig. 1 (b) is comparative example 1
Piece.
Embodiment
The package paper of the present invention with olefin-based synthetic paper-pulp by natural pulp by mixing copy paper to obtain.The present invention
In, as natural pulp, mainly using coniferous tree bleached sulfate pulp (NBKP), bleached hardwood sulfate pulp
(LBKP), the Wood Bleaching chemical pulp such as coniferous tree bleached sulfite pulp (NBSP), as needed using photogrammetry pulp mill
(GP), the mechanical pulp such as thermomechanical paper pulp (TMP), chemithermomechanical pulps (BCTMP);Fiber crops, bamboo, straw, mestha, knot
The non-wood pulps such as perfume, paper mulberry, cotton;Old paper stock.In the present invention, a kind of these natural pulps can be used alone or by 2
Kind combination of the above uses.
Canadian Standard Freeness (Canadian specified in the JIS P8121 of the natural pulp used in the present invention
Standard freeness) it is preferably 100~500ml, more preferably 250~400ml.Freedom is to represent that paper pulp is beaten
The value of the degree of slurry (carrying out the processing that machinery beats, ground to paper pulp in the presence of water), the value of usual freedom is smaller, mashing
Degree it is stronger, be beaten that damage to fiber is bigger, fibrillation is carried out.The freedom of natural pulp within the above range when, bag
The balance for each characteristics such as the weight per unit area of dress paper reduces, liquid permeability improves becomes good.The adjustment of freedom, i.e.
The mashing degree of paper pulp adjustment can by the species to beating apparatus, treatment conditions (pulp density, temperature, pressure, rotating speed,
The shape of knife, number of processes etc.) appropriate adjustment is carried out to carry out.As beating apparatus, known device can be used, such as except
Outside the beater such as beater, PFI mills, single-deck disc mill, double plate disc mill, can also use pigment etc. it is scattered, crush
The dispersion machines such as the middle ball mill used, DYNO-MILL.
As the olefin-based resin of olefin-based synthetic paper-pulp that is used in the present invention is formed, can include such as polyethylene,
Polypropylene etc..
The olefin-based synthetic paper-pulp used in the present invention from the viewpoint such as sufficient paper power in practicality is ensured, preferably with day
Right paper pulp has similarly carried out the paper pulp of fibrillation.The fibrillation of olefin-based synthetic paper-pulp can use the fibril with natural pulp
Change same method to carry out.The freedom of the olefin-based synthetic paper-pulp used in the present invention be preferably 100~700ml, further
Preferably 300~600ml.
As the commercially available olefin-based synthetic paper-pulp preferably used in the present invention, Mitsui Chemicals, Inc's system can be included
SWP (registration mark).The SWP is the olefin-based synthetic paper-pulp through fibrillation.
In addition, the fibre length of the olefin-based synthetic paper-pulp used in the present invention be preferably 0.1~2.0mm, further it is excellent
Elect 0.5~1.5mm as.The fibre length of olefin-based synthetic paper-pulp within the range when, passing through wet paper manufacturing method manufacture packaging
With the wire-cloths in copy paper process during paper, draining improves, and is easily formed watermark portion.
Contain other in addition to natural pulp and olefin-based synthetic paper-pulp in the package paper of the present invention as needed
Composition, such as the paper power reinforcing agent such as starch, polyacrylamide, polyamine polyamide epoxychloropropane or sticking agent, sizing agent, fill out
The additive usually used in wet paper manufacturing method such as material, drainage retention agent, resistance to hydrated agent, sticking agent, defoamer, slimicide
In it is one kind or two or more.
The package paper of the present invention has the light transmittance watermark portion higher than periphery.The watermark portion of the present invention is in the absence of paper
Slurry or the paper pulp part fewer than periphery (non-watermark portion), in other words, for the through hole for penetrating package paper through-thickness
Or the low paper pulp accumulation portion that the accumulating amount of paper pulp is fewer than periphery (non-watermark portion), when observing in transmitted light, for than periphery
Bright, penetrating visible so-called white watermark.In the package paper of the present invention, the plan view shape in watermark portion, size, quantity, shape
It is not particularly limited, can be suitably adjusted according to purposes etc. into pattern (pattern) etc..One as the package paper of the present invention
Individual example, multiple watermark portions can be included and formed with defined pattern, the form that each watermark portion is surrounded by non-watermark portion.Watermark portion
It can be only through hole, also can be only low paper pulp accumulation portion, can also include both, as an example of such a situation, can arrange
Enumerate comprising the through hole that penetrates package paper through-thickness and surround the through hole and the accumulating amount of paper pulp compares periphery
Few low paper pulp accumulation portion and the watermark portion formed.On the other hand, the periphery in watermark portion is the accumulation that non-watermark portion is paper pulp
The high paper pulp accumulation portion more than watermark portion is measured, is the position for not making light transmission or light transmittance lower than watermark portion.
According to the cognition of the present inventors, the paper with white watermark comprising natural pulp and olefin-based synthetic paper-pulp with comprising
Natural pulp but compared not comprising the common paper of olefin-based synthetic paper-pulp, the contrast in watermark portion and non-watermark portion when in face of light
Degree becomes apparent, therefore can give observer just like watermark portion floats such impression, therefore watermark portion is clear, design
It is high.That is, olefin-based synthetic paper-pulp plays and improves the opacity of paper, makes the high-visible effect of white watermark.In addition generally, alkene
Hydrocarbon system synthetic paper-pulp fibre length compared with natural pulp is short and drainage is good, and its result is when the alkene that will be had characteristics that
When being that synthetic paper-pulp is used as fibrous raw material, the paper machine in copy paper process when package paper is manufactured by wet paper manufacturing method
In wet end, through hole or low paper pulp accumulation portion can be easily formed on l Water Paper, therefore also the formation with watermark portion is easy
The advantages of.The invention that the package paper of the present invention is based on such cognition and completed.
Opacity (part (the non-watermark in addition to watermark portion specified in the JIS P8149 of the package paper of the present invention
Portion) opacity) be preferably 35~80%, more preferably 40~65%.The opacity of package paper can be by right
Species, the content of olefin-based synthetic paper-pulp carry out appropriate adjustment to adjust.
In addition, other action effects as olefin-based synthetic paper-pulp, the effect of resiliency is also improved.That is, comprising day
The package paper of the invention of right paper pulp and olefin-based synthetic paper-pulp is not with comprising natural pulp but including olefin-based synthetic paper-pulp
Common paper compare, there is low-density and the high speciality of resiliency, be consequently adapted to the bag of article for making full use of its resiliency
Fill purposes.
The density of the package paper of the present invention is preferably 0.2~0.6g/cm3, more preferably 0.3~0.5g/cm3.Separately
Outside, the package paper of the present invention (is formed into through hole or low paper by method 1) or 2) described later on l Water Paper before it is dried
The method for starching accumulation portion) when being manufactured, i.e., (l Water Paper exists " paper pulp or the paper pulp part fewer than periphery is not present " in l Water Paper
Turn into the part in watermark portion after drying) in the formation process of l Water Paper, by the formation reservations for purposefully hindering watermark portion
When the accumulation of paper pulp in point is to form, the density in the watermark portion in so obtained package paper and the non-watermark portion on its periphery
It is identical or lower.On the other hand, the watermark portion (white watermark) in the paper that patent document 1 is recorded is due to additional by the machine after copy paper
The hot-pressing processing of work forms polyolefin series fiber softening melting, therefore speculates that the non-watermark portion on its density ratio periphery is high.
In addition, the paper that patent document 1 is recorded implements heat by a part for the homogeneous paper of the weight per unit area to paper pulp
Pressure handles and forms watermark portion, and due to its manufacture method, hot-pressing processing is not carried out in watermark portion and its periphery that hot-pressing processing is formed
Non-watermark portion there is no substantial variations in the amount of paper pulp.On this point, watermark portion of the invention is as it was previously stated, in the absence of paper
Slurry or the paper pulp part fewer than periphery (non-watermark portion), with by dry paper by hot-pressing processing and the watermark portion that is formed not only
All it is different in terms of amount in terms of the density and in paper pulp.The relatively little of watermark portion of amount of such paper pulp can not pass through paper
Hot-pressing processing formed, but as described later, by purposefully hindering the formation in watermark portion pre- in the formation process of l Water Paper
The accumulation of the paper pulp in part is determined to be formed.
In addition, as described in patent document 1, the watermark portion formed by hot-pressing processing is also dependent upon hot-pressing processing
Condition, but the olefin-based synthetic paper-pulp melting softening generally under hot-pressing processing therefore is unable to maintain that fibre morphology, with periphery
The non-watermark portion that hot-pressing processing is not carried out compares, and Inter-fiber voids are small, according to circumstances Inter-fiber voids substantially completely disappear and can
It may be the membranaceous form of film sample.On this point, the fibre morphology in the watermark portion of the invention without hot-pressing processing is able to
Maintain, compared with the non-watermark portion of periphery, the form as fiber assembly does not have substantial difference.
The resiliency used pack of package paper is evaluated with the compressive strength of paper, and the numerical value of compressive strength is bigger, the bag
The evaluation of the resiliency of dress paper is higher.But the numerical value of compressive strength it is excessive when, due to package paper rigidity increase, because
This package paper is difficult to the shape for following packed article, there is the worry of the function reduction as package paper.In view of above feelings
Condition, the compressive strength of package paper of the invention is preferably 0.2~0.9, more preferably 0.4~0.6.The pressure of package paper
Contracting intensity (resiliency) can carry out appropriate adjustment to adjust by the species to olefin-based synthetic paper-pulp, content.In addition, in order to incite somebody to action
The compressive strength of package paper is adjusted to above range, and as described later, package paper is being manufactured by wet paper manufacturing method
When copy paper process in, paper (package paper) obtained from preferred pair dries l Water Paper without pressing.
" compressive hardness of package paper " is determined using known KES compression tests, by subtracting the measured value from 1
To calculate the compressive strength of package paper.That is, " compressive strength=1- compressive hardnesses ", the numerical value of compressive hardness is bigger, the packaging
With compressive strength (resiliency) the more lower assessment valency of paper.The assay method for having used the compressive hardness of KES compression tests is use
Circular flat (2cm2) stress of measure when measure object (package paper) compress method, the straight line that compressive hardness compresses
Property represent, its numerical value is closer to 1, then it represents that measure object is harder.
The assay method of compressive strength is more specifically illustrated.The KES compression tests used in measure possess with
The area of the contact portion of measure object is 2cm2Metal pressurized, as the KES compression tests so formed, can arrange
Enumerate and for example possess discoideus metal pressurized, Kato Tech Co. Ltd. systems trade name " KES-G5 ".Will measure
Object (package paper) is fixed in the sample mounting table of KES compression tests, from the top of the measure object by pressurized with
Defined press-in speed is pressed into the thickness direction of measure object with defined pressure, determines the maximum of now stress.Make to add
The press-in speed of pressure is 50~500gf/cm in 0.0067~0.02mm/ seconds, press-in pressure2In the range of.To measure object
Area be 100cm2Each region implement the measure of the maximum stress at any 3, by so obtained multiple measured values
Compressive hardness of the average value as measure object, the compressive strength of measure object is calculated by following formula.
Compressive strength=1- compressive hardnesses
Resiliency (compressive strength) or paper power etc. as package paper key property by possessed by its package paper
The not small influence of the pattern in watermark portion.That is, the compressive strength of package paper can be because of the vertical view shape in the watermark portion in its package paper
Shape, size, quantity etc. and change.Particularly, if weight per unit area is 30g/m2Such low weight per unit area below
Package paper has that the absolute magnitude of the paper pulp of positive acting is few to resiliency or paper power, therefore the watermark portion in the package paper
Influence of the pattern to resiliency etc. is very important.Moreover, the watermark portion of the present invention is as it was previously stated, in the absence of paper pulp or paper pulp ratio
The few part of periphery (non-watermark portion), its result in order to further positively meet key property as package paper, this
The relatively little of part of sample paper pulp in package paper compared with locally lying in, more preferably discrete in package paper entirety or scatterplot
Exist shape.
In the present invention, the pattern in watermark portion is not particularly limited, such as can be from one end of package paper to another
Hold continuous wire is such, the watermark portion of " shape do not surrounded by non-watermark portion " (non-closed shape) is multiple discretely to exist
Form, but in view of the key property of the package paper such as resiliency, preferably " multiple watermark portion scatterplot shapes are present in package paper
Overall and each watermark portion is surrounded the pattern for the shape for forming closure by non-watermark portion ".The package paper of each embodiment described later
For the specific manifestation of the pattern in the preferable watermark portion.The plan view shape in each watermark portion is not particularly limited, can from toroidal,
Arbitrarily selected in wire such as more than elliptical shape, triangular shaped, quadrangle polygonal shape, straight line or curve etc., separately
Outside can also be by two or more different combination of plan view shape.
From the viewpoint of the key property as package paper such as resiliency is positively met, 1 in package paper
The area in watermark portion is preferably 1.5cm2Below, it is more preferably 0.01~1.0cm2。
In addition from the same viewpoint, when the area in 1 watermark portion is in above-mentioned preferable scope, package paper it is every
100cm2The quantity in the watermark portion of area is preferably more than 5, more preferably 10~600.
In addition from the same viewpoint, the distance (spacing in watermark portion) between the center between adjacent watermark portion is preferred
For 1~50mm, more preferably 3~30mm.
In addition, from the viewpoint of the action effect for more reliably playing previously described olefin-based synthetic paper-pulp, this hair
The content of olefin-based synthetic paper-pulp in bright package paper is excellent relative to the mass parts of natural pulp 100 in the package paper
Elect 1~70 mass parts, more preferably 5~40 mass parts as.Olefin-based synthetic paper-pulp relative to natural pulp content mistake
When few, there is the worry for the action effect that can not fully obtain previously described olefin-based synthetic paper-pulp, when olefin-based synthetic paper-pulp
When excessive relative to the content of natural pulp, there is sheet strength to die down, worry as the intensity needed for wrapping paper can not be obtained.
The package paper of the present invention can be manufactured by known wet paper manufacturing method, specifically be carried out by following processes
Manufacture:Two paper pulp are ferreted out to form l Water Paper from the dispersion liquid of natural pulp and synthetic paper-pulp using copy paper net, it is then that this is wet
Paper is dried.The accumulating amount in above-mentioned watermark portion, i.e., the through hole penetrated package paper through-thickness or paper pulp is fewer than periphery
Low paper pulp accumulation portion can as to make l Water Paper dry obtained from paper press outer surface apply relief pattern roller the appearance
Face carries out figuration, the method (dry-pressing pattern method) of relief pattern progress figuration is transferred to the paper to be formed, but press such
In the method for pressing dry dry paper, load that the effect that has the resiliency that previously described olefin-based synthetic paper-pulp brings to improve reduces
Sorrow.Therefore, from the viewpoint of the excellent package paper of resiliency is positively obtained, formed not on l Water Paper preferably before it is dried
Paper pulp or the paper pulp part fewer than periphery (through hole or low paper pulp accumulation portion) be present.The through hole or low paper formed on l Water Paper
Slurry accumulation portion turns into watermark portion (white watermark) in paper (package paper) obtained from the l Water Paper is dried.
As on l Water Paper, (suppression olefin-based synthetic paper-pulp brings slow the method in formation through hole or low paper pulp accumulation portion
The method that the effect that punching property improves reduces), it can include 1) will for example be provided with and (be packed for through hole or low paper pulp accumulation portion
Watermark portion in paper) corresponding to jog copy paper net or alignment through hole or low paper pulp accumulation portion by mesh resin etc.
The copy paper net clogged is used as online of dandyprat of cylinder cylinder or fourdrinier machine etc. of cylinder mould machine, from natural pulp and
Two paper pulp are ferreted out in the dispersion liquid of synthetic paper-pulp to form the method for l Water Paper, 2) by from the dispersion liquid of natural pulp and synthetic paper-pulp
The l Water Paper that the wire-cloths of the middle paper machine known in fourdrinier machine, cylinder mould machine etc. are ferreted out and formed has with outer surface
The method of the outer surface pressing of the roller (pressure roller, absorption roller etc.) of jog corresponding with through hole or low paper pulp accumulation portion.On
Method 2) is stated due to l Water Paper partly being pressed, therefore has its pressed portion in package paper obtained from being dried
The worry that resiliency reduces, therefore preferably reduce pressure when pressing l Water Paper as far as possible (pressure roller etc. presses the line pressures of means).With
This is relative, and above-mentioned method 1), accumulation, the formation of paper pulp are pre-formed with insertion when partly hindering or limiting l Water Paper formation
The worry that the method for the l Water Paper in hole or low paper pulp accumulation portion is reduced due to no resiliency, therefore preferably use in the present invention.
The weight per unit area of package paper of the present invention is not particularly limited, package paper of the invention due to
" form low weight per unit area, as a result, even if the package paper opacity reduce, when in face of light watermark portion with it is non-
The contrast in watermark portion is obvious, watermark portion is high-visible " feature, therefore from the viewpoint of this feature is given full play to, preferably
Relatively low weight per unit area, specifically, preferably 30g/m2Below, it is more preferably 10~25g/m2。
The present invention package paper can be colored as random color, can be single layer structure, or it is multilayer laminated and
Into sandwich construction.During sandwich construction, preferably each layer is copied and integrated.In addition, during sandwich construction, can be in the whole of multilayer
Or watermark portion is formed in only a part, the watermark portion in a layer can be with overlapping under vertical view with the watermark portion in other layers.
Embodiment
Hereinafter, enumerate embodiment to illustrate the present invention in more detail, but the present invention is not limited by following examples
System.
(embodiment 1)
NBKP is used as natural pulp.NBKP double plates beating of disk refiner to Canadian Standard Freeness is reached
400ml, relative to NBKP100 mass parts, the olefin-based synthetic paper-pulp (SWP (notes of Mitsui Chemicals, Inc are added thereto
Volume trade mark), the name of an article " E620 ") 40 mass parts, prepare paper stock.Using the paper stock, with cylinder mould machine according to above-mentioned method 1)
It is 17g/m to obtain weight per unit area2Single layer structure and non-coloring package paper.Obtained package paper such as Fig. 1 (a) institutes
Show, form with being largely dispersed in the absence of paper pulp or paper pulp the watermark portion fewer than periphery.More specifically, wrapped by non-watermark portion
The close-shaped watermark portion enclosed is that scatterplot shape is present in the overall pattern of package paper, and the area in 1 watermark portion is
0.04cm2, per 100cm2The quantity in the watermark portion of area is the spacing average out to 7mm between 311, adjacent watermark portion.
(embodiment 2)
The olefin-based synthetic paper-pulp of 5 mass parts is added relative to NBKP100 mass parts, in addition, similarly to Example 1
Ground operates, and it is 17g/m to obtain weight per unit area2Single layer structure and non-coloring package paper.
(embodiment 3)
The olefin-based synthetic paper-pulp of 10 mass parts is added relative to NBKP100 mass parts, it is in addition, same with embodiment 1
Operate sample, obtain weight per unit area 17g/m2Single layer structure and non-coloring package paper.
(embodiment 4)
The olefin-based synthetic paper-pulp of 20 mass parts is added relative to NBKP100 mass parts, it is in addition, same with embodiment 1
Operate sample, obtain weight per unit area 17g/m2Single layer structure and non-coloring package paper.
(embodiment 5)
Except making weight per unit area be 30g/m2In addition, operate similarly to Example 1, obtain single layer structure and undeliverable
The package paper of color.
(comparative example 1)
In addition to without using olefin-based synthetic paper-pulp, operate similarly to Example 1, obtaining weight per unit area is
17g/m2Single layer structure and non-coloring package paper.
(comparative example 2)
By watermark portion according to patent document 1 method, i.e. as to paper obtained from l Water Paper is dried with defined pattern
The method for implementing hot-pressing processing is formed, and in addition, is operated similarly to Example 1, it is 17g/ to obtain weight per unit area
m2Single layer structure and non-coloring package paper.More specifically, using paper stock same as Example 1, made by cylinder
The homogeneous paper of paper machine manufacture weight per unit area, heating is implemented with the watermark portion pattern identical pattern with embodiment 1 to the paper
The hot-pressing processing that temperature is 140 DEG C, the heat time is 4 seconds, form watermark portion.The watermark portion formed by hot-pressing processing is due to it
Present in olefin-based synthetic paper-pulp melting softening, therefore compared with the non-watermark portion on periphery, paper pulp occur under hot-pressing processing
Amount there is no substantial difference, but density is high and fibre morphology fails to maintain.
Opacity and compressive strength are evaluated according to the method described above respectively to the package paper of each embodiment and comparative example.Will
The results are shown in table 1 below.
Table 1
As shown in table 1, the package paper of each embodiment outside natural pulp due to also including olefin-based synthetic paper-pulp, therefore
Compared with the package paper of the comparative example 1 not comprising olefin-based synthetic paper-pulp, the opacity height and compressive strength in non-watermark portion
I.e. resiliency is high.As it was noted above, when the opacity in non-watermark portion is high, due to package paper when in face of light watermark portion with
The contrast in non-watermark portion becomes obvious, therefore plays the visual effect that watermark portion floats, and watermark portion is high-visible, design carries
It is high.In fact, the as shown in figure 1, package paper (reference picture 1 of the package paper (reference picture 1 (a)) of embodiment 1 and comparative example 1
(b)) compare, the contrast in watermark portion and non-watermark portion is obvious, and watermark portion is high-visible.
From the above content, it can be seen that in order to obtain design and the excellent package paper with watermark portion of resiliency, will be natural
It is effective that paper pulp mixes copy paper with olefin-based synthetic paper-pulp.
In addition, comparative example 2 is formed by hot-pressing processing different from embodiment 1 on this aspect in watermark portion, its result is due to this
The difference of manufacture method, the paper pulp quality entity at the non-watermark portion on watermark portion and periphery (non-hot pressing processing unit) place in comparative example 2
Upper identical, this point is different in the absence of the composition of paper pulp or the paper pulp embodiment 1 fewer than periphery from watermark portion.In addition, comparative example 2
Because hot-pressing processing is passed through in watermark portion, therefore fibre morphology is unable to maintain that, the fibre morphology in this point and watermark portion is maintained, is fine
It is different from the composition for the embodiment 1 that non-watermark portion is substantially the same to tie up form.Moreover, embodiment 1 and comparative example 2 are although watermark portion
Pattern it is identical, the visible significant difference in terms of compressive strength, be that the resiliency of embodiment 1 is more excellent but as shown in table 1
Result.
From above content, in order to obtain the high package paper with watermark of resiliency, paper is not present in preferably watermark portion
Slurry or paper pulp are fewer than periphery (non-watermark portion), or preferably maintain fibre morphology in watermark portion.
Claims (4)
1. a kind of package paper, it is package paper obtained from natural pulp is mixed into copy paper with olefin-based synthetic paper-pulp, its
With the light transmittance watermark portion higher than periphery, paper pulp is not present in the watermark portion or paper pulp is fewer than periphery.
2. package paper according to claim 1, its weight per unit area is 30g/m2Below.
3. package paper according to claim 1 or 2, its compressive strength determined by following methods is 0.2~0.9,
The assay method of compressive strength:Area using the contact portion with measure object is 2cm2Metal pressurized, by institute
State pressurized to be pressed into defined pressure to the thickness direction of measure object with defined press-in speed, now stress is most for measure
Big value;The press-in speed of pressurized is set in 0.0067~0.02mm/ seconds, press-in pressure to be 50~500gf/cm2In the range of;It is right
Area in measure object is 100cm2Each region the measure of the maximum stress is carried out at any 3, will be so obtained
Compressive hardness of the average value of multiple measured values as measure object, the compressive strength of measure object is calculated by following formula,
Compressive strength=1- compressive hardnesses.
4. the manufacture method of the package paper in claims 1 to 3 described in wantonly 1, it has from the natural pulp and described
Two paper pulp are ferreted out the process to form l Water Paper and then dry the l Water Paper in the dispersion liquid of synthetic paper-pulp, institute before it is dried
State in l Water Paper formed with the absence of paper pulp or the paper pulp part fewer than periphery.
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JP2015038896 | 2015-02-27 | ||
JP2015-038896 | 2015-02-27 | ||
PCT/JP2016/055858 WO2016136954A1 (en) | 2015-02-27 | 2016-02-26 | Wrapping paper |
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CN201680011852.8A Pending CN107407056A (en) | 2015-02-27 | 2016-02-26 | Package paper |
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JP (1) | JP6781691B2 (en) |
CN (1) | CN107407056A (en) |
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CN110344284A (en) * | 2018-04-04 | 2019-10-18 | 特种东海制纸株式会社 | Printing |
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JPS49110905A (en) * | 1973-03-01 | 1974-10-22 | ||
JP2592377B2 (en) * | 1992-05-08 | 1997-03-19 | 特種製紙株式会社 | Pattern net for see-through and method for manufacturing see-through paper using the same |
JP2005041012A (en) * | 2003-07-23 | 2005-02-17 | Mitsui Chemicals Inc | Film for in-mold label and container using it |
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2016
- 2016-02-26 JP JP2017502515A patent/JP6781691B2/en active Active
- 2016-02-26 WO PCT/JP2016/055858 patent/WO2016136954A1/en active Application Filing
- 2016-02-26 CN CN201680011852.8A patent/CN107407056A/en active Pending
- 2016-02-26 TW TW105106091A patent/TW201641780A/en unknown
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CN1207784A (en) * | 1996-01-12 | 1999-02-10 | 波特尔斯有限公司 | Security paper |
CN101748660A (en) * | 2008-12-01 | 2010-06-23 | 中国印钞造币总公司 | Anti-counterfeit water marked paper and manufacturing method thereof |
CN102400420A (en) * | 2010-09-16 | 2012-04-04 | 保定钞票纸业有限公司 | Anti-counterfeiting paper with wide multilayer white watermark and manufacturing method thereof |
CN102296485A (en) * | 2011-08-22 | 2011-12-28 | 保定钞票纸业有限公司 | Watermarked paper having multiple observed effects, and preparation method thereof |
CN103321104A (en) * | 2013-05-14 | 2013-09-25 | 珠海经济特区红塔仁恒纸业有限公司 | Thermosensitive color-changing anti-counterfeiting coating white cardboard and producing method thereof |
Cited By (1)
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CN110344284A (en) * | 2018-04-04 | 2019-10-18 | 特种东海制纸株式会社 | Printing |
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JP6781691B2 (en) | 2020-11-04 |
TW201641780A (en) | 2016-12-01 |
WO2016136954A1 (en) | 2016-09-01 |
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