CN107407056A - Package paper - Google Patents

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Publication number
CN107407056A
CN107407056A CN201680011852.8A CN201680011852A CN107407056A CN 107407056 A CN107407056 A CN 107407056A CN 201680011852 A CN201680011852 A CN 201680011852A CN 107407056 A CN107407056 A CN 107407056A
Authority
CN
China
Prior art keywords
paper
pulp
package
watermark portion
watermark
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201680011852.8A
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Chinese (zh)
Inventor
铃木幸惠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokushu Tokai Paper Co Ltd
Original Assignee
Tokushu Tokai Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokushu Tokai Paper Co Ltd filed Critical Tokushu Tokai Paper Co Ltd
Publication of CN107407056A publication Critical patent/CN107407056A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/12Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/14Polyalkenes, e.g. polystyrene polyethylene
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/02Patterned paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper

Abstract

The present invention provides a kind of watermark portion when in face of light and non-watermark portion produces contrast, watermark portion is high-visible, design is excellent and resiliency also excellent package paper.The package paper of the present invention is package paper obtained from natural pulp is mixed into copy paper with olefin-based synthetic paper-pulp, and it has the light transmittance watermark portion higher than periphery, and paper pulp is not present in the watermark portion or paper pulp is fewer than periphery.The weight per unit area of the package paper of the present invention is preferably 30g/m2Below.The package paper of the present invention to form l Water Paper and then the process for drying l Water Paper manufacture by being ferreted out two paper pulp from the dispersion liquid of natural pulp and synthetic paper-pulp, formed with the absence of paper pulp or the paper pulp part fewer than periphery in the l Water Paper before it is dried.

Description

Package paper
Technical field
The present invention relates to package paper, specifically, is related to the package paper formed by the bristol paper for applying white watermark.
Background technology
The bristol paper of watermarked pattern is widely used in being packed for, decorates the necks such as use, printing use according to its external appearance characteristic Domain.Applying the watermark recovery on paper, to have pattern part to appear black and visible around visible " white watermark " and pattern part ratio " Heisui River print ".L Water Paper formation stages (wire-cloths) of these watermark recoveries generally in copy paper process are by making the list of paper pulp Change and formed plane product wt part.In wire-cloths, using the pattern for applying punch-pin copy paper net when, to wet Corresponding with the pattern part of the punch-pin in paper partly to implement the thin pressing mold of thickness ratio periphery, the part through pressing mold turns into will White watermark in paper obtained from the l Water Paper is dried.In addition, other forming methods as white watermark, it is also known that in paper machine The l Water Paper (the homogeneous l Water Paper of pulp unit area weight) that wet end is formed is pressed against outer surface and applies pressure roller of pattern of punch-pin etc. Outer surface of pressing means, so as to the method that the pattern is transferred into l Water Paper and figuration.
Patent Document 1 discloses the counterfeit prevention paper with white watermark.The counterfeit prevention paper with white watermark is by will be to natural Paper obtained from paper pulp and polyolefin series fiber mixing copy paper carries out hot-pressing processing with processing outside the machine after copy paper and obtained, plain boiled water Print by under the hot-pressing processing polyolefin series fiber softening melting and formed.
Patent document
Patent document 1:Japanese Unexamined Patent Publication 2005-330622 publications
The content of the invention
Invent problem to be solved
The present invention relates to producing contrast at non-watermark portion, watermark portion is high-visible, designs in watermark portion when in face of light The excellent and resiliency of property also excellent package paper.
Means for solving the problems
The package paper of the present invention is package paper obtained from natural pulp is mixed into copy paper with olefin-based synthetic paper-pulp, It has the light transmittance watermark portion higher than periphery, and paper pulp is not present in the watermark portion or paper pulp is fewer than periphery.
In addition, manufacture method of the manufacture method of the package paper of the present invention for the package paper of the invention described above, it has Have and be ferreted out to form l Water Paper and then dry the l Water Paper by two paper pulp from the dispersion liquid of above-mentioned natural pulp and above-mentioned synthetic paper-pulp Process, formed with the absence of paper pulp or the paper pulp part fewer than periphery in the l Water Paper before it is dried.
In the manufacture method of the package paper of the invention described above, " paper pulp is not present or paper pulp compares periphery in l Water Paper In formation predetermined portions of the few part " preferably in the formation process of l Water Paper, by purposefully hindering above-mentioned watermark portion The accumulation of paper pulp is formed.
Invention effect
According to the present invention, there is provided produced when in face of light at watermark portion and non-watermark portion contrast, watermark portion it is high-visible, Design is excellent and resiliency also excellent package paper.
Brief description of the drawings
In Fig. 1, the photograph for the package paper that Fig. 1 (a) is the photo of the package paper of embodiment 1, Fig. 1 (b) is comparative example 1 Piece.
Embodiment
The package paper of the present invention with olefin-based synthetic paper-pulp by natural pulp by mixing copy paper to obtain.The present invention In, as natural pulp, mainly using coniferous tree bleached sulfate pulp (NBKP), bleached hardwood sulfate pulp (LBKP), the Wood Bleaching chemical pulp such as coniferous tree bleached sulfite pulp (NBSP), as needed using photogrammetry pulp mill (GP), the mechanical pulp such as thermomechanical paper pulp (TMP), chemithermomechanical pulps (BCTMP);Fiber crops, bamboo, straw, mestha, knot The non-wood pulps such as perfume, paper mulberry, cotton;Old paper stock.In the present invention, a kind of these natural pulps can be used alone or by 2 Kind combination of the above uses.
Canadian Standard Freeness (Canadian specified in the JIS P8121 of the natural pulp used in the present invention Standard freeness) it is preferably 100~500ml, more preferably 250~400ml.Freedom is to represent that paper pulp is beaten The value of the degree of slurry (carrying out the processing that machinery beats, ground to paper pulp in the presence of water), the value of usual freedom is smaller, mashing Degree it is stronger, be beaten that damage to fiber is bigger, fibrillation is carried out.The freedom of natural pulp within the above range when, bag The balance for each characteristics such as the weight per unit area of dress paper reduces, liquid permeability improves becomes good.The adjustment of freedom, i.e. The mashing degree of paper pulp adjustment can by the species to beating apparatus, treatment conditions (pulp density, temperature, pressure, rotating speed, The shape of knife, number of processes etc.) appropriate adjustment is carried out to carry out.As beating apparatus, known device can be used, such as except Outside the beater such as beater, PFI mills, single-deck disc mill, double plate disc mill, can also use pigment etc. it is scattered, crush The dispersion machines such as the middle ball mill used, DYNO-MILL.
As the olefin-based resin of olefin-based synthetic paper-pulp that is used in the present invention is formed, can include such as polyethylene, Polypropylene etc..
The olefin-based synthetic paper-pulp used in the present invention from the viewpoint such as sufficient paper power in practicality is ensured, preferably with day Right paper pulp has similarly carried out the paper pulp of fibrillation.The fibrillation of olefin-based synthetic paper-pulp can use the fibril with natural pulp Change same method to carry out.The freedom of the olefin-based synthetic paper-pulp used in the present invention be preferably 100~700ml, further Preferably 300~600ml.
As the commercially available olefin-based synthetic paper-pulp preferably used in the present invention, Mitsui Chemicals, Inc's system can be included SWP (registration mark).The SWP is the olefin-based synthetic paper-pulp through fibrillation.
In addition, the fibre length of the olefin-based synthetic paper-pulp used in the present invention be preferably 0.1~2.0mm, further it is excellent Elect 0.5~1.5mm as.The fibre length of olefin-based synthetic paper-pulp within the range when, passing through wet paper manufacturing method manufacture packaging With the wire-cloths in copy paper process during paper, draining improves, and is easily formed watermark portion.
Contain other in addition to natural pulp and olefin-based synthetic paper-pulp in the package paper of the present invention as needed Composition, such as the paper power reinforcing agent such as starch, polyacrylamide, polyamine polyamide epoxychloropropane or sticking agent, sizing agent, fill out The additive usually used in wet paper manufacturing method such as material, drainage retention agent, resistance to hydrated agent, sticking agent, defoamer, slimicide In it is one kind or two or more.
The package paper of the present invention has the light transmittance watermark portion higher than periphery.The watermark portion of the present invention is in the absence of paper Slurry or the paper pulp part fewer than periphery (non-watermark portion), in other words, for the through hole for penetrating package paper through-thickness Or the low paper pulp accumulation portion that the accumulating amount of paper pulp is fewer than periphery (non-watermark portion), when observing in transmitted light, for than periphery Bright, penetrating visible so-called white watermark.In the package paper of the present invention, the plan view shape in watermark portion, size, quantity, shape It is not particularly limited, can be suitably adjusted according to purposes etc. into pattern (pattern) etc..One as the package paper of the present invention Individual example, multiple watermark portions can be included and formed with defined pattern, the form that each watermark portion is surrounded by non-watermark portion.Watermark portion It can be only through hole, also can be only low paper pulp accumulation portion, can also include both, as an example of such a situation, can arrange Enumerate comprising the through hole that penetrates package paper through-thickness and surround the through hole and the accumulating amount of paper pulp compares periphery Few low paper pulp accumulation portion and the watermark portion formed.On the other hand, the periphery in watermark portion is the accumulation that non-watermark portion is paper pulp The high paper pulp accumulation portion more than watermark portion is measured, is the position for not making light transmission or light transmittance lower than watermark portion.
According to the cognition of the present inventors, the paper with white watermark comprising natural pulp and olefin-based synthetic paper-pulp with comprising Natural pulp but compared not comprising the common paper of olefin-based synthetic paper-pulp, the contrast in watermark portion and non-watermark portion when in face of light Degree becomes apparent, therefore can give observer just like watermark portion floats such impression, therefore watermark portion is clear, design It is high.That is, olefin-based synthetic paper-pulp plays and improves the opacity of paper, makes the high-visible effect of white watermark.In addition generally, alkene Hydrocarbon system synthetic paper-pulp fibre length compared with natural pulp is short and drainage is good, and its result is when the alkene that will be had characteristics that When being that synthetic paper-pulp is used as fibrous raw material, the paper machine in copy paper process when package paper is manufactured by wet paper manufacturing method In wet end, through hole or low paper pulp accumulation portion can be easily formed on l Water Paper, therefore also the formation with watermark portion is easy The advantages of.The invention that the package paper of the present invention is based on such cognition and completed.
Opacity (part (the non-watermark in addition to watermark portion specified in the JIS P8149 of the package paper of the present invention Portion) opacity) be preferably 35~80%, more preferably 40~65%.The opacity of package paper can be by right Species, the content of olefin-based synthetic paper-pulp carry out appropriate adjustment to adjust.
In addition, other action effects as olefin-based synthetic paper-pulp, the effect of resiliency is also improved.That is, comprising day The package paper of the invention of right paper pulp and olefin-based synthetic paper-pulp is not with comprising natural pulp but including olefin-based synthetic paper-pulp Common paper compare, there is low-density and the high speciality of resiliency, be consequently adapted to the bag of article for making full use of its resiliency Fill purposes.
The density of the package paper of the present invention is preferably 0.2~0.6g/cm3, more preferably 0.3~0.5g/cm3.Separately Outside, the package paper of the present invention (is formed into through hole or low paper by method 1) or 2) described later on l Water Paper before it is dried The method for starching accumulation portion) when being manufactured, i.e., (l Water Paper exists " paper pulp or the paper pulp part fewer than periphery is not present " in l Water Paper Turn into the part in watermark portion after drying) in the formation process of l Water Paper, by the formation reservations for purposefully hindering watermark portion When the accumulation of paper pulp in point is to form, the density in the watermark portion in so obtained package paper and the non-watermark portion on its periphery It is identical or lower.On the other hand, the watermark portion (white watermark) in the paper that patent document 1 is recorded is due to additional by the machine after copy paper The hot-pressing processing of work forms polyolefin series fiber softening melting, therefore speculates that the non-watermark portion on its density ratio periphery is high.
In addition, the paper that patent document 1 is recorded implements heat by a part for the homogeneous paper of the weight per unit area to paper pulp Pressure handles and forms watermark portion, and due to its manufacture method, hot-pressing processing is not carried out in watermark portion and its periphery that hot-pressing processing is formed Non-watermark portion there is no substantial variations in the amount of paper pulp.On this point, watermark portion of the invention is as it was previously stated, in the absence of paper Slurry or the paper pulp part fewer than periphery (non-watermark portion), with by dry paper by hot-pressing processing and the watermark portion that is formed not only All it is different in terms of amount in terms of the density and in paper pulp.The relatively little of watermark portion of amount of such paper pulp can not pass through paper Hot-pressing processing formed, but as described later, by purposefully hindering the formation in watermark portion pre- in the formation process of l Water Paper The accumulation of the paper pulp in part is determined to be formed.
In addition, as described in patent document 1, the watermark portion formed by hot-pressing processing is also dependent upon hot-pressing processing Condition, but the olefin-based synthetic paper-pulp melting softening generally under hot-pressing processing therefore is unable to maintain that fibre morphology, with periphery The non-watermark portion that hot-pressing processing is not carried out compares, and Inter-fiber voids are small, according to circumstances Inter-fiber voids substantially completely disappear and can It may be the membranaceous form of film sample.On this point, the fibre morphology in the watermark portion of the invention without hot-pressing processing is able to Maintain, compared with the non-watermark portion of periphery, the form as fiber assembly does not have substantial difference.
The resiliency used pack of package paper is evaluated with the compressive strength of paper, and the numerical value of compressive strength is bigger, the bag The evaluation of the resiliency of dress paper is higher.But the numerical value of compressive strength it is excessive when, due to package paper rigidity increase, because This package paper is difficult to the shape for following packed article, there is the worry of the function reduction as package paper.In view of above feelings Condition, the compressive strength of package paper of the invention is preferably 0.2~0.9, more preferably 0.4~0.6.The pressure of package paper Contracting intensity (resiliency) can carry out appropriate adjustment to adjust by the species to olefin-based synthetic paper-pulp, content.In addition, in order to incite somebody to action The compressive strength of package paper is adjusted to above range, and as described later, package paper is being manufactured by wet paper manufacturing method When copy paper process in, paper (package paper) obtained from preferred pair dries l Water Paper without pressing.
" compressive hardness of package paper " is determined using known KES compression tests, by subtracting the measured value from 1 To calculate the compressive strength of package paper.That is, " compressive strength=1- compressive hardnesses ", the numerical value of compressive hardness is bigger, the packaging With compressive strength (resiliency) the more lower assessment valency of paper.The assay method for having used the compressive hardness of KES compression tests is use Circular flat (2cm2) stress of measure when measure object (package paper) compress method, the straight line that compressive hardness compresses Property represent, its numerical value is closer to 1, then it represents that measure object is harder.
The assay method of compressive strength is more specifically illustrated.The KES compression tests used in measure possess with The area of the contact portion of measure object is 2cm2Metal pressurized, as the KES compression tests so formed, can arrange Enumerate and for example possess discoideus metal pressurized, Kato Tech Co. Ltd. systems trade name " KES-G5 ".Will measure Object (package paper) is fixed in the sample mounting table of KES compression tests, from the top of the measure object by pressurized with Defined press-in speed is pressed into the thickness direction of measure object with defined pressure, determines the maximum of now stress.Make to add The press-in speed of pressure is 50~500gf/cm in 0.0067~0.02mm/ seconds, press-in pressure2In the range of.To measure object Area be 100cm2Each region implement the measure of the maximum stress at any 3, by so obtained multiple measured values Compressive hardness of the average value as measure object, the compressive strength of measure object is calculated by following formula.
Compressive strength=1- compressive hardnesses
Resiliency (compressive strength) or paper power etc. as package paper key property by possessed by its package paper The not small influence of the pattern in watermark portion.That is, the compressive strength of package paper can be because of the vertical view shape in the watermark portion in its package paper Shape, size, quantity etc. and change.Particularly, if weight per unit area is 30g/m2Such low weight per unit area below Package paper has that the absolute magnitude of the paper pulp of positive acting is few to resiliency or paper power, therefore the watermark portion in the package paper Influence of the pattern to resiliency etc. is very important.Moreover, the watermark portion of the present invention is as it was previously stated, in the absence of paper pulp or paper pulp ratio The few part of periphery (non-watermark portion), its result in order to further positively meet key property as package paper, this The relatively little of part of sample paper pulp in package paper compared with locally lying in, more preferably discrete in package paper entirety or scatterplot Exist shape.
In the present invention, the pattern in watermark portion is not particularly limited, such as can be from one end of package paper to another Hold continuous wire is such, the watermark portion of " shape do not surrounded by non-watermark portion " (non-closed shape) is multiple discretely to exist Form, but in view of the key property of the package paper such as resiliency, preferably " multiple watermark portion scatterplot shapes are present in package paper Overall and each watermark portion is surrounded the pattern for the shape for forming closure by non-watermark portion ".The package paper of each embodiment described later For the specific manifestation of the pattern in the preferable watermark portion.The plan view shape in each watermark portion is not particularly limited, can from toroidal, Arbitrarily selected in wire such as more than elliptical shape, triangular shaped, quadrangle polygonal shape, straight line or curve etc., separately Outside can also be by two or more different combination of plan view shape.
From the viewpoint of the key property as package paper such as resiliency is positively met, 1 in package paper The area in watermark portion is preferably 1.5cm2Below, it is more preferably 0.01~1.0cm2
In addition from the same viewpoint, when the area in 1 watermark portion is in above-mentioned preferable scope, package paper it is every 100cm2The quantity in the watermark portion of area is preferably more than 5, more preferably 10~600.
In addition from the same viewpoint, the distance (spacing in watermark portion) between the center between adjacent watermark portion is preferred For 1~50mm, more preferably 3~30mm.
In addition, from the viewpoint of the action effect for more reliably playing previously described olefin-based synthetic paper-pulp, this hair The content of olefin-based synthetic paper-pulp in bright package paper is excellent relative to the mass parts of natural pulp 100 in the package paper Elect 1~70 mass parts, more preferably 5~40 mass parts as.Olefin-based synthetic paper-pulp relative to natural pulp content mistake When few, there is the worry for the action effect that can not fully obtain previously described olefin-based synthetic paper-pulp, when olefin-based synthetic paper-pulp When excessive relative to the content of natural pulp, there is sheet strength to die down, worry as the intensity needed for wrapping paper can not be obtained.
The package paper of the present invention can be manufactured by known wet paper manufacturing method, specifically be carried out by following processes Manufacture:Two paper pulp are ferreted out to form l Water Paper from the dispersion liquid of natural pulp and synthetic paper-pulp using copy paper net, it is then that this is wet Paper is dried.The accumulating amount in above-mentioned watermark portion, i.e., the through hole penetrated package paper through-thickness or paper pulp is fewer than periphery Low paper pulp accumulation portion can as to make l Water Paper dry obtained from paper press outer surface apply relief pattern roller the appearance Face carries out figuration, the method (dry-pressing pattern method) of relief pattern progress figuration is transferred to the paper to be formed, but press such In the method for pressing dry dry paper, load that the effect that has the resiliency that previously described olefin-based synthetic paper-pulp brings to improve reduces Sorrow.Therefore, from the viewpoint of the excellent package paper of resiliency is positively obtained, formed not on l Water Paper preferably before it is dried Paper pulp or the paper pulp part fewer than periphery (through hole or low paper pulp accumulation portion) be present.The through hole or low paper formed on l Water Paper Slurry accumulation portion turns into watermark portion (white watermark) in paper (package paper) obtained from the l Water Paper is dried.
As on l Water Paper, (suppression olefin-based synthetic paper-pulp brings slow the method in formation through hole or low paper pulp accumulation portion The method that the effect that punching property improves reduces), it can include 1) will for example be provided with and (be packed for through hole or low paper pulp accumulation portion Watermark portion in paper) corresponding to jog copy paper net or alignment through hole or low paper pulp accumulation portion by mesh resin etc. The copy paper net clogged is used as online of dandyprat of cylinder cylinder or fourdrinier machine etc. of cylinder mould machine, from natural pulp and Two paper pulp are ferreted out in the dispersion liquid of synthetic paper-pulp to form the method for l Water Paper, 2) by from the dispersion liquid of natural pulp and synthetic paper-pulp The l Water Paper that the wire-cloths of the middle paper machine known in fourdrinier machine, cylinder mould machine etc. are ferreted out and formed has with outer surface The method of the outer surface pressing of the roller (pressure roller, absorption roller etc.) of jog corresponding with through hole or low paper pulp accumulation portion.On Method 2) is stated due to l Water Paper partly being pressed, therefore has its pressed portion in package paper obtained from being dried The worry that resiliency reduces, therefore preferably reduce pressure when pressing l Water Paper as far as possible (pressure roller etc. presses the line pressures of means).With This is relative, and above-mentioned method 1), accumulation, the formation of paper pulp are pre-formed with insertion when partly hindering or limiting l Water Paper formation The worry that the method for the l Water Paper in hole or low paper pulp accumulation portion is reduced due to no resiliency, therefore preferably use in the present invention.
The weight per unit area of package paper of the present invention is not particularly limited, package paper of the invention due to " form low weight per unit area, as a result, even if the package paper opacity reduce, when in face of light watermark portion with it is non- The contrast in watermark portion is obvious, watermark portion is high-visible " feature, therefore from the viewpoint of this feature is given full play to, preferably Relatively low weight per unit area, specifically, preferably 30g/m2Below, it is more preferably 10~25g/m2
The present invention package paper can be colored as random color, can be single layer structure, or it is multilayer laminated and Into sandwich construction.During sandwich construction, preferably each layer is copied and integrated.In addition, during sandwich construction, can be in the whole of multilayer Or watermark portion is formed in only a part, the watermark portion in a layer can be with overlapping under vertical view with the watermark portion in other layers.
Embodiment
Hereinafter, enumerate embodiment to illustrate the present invention in more detail, but the present invention is not limited by following examples System.
(embodiment 1)
NBKP is used as natural pulp.NBKP double plates beating of disk refiner to Canadian Standard Freeness is reached 400ml, relative to NBKP100 mass parts, the olefin-based synthetic paper-pulp (SWP (notes of Mitsui Chemicals, Inc are added thereto Volume trade mark), the name of an article " E620 ") 40 mass parts, prepare paper stock.Using the paper stock, with cylinder mould machine according to above-mentioned method 1) It is 17g/m to obtain weight per unit area2Single layer structure and non-coloring package paper.Obtained package paper such as Fig. 1 (a) institutes Show, form with being largely dispersed in the absence of paper pulp or paper pulp the watermark portion fewer than periphery.More specifically, wrapped by non-watermark portion The close-shaped watermark portion enclosed is that scatterplot shape is present in the overall pattern of package paper, and the area in 1 watermark portion is 0.04cm2, per 100cm2The quantity in the watermark portion of area is the spacing average out to 7mm between 311, adjacent watermark portion.
(embodiment 2)
The olefin-based synthetic paper-pulp of 5 mass parts is added relative to NBKP100 mass parts, in addition, similarly to Example 1 Ground operates, and it is 17g/m to obtain weight per unit area2Single layer structure and non-coloring package paper.
(embodiment 3)
The olefin-based synthetic paper-pulp of 10 mass parts is added relative to NBKP100 mass parts, it is in addition, same with embodiment 1 Operate sample, obtain weight per unit area 17g/m2Single layer structure and non-coloring package paper.
(embodiment 4)
The olefin-based synthetic paper-pulp of 20 mass parts is added relative to NBKP100 mass parts, it is in addition, same with embodiment 1 Operate sample, obtain weight per unit area 17g/m2Single layer structure and non-coloring package paper.
(embodiment 5)
Except making weight per unit area be 30g/m2In addition, operate similarly to Example 1, obtain single layer structure and undeliverable The package paper of color.
(comparative example 1)
In addition to without using olefin-based synthetic paper-pulp, operate similarly to Example 1, obtaining weight per unit area is 17g/m2Single layer structure and non-coloring package paper.
(comparative example 2)
By watermark portion according to patent document 1 method, i.e. as to paper obtained from l Water Paper is dried with defined pattern The method for implementing hot-pressing processing is formed, and in addition, is operated similarly to Example 1, it is 17g/ to obtain weight per unit area m2Single layer structure and non-coloring package paper.More specifically, using paper stock same as Example 1, made by cylinder The homogeneous paper of paper machine manufacture weight per unit area, heating is implemented with the watermark portion pattern identical pattern with embodiment 1 to the paper The hot-pressing processing that temperature is 140 DEG C, the heat time is 4 seconds, form watermark portion.The watermark portion formed by hot-pressing processing is due to it Present in olefin-based synthetic paper-pulp melting softening, therefore compared with the non-watermark portion on periphery, paper pulp occur under hot-pressing processing Amount there is no substantial difference, but density is high and fibre morphology fails to maintain.
Opacity and compressive strength are evaluated according to the method described above respectively to the package paper of each embodiment and comparative example.Will The results are shown in table 1 below.
Table 1
As shown in table 1, the package paper of each embodiment outside natural pulp due to also including olefin-based synthetic paper-pulp, therefore Compared with the package paper of the comparative example 1 not comprising olefin-based synthetic paper-pulp, the opacity height and compressive strength in non-watermark portion I.e. resiliency is high.As it was noted above, when the opacity in non-watermark portion is high, due to package paper when in face of light watermark portion with The contrast in non-watermark portion becomes obvious, therefore plays the visual effect that watermark portion floats, and watermark portion is high-visible, design carries It is high.In fact, the as shown in figure 1, package paper (reference picture 1 of the package paper (reference picture 1 (a)) of embodiment 1 and comparative example 1 (b)) compare, the contrast in watermark portion and non-watermark portion is obvious, and watermark portion is high-visible.
From the above content, it can be seen that in order to obtain design and the excellent package paper with watermark portion of resiliency, will be natural It is effective that paper pulp mixes copy paper with olefin-based synthetic paper-pulp.
In addition, comparative example 2 is formed by hot-pressing processing different from embodiment 1 on this aspect in watermark portion, its result is due to this The difference of manufacture method, the paper pulp quality entity at the non-watermark portion on watermark portion and periphery (non-hot pressing processing unit) place in comparative example 2 Upper identical, this point is different in the absence of the composition of paper pulp or the paper pulp embodiment 1 fewer than periphery from watermark portion.In addition, comparative example 2 Because hot-pressing processing is passed through in watermark portion, therefore fibre morphology is unable to maintain that, the fibre morphology in this point and watermark portion is maintained, is fine It is different from the composition for the embodiment 1 that non-watermark portion is substantially the same to tie up form.Moreover, embodiment 1 and comparative example 2 are although watermark portion Pattern it is identical, the visible significant difference in terms of compressive strength, be that the resiliency of embodiment 1 is more excellent but as shown in table 1 Result.
From above content, in order to obtain the high package paper with watermark of resiliency, paper is not present in preferably watermark portion Slurry or paper pulp are fewer than periphery (non-watermark portion), or preferably maintain fibre morphology in watermark portion.

Claims (4)

1. a kind of package paper, it is package paper obtained from natural pulp is mixed into copy paper with olefin-based synthetic paper-pulp, its With the light transmittance watermark portion higher than periphery, paper pulp is not present in the watermark portion or paper pulp is fewer than periphery.
2. package paper according to claim 1, its weight per unit area is 30g/m2Below.
3. package paper according to claim 1 or 2, its compressive strength determined by following methods is 0.2~0.9,
The assay method of compressive strength:Area using the contact portion with measure object is 2cm2Metal pressurized, by institute State pressurized to be pressed into defined pressure to the thickness direction of measure object with defined press-in speed, now stress is most for measure Big value;The press-in speed of pressurized is set in 0.0067~0.02mm/ seconds, press-in pressure to be 50~500gf/cm2In the range of;It is right Area in measure object is 100cm2Each region the measure of the maximum stress is carried out at any 3, will be so obtained Compressive hardness of the average value of multiple measured values as measure object, the compressive strength of measure object is calculated by following formula,
Compressive strength=1- compressive hardnesses.
4. the manufacture method of the package paper in claims 1 to 3 described in wantonly 1, it has from the natural pulp and described Two paper pulp are ferreted out the process to form l Water Paper and then dry the l Water Paper in the dispersion liquid of synthetic paper-pulp, institute before it is dried State in l Water Paper formed with the absence of paper pulp or the paper pulp part fewer than periphery.
CN201680011852.8A 2015-02-27 2016-02-26 Package paper Pending CN107407056A (en)

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