CN107405623A - Rice huller paddy roller - Google Patents
Rice huller paddy roller Download PDFInfo
- Publication number
- CN107405623A CN107405623A CN201680013692.0A CN201680013692A CN107405623A CN 107405623 A CN107405623 A CN 107405623A CN 201680013692 A CN201680013692 A CN 201680013692A CN 107405623 A CN107405623 A CN 107405623A
- Authority
- CN
- China
- Prior art keywords
- rice huller
- huller paddy
- silicone oil
- rubber layer
- roller
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000007164 Oryza sativa Nutrition 0.000 title claims abstract description 172
- 235000009566 rice Nutrition 0.000 title claims abstract description 172
- 240000007594 Oryza sativa Species 0.000 title 1
- 241000209094 Oryza Species 0.000 claims abstract description 171
- 229920001971 elastomer Polymers 0.000 claims abstract description 112
- 239000005060 rubber Substances 0.000 claims abstract description 112
- 239000000203 mixture Substances 0.000 claims abstract description 111
- 229920002545 silicone oil Polymers 0.000 claims abstract description 84
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims abstract description 83
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 76
- 239000012948 isocyanate Substances 0.000 claims abstract description 24
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 21
- 229920005862 polyol Polymers 0.000 claims abstract description 21
- 150000003077 polyols Chemical class 0.000 claims abstract description 21
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 19
- 230000002093 peripheral effect Effects 0.000 claims abstract description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 8
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 7
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 4
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 21
- 239000000306 component Substances 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 description 45
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 42
- 238000005299 abrasion Methods 0.000 description 36
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 30
- 238000000034 method Methods 0.000 description 25
- 230000000052 comparative effect Effects 0.000 description 24
- 238000004519 manufacturing process Methods 0.000 description 20
- -1 polymethylene Polymers 0.000 description 20
- 238000011156 evaluation Methods 0.000 description 15
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 15
- 238000012360 testing method Methods 0.000 description 13
- 238000012545 processing Methods 0.000 description 11
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 235000021329 brown rice Nutrition 0.000 description 9
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 8
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 7
- 235000017491 Bambusa tulda Nutrition 0.000 description 7
- 241001330002 Bambuseae Species 0.000 description 7
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 7
- 239000011425 bamboo Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 description 6
- 101710130081 Aspergillopepsin-1 Proteins 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 description 6
- 239000010903 husk Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 6
- 229920000459 Nitrile rubber Polymers 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 150000001991 dicarboxylic acids Chemical class 0.000 description 5
- 229940008099 dimethicone Drugs 0.000 description 5
- 229920000921 polyethylene adipate Polymers 0.000 description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 235000011037 adipic acid Nutrition 0.000 description 4
- 239000001361 adipic acid Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 230000037452 priming Effects 0.000 description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000002174 Styrene-butadiene Substances 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 235000014692 zinc oxide Nutrition 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 2
- AKCRQHGQIJBRMN-UHFFFAOYSA-N 2-chloroaniline Chemical class NC1=CC=CC=C1Cl AKCRQHGQIJBRMN-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004512 die casting Methods 0.000 description 2
- VYSYZMNJHYOXGN-UHFFFAOYSA-N ethyl n-aminocarbamate Chemical compound CCOC(=O)NN VYSYZMNJHYOXGN-UHFFFAOYSA-N 0.000 description 2
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 229920001610 polycaprolactone Polymers 0.000 description 2
- 239000004632 polycaprolactone Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 150000003376 silicon Chemical class 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 238000004441 surface measurement Methods 0.000 description 2
- ZSUXOVNWDZTCFN-UHFFFAOYSA-L tin(ii) bromide Chemical compound Br[Sn]Br ZSUXOVNWDZTCFN-UHFFFAOYSA-L 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 1
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical class OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 1
- XXCRXPYEAMCJKH-UHFFFAOYSA-N 3,3,4-trimethyloxepan-2-one Chemical compound CC1CCCOC(=O)C1(C)C XXCRXPYEAMCJKH-UHFFFAOYSA-N 0.000 description 1
- AXPZIVKEZRHGAS-UHFFFAOYSA-N 3-benzyl-5-[(2-nitrophenoxy)methyl]oxolan-2-one Chemical compound [O-][N+](=O)C1=CC=CC=C1OCC1OC(=O)C(CC=2C=CC=CC=2)C1 AXPZIVKEZRHGAS-UHFFFAOYSA-N 0.000 description 1
- IBOFVQJTBBUKMU-UHFFFAOYSA-N 4,4'-methylene-bis-(2-chloroaniline) Chemical compound C1=C(Cl)C(N)=CC=C1CC1=CC=C(N)C(Cl)=C1 IBOFVQJTBBUKMU-UHFFFAOYSA-N 0.000 description 1
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-M 4-hydroxybenzoate Chemical compound OC1=CC=C(C([O-])=O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-M 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- AYDQIZKZTQHYIY-UHFFFAOYSA-N OC(=O)C1(C)CC(C(O)=O)=CC=C1 Chemical class OC(=O)C1(C)CC(C(O)=O)=CC=C1 AYDQIZKZTQHYIY-UHFFFAOYSA-N 0.000 description 1
- 240000008467 Oryza sativa Japonica Group Species 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000013036 cure process Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- XGZNHFPFJRZBBT-UHFFFAOYSA-N ethanol;titanium Chemical compound [Ti].CCO.CCO.CCO.CCO XGZNHFPFJRZBBT-UHFFFAOYSA-N 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical class C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical class C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium(IV) ethoxide Substances [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02B—PREPARING GRAIN FOR MILLING; REFINING GRANULAR FRUIT TO COMMERCIAL PRODUCTS BY WORKING THE SURFACE
- B02B3/00—Hulling; Husking; Decorticating; Polishing; Removing the awns; Degerming
- B02B3/04—Hulling; Husking; Decorticating; Polishing; Removing the awns; Degerming by means of rollers
Landscapes
- Polyurethanes Or Polyureas (AREA)
- Adjustment And Processing Of Grains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of rice huller paddy roller of rubber composition for possessing durability and excellent water resistance, the rice huller paddy roller of the present invention possesses core portion and is laminated in the rubber layer of the outer peripheral face in the core portion, the rubber layer includes the hardening thing of the thermosetting carbamate composition containing polyol component, isocyanate prepolymer composition, crosslinking agent and silicone oil, the isocyanate prepolymer composition is TDI and/or MDI, and kinematic viscosity of the silicone oil at 25 DEG C is 10mm2/ s~3000mm2/ s, relative to the total amount of polyol component, isocyanates and crosslinking agent, the content of the silicone oil in the thermosetting carbamate composition is the weight % of 0.3 weight %~10.0.
Description
Technical field
The present invention relates to one kind rice huller paddy roller.
Background technology
Agricultural be provided with hulling machine rice huller paddy roller.Using two rice huller paddy rollers as a pair, and there are rule each other with paddy roller of hulling
Surely the mode being spaced is configured to use the rice huller paddy roller.In so configured a pair of rice hullers paddy rollers, simultaneously make each rice huller paddy roller with
Different peripheral speed rotations, one, towards input paddy (rice with rice husk) in the mutual gap of rice huller paddy roller, thus can slough rice
Shell is simultaneously separated into rice husk and brown rice.
As the rice huller paddy roller, usually using the core portion comprising cylindrical shape and the roller structure for the rubber section being arranged at around it
Part (for example, referring to patent document 1).
The rubber section is for example using nitrile rubber (nitrile butadiene rubber, NBR) or styrene fourth
The synthetic rubber such as diene rubber (styrene butadiene rubber, SBR) are formed.
Due to rice huller paddy roller possess it is described as composition, therefore with sloughing for rice husk and rubber section is gradually worn away, if rubber
The thickness of layer is thinning, can not play the performance as rice huller paddy roller.Therefore in the case where the thickness of rubber layer reaches setting value,
Need to change rice huller paddy roller.
Therefore rice husk is sloughed in order to be changed without rice huller paddy roller for a long time, is just seeking one kind to possess durability (abrasion performance) excellent
The rice huller paddy roller of different rubber layer.But the durability of rubber layer of the rice huller paddy roller described in patent document 1 and insufficient.
It is proposed to have possess using amino first as the rice huller paddy roller of excellent in te pins of durability, such as in patent document 2, patent document 3
The rice huller paddy roller for the rubber layer that acid ester resin makes, because rubber layer is carbamate resins system, is accordingly regarded as excellent in te pins of durability.
Prior art literature
Patent document
Patent document 1：Japanese Patent Laid-Open 2001-029809 publications
Patent document 2：Japanese Patent Laid-Open No. Sho 51-107948 publications
Patent document 3：Japanese Patent Laid-Open No. Sho 51-74865 publications
The content of the invention
[inventing problem to be solved]
As described above, described in patent document 1 rice huller paddy roller rubber layer durability (abrasion performance) it is insufficient.Therefore
The problem of in the presence of must frequently change rice huller paddy roller.
In addition, the rubber layer of the rice huller paddy roller described in patent document 2, patent document 3 is to use carbamate composition
To be formed, therefore the tendency of the excellent in te pins of durability compared with the rice huller paddy roller for possessing the rubber layer of NBR systems or SBR be present.
However, preferably further lifted on its durability.
In addition, on possessing the rice huller paddy roller for the rubber layer for including carbamate composition, carbamate resins are because of water
Solve and easily deteriorate, and the water resistance (moisture resistance) of rubber layer is worse compared with NBR systems or SBR rubber layer, if therefore
Using the rice huller paddy roller after long-time keeping, then the performance for paddy roller of hulling sometimes can reduce.The frequency of use of rice huller paddy roller is because of period in addition
(season) and it is different, therefore sometimes prolonged stoppage be provided with rice huller paddy roller hulling machine operating.If in this case, use amino
Urethane composition forms rubber layer, then when the hulling machine is operated again, there is also can not be played the deterioration because of rubber layer
The situation of defined performance.
[technological means for solving problem]
The present inventor et al. is studied to solve the problem, and discovery possesses the rice huller paddy roller of following rubber layer
Durability and excellent water resistance, so as to complete the present invention, the rubber layer includes the special exercise viscosity containing ormal weight
The hardening thing of the thermosetting carbamate composition of silicone oil.
The rice huller paddy roller of the present invention possesses core portion and is laminated in the rubber layer of the outer peripheral face in the core portion, the rice huller paddy roller
It is characterised by：
The rubber layer includes the thermosetting amino containing polyol component, isocyanate prepolymer composition, crosslinking agent and silicone oil
The hardening thing of urethane composition,
The isocyanate prepolymer composition is toluene di-isocyanate(TDI) (tolylene diisocyanate, TDI) and/or hexichol
Dicyclohexylmethane diisocyanate (diphenyl methane diisocyanate, MDI),
Kinematic viscosity of the silicone oil at 25 DEG C is 10mm2/ s~3000mm2/ s,
Relative to the total amount of polyol component, isocyanate prepolymer composition and crosslinking agent, the thermosetting carbamate
The content of the silicone oil in composition is the weight % of 0.3 weight %~10.0.
The rice huller paddy roller of the present invention possesses following rubber layer, and the rubber layer, which includes allotment, the special exercise viscosity of ormal weight
Silicone oil thermosetting carbamate composition hardening thing, and the rubber layer is due to containing silicone oil, therefore durability
(abrasion performance) and water resistance (moisture resistance) are excellent.
Therefore, rice huller paddy roller of the invention can use with being changed without for a long time.
In addition, the rice huller paddy roller of the present invention is due to excellent water resistance, therefore during keeping before use or will the roller installation of rice huller paddy
In the stopped process of the hulling machine after hulling machine (during interrupting) etc., the rubber because caused by absorbing moisture can be suppressed
The deterioration of layer.Therefore the rice huller paddy roller of the present invention can ensure stable performance for a long time.
In the rice huller paddy roller of the present invention, the silicone oil is preferably dimethyl polysiloxane.
In addition in the rice huller paddy roller of the present invention, the crosslinking agent is more preferably at least BDO (Isosorbide-5-Nitrae-butanediol).
[The effect of invention]
On the rice huller paddy roller of the present invention, the heat that the silicone oil of the special exercise viscosity containing ormal weight is included due to rubber layer is hard
The hardening thing of the property changed carbamate composition, therefore durability and excellent water resistance.Therefore, excellent property can be maintained for a long time
Can and use with being changed without.
In addition, the rice huller paddy roller of the present invention is also suitable for long-term keeping.
Brief description of the drawings
Fig. 1 (a) is the stereogram of one for schematically showing the rice huller paddy roller of the present invention, and (b) is the rice huller paddy roller shown in (a)
Front view, (c) is the line A-A profile of (a).
Fig. 2 is the schematic diagram for illustrating the application method of the rice huller paddy roller of the present invention.
Embodiment
Hereinafter, simultaneously one illustrated referring to the drawings in face of embodiments of the present invention.
The rice huller paddy roller of the present invention possesses core portion and is laminated in the rubber layer of the outer peripheral face in the core portion, and the rice huller paddy
Roller is characterised by：The rubber layer includes the thermosetting containing polyol component, isocyanate prepolymer composition, crosslinking agent and silicone oil
The hardening thing of carbamate composition, the isocyanate prepolymer composition are TDI and/or MDI, motion of the silicone oil at 25 DEG C
Viscosity is 10mm2/ s~3000mm2/ s, it is described relative to the total amount 100 of polyol component, isocyanate prepolymer composition and crosslinking agent
The content of the silicone oil in thermosetting carbamate composition is the weight % of 0.3 weight %~10.0.
Fig. 1 (a) is the stereogram of one for schematically showing the rice huller paddy roller of the present invention, and (b) is the rice huller paddy roller shown in (a)
Front view, (c) is the line A-A profile of (a).
Rice huller paddy roller 10 shown in Fig. 1 (a)~(c) includes metal core portion 11 and is laminated in the outer peripheral face in core portion 11
Rubber layer 12.
Core portion 11 is the cylinder that the mounting flange 11a for paddy roller 10 of hulling to be installed on to hulling machine is provided with cylinder
Shape component.
Core portion 11 whole outer peripheral face with uniform thickness formed with rubber layer 12.
Hereinafter, the member of formation of the rice huller paddy roller of the present invention is illustrated.
As the core portion, person identical with the core portion used in existing known rice huller paddy roller can be used.Described
Core portion is as material, such as can enumerate：Aluminium, stainless steel, iron, molybdenum, titanium etc..
In addition, the shape or size in the core portion are not particularly limited, and it is same with existing product, rice huller is installed as long as coordinating
The specification of the hulling machine of paddy roller or Japanese Industrial Standards (Japanese industrial standard, JIS) standard (JIS B
9214：Rice huller paddy rubber rollers) suitably setting.
The rubber layer includes the thermosetting amino containing polyol component, isocyanate prepolymer composition, crosslinking agent and silicone oil
The hardening thing of urethane composition, the kinematic viscosity at 25 DEG C of the silicone oil is 10mm2/ s~3000mm2/s。
In the rice huller paddy roller of the present invention, by the silicon for containing the scope in the thermosetting carbamate composition
Oil, it can especially lift the durability (abrasion performance) of rubber layer.
In contrast, the kinematic viscosity at 25 DEG C of the silicone oil is less than 10mm2/ s situation or the kinematic viscosity
More than 3000mm2In the case of/s, the durability of rubber layer significantly reduces.
And then rice huller paddy roller of the invention as be described hereinafter as, by containing silicone oil in thermosetting carbamate composition,
And realize the lifting of water resistance.Herein, silicone oil the kinematic viscosity less than 10mm2In the case of/s, although can ensure that rubber
The water resistance at glue-line initial stage, but that the water resistance after rubber layer abrasion becomes insufficient be present.In addition described in silicone oil
Kinematic viscosity is less than 10mm2In the case of/s, produce silicone oil sometimes oozes out (bleed), if producing oozing out for silicone oil,
Brown rice can be polluted during rice huller paddy or rice husk is attached on hulling machine.
In addition, if the kinematic viscosity of silicone oil is more than 3000mm2/ s, then it is difficult to handle, and is preparing thermosetting ammonia
During carbamate composition, it is difficult to equably mix silicone oil.Included on possessing not by the mixed uniformly thermosetting of silicone oil
The rice huller paddy roller of the rubber layer of the hardening thing of carbamate composition, produced sometimes in the durability reduction of rice huller paddy roller or rubber layer
Husking yield when raw uneven abrasion or rice huller paddy reduces.
The rice huller paddy roller of the present invention reaches rubber layer by the way that silicone oil is formulated in thermosetting carbamate composition
Durability lifting.Now, it is important that not only allocate silicone oil, but allocate the silicon with the special exercise viscosity
Oil.In this way, it is by the newfound opinion of the present inventor et al.：, can outstandingly by allocating the silicone oil with special exercise viscosity
Lift the durability of rubber layer.
In the thermosetting carbamate composition, relative to polyol component, isocyanate prepolymer composition and crosslinking
The total amount of agent, the content of the silicone oil are the weight % of 0.3 weight %~10.0.
If the content of the silicone oil can not assign sufficient water resistance less than 0.3 weight % to rubber layer.In addition, such as
Upper described, rice huller paddy roller of the invention containing silicone oil in thermosetting carbamate composition by realizing the resistance to of rubber layer
The lifting of long property, if but silicone oil content less than 0.3 weight %, can not fully lift durability.
On the other hand, if the content of the silicone oil is more than 10 weight %, although durability and water resistance are good, can produce
Raw silicone oil oozes out.If producing oozing out for silicone oil, there is the unfavorable condition.
Relative to the total amount of polyol component, isocyanate prepolymer composition and crosslinking agent, content preferably 0.5 weight of the silicone oil
Measure the weight % of %~5.0 weight %, more preferably 0.7 weight %~2.5.
It is considered following reason by allocating the reasons why silicone oil is lifted and water resistance：Situation phase with not allocating silicone oil
Than, the hydrophobicity enhancing on the surface of rubber layer, therefore rubber layer is not easy moisture absorption, so as to be not likely to produce the water because of polyurethanes
Deterioration caused by solution.
On the rice huller paddy roller, building rubber compound is formed using the thermosetting carbamate composition containing silicone oil
Thing, and be scattered here and there silicone oil in whole rubber layer.So even the rubber layer abrasion by using rice huller paddy roller, the surface of rubber layer
Hydrophobicity can also be ensured all the time by silicone oil, after manufacture, can maintain excellent water resistance until being finished rice huller paddy roller.
Therefore, rice huller paddy roller of the invention is installed on after hulling machine, even if hulling machine interrupts operating for a long time, can also be avoided
The rubber layer deteriorates during interruption and the performance for paddy roller of hulling reduces.
It is not particularly limited, such as can enumerates as the silicone oil：Dimethicone, methyl phenyl silicone oil, methyl hydrogen silicon
Oil, modified silicon oil that organic group forms is imported in the side chain of these silicone oil and/or end (for example, the terminal-modified silicone oil of silanol base
Deng) etc..
Among these, preferred dimethicone.Dimethicone structure in silicone oil is more simple, does not have in space big
Steric hindrance (steric hindrance), therefore when being scattered in carbamate composition, it is easily dispersed in polyurethanes
In molecule, and suitable for making the hardening thing of thermosetting carbamate composition become uniform.On the other hand, on such as modified silicon oil
As have be likely to become steric hindrance position silicone oil, following situation be present：In the entangled to each other of polyurethane ester molecule
Middle silicone oil causes silicone oil to locally lie in the hardening thing of thermosetting carbamate composition without importing.Such as sometimes
Silicone oil locally lies in the near surface in rubber layer.
The thermosetting carbamate composition contains TDI and/or MDI and is used as the isocyanate prepolymer composition.
Existing known TDI can be used as the TDI (toluene di-isocyanate(TDI)).In the TDI, 2,4-TDI and 2,
6-TDI allotment is not particularly limited than (2,4-TDI/2,6-TDI), but preferably 65/35~80/20 (weight ratio).As institute
TDI is stated, such as T-80 (2,4-TDI/2,6-TDI=80/20), T-100 (2,4-TDI/2,6-TDI=100/0), T- can be used
65 (2,4-TDI/2,6-TDI=65/35) etc..
Various commercially available products also can be used as the TDI.
The MDI (methyl diphenylene diisocyanate or polymethylene polyphenylene PIC) has no special limit
It is fixed, no matter the width of its molecular weight distribution can be used, such as pure MDI (4,4 '-MDI), polymeric MDI etc. can be used.
As the MDI, various commercially available products also can be used.
Isocyanate group concentration in the thermosetting carbamate composition is preferably the weight of 1.2 weight %~4.5
Measure %.
If the isocyanate group concentration can reduce less than 1.2 weight %, the sometimes abrasion performance of hardening thing.The opposing party
Face, if the isocyanate group concentration, more than 4.5 weight %, the hardness of hardening thing can become too high sometimes.
The so-called isocyanate group concentration (weight %) refers to the conjunction of isocyanate prepolymer composition, polyol component and crosslinking agent
The part by weight of contained NCO in metering.
As the polyol component, as long as the polyol component used in the synthesis of conventional polyurethanes is then
It is not particularly limited, such as can enumerates：PEPA, PPG, polycaprolactone polyol etc..
Among these, preferred PEPA.Reason is the height by being shown by the high polyester polyols alcohol radical of polarity
Molecular separating force, the rubber layer of excellent wear resistance can be formed.
As the PEPA, such as can enumerate by making dicarboxylic acids enter with glycol (glycol) according to common method
Row reacts and winner etc..
As the dicarboxylic acids, such as can enumerate：The aromatic series such as terephthalic acid (TPA), M-phthalic acid, 2,6- naphthalene dicarboxylic acids
The hydroxycarboxylic acids such as the aliphatic dicarboxylic acids such as dicarboxylic acids, adipic acid, azelaic acid, decanedioic acid, hydroxybenzoic acid, these ester formative
Derivative etc..
Preferred adipic acid among these, in the case where BDO is used as into glycol or crosslinking agent, particularly preferably oneself two
Acid.The C atomic arrangements of adipic acid are identical with BDO, arranged for four platoons, therefore oriented crystalline is excellent, and by with
Crystallize structure and show firm molecular separating force.Further, since adipic acid is cheap, thus it is economically also excellent.
The dicarboxylic acids can be used alone, also can and with two or more.
As the glycol, such as can enumerate：Ethylene glycol, BDO, diethylene glycol, neopentyl glycol, 3- methyl isophthalic acids,
The alicyclic diol such as aliphatic diol, 1,4-CHDM such as 5- pentanediols, 1,9- nonanediols, triethylene glycol, to diformazan
Polyether polyols such as the aromatic diols such as Benzenediol, polyethylene glycol, polypropylene glycol, polytetramethylene glycol etc..
As the glycol, preferred aliphat glycol, and then preferably ethylene glycol, BDO.These materials are suitable to shape
Into the rubber layer that JIS-A hardness is 90 ° or so, and inexpensively.
It is linear structure as the PEPA of dicarboxylic acids and the reactant of glycol, but is alternatively using more than ternary
The branched polyester of ester forming component.
The glycol can be used alone, also can and with two or more.
As the PEPA, particularly preferably polyethylene adipate system PEPA, polyadipate butylidene
Ester system polyester and base ester system of polyadipate ethylidene Aden polyester.Those, which have, suitably forms JIS-A hardness as 90 ° or so
Rubber layer molecular structure, and inexpensively.
As the PPG, such as can enumerate：Polyethylene glycol, polypropylene glycol, polytetramethylene glycol, these copolymer
Etc. poly- alkane glycol etc..Among these, for the good aspect of abrasion performance, preferred polytetramethylene glycol.
As the polycaprolactone polyol, for example, can enumerate by the presence of a catalyst using low molecular weight diols as
Initiator come make 6-caprolactone open loop addition and winner.
As the low molecular weight diols, it is preferable to use ethylene glycol, propane diols, 1,3-BDO, neopentyl glycol etc.
The trihydroxylic alcohol such as dihydric alcohol and 1,3-PD (trimethylene glycol), glycerine.As the catalyst, it is preferable to
Use organic titanium sub-group compounds such as butyl titanate, metatitanic acid orthocarbonate, tetraethyl titanate, tin octoate, Dibutyltin oxide, bay
Tin based compound such as sour dibutyl tin, stannous chloride, stannous bromide etc..
In addition, in addition to the 6-caprolactone, a part such as trimethyl caprolactone or valerolactone etc can also be mixed
Other annular lactones.
The polyalcohol can be used alone, also can and with two or more.
The polyalcohol preferred amount mean molecule quantity is 1000~3000.If number average molecular weight less than 1000,
Sometimes satisfied caoutchouc elasticity is not shown in rubber layer and is rigidly uprised.On the other hand, if number average molecular weight exceedes
3000, then it can not assign satisfied rubbery intensity to rubber layer sometimes and turn into excessively soft rubber layer.
The number average molecular weight be using gel permeation chromatograph (gel permeation chromatograph,
GPC) the measured value of the polystyrene conversion of measure.
As the crosslinking agent, such as can enumerate：BDO (Isosorbide-5-Nitrae-butanediol, Isosorbide-5-Nitrae-BD), Isosorbide-5-Nitrae-bis- (β-
Hydroxyl-oxethyl) benzene (Isosorbide-5-Nitrae-bis (β-hydroxyethoxy) benzene, BHEB), ethylene glycol, propane diols, hexylene glycol, diethyl
Glycol, trimethylolpropane (trimethylolpropane, TMP), glycerine, 4,4 '-di-2-ethylhexylphosphine oxide (2- chloroanilines) (4,4 '-
Methylene bis (2-chloroaniline)), hydrazine (hydrazine), ethylenediamine, Diethylenetriamine, 4,4 '-diaminourea hexichol
Methylmethane, 4,4 '-diamino-dicyclohexyl methane, N, double (2- hydroxypropyls) aniline, the water of N- etc..
Among these, it is easy for for showing appropriate rubber hardness, rubber rigidity, preferably BDO, BHEB.Separately
Outside, the working life (pot life) of the thermosetting carbamate composition comprising BDO or BHEB is long, i.e.,
It is that manual cast is also plastic.
The crosslinking agent can be used alone, also can and with two or more.In addition, and with the case of a variety of crosslinking agents,
The crosslinking agent preferably at least contains BDO.Reason is that it is suitable to the lifting of durability.
The thermosetting carbamate composition so also can optionally and containing chain elongation agent, crosslinking accelerator or
The reinforcing materials such as the reaction promoters such as crosslinking delay agent, hydrolysis-resisting agent, inorfil or inorganic filler, colouring agent, light stabilizer, heat
Various additives such as stabilizer, antioxidant, mould inhibitor, fire retardant, filler (extender) etc..
JIS-A hardness at preferably 20 DEG C of the rubber layer (hardening thing of the thermosetting carbamate composition)
For more than 85 °.If for the JIS-A hardness less than 85 °, the rubber layer is excessively soft, therefore abrasion performance can reduce sometimes.
More preferably more than 88 ° of the JIS-A hardness, and then preferably more than 90 °.
On the other hand, the JIS-A hardness at 20 DEG C of the rubber layer is preferably less than 99 °.If more than 99 °, have and hulling
Damaged, the so-called increased worry of incidence cracked rice occurs for rice during paddy.
In addition, in the case of as the rice of rice huller paddy object for soft polished rice (Japonica rice) etc., it is described
Preferably 88 °~92 ° or so of the JIS-A hardness of rubber layer, it is harder long-grained nonglutinous rice (Indica in the rice as rice huller paddy object
) etc. rice preferably 92 °~96 ° or so in the case of.
As long as the JIS-A hardness (wherein, determines according to the JIS K 6253 quoted in JIS K 9124 to determine
Temperature is 20 DEG C).
In addition, " rubber layer " in the present invention is equivalent to " rubber section " referred in JIS K 9124.
The tan δ of the rubber layer (hardening thing of the thermosetting carbamate composition) peak temperature (Tg)
Preferably less than 10 DEG C.Reason is to show appropriate rubber bullet at 30 DEG C~50 DEG C of the temperature of rubber layer when in use
Property.
The Deutsche industry norm (DIN) of the rubber layer (hardening thing of the thermosetting carbamate composition)
(Deutsche Industrie Normen, DIN) wear loss is preferably 40mm3~100mm3。
If the DIN wear losses are less than 40mm3, then there is a situation where to hull paddy when the incidence cracked rice uprise.The opposing party
Face, if DIN wear losses are more than 100mm3, then durability become insufficient.
As long as the DIN wear losses determine according to JIS K 6264 DIN abrasion tests.
The DIN wear losses more preferably 40mm3~85mm3。
The thickness of the rubber layer, which has no, to be especially particularly limited to, same with existing product, and rice huller paddy roller is provided with as long as coordinating
The specification or JIS standards (JIS B 9214) of hulling machine are suitably set.
The external diameter and internal diameter of rubber layer when the thickness (being represented in Fig. 1 (b) with T) of the so-called rubber layer refers to be not used
Difference 1/2 value.
The rice huller paddy roller of the present invention, also can be at both in order to further lift the adhesion in the core portion and the rubber layer
Between form priming coat and/or adhesive phase, or the outer peripheral face in the core portion is implemented close with rubber layer for improving
The surface treatment of connecing property.
The formation of described adhesive is carried out such as can be used phenolic aldehyde system adhesive.The formation example of the other priming coat
Carbamate system, Polyester, silane system, polyamide-based, phenolic aldehyde system priming paint or silane coupling agent such as can be used to enter
OK.
As the surface treatment, such as the formation in roughening face can be enumerated etc..As long as the formation in the roughening face is for example logical
Overspray (blast) processing, grinding processing, etching process, plating processing, milled processed, oxidation processes etc. are carried out.
The out of roundness of the section (section vertical with rotary shaft during use) of the rice huller paddy roller is preferably below 0.5mm.
If the deviation that the out of roundness more than 0.5mm, deposits the mutual interval of paddy roller of hulling when in use becomes big, and husking yield reduces or
The increased situation of incidence cracked rice.
Then the manufacture method of the rice huller paddy roller of the present invention is illustrated.
The rice huller paddy roller can for example be manufactured by the process by following (1) and (2).
(1) core portion is made first.The core portion can be made using existing known method, such as can pass through aluminium pressure
(aluminum die casting) etc. is cast to make.
Afterwards, adhesive phase and/or priming coat optionally are formed or to core portion to periphery to the outer peripheral face in core portion
Implement surface treatment in face.
(2) then, rubber layer is formed around the core portion.Herein, core portion is placed in columnar mould
Interior, the outer peripheral face in core portion combines with injecting the thermosetting carbamate in the gap of the internal face of mould afterwards
Thing, and its hardening is made with defined curing condition, it is consequently formed rubber layer.
The curing condition is not particularly limited, as long as according to composition come to the thermosetting carbamate composition
Suitable setting, it can generally use the condition heated at 100 DEG C~160 DEG C 30 minutes~90 minutes.
In addition, after carrying out cure process with the condition and being stripped from mould, such as also can be with 100 DEG C~160
The condition of 3 hours~48 hours carries out after-hardening at DEG C.
Rubber layer is laminated in the outer peripheral face in core portion by such a method, thus can manufacture and generally form with equal
The rice huller paddy roller of the rubber layer of even density.
Reason is that the hardening after the preparation of the thermosetting carbamate composition used in the present invention is carried out
Compare slowly.
In addition in the manufacture method of the rice huller paddy roller, the table of rubber layer optionally can be also formed by grinding
Face.Certainly without the grinding after being also stripped from mould.
Then, the application method of the rice huller paddy roller of the present invention is illustrated.
Fig. 2 is the schematic diagram for illustrating the application method of the rice huller paddy roller of the present invention.
The rice huller paddy roller of the present invention is that two rice huller paddy rollers are set into one group, and is installed on the rice huller paddy of existing known rubber roll-type
Used on machine.
That is, as shown in Fig. 2 abreast installing a pair of rice huller paddy roller 10A, rice huller paddy roller in a manner of with defined interval L
10B, and make rice huller paddy roller 10A, rice huller paddy roller 10B difference in the opposite directions to each other and (hull paddy roller 10A's with different rotary speeies
Rotary speed Va ≠ rice huller paddy roller 10B rotary speed Vb) rotation.If moreover, in this condition to rice huller paddy roller 10A, rice huller paddy roller 10B
Paddy 1 is put into each other, then is sloughed rice husk from paddy 1 using the difference for the paddy roller 10A and paddy roller 10B that hulls that hulls.
The distance L in rice huller paddy roller 10A during the use of the rice huller paddy roller and rice huller paddy roller 10B gap or hull paddy roller 10A and
Rice huller paddy roller 10B respective rotary speed (peripheral speed) Va, rotary speed (peripheral speed) Vb are not particularly limited, as long as according to
Suitably setting is the various conditions such as the specification of hulling machine, the species of input paddy or the index of aridity, processing speed, husking yield
Can.
[embodiment]
Hereinafter, the present invention is further specifically described by embodiment, but the present invention is not limited to following examples.
1. the preparation of thermosetting carbamate composition
(preparation example 1)
MDI is set to isocyanate prepolymer composition and by polyethylene adipate glycol by mixing in the agitator (agitator)
(polyethylene adipate diol, PEA) is set to the carbamate prepolymer (Sang Pu of polyol component
(Sanprene) P6814, the manufacture of chemical conversion company of Sanyo) 100 parts by weight, silicone oil (the beautiful DOW CORNING (Toray Dow Corning) in east
Company manufactures, SH200-100CS (dimethicones：Kinematic viscosity 100mm2/ s)) 1.0 parts by weight, yellow uitramarine (ZA Huangs #
200, drive the manufacture of state chemistry limited company) (the white #2200 of ZA, imperial state chemistry share have for 0.02 parts by weight and Chinese white
Limit company manufactures) 0.02 parts by weight.Then additional mixing BDO (the BASF Japan into the mixture obtained
(BASF Japan) company manufactures) 1.59 parts by weight, the parts by weight of BHEB (Mitsui Chemicals, Inc.'s system is made) 10.50, and it is hard to prepare heat
The property changed carbamate composition (1).
(preparation example 2)
In addition to by the allotment quantitative change of silicone oil more 0.34 parts by weight, by with preparation example 1 it is same in a manner of prepare it is hot hard
The property changed carbamate composition (2).
(preparation example 3)
In addition to by the allotment quantitative change of silicone oil more 11.2 parts by weight, by with preparation example 1 it is same in a manner of prepare it is hot hard
The property changed carbamate composition (3).
(preparation example 4)
SH200-10CS (two except silicone oil to be changed to beautiful DOW CORNING (Toray Dow Corning) the company manufacture in east
Methyl-silicone oil：Kinematic viscosity 10mm2/ s) beyond, thermosetting carbamate is prepared in a manner of same with preparation example 1 and is combined
Thing (4).
(preparation example 5)
SH200-3000CS except silicone oil to be changed to beautiful DOW CORNING (Toray Dow Corning) the company manufacture in east
(dimethicone：Kinematic viscosity 3000mm2/ s) beyond, by with preparation example 1 it is same in a manner of prepare thermosetting carbamic acid
Ester composition (5).
(preparation example 6)
In addition to by the allotment quantitative change of silicone oil more 0.56 parts by weight, by with preparation example 1 it is same in a manner of prepare it is hot hard
The property changed carbamate composition (6).
(preparation example 7)
In addition to by the allotment quantitative change of silicone oil more 5.60 parts by weight, by with preparation example 1 it is same in a manner of prepare it is hot hard
The property changed carbamate composition (7).
(preparation example 8)
BY16-873 (silanols except silicone oil to be changed to beautiful DOW CORNING (Toray Dow Corning) the company manufacture in east
The terminal-modified silicone oil of base：Kinematic viscosity 2250mm2/ s) beyond, by with preparation example 1 it is same in a manner of prepare thermosetting amino first
Acid ester composite (8).
(preparation example 9)
SH550 (aminomethyl phenyls except silicone oil to be changed to beautiful DOW CORNING (Toray Dow Corning) the company manufacture in east
Silicone oil：Kinematic viscosity 130mm2/ s) beyond, by with preparation example 1 it is same in a manner of prepare thermosetting carbamate composition
(9)。
(preparation example 10)
Except the allotment amount of BDO is set into 6.42 parts by weight, BHEB is not allocated and sets the allotment amount of silicone oil
Beyond 0.97 parts by weight, by with preparation example 1 it is same in a manner of prepare thermosetting carbamate composition (10).
(preparation example 11)
Except not allocating BDO, BHEB allotment amount is set to 14.14 parts by weight and setting the allotment amount of silicone oil
Beyond 1.04 parts by weight, by with preparation example 1 it is same in a manner of prepare thermosetting carbamate composition (11).
(preparation example 12)
Except by allotment quantitative change more 0.95 parts by weight of BDO, by BHEB allotment quantitative change more 11.90 weights
The allotment amount of silicone oil and is set to beyond 1.02 parts by weight part by amount, by with preparation example 1 it is same in a manner of prepare thermosetting amino
Urethane composition (12).
(preparation example 13)
TDI is set to isocyanate prepolymer composition and is set to polyethylene adipate glycol (PEA) by mixing in agitator
Carbamate prepolymer (the resistance to moral of Plutarch (Takenate) L-1290, Mitsui Chemicals, Inc.'s system are made) 100 weights of polyol component
Measure part, silicone oil (beautiful DOW CORNING (Toray Dow Corning) the company manufacture in east, SH200-100CS) 1.0 parts by weight, yellow face
Expect (ZA Huang #200) 0.02 parts by weight and the parts by weight of Chinese white (ZA#2200) 0.02.Then into the mixture obtained
(her former chemical industry (Ihara Chemical Industry) company manufactures additional mixing di-2-ethylhexylphosphine oxide (2- chloroanilines), Yi Yuan
Amine though (Ihara Cuamine) MT) 12.6 parts by weight, prepare thermosetting carbamate composition (13).
(preparation example 14)
MDI is set to isocyanate prepolymer composition and is set to polyethylene adipate glycol (PEA) by mixing in agitator
Carbamate prepolymer (Sang Pu comes (Sanprene) P6814, the manufacture of chemical conversion company of Sanyo) 100 weight of polyol component
Part, silicone oil (beautiful DOW CORNING (Toray Dow Corning) the company manufacture in east, SH200-100CS (methyl-silicone oils：Kinematic viscosity
100mm2/ s)) 1.02 parts by weight, yellow uitramarine (ZA Huang #200, driving the manufacture of state chemistry limited company) 0.02 parts by weight, with
And Chinese white (the white #2200 of ZA, driving the manufacture of chemistry limited company of state) 0.02 parts by weight.Then to the mixture obtained
0.32 parts by weight of middle additional mixing BDO (manufacture of (BASF Japan) company of BASF Japan), BHEB (Mitsui Chemicals
Company manufacture) 10.61 parts by weight, trimethylolpropane (manufacture of combustion gas chemistry limited company of Mitsubishi) 1.28 parts by weight, and
Prepare thermosetting carbamate composition (14).
(preparation example 15)
Except by allotment quantitative change more 0.32 parts by weight of BDO, by BHEB allotment quantitative change more 12.02 weights
Measure part, by allotment quantitative change more 0.64 parts by weight of trimethylolpropane and by the allotment quantitative change of silicone oil more 1.03 parts by weight
In addition, by with preparation example 14 it is same in a manner of prepare thermosetting carbamate composition (15).
(comparing preparation example 1)
In addition to not allocating silicone oil, by with preparation example 1 it is same in a manner of prepare thermosetting carbamate composition
(16)。
(comparing preparation example 2)
SH200-2CS (methyl except silicone oil to be changed to beautiful DOW CORNING (Toray Dow Corning) the company manufacture in east
Silicone oil：Kinematic viscosity 2mm2/ s) beyond, by with preparation example 1 it is same in a manner of prepare thermosetting carbamate composition
(17)。
(comparing preparation example 3)
SH200-10000CS except silicone oil to be changed to beautiful DOW CORNING (Toray Dow Corning) the company manufacture in east
(dimethicone：Kinematic viscosity 10000mm2/ s) beyond, by with preparation example 1 it is same in a manner of prepare thermosetting carbamic acid
Ester composition (18).
(comparing preparation example 4)
In addition to by the allotment quantitative change of silicone oil more 0.22 parts by weight, by with preparation example 1 it is same in a manner of prepare it is hot hard
The property changed carbamate composition (19).
(comparing preparation example 5)
In addition to by the allotment quantitative change of silicone oil more 13.5 parts by weight, by with preparation example 1 it is same in a manner of prepare it is hot hard
The property changed carbamate composition (20).
(comparing preparation example 6)
In addition to not allocating silicone oil, by with preparation example 10 it is same in a manner of prepare thermosetting carbamate composition
(21)。
(comparing preparation example 7)
In addition to not allocating silicone oil, by with preparation example 11 it is same in a manner of prepare thermosetting carbamate composition
(22)。
(comparing preparation example 8)
In addition to not allocating silicone oil, by with preparation example 13 it is same in a manner of prepare thermosetting carbamate composition
(23)。
Thermosetting carbamate composition (1)~thermosetting carbamate group has been recorded in table 1 below, table 2
The composition of compound (23).
2. the making and evaluation (1) of paddy roller of hulling
(embodiment 1)
In the present embodiment, pattern is made：Integrate the rice huller paddy roller of big 60 type.
First, the core portion of shape shown in Fig. 1 is manufactured by aluminium die casting.
Then, it is whole with the outer peripheral face in the core portion and being spaced in for the inner peripheral surface of the mould in columnar mould
The core portion is set as the mode at roughly equal interval on individual circumference.
Afterwards, thermosetting carbamic acid is injected in the gap of the outer peripheral face to the core portion and the inner peripheral surface of the mould
Ester composition (1), make its hardening with following conditions, and outside dimension and width dimensions are adjusted by cutting, and be produced on institute
The outer peripheral face for stating core portion is laminated with the rice huller paddy roller of rubber layer.
(curing condition)
The temperature of thermosetting carbamate composition (1) when injecting is set to 105 DEG C, and in mold temperature 130
It is set to harden at DEG C 60 minutes.
Afterwards, it is stripped from mould, and after-hardening is carried out with the condition of 110 DEG C, 24 hours.
(2~embodiment of embodiment 10 and embodiment 12)
Thermosetting carbamate composition is used respectively except replacing thermosetting carbamate composition (1)
(2) beyond any one of~thermosetting carbamate composition (10) and thermosetting carbamate composition (12),
Rice huller paddy roller is made in a manner of similarly to Example 1.
(embodiment 11)
Thermosetting carbamate composition (11) is used except replacing thermosetting carbamate composition (1)
And made with following conditions beyond its hardening, rice huller paddy roller is made in a manner of similarly to Example 1.
(curing condition)
The temperature of thermosetting carbamate composition (11) when injecting is set to 105 DEG C, and in mold temperature 130
It is set to harden at DEG C 90 minutes.
Afterwards, it is stripped from mould, and after-hardening is carried out with the condition of 110 DEG C, 24 hours.
(embodiment 13)
Thermosetting carbamate composition (13) is used except replacing thermosetting carbamate composition (1)
And made with following conditions beyond its hardening, rice huller paddy roller is made in a manner of similarly to Example 1.
(curing condition)
The temperature of thermosetting carbamate composition (13) when injecting is set to 85 DEG C, and in mold temperature 130
It is set to harden at DEG C 60 minutes.
Afterwards, it is stripped from mould, and after-hardening is carried out with the condition of 110 DEG C, 24 hours.
(embodiment 14)
Thermosetting carbamate composition (14) is used except replacing thermosetting carbamate composition (1)
And made with following conditions beyond its hardening, rice huller paddy roller is made in a manner of similarly to Example 1.
(curing condition)
The temperature of thermosetting carbamate composition (14) when injecting is set to 105 DEG C, and in mold temperature 130
It is set to harden at DEG C 60 minutes.
Afterwards, it is stripped from mould, and after-hardening is carried out with the condition of 110 DEG C, 24 hours.
(embodiment 15)
Thermosetting carbamate composition is used except replacing thermosetting carbamate composition (14)
(15) beyond, rice huller paddy roller is made in a manner of similarly to Example 14.
(1~comparative example of comparative example 6)
Thermosetting carbamate composition is used respectively except replacing thermosetting carbamate composition (1)
(16) beyond any one of~thermosetting carbamate composition (21), rice huller paddy is made in a manner of similarly to Example 1
Roller.
(comparative example 7)
Thermosetting carbamate composition is used except replacing thermosetting carbamate composition (11)
(22) beyond, rice huller paddy roller is made in a manner of similarly to Example 11.
(comparative example 8)
Thermosetting carbamate composition is used except replacing thermosetting carbamate composition (13)
(23) beyond, rice huller paddy roller is made in a manner of similarly to Example 13.
(evaluation)
(1) JIS-A hardness
According to the JIS K 6253 quoted in JIS K 9124 in 1~embodiment of embodiment 15 and comparative example 1~ratio
JIS-A hardness compared with the rubber layer formed on the rice huller paddy roller made in example 8 is measured.Wherein measurement temperature is set to 20 DEG C,
Measurement site is set at three.Show the result in table 3.
(2) DIN wear losses
To the rubber layer formed on the rice huller paddy roller that is made in 1~embodiment of embodiment 15 and 1~comparative example of comparative example 8
DIN wear losses be measured.
The test piece (diameter 16mm × thickness 6mm) formed same with the rubber layer is separately made, and uses the test piece,
In method according to JIS K 6264, with the rotation of test piece：Without (A methods), the additional force of test piece：10N carries out the DIN abrasion
The evaluation of decrement.Show the result in table 3.
(3) water-repellancy (contact angle of water)
Using following methods to institute on the rice huller paddy roller that is made in 1~embodiment of embodiment 15 and 1~comparative example of comparative example 8
The contact angle of the water of the rubber layer of formation is measured.Herein, the measure of contact angle is the survey in (2) the DIN wear losses
Fixed front and rear progress.
That is, the test piece made by described in (2) is set to determine sample, respectively before being measured to DIN wear losses
After measure, the contact angle of the water on the surface (wearing course) of test piece is measured using following methods.Show the result in table
3。
The automatic contact angle meter DMe-200 manufactured using consonance interface science limited company, and by JIS R 3257
Glass coupon in " base plate glass wettability of the surface test method " is replaced into used in the measure of the DIN wear losses
Test piece, the contact angle is determined using sessile drop method.
In addition, refer to that contact angle is bigger in the evaluation, surface more hydrophobicity, and water resistance is more excellent.
(4) ocular estimate (whether there is and ooze out (1))
For the rice huller paddy roller made in 1~embodiment of embodiment 15 and 1~comparative example of comparative example 8, its outward appearance is observed, and it is right
Surface, which whether there is the generation oozed out, to be evaluated.Show the result in table 3.
Specifically, to hull paddy roller rubber layer surface carry out finger touch observation, judgement can with finger tip wipe take oily into
Point.As a result, will can not wipe the situation that takes oil component is judged as " without the generation oozed out ", it will can wipe and take the situation of oil component to judge
For " having the generation oozed out ".
(5) other (whether there is and ooze out (2))
The test piece made by described in (2) is set to determine sample, before being measured to DIN wear losses and surveys respectively
After fixed, using the gimmick same with the evaluation of (4), the generation oozed out whether there is to the surface of test piece and evaluated.
As a result, in the evaluation of (4), be judged as " without the generation oozed out " 1~embodiment of embodiment 15 and
In the test piece of comparative example 1,3~comparative example of comparative example 4 and 6~comparative example of comparative example 8, in this evaluation, in DIN wear losses
Two time points before measure and after measure are without the generation oozed out.
On the other hand, in the test piece of comparative example 2, although there is the generation oozed out before the measure of DIN wear losses,
The generation that DIN wear losses are oozed out after measure disappears.
In addition, in the test piece of comparative example 5, two time points before the measure of DIN wear losses and after measure, which have, oozes out
Generation.
As shown in table 3, the durability (abrasion performance) and water resistance of the rice huller paddy roller for possessing following rubber layer specify that
Excellent, the rubber layer includes contains 0.3 weight relative to the total amount of polyol component, isocyanate prepolymer composition and crosslinking agent
The kinematic viscosity measured at 25 DEG C of the weight % of %~10.0 is 10mm2/ s~3000mm2The thermosetting carbamic acid of/s silicone oil
The hardening thing of ester composition.In addition, it also specify that the rice huller paddy roller is not in the unfavorable condition that silicone oil oozes out.
3. the making and evaluation (2) of paddy roller of hulling
(embodiment 16)
In the present embodiment, pattern is made：The rice huller paddy roller of integrated 100 types.
Herein, in addition to change shape and size, rice huller paddy roller is made using method similarly to Example 1.
For made rice huller paddy roller, in rice U.S. small towns warehouse (country elevator) (Hyogo south agricultural cooperative society)
Relation between rice huller paddy amount and the abrasion loss of rubber layer is evaluated.
The model that hulling machine is manufactured using assistant bamboo (Satake) limited company：HPS-100HEA (is introduced) for 1999.
Paddy is set to kind：Thin,tough silk light (Kinuhikari), moisture content (on the basis of brown rice) 14.1%~14.3%.
Processing speed is set to about 2.5 ton hours.
In addition, the husking yield of the present embodiment is 79%.
About 1417 tons of paddy have been handled in this evaluation, and have measured the abrasion loss of the rubber layer for paddy roller of now hulling.Now on
Abrasion loss, ruler is pressed against on a pair of respective end faces of rice huller paddy roller (home roll and deputy roller), and measures the thickness of the rubber layer of remaining
Degree, calculated as the difference of the thickness (25mm) of the rubber layer with initial stage.Show the result in table 4.
In addition, in table 4, the abrasion loss before so-called home roll and before deputy roller refer to will rice huller paddy roller when being installed on hulling machine positioned at
The abrasion loss of end surface measurement nearby, the abrasion loss after so-called home roll and after deputy roller refer to will rice huller paddy roller when being installed on hulling machine
Positioned at the abrasion loss of the end surface measurement of inboard.
And then based on the measurement result of the abrasion loss, calculate and rice huller paddy roller is used untill service life (rubber layer
Untill thickness turns into 5mm) when prediction limits rice huller paddy amount (predicted value of the weight of the paddy for the paddy that can carry out hulling).Result is shown
In table 4.
In addition, the average value (average wear amount) of the abrasion loss everywhere using methods described measurement is calculated, based on average
The weight (B) of the paddy of abrasion loss (A) and actual treatment simultaneously calculates prediction limits rice huller paddy amount using following formulas (1).
Weight (B) ÷ [average wear amount (A)/20] ... (1) of prediction limits rice huller paddy amount=paddy
(embodiment 17)
In the present embodiment, pattern is made：The rice huller paddy roller of integrated 100 types.
Herein, in addition to change shape and size, rice huller paddy roller is made using method similarly to Example 12.
For made rice huller paddy roller, the mill in Feng Gang small towns warehouse (Tian Dao agricultural cooperative societys) to rice huller paddy amount and rubber layer
Relation between consumption is evaluated.
The model that hulling machine is manufactured using company of assistant bamboo (Satake) limited company：HPS-100HEA-K (2004
Introduce).
Paddy is set to kind：More light (Kosihikari), moisture content (on the basis of brown rice) 14.1%~14.5%.
Processing speed is set to about 2.8 ton hours.
In addition, the husking yield of the present embodiment is 78%.
About 378 tons of paddy have been handled in this evaluation, the rubber for paddy roller of now hulling is measured in a manner of similarly to Example 16
The abrasion loss of layer.
And then the measurement result based on the abrasion loss calculates prediction limits rice huller paddy amount.
Show the result in table 4.
(embodiment 18)
In the present embodiment, pattern is made：The rice huller paddy roller of integrated 100 types.
Herein, in addition to change shape and size, rice huller paddy roller is made using method similarly to Example 13.
For made rice huller paddy roller, in rice U.S. small towns warehouse (Hyogo south agricultural cooperative society) to rice huller paddy amount and rubber layer
Relation between abrasion loss is evaluated.
The model that hulling machine is manufactured using assistant bamboo (Satake) company：HPS100HEA (is introduced) for 1999.
Paddy is set to kind：Daylight (Hinohikari) and thin,tough silk light, moisture content (on the basis of brown rice)：14.3% (day
Light), 14.1% (thin,tough silk light).
Processing speed is set to about 2.0 ton hours.
In addition, the husking yield of the present embodiment is 78%.
About 588 tons of paddy have been handled in this evaluation, the rubber for paddy roller of now hulling is measured in a manner of similarly to Example 16
The abrasion loss of layer.
And then the measurement result based on the abrasion loss calculates prediction limits rice huller paddy amount.
Show the result in table 4.
(embodiment 19)
In the present embodiment, pattern is made：The rice huller paddy roller of integrated 100 types.
Herein, in addition to change shape and size, rice huller paddy roller is made using method similarly to Example 14.
For made rice huller paddy roller, the mill in day high small towns warehouse (Tian Dao agricultural cooperative societys) to rice huller paddy amount and rubber layer
Relation between consumption is evaluated.
The use that hulling machine is manufactured using assistant bamboo (Satake) limited company integrates the hulling machine (1972 of 100 type rollers
Year introduces).
Paddy is set to kind：More light, moisture content (on the basis of brown rice)：14.2%~14.6%.
Processing speed is set to about 2.8 ton hours.
In addition, the husking yield of the present embodiment is 78%.
About 175 tons of paddy have been handled in this evaluation, the rubber for paddy roller of now hulling is measured in a manner of similarly to Example 16
The abrasion loss of layer.
And then the measurement result based on the abrasion loss calculates prediction limits rice huller paddy amount.
Show the result in table 4.
(embodiment 20)
In the present embodiment, pattern is made：The rice huller paddy roller of integrated 100 types.
Herein, in addition to change shape and size, rice huller paddy roller is made using method similarly to Example 15.
For made rice huller paddy roller, the mill in day high small towns warehouse (Tian Dao agricultural cooperative societys) to rice huller paddy amount and rubber layer
Relation between consumption is evaluated.
The use that hulling machine is manufactured using assistant bamboo (Satake) limited company integrates the hulling machine (1972 of 100 type rollers
Year introduces).
Paddy is set to kind：More light, moisture content (on the basis of brown rice)：14.2%~14.6%.
Processing speed is set to about 2.8 ton hours.
In addition, the husking yield of the present embodiment is 78%.
About 145 tons of paddy have been handled in this evaluation, the rubber for paddy roller of now hulling is measured in a manner of similarly to Example 16
The abrasion loss of layer.
And then the measurement result based on the abrasion loss calculates prediction limits rice huller paddy amount.
Show the result in table 4.
(comparative example 9)
In this comparative example, pattern is made：The rice huller paddy roller of integrated 100 types.
Herein, in addition to change shape and size, rice huller paddy roller is made using with the same method of comparative example 1.
For made rice huller paddy roller, going out mill of the stone small towns warehouse (Tian Dao agricultural cooperative societys) to rice huller paddy amount and rubber layer
Relation between consumption is evaluated.
The use that hulling machine is manufactured using company of assistant bamboo (Satake) limited company integrates the hulling machine of 100 type rollers
(introducing within 1972).
Paddy is set to kind：More light, moisture content (on the basis of brown rice) 14.8%~15.0%.
Processing speed is set to about 2.5 ton hours.
In addition, the husking yield of the present embodiment is 79%.
About 142 tons of paddy have been handled in this evaluation, the rubber for paddy roller of now hulling is measured in a manner of similarly to Example 16
The abrasion loss of layer.
And then the measurement result based on the abrasion loss calculates prediction limits rice huller paddy amount.
Show the result in table 4.
(comparative example 10)
In this comparative example, pattern is made：The rice huller paddy roller of integrated 100 types.
Herein, in addition to change shape and size, rice huller paddy roller is made using with the same method of comparative example 6.
For made rice huller paddy roller, going out mill of the stone small towns warehouse (Tian Dao agricultural cooperative societys) to rice huller paddy amount and rubber layer
Relation between consumption is evaluated.
The use that hulling machine is manufactured using company of assistant bamboo (Satake) limited company integrates the hulling machine of 100 type rollers
(introducing within 1972).
Paddy is set to kind：More light, moisture content (on the basis of brown rice) 14.8%~15.0%.
Processing speed is set to about 2.5 ton hours.
In addition, the husking yield of the present embodiment is 79%.
About 220 tons of paddy have been handled in this evaluation, the rubber for paddy roller of now hulling is measured in a manner of similarly to Example 16
The abrasion loss of layer.
And then the measurement result based on the abrasion loss calculates prediction limits rice huller paddy amount.
Show the result in table 4.
As shown in table 4, it specify that due to possessing the excellent in te pins of durability of the rice huller paddy roller of the invention of following rubber layer, because
This can be long-term use of, and can reduce the replacement frequency of rice huller paddy roller, and the rubber layer includes the special exercise viscosity containing ormal weight
Silicone oil thermosetting carbamate composition hardening thing.
[explanation of symbol]
10、10A、10B：Rice huller paddy roller
11：Core portion
11a：Mounting flange
12：Rubber layer
Claims (3)
1. one kind rice huller paddy roller, it possesses core portion and is laminated in the rubber layer of the outer peripheral face in the core portion, and the rice huller paddy roller
It is characterised by：
The rubber layer includes the thermosetting carbamic acid containing polyol component, isocyanate prepolymer composition, crosslinking agent and silicone oil
The hardening thing of ester composition,
The isocyanate prepolymer composition is toluene di-isocyanate(TDI) and/or methyl diphenylene diisocyanate,
Kinematic viscosity of the silicone oil at 25 DEG C is 10mm2/ s~3000mm2/ s,
Relative to the total amount of polyol component, isocyanate prepolymer composition and crosslinking agent, the thermosetting carbamate combination
The content of the silicone oil in thing is the weight % of 0.3 weight %~10.0.
2. rice huller paddy roller according to claim 1, wherein the silicone oil is dimethyl polysiloxane.
3. rice huller paddy roller according to claim 1 or 2, wherein the crosslinking agent is at least BDO.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015046210A JP5848473B1 (en) | 2015-03-09 | 2015-03-09 | Hulling roll |
| JP2015-046210 | 2015-03-09 | ||
| PCT/JP2016/056422 WO2016143633A1 (en) | 2015-03-09 | 2016-03-02 | Husking roll |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107405623A true CN107405623A (en) | 2017-11-28 |
| CN107405623B CN107405623B (en) | 2019-05-07 |
Family
ID=55176128
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680013692.0A Expired - Fee Related CN107405623B (en) | 2015-03-09 | 2016-03-02 | Husking roller |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5848473B1 (en) |
| CN (1) | CN107405623B (en) |
| MY (1) | MY197584A (en) |
| WO (1) | WO2016143633A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114173927A (en) * | 2019-08-06 | 2022-03-11 | 阪东化学株式会社 | Rice hulling roller and rice hulling method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6661413B2 (en) * | 2016-03-03 | 2020-03-11 | 三井化学株式会社 | Hulling roll and method for producing the hulling roll |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5174865A (en) * | 1974-12-14 | 1976-06-29 | Bridgestone Tire Co Ltd | |
| JPS51107948A (en) * | 1975-03-12 | 1976-09-24 | Bridgestone Tire Co Ltd | |
| JP2001029809A (en) * | 1999-07-27 | 2001-02-06 | Iseki & Co Ltd | Husking roll |
| JP2011046812A (en) * | 2009-08-26 | 2011-03-10 | Toyo Tire & Rubber Co Ltd | Lubricating rubber composition and vibration-proof rubber |
| CN202044972U (en) * | 2011-03-28 | 2011-11-23 | 来安县安泰聚氨酯制品有限公司 | Paddy hulling rubber roll |
| CN106457254A (en) * | 2014-04-16 | 2017-02-22 | 阪东化学株式会社 | Husking roll |
-
2015
- 2015-03-09 JP JP2015046210A patent/JP5848473B1/en not_active Expired - Fee Related
-
2016
- 2016-03-02 MY MYPI2017703235A patent/MY197584A/en unknown
- 2016-03-02 WO PCT/JP2016/056422 patent/WO2016143633A1/en active Application Filing
- 2016-03-02 CN CN201680013692.0A patent/CN107405623B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5174865A (en) * | 1974-12-14 | 1976-06-29 | Bridgestone Tire Co Ltd | |
| JPS51107948A (en) * | 1975-03-12 | 1976-09-24 | Bridgestone Tire Co Ltd | |
| JP2001029809A (en) * | 1999-07-27 | 2001-02-06 | Iseki & Co Ltd | Husking roll |
| JP2011046812A (en) * | 2009-08-26 | 2011-03-10 | Toyo Tire & Rubber Co Ltd | Lubricating rubber composition and vibration-proof rubber |
| CN202044972U (en) * | 2011-03-28 | 2011-11-23 | 来安县安泰聚氨酯制品有限公司 | Paddy hulling rubber roll |
| CN106457254A (en) * | 2014-04-16 | 2017-02-22 | 阪东化学株式会社 | Husking roll |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114173927A (en) * | 2019-08-06 | 2022-03-11 | 阪东化学株式会社 | Rice hulling roller and rice hulling method |
| CN114173927B (en) * | 2019-08-06 | 2022-08-23 | 阪东化学株式会社 | Rice hulling roller and rice hulling method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5848473B1 (en) | 2016-01-27 |
| CN107405623B (en) | 2019-05-07 |
| WO2016143633A1 (en) | 2016-09-15 |
| MY197584A (en) | 2023-06-26 |
| JP2016165672A (en) | 2016-09-15 |
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