CN107400496A - A kind of silazane hydridization cyanate ester adhesive - Google Patents
A kind of silazane hydridization cyanate ester adhesive Download PDFInfo
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- CN107400496A CN107400496A CN201710623592.6A CN201710623592A CN107400496A CN 107400496 A CN107400496 A CN 107400496A CN 201710623592 A CN201710623592 A CN 201710623592A CN 107400496 A CN107400496 A CN 107400496A
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- silazane
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J179/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09J161/00 - C09J177/00
- C09J179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0638—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with at least three nitrogen atoms in the ring
- C08G73/0644—Poly(1,3,5)triazines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0638—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with at least three nitrogen atoms in the ring
- C08G73/065—Preparatory processes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The present invention relates to high-temperature resistance adhesive technical field, a kind of more particularly to silazane hydridization cyanate ester adhesive, in terms of mass fraction, the silazane hydridization cyanate ester adhesive raw material mainly includes 100 parts of cyanates, 5~30 parts of silazane, 0~200 part of solid packing, 0~20 part of solid pigment, 0~5 part of chopped strand.Beneficial effects of the present invention are:The present invention improves the temperature tolerance and inoxidizability of cyanate, while match corresponding filler and prepare resistant to elevated temperatures adhesive by the use of silazane hydridization cyanate as the matrix resin of high-temperature resistance adhesive;While cyanate ester adhesive adhesive property is kept, its high-temperature behavior is improved;Adhesive prepared by the present invention disclosure satisfy that demand of the fields such as Aeronautics and Astronautics to high-temperature-resistant structure adhesive.
Description
Technical field
The present invention relates to high-temperature resistance adhesive technical field, more particularly to a kind of silazane hydridization cyanate ester adhesive.
Background technology
With the development of the industry such as high-tech development, particularly Aero-Space, electronics, machinery, weapons, for structure glue
Stick proposes higher requirement, such as temperature tolerance, anti-fatigue performance.
Current organic structure adhesive mainly includes epoxide resin type and polyimide type etc., but based on epoxy resin
Adhesive heatproof be less than 200 DEG C;Polyimide type adhesive has good temperature tolerance, but solidification temperature is high;Cyanate resin
Fat has good heat resistance and manufacturability, the adhesive structure part high available for heat resistant requirements, but its temperature tolerance still is apparent not enough, and
And high-temperature oxidation resistance is poor.
The content of the invention
In view of above-mentioned analysis, the present invention is intended to provide a kind of high temperature resistant silicon azane hydridization cyanate ester adhesive, to solve
The problem of certainly existing cyanate ester adhesive binding agent temperature tolerance deficiency, high-temperature oxidation resistance difference.
The purpose of the present invention is mainly achieved through the following technical solutions:
A kind of silazane hydridization cyanate ester adhesive, in terms of mass fraction, the silazane hydridization cyanate ester adhesive is former
Material mainly includes:
100 parts of cyanates,
5~30 parts of silazane,
0~200 part of solid packing,
0~20 part of solid pigment,
0~5 part of chopped strand.
The present invention, as the matrix resin of high-temperature resistance adhesive, improves silazane hydridization by the use of silazane hydridization cyanate
The heat-resisting quantity and inoxidizability of cyanate ester adhesive, while match corresponding filler and prepare resistant to elevated temperatures adhesive, can
Meets the needs of fields such as Aeronautics and Astronautics are to high-temperature-resistant structure adhesive.
Further, the cyanate is at least the cyanate of difunctionality.
The cyanate that present invention selection is at least difunctionality is because degree of functionality is related to the formation of cross-linking system, if official
Energy degree is few, then can not form cross-linking system, can not solidify.
Further, the cyanate is difunctionality or polyfunctional cyanate, cyanic acid ester oligomer, cyanate prepolymer
In one or more of mixtures.
Raw material cyanate can be liquid cyanate or the organic solvent solution of cyanate, the concentration control of cyanic acid ester solution
System is more than 70%.
Further, the structural formula of the cyanate is
Or at least one of aliphatic cyanate;
In formula I, R1To R4For hydrogen, C1-C10 alkyl, C3-C8 cycloalkyl, C1-C10 alkoxies, halogen, phenyl or phenoxy group
In one kind, wherein alkyl or aryl can be fluorinated or partially fluorinated;
In formula II, R1To R8For hydrogen, C1-C10 alkyl, C3-C8 cycloalkyl, C1-C10 alkoxies, halogen, phenyl or benzene oxygen
One kind in base, wherein alkyl or aryl can be fluorinated or partially fluorinated;
Z represents chemical bond, SO2、CF2、CH2、CHF、CH(CH3), isopropylidene, hexafluoroisopropyli,ene, C1-C10 alkylenes
Base, O, NR9, N=N, CH=N, CH=CH, COO, CH=N-N=CH, there is the alkylene oxide groups of C1-C8 alkylidenes, S, Si
(CH3)2Or
In formula III, R9For one kind in H or C1-C10 alkyl, 0≤n≤20, n are integer.
Preferably, when the cyanate is Formulas I, the cyanate be phenylene -1,3- dicyanate, phenylene-Isosorbide-5-Nitrae -
Dicyanate or 2,4,5- trifluoro phenylene -1,3- dicyanates;When the cyanate is formula II, the cyanate be 4,4 '-
Double (phenylcyanate) methane, dicyclopentadiene type ethylene rhodanate, 4,4 '-bis- (phenylcyanate) isopropyl alkanes, 2,2- double (4- cyanic acid
Ester group-phenyl) HFC-236fa;The aliphatic cyanate is difunctionality aliphatic cyanate or multifunctional aliphatic cyanate,
The structural formula of the aliphatic cyanate is
N≡C-O-R10- O-C ≡ N formulas IV
One can be contained in the aliphatic group of the difunctionality aliphatic cyanate or multifunctional aliphatic cyanate
Or multiple fluorine atoms;
In formula IV, R10Divalent hydrocarbon/alkyl of the organic non-aromatic containing 3~12 carbon atoms is represented, it is described organic non-aromatic
The hydrogen atom of divalent hydrocarbon/alkyl of race can partly or entirely be substituted by fluorine atom.
Further, the cyanate is cyanate ester monomer or cyanate prepolymer, the cyanate ester monomer or cyanogen
Acid esters prepolymer is made individually or as mutual mixture or as the mixture of other simple function cyanates
With.
The prepolymer is the material for referring to further be crosslinked, and can act as difunctionality cyanate or oligomeric cyanate
It is:4,4 '-bis- (phenylcyanate) isopropyl alkanes (B10), 4,4 '-bis- (phenylcyanate) ethane (L10), Novolac Cyanate Eater Resin
Or Cyclopeutadiene type cyanate (P10) (N10).
Further, the silazane is one or more of mixtures of silazane oligomer or silicon nitrogen silane copolymer;
Contain silazine link in the molecular structure of the silazane oligomer or silicon nitrogen silane copolymer;The silazane oligomer is molecule knot
There is the silazane of 2~10 silicon atoms, the silicon nitrogen silane copolymer is at least to contain 11 silicon atoms in molecular structure in structure
Silazane above.
Present invention selection silazane oligomer or silicon nitrogen silane copolymer are because silazane oligomer or silicon nitrogen silane copolymer
The solidification temperature of cyanate can be reduced, improves the temperature tolerance of cyanate.
Further, the silazane be silazane, boron aluminium silazane, carbon silazane or silica silazane one kind or
Several mixtures.
Further, the formula of the silazane is
The formula of the boron aluminium silazane is
The formula of the silica silazane is
The formula of the carbon silazane is
R in formula17、R11、R11'、R13、R13'、R15And R15'For H, the alkyl of straight or branched, straight or branched alkenyl, straight
The aryl of chain or side chain, the aryl alkyl of straight or branched, straight or branched alkenyl aryl in one kind;
R17'For in H, the alkyl of straight or branched, the alkenyl of straight or branched, the aryl of straight or branched, logical formula (V)
One kind, logical formula (V) are
R12And R12'For one kind in H, C1~C4 alkyl, phenyl;
R14And R14'For one kind in H, the alkyl of straight or branched, the alkenyl of straight or branched, logical formula (VI), formula
(VI) it is
R16For C1~C10 alkylidene;
M is B or Al;
M, k, p, q, o, s are integer;0≤m≤2000,0≤k≤2000, as m=0, k ≠ 0, as k=0, m ≠ 0;1
≤s≤50;1≤p≤100;0≤q≤2000,1≤o≤1000.
Further, the solid packing is III A, IV A main groups, B races, the oxide of lanthanide series metal, carbide, nitridation
At least one of thing, boride, silicide.
Solid packing is added in the present invention can play enhancing, toughness reinforcing to adhesive and improve durothermic effect.
Further, the solid pigment is inorganic pigment.
Preferably, the solid pigment is iron oxide red, chrome yellow or titanium white.
Further, the chopped strand is carbon fiber, silicon carbide fibre, alumina fibre, quartz fibre, glass fibers
Dimension, silicon nitride fiber, silicon nitride or boron nitride, the chopped strand length are 1~5 millimeter.
The chopped strand of the present invention 1~5 mm length of selection, can play a part of toughness reinforcing, if chopped strand is too short, nothing
Method plays the effect of toughness reinforcing, if chopped strand is oversize, can not be well mixed the various raw materials of cyanate ester adhesive.
The present invention has the beneficial effect that:
(1) present invention improves cyanate by the use of silazane hydridization cyanate as the matrix resin of high-temperature resistance adhesive
Temperature tolerance and inoxidizability, while match corresponding filler and prepare resistant to elevated temperatures adhesive;
(2) adhesive of the invention improves its high-temperature behavior while cyanate ester adhesive adhesive property is kept;
(3) adhesive prepared by the present invention disclosure satisfy that demand of the fields such as Aeronautics and Astronautics to high-temperature-resistant structure adhesive.
Embodiment
The present invention is using cyanate or its difunctionality, oligomer or polyfunctional cyanate or its prepolymer and silicon for being modified
Azane oligomer or polymer, solid packing, chopped strand, solid pigment carry out quantitative mixing, you can high temperature resistant is prepared
Sqtructural adhesive.
The preparation method of high-temperature-resistant structure adhesive of the present invention is:
One is added in 100 parts of cyanates or its difunctionality, oligomer or polyfunctional cyanate for being modified or its prepolymer
After quantitative auxiliary packing is well mixed, corresponding curing agent is added, is deaerated 5~10 minutes after mixing well, you can as resistance to height
Warm sqtructural adhesive uses.
The curing of high-temperature-resistant structure adhesive of the present invention is:
The adhesive first in 30~70 DEG C of preferably 45~60 DEG C of precuring 1~5 hour, is then warming up to 130~240 again
DEG C, preferably 150~200 DEG C, 1~4 hour hardening time.
Wherein, cyanate is one kind in difunctionality or polyfunctional cyanate, cyanic acid ester oligomer, cyanate prepolymer
Or several mixture;Cyanate can be the organic solvent solution of liquid cyanate or cyanate, cyanic acid ester solution it is dense
Degree control is more than 70%.
The structural formula of cyanate is
Or at least one of aliphatic cyanate;
In formula I, R1To R4For hydrogen, C1-C10 alkyl, C3-C8 cycloalkyl, C1-C10 alkoxies, halogen, phenyl or phenoxy group
In one kind, wherein alkyl or aryl can be fluorinated or partially fluorinated;
In formula II, R1To R8For hydrogen, C1-C10 alkyl, C3-C8 cycloalkyl, C1-C10 alkoxies, halogen, phenyl or benzene oxygen
One kind in base, wherein alkyl or aryl can be fluorinated or partially fluorinated;
Z represents chemical bond, SO2、CF2、CH2、CHF、CH(CH3), isopropylidene, hexafluoroisopropyli,ene, C1-C10 alkylenes
Base, O, NR9, N=N, CH=N, CH=CH, COO, CH=N-N=CH, there is the alkylene oxide groups of C1-C8 alkylidenes, S, Si
(CH3)2Or
In formula III, R9For one kind in H or C1-C10 alkyl, 0≤n≤20, n are integer.
Preferably, when cyanate is Formulas I, cyanate can select phenylene -1,3- dicyanate, phenylene-Isosorbide-5-Nitrae -
Dicyanate or 2,4,5- trifluoro phenylene -1,3- dicyanates;When cyanate is formula II, cyanate can select 4,4 '-
Double (phenylcyanate) methane, dicyclopentadiene type ethylene rhodanate, 4,4 '-bis- (phenylcyanate) isopropyl alkanes, 2,2- double (4- cyanic acid
Ester group-phenyl) HFC-236fa;Aliphatic cyanate is difunctionality aliphatic cyanate or multifunctional aliphatic cyanate,
The structural formula of aliphatic cyanate is
N≡C-O-R10- O-C ≡ N formulas IV
One or more fluorine atoms can be contained in the aliphatic group of difunctionality or polyfunctional aliphatic cyanate;
In formula IV, R10Divalent hydrocarbon/alkyl of the organic non-aromatic containing 3~12 carbon atoms is represented, organic non-aromatic
The hydrogen atom of divalent hydrocarbon/alkyl can partly or entirely be substituted by fluorine atom.
It is noted that cyanate can be cyanate ester monomer or cyanate prepolymer, cyanate ester monomer or cyanic acid
Ester prepolymer is used individually or as mutual mixture or as the mixture of other simple function cyanates;
Prepolymer is the material for referring to further be crosslinked, and can act as difunctionality cyanate or oligomeric cyanate is:4,4 '-bis-
(phenylcyanate) isopropyl alkane (B10), 4,4 '-bis- (phenylcyanate) ethane (L10), Novolac Cyanate Eater Resin (N10) or rings penta
Diene type cyanate (P10).
It is noted that silazane is that silazane oligomer or the one or more of of silicon nitrogen silane copolymer mix in the present invention
Compound;Contain silazine link in the molecular structure of silazane oligomer or silicon nitrogen silane copolymer;Silazane oligomer is molecular structure
In there is the silazane of 2~10 silicon atoms, silicon nitrogen silane copolymer be in molecular structure at least containing 11 silicon atoms more than
Silazane.
It is noted that silazane be silazane, boron aluminium silazane, carbon silazane or one kind in silica silazane or
A variety of mixtures or modified silazane, modified borosilicate azane, carbon modified silazane, modified aluminium silazane or modification
One or more of mixtures in silica silazane.
It is noted that the formula of silazane is
The formula of boron aluminium silazane is
The formula of silica silazane is
The formula of carbon silazane is
R in formula17、R11、R11'、R13、R13'、R15And R15'For H, the alkyl of straight or branched, straight or branched alkenyl, straight
The aryl of chain or side chain, the aryl alkyl of straight or branched, straight or branched alkenyl aryl in one kind;
R17'For in H, the alkyl of straight or branched, the alkenyl of straight or branched, the aryl of straight or branched, logical formula (V)
One kind, logical formula (V) are
R12And R12'For one kind in H, C1~C4 alkyl, phenyl;
R14And R14'For one kind in H, the alkyl of straight or branched, the alkenyl of straight or branched, logical formula (VI), formula
(VI) it is
R16For C1~C10 alkylidene;
M is B or Al;
M, k, p, q, o, s are integer;0≤m≤2000,0≤k≤2000, as m=0, k ≠ 0, as k=0, m ≠ 0;1
≤s≤50;1≤p≤100;0≤q≤2000,1≤o≤1000.
It is noted that in the present invention solid packing be III A, IV A main groups, B races, the oxide of lanthanide series metal, carbide,
At least one of nitride, boride, silicide.
It is noted that solid pigment is inorganic pigment in the present invention, such as iron oxide red, chrome yellow or titanium white.
It is noted that chopped strand is carbon fiber, silicon carbide fibre, alumina fibre, quartz fibre, glass in the present invention
Glass fiber, silicon nitride fiber, silicon nitride or boron nitride, chopped strand length are 1~5 millimeter.
Wherein, the method for respective performances involved in present invention test and standard are according to following standard
GJB444-1988《Adhesive drawing by high temperature shear strength experimental method (metal to metal)》
GB/T7124-2008《Adhesive tensile shear method of testing (metal to metal)》
GB/T14992-2005《The classification of high temperature alloy and intermetallic compound high-temperature material and the trade mark》
Embodiment 1
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 3 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
20 parts of silazane are added, after vacuum outgas 5 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, invention adhesive
For plastics, metal, graphite, ceramic composite materials bonding, wherein, 4,4 '-bis- (phenylcyanate) ethane (L10)
Structural formula is shown in formula 1, and the structural formula of silazane is shown in formula 2.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, the high temperature resistant silicon azane after test solidification is miscellaneous
Change the room temperature adhesion strength of cyanate ester adhesive.
The structural formula of 4,4 '-bis- (phenylcyanate) ethane is
The structural formula of silazane is
High temperature resistant silicon azane hydridization cyanate ester adhesive after this implementation is solidified is used for the bonding of different substrate materials, tests it
Room temperature shear strength, as shown in table 1.
Room temperature adhesion strength of the silazane hydridization cyanate ester adhesive of table 1 to different substrate materials
Embodiment 2
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 3 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
Add silazane, the addition mass fraction of silazane is 5 parts of (a), 10 parts of (b), 15 parts of (c), 20 parts of (d), 25 parts of (e), (f) 30
Part, after vacuum outgas 5 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive;
The present invention from steel as bonding substrates, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in
Formula 1, the structural formula of silazane are shown in formula 2.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties;
Meanwhile the present embodiment prepares comparative example 1, comparative example 1 is to mix L10 with filler, and specific test result is shown in Table 2.
The adhesive property of silazane hydridization cyanate ester adhesive prepared by the different silazane dosages of table 2
Sample | Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) |
a | 16.9 | 8.5 |
b | 17.6 | 10.8 |
c | 18.3 | 11.0 |
d | 19.2 | 12.2 |
e | 16.1 | 8.6 |
f | 15.4 | 7.8 |
Comparative example 1 | 16.2 | 8.4 |
By table 2, it can be seen that silazane hydridization cyanate ester adhesive prepared by addition silazane is glued at room temperature with 250 DEG C
Connect functional.
Embodiment 3
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
20 parts of silazane are added, after vacuum outgas 10 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention selects steel
For bonding substrates, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in formula 1, and the structural formula of silazane is shown in formula
2。
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specifically it is shown in Table 3.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 3
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 16.1 | 10.4 |
By table 3, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is be bonded with 250 DEG C in room temperature
It is functional.
Embodiment 4
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
20 parts of silazane are added, after vacuum outgas 10 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention selects steel
For bonding substrates, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in formula 1, and the structural formula of silazane is shown in formula
3。
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specifically it is shown in Table 4.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 4
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 18.6 | 11.9 |
By table 4, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is be bonded with 250 DEG C in room temperature
It is functional.
Embodiment 5
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
20 parts of silazane are added, after vacuum outgas 10 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention selects steel
For bonding substrates, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in formula 1, and the structural formula of silazane is shown in formula
4。
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specifically it is shown in Table 5.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 5
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 18.2 | 10.6 |
By table 5, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is be bonded with 250 DEG C in room temperature
It is functional.
Embodiment 6
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
20 parts of silazane are added, after vacuum outgas 10 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention selects steel
For bonding substrates, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in formula 1, and the structural formula of silazane is shown in formula
5。
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specifically it is shown in Table 6.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 6
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 18.3 | 10.5 |
By table 6, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is be bonded with 250 DEG C in room temperature
It is functional.
Embodiment 7
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
Add 20 parts of silazane, it is 1 that silazane, which is formula 5 and formula 4 according to mass ratio,:1 is mixed to get, after vacuum outgas 10 minutes,
Obtaining high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention is bonding substrates from steel, wherein, 4,4 '-bis- (phenyl cyanic acid
Ester) structural formula of ethane (L10) is shown in formula 1, the structural formula of silazane is shown in formula 4 and formula 5.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specifically it is shown in Table 7.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 7
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 18.5 | 10.5 |
By table 7, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is be bonded with 250 DEG C in room temperature
It is functional.
Embodiment 8
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
20 parts of silazane are added, after vacuum outgas 10 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention selects steel
For bonding substrates, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in formula 1, and the structural formula of silazane is shown in formula
4。
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first small in 30 DEG C of precuring 5
When, 130 DEG C are then warming up to again, 4 hours hardening times, is cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties, specifically
It is shown in Table 8.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 8
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 18.0 | 9.7 |
By table 8, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is be bonded with 250 DEG C in room temperature
It is functional.
Embodiment 9
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
20 parts of silazane are added, after vacuum outgas 10 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention selects steel
For bonding substrates, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in formula 1, and the structural formula of silazane is shown in formula
4。
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first small in 55 DEG C of precuring 2
When, 170 DEG C are then warming up to again, 2 hours hardening times, is cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties, specifically
It is shown in Table 9.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 9
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 19.1 | 11.3 |
By table 9, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is be bonded with 250 DEG C in room temperature
It is functional.
Embodiment 10
The present embodiment adds Si in 100 part 4,4 '-bis- (phenylcyanate) ethane (L10)3N4150 parts, B430 parts of C,
SiO210 parts, Al2O35 parts are used as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3It is fully mixed as solid pigment
It is even, add 20 parts of silazane, after vacuum outgas 10 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention
It is bonding substrates from steel, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in formula 1, the structure of silazane
Formula is shown in formula 4.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specifically it is shown in Table 10.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 10
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 18.5 | 10.4 |
By table 10, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is glued at room temperature with 250 DEG C
Connect functional.
Embodiment 11
The present embodiment is in 100 part 4,4 '-bis- (phenylcyanate) ethane (L10) and the cyanic acid of 4,4 '-methylenediphenyl two
80 parts of SiO are added in the mixture of ester2, 40 parts of ZrB2, 10 parts of SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped
Fiber, 3 parts of Fe2O3As solid pigment, fully mix, add 20 parts of silazane, after vacuum outgas 10 minutes, obtain resistance to height
Warm silazane hydridization cyanate ester adhesive, 4,4 '-bis- (phenylcyanate) ethane (L10) and 4,4 '-methylenediphenyl dicyan
The quality parts ratio of acid esters is 2:10, the present invention from steel is bonding substrates, wherein, 4,4 '-bis- (phenylcyanate) ethane
(L10) structural formula is shown in formula 1, and the structural formula of silazane is shown in formula 4.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specifically it is shown in Table 11.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 11
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 18.9 | 10.8 |
By table 11, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is glued at room temperature with 250 DEG C
Connect functional.
Embodiment 12
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
20 parts of borosilicate azane are added, after vacuum outgas 10 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention selects
Steel is bonding substrates, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in formula 1, the structural formula of borosilicate azane
See formula 6.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specifically it is shown in Table 12.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 12
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 19.8 | 12.2 |
By table 12, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is glued at room temperature with 250 DEG C
Connect functional.
Embodiment 13
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
20 parts of silica azane are added, after vacuum outgas 10 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention selects
Steel is bonding substrates, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in formula 1, the structural formula of silica azane
See formula 7.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specifically it is shown in Table 13.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 13
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 18.5 | 10.1 |
By table 13, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is glued at room temperature with 250 DEG C
Connect functional.
Embodiment 14
The present embodiment is in 100 part 4,4 '-bis- middle additions of (phenylcyanate) ethane (L10), 80 parts of SiO2, 40 parts of ZrB2、10
Part SiC, 10 parts of TiC are as solid packing, 5 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, then
20 parts of carbon silazane are added, after vacuum outgas 10 minutes, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive, the present invention selects
Steel is bonding substrates, wherein, the structural formula of 4,4 '-bis- (phenylcyanate) ethane (L10) is shown in formula 1, the structural formula of carbon silazane
See formula 8.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specifically it is shown in Table 14.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 14
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 18.8 | 11.2 |
By table 14, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is glued at room temperature with 250 DEG C
Connect functional.
Embodiment 15
The present embodiment 100 parts to phenyl dicyanate in add 80 parts of SiO2, 40 parts of ZrB2, 10 parts of SiC, 10 parts of TiC make
For solid packing, 3 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, add silazane, silicon nitrogen
The addition mass fraction of alkane is 5 parts of (a), and 10 parts of (b), 15 parts of (c), 20 parts of (d), 25 parts of (e), 30 parts of (f), vacuum outgas 5 divides
Zhong Hou, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive;Phenylcyanate is made into 75% solution,
The present invention selects steel as bonding substrates, wherein, formula 9, the knot of silazane are shown in the structural formula of phenyl dicyanate
Structure formula is shown in formula 2.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specific test result is shown in Table 15.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 15
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 14.4 | 10.1 |
By table 15, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is glued at room temperature with 250 DEG C
Connect functional.
Embodiment 16
The present embodiment adds 80 parts of SiO in 100 parts of Bisphenol F dicyanates2, 40 parts of ZrB2, 10 parts of SiC, 10 parts of TiC make
For solid packing, 3 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, add silazane, silicon nitrogen
The addition mass fraction of alkane is 5 parts of (a), and 10 parts of (b), 15 parts of (c), 20 parts of (d), 25 parts of (e), 30 parts of (f), vacuum outgas 5 divides
Zhong Hou, obtain high temperature resistant silicon azane hydridization cyanate ester adhesive;Bisphenol F dicyanate is made into 85% solution,
The present invention selects steel as bonding substrates, wherein, formula 10, the knot of silazane are shown in the structural formula of phenyl dicyanate
Structure formula is shown in formula 2.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specific test result is shown in Table 16.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 16
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 15.2 | 12.7 |
By table 16, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is glued at room temperature with 250 DEG C
Connect functional.
Embodiment 17
The present embodiment adds 80 parts of SiO in 100 parts of dicyanates2, 40 parts of ZrB2, 10 parts of SiC, 10 parts of TiC are as solid
Filler, 3 parts of SiO2As chopped strand, 3 parts of Fe2O3As solid pigment, fully mix, add silazane, silazane adds
It is 5 parts of (a) to enter mass fraction, 10 parts of (b), 15 parts of (c), 20 parts of (d), 25 parts of (e), 30 parts of (f), after vacuum outgas 5 minutes, is obtained
To high temperature resistant silicon azane hydridization cyanate ester adhesive;Dicyanate is made into 85% solution,
The present invention selects steel as bonding substrates, wherein, formula 11, the knot of silazane are shown in the structural formula of phenyl dicyanate
Structure formula is shown in formula 2.
The curing process of high temperature resistant silicon azane hydridization cyanate ester adhesive is in the present embodiment:It is first pre- solid under the conditions of 45 DEG C
Change 2 hours, be then warming up to 150 DEG C of 2 hours hardening times again, be cooled to room temperature, test its room temperature and 250 DEG C of adhesive properties,
Specific test result is shown in Table 17.
The adhesive property of the high temperature resistant silicon azane hydridization cyanate ester adhesive of table 17
Room temperature adhesion strength (MPa) | 250 DEG C of adhesion strengths (MPa) | |
Adhesion strength (MPa) | 13.1 | 10.5 |
By table 17, it can be seen that silazane hydridization cyanate ester adhesive manufactured in the present embodiment is glued at room temperature with 250 DEG C
Connect functional.
In summary, the invention provides a kind of high temperature resistant silicon azane hydridization cyanate ester adhesive and its preparation, solidification side
Method, the present invention improve the temperature tolerance of cyanate by the use of silazane hydridization cyanate as the matrix resin of high-temperature resistance adhesive
And inoxidizability, while match corresponding filler and prepare resistant to elevated temperatures adhesive;Meanwhile the adhesive energy prepared by the present invention
Enough meets the needs of fields such as Aeronautics and Astronautics are to high-temperature-resistant structure adhesive.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, the change or replacement that can readily occur in,
It should all be included within the scope of the present invention.
Claims (10)
- A kind of 1. silazane hydridization cyanate ester adhesive, it is characterised in that in terms of mass fraction, the silazane hydridization cyanate Adhesive raw materials mainly include:100 parts of cyanates,5~30 parts of silazane,0~200 part of solid packing,0~20 part of solid pigment,0~5 part of chopped strand.
- 2. a kind of silazane hydridization cyanate ester adhesive according to claim 1, it is characterised in that the cyanate is double One or more of mixtures in function or polyfunctional cyanate, cyanic acid ester oligomer, cyanate prepolymer.
- A kind of 3. silazane hydridization cyanate ester adhesive according to claim 1 or 2, it is characterised in that the cyanate Structural formula beOr at least one of aliphatic cyanate;In formula I, R1To R4For hydrogen, C1-C10 alkyl, C3-C8 cycloalkyl, in C1-C10 alkoxies, halogen, phenyl or phenoxy group It is a kind of;In formula II, R1To R8For hydrogen, C1-C10 alkyl, C3-C8 cycloalkyl, in C1-C10 alkoxies, halogen, phenyl or phenoxy group One kind;Z represents chemical bond, SO2、CF2、CH2、CHF、CH(CH3), isopropylidene, hexafluoroisopropyli,ene, C1-C10 alkylidenes, O, NR9, N=N, CH=N, CH=CH, COO, CH=N-N=CH, there is the alkylene oxide groups of C1-C8 alkylidenes, S, Si (CH3)2OrIn formula III, R9For one kind in H or C1-C10 alkyl, 0≤n≤20, n are integer.
- 4. a kind of silazane hydridization cyanate ester adhesive according to claim 3, it is characterised in that the cyanate is formula During I, the cyanate is phenylene -1,3- dicyanate, phenylene-Isosorbide-5-Nitrae-dicyanate or 2,4,5- trifluoro phenylene -1, 3- dicyanates;When the cyanate is formula II, the cyanate is 4,4 '-bis- (phenylcyanate) methane, dicyclopentadiene Type cyanate, 4,4 '-bis- (phenylcyanate) isopropyl alkanes, 2,2- double (4- cyanic acid ester group-phenyl) HFC-236fas;The aliphatic Cyanate is difunctionality aliphatic cyanate or multifunctional aliphatic cyanate,The structural formula of the aliphatic cyanate isN≡C-O-R10- O-C ≡ N formulas IVIn formula IV, R10Divalent hydrocarbon/alkyl of the organic non-aromatic containing 3~12 carbon atoms is represented, the organic non-aromatic The hydrogen atom of divalent hydrocarbon/alkyl can partly or entirely be substituted by fluorine atom.
- 5. a kind of silazane hydridization cyanate ester adhesive according to claim 1, it is characterised in that the silazane is silicon One or more of mixtures of azane oligomer or silicon nitrogen silane copolymer;The silazane oligomer or silicon nitrogen silane copolymer Contain silazine link in molecular structure;The silazane oligomer is the silazane for having in molecular structure 2~10 silicon atoms, institute It is at least containing silazane more than 11 silicon atoms in molecular structure to state silicon nitrogen silane copolymer.
- 6. a kind of silazane hydridization cyanate ester adhesive according to claim 5, it is characterised in that the silazane is silicon Azane, boron aluminium silazane, one or more of mixtures of carbon silazane or silica silazane.
- 7. a kind of silazane hydridization cyanate ester adhesive according to claim 6, it is characterised in that the silazane leads to Formula isThe formula of the boron aluminium silazane isThe formula of the silica silazane isThe formula of the carbon silazane isR in formula17、R11、R11'、R13、R13'、R15And R15'For H, the alkyl of straight or branched, the alkenyl of straight or branched, straight chain or The aryl of side chain, the aryl alkyl of straight or branched, straight or branched alkenyl aryl in one kind;R17'For one in H, the alkyl of straight or branched, the alkenyl of straight or branched, the aryl of straight or branched, logical formula (V) Kind, logical formula (V) isR12And R12'For one kind in H, C1~C4 alkyl, phenyl;R14And R14'For one kind in H, the alkyl of straight or branched, the alkenyl of straight or branched, logical formula (VI), logical formula (VI) isR16For C1~C10 alkylidene;M is B or Al;M, k, p, q, o, s are integer;0≤m≤2000,0≤k≤2000, as m=0, k ≠ 0, as k=0, m ≠ 0;1≤s ≤50;1≤p≤100;0≤q≤2000,1≤o≤1000.
- 8. a kind of silazane hydridization cyanate ester adhesive according to claim 1, it is characterised in that the solid packing is At least one of III A, IV A main groups, B races, the oxide of lanthanide series metal, carbide, nitride, boride, silicide.
- 9. a kind of silazane hydridization cyanate ester adhesive according to claim 1, it is characterised in that the solid pigment is Inorganic pigment.
- A kind of 10. silazane hydridization cyanate ester adhesive according to claim 1, it is characterised in that the chopped strand For carbon fiber, silicon carbide fibre, alumina fibre, quartz fibre, glass fibre, silicon nitride fiber, silicon nitride or boron nitride, institute Chopped strand length is stated as 1~5 millimeter.
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