CN107400464A - A kind of medical acrylate conducting resinl and preparation method thereof - Google Patents
A kind of medical acrylate conducting resinl and preparation method thereof Download PDFInfo
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- CN107400464A CN107400464A CN201710585080.5A CN201710585080A CN107400464A CN 107400464 A CN107400464 A CN 107400464A CN 201710585080 A CN201710585080 A CN 201710585080A CN 107400464 A CN107400464 A CN 107400464A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
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Abstract
The invention discloses a kind of medical acrylate conducting resinl and preparation method thereof, medical acrylate conducting resinl, its raw material components include：10 parts of polyacrylic acid oligomer, 0.3~0.9 part of Sodium Polyacrylate, 12~26 parts of water-borne acrylic type monomer, 18~43 parts of oiliness acrylic monomer, 0.1~1 part of polyethylene glycol dimethacrylate, 5~18 parts of polyacrylate oligomer, 12~33 parts of surfactant, 11~27 parts of polyglycereol, 1~6 part of polyacrylamide, 0.5~4 part of polyethylene glycol, 17~47 parts of salting liquid, 0.4~1.5 part of light trigger, 0.4~3 part of tackifier, 2~16 parts of 0.05~0.3 part of crosslinking agent, 0.1~2 part of Vitamin K3 and aerosil.The present invention in tack, hold viscosity, electrical property, biocompatibility, water-retaining property, mildew resistance etc. and have the lifting of highly significant.
Description
Technical field
The present invention relates to a kind of medical acrylate conducting resinl and preparation method thereof, belongs to medical conducting resinl field.
Background technology
Medical conducting resinl is the adhesive with certain electric conductivity after a kind of solidification, and it is generally with matrix resin and conduction
Filler is main constituents, and conducting particles is combined together by the bonding effect of matrix resin, forms conductive path, real
Existing detection device passes through adhesive and human contact and transmitting telecommunication number.
At present, medical conducting resinl in tack, hold the performances such as viscosity, electrical property, biocompatibility, water-retaining property, mildew resistance
Need further to be lifted.
The content of the invention
In order to solve in the prior art medical conducting resinl tack, hold viscosity, electrical property, biocompatibility, water-retaining property, anti-
The defects of poor performances such as mouldiness, the present invention provide a kind of medical acrylate conducting resinl and preparation method thereof, at the beginning of excellent
Viscosity, hold the performances such as viscosity, electrical property, biocompatibility, water-retaining property, mildew resistance.
In order to solve the above technical problems, the technical solution adopted in the present invention is as follows：
A kind of medical acrylate conducting resinl, its raw material components include：10 parts of polyacrylic acid oligomer, Sodium Polyacrylate
0.3~0.9 part, 12~26 parts of water-borne acrylic type monomer, 18~43 parts of oiliness acrylic monomer, polyethylene glycol dimethyl propylene
0.1~1 part of olefin(e) acid ester, 5~18 parts of polyacrylate oligomer, 12~33 parts of surfactant, 11~27 parts of polyglycereol, poly- third
1~6 part of acrylamide, 0.5~4 part of polyethylene glycol, 17~47 parts of salting liquid, 0.4~1.5 part of light trigger, tackifier 0.4~3
2~16 parts of part, 0.05~0.3 part of crosslinking agent, 0.1~2 part of Vitamin K3 and aerosil, the number is mass parts
Number；
Polyacrylic acid oligomer is 10 by mass ratio：(0.03~0.1)：(1~7)：(0.2~1.3)：(0.1~0.6)：
Acrylic acid, light trigger, hydroxy-ethyl acrylate, hydroxy propyl methacrylate, PAA and the acrylic acid hydroxyl of (1.2~3.2)
Propyl ester reaction is made,
Polyacrylate oligomer is 10 by mass ratio：0.5~3：1~5：0.8~2：2~6：0.04~0.09 propylene
Acetoacetic ester, n-butyl acrylate, Isooctyl acrylate monomer, isobutyl acrylate, Hexyl 2-propenoate and light trigger reaction are made.
Applicant it has been investigated that, the cooperative effect between above-mentioned each material component is notable, so that medical acrylate
The tack of conducting resinl, hold the performances such as viscosity, electrical property, biocompatibility, water-retaining property, mildew resistance and have carrying for highly significant
Rise.
In order to further improve the tack of medical acrylate conducting resinl, hold viscosity and electrical property, water-borne acrylic type
Monomer is at least one of acrylic acid, hydroxy-ethyl acrylate or hydroxypropyl acrylate；Oiliness acrylic monomer is acrylic acid
At least one of ethyl ester, butyl acrylate, isobutyl acrylate, Isooctyl acrylate monomer, Hexyl 2-propenoate or propyl acrylate.
In order to further improve the electrical property of medical acrylate conducting resinl and compatibility, glycol dimethacrylates
The molecular weight of polyethylene glycol is 400~1000 in ester；Tackifier is rosin resinoid, polyterpene resinoid, gum dammar, oil
At least one of resin or coumarone-indene resin.
In order to further improve the electrical property of medical acrylate conducting resinl, biocompatibility, water-retaining property and mildew resistance, hand over
Connection agent is ethoxyquin trimethylolpropane trimethacrylate, ethoxyquin tetramethylol methane tetraacrylate, diethylene glycol diacrylate
At least one of ester or tetramethylol methane tetraacrylate.
In order to further improve the combination property of medical acrylate conducting resinl, light trigger is 1- hydroxycyclohexylphenyls
Ketone, double (2,4,6- trimethylbenzoyls)-phenyl phosphine oxides, benzoin dimethylether, diaryl group iodized salt, triaryl iodine
At least one of salt, alkyl salt compounded of iodine or isopropylbenzene cyclopentadienyl iron hexafluorophosphate.Light trigger herein includes preparing polypropylene
Also include preparing used in medical acrylate conducting resinl used in acid oligomer.
In order to further improve the electrical property of medical acrylate conducting resinl, biocompatibility and gluing performance, salting liquid
For at least one of potassium chloride solution, sodium-chloride water solution or aqueous ammonium chloride solution, the mass concentration of salting liquid is 5-
10%wt；Surfactant is allyloxy hydroxy propylene sodium sulfonate, moist type non-ionic reaction emulsifying agent SM-JR-3 or polyphenyl
At least one of vinyl sulfonic acid sodium.
The preparation method of above-mentioned medical acrylate conducting resinl, by polyacrylic acid oligomer, Sodium Polyacrylate, aqueous acrylamide
Acrylic monomer, oiliness acrylic monomer, polyethylene glycol dimethacrylate, polyacrylate oligomer, surfactant,
Polyglycereol, polyacrylamide, polyethylene glycol, salting liquid, light trigger, tackifier, crosslinking agent, Vitamin K3 and gas phase titanium dioxide
Silicon, under conditions of low whipping speed is 80~100r/min, temperature is 25~30 DEG C, react 0.2~0.8h, then through 400~
1000W mercury lamp 1~6s of illumination, resulting material is coated in mould release membrance surface, through 1000~3000W mercury lamp 3~20s of illumination, i.e.,
Obtain medical acrylate conducting resinl.
In order to further improve the tack of medical acrylate conducting resinl, hold viscosity and electrical property, polyacrylate it is low
The preparation method of polymers is：By ethyl acrylate, n-butyl acrylate, Isooctyl acrylate monomer, isobutyl acrylate, acrylic acid oneself
Ester and light trigger, under conditions of low whipping speed is 90~120r/min, temperature is 25~30 DEG C, 0.1~0.5h is reacted, so
By 100~1000W mercury lamp 1~8s of illumination, polyacrylate oligomer is produced.
In order to further improve the tack of medical acrylate conducting resinl and hold viscosity, the preparation of polyacrylic acid oligomer
Method is：By acrylic acid, light trigger, hydroxy-ethyl acrylate, hydroxy propyl methacrylate, PAA and acrylic acid hydroxypropyl
Ester, under the conditions of low whipping speed is 100~130r/min, temperature is 25~30 DEG C, react 0.1~0.5h, then through 400~
1000W mercury lamp 2~12s of illumination, produce polyacrylic acid oligomer.
Polyacrylate oligomer prepared by the application has excellent lipophile, film forming, initial bonding strength and holding power, energy
Assign medical acrylate conducting resinl equally has excellent initial bonding strength and holding power on Oily surface；Prepared by the application
Polyacrylic acid oligomer has excellent hydrophily, film forming, initial bonding strength and holding power, can assign medical acrylate conducting resinl
Equally there is excellent initial bonding strength and holding power in water-based skin surface；Polyacrylate oligomer and polyacrylic acid oligomer energy
Improve the performances such as the storage stability of medical acrylate conducting resinl, water retention property, regulation application viscosity；Surfactant can be with
Improve the stability of heterogeneous system；Polyethylene glycol dimethacrylate and polyglycereol can improve medical acrylate conducting resinl
Water retention property；Tackifier and crosslinking agent can improve the cohesive force, initial bonding strength and holding power of medical acrylate conducting resinl；Each component
Between collaboration and promote effect clearly, make product tack, hold viscosity, electrical property, biocompatibility, water-retaining property,
Mildew resistance etc. has the lifting of highly significant.
The NM technology of the present invention is with reference to prior art.
Medical acrylate conducting resinl of the present invention, the cooperative effect between each material component used is notable, so that medical
The tack of acrylate conducting resinl, hold the performances such as viscosity, electrical property, biocompatibility, water-retaining property, mildew resistance and have very
It is obviously improved；And preparation method is simple, easy to operate.
Embodiment
For a better understanding of the present invention, with reference to the embodiment content that the present invention is furture elucidated, but the present invention
Content is not limited solely to the following examples.
Embodiment 1
A kind of medical acrylate conducting resinl, its preparation method comprise the following steps：
(1) 10 parts of ethyl acrylates, 0.7 part of n-butyl acrylate, 2 parts of Isooctyl acrylate monomers, 1.3 parts of acrylic acid, are weighed
Isobutyl ester, 3 parts of Hexyl 2-propenoates, 0.06 part of double (2,4,6- trimethylbenzoyl)-phenyl phosphine oxide are added in reactor,
Mixing speed is 100r/min, stirring reaction 0.3h under the conditions of 27 DEG C of maintenance system temperature, through 400W mercury lamp illumination 2s, is gathered
Acrylate oligomer；
(2) 10 parts of acrylic acid, 0.05 part of 1- hydroxycyclohexyl phenyl ketone, 2 parts of hydroxy-ethyl acrylates, 0.7 part of first, are weighed
Base hydroxypropyl acrylate, 0.2 part of PAA, 1.6 parts of hydroxypropyl acrylates are added in reactor, mixing speed 120r/
Min, stirring reaction 0.3h under the conditions of 28 DEG C of maintenance system temperature, through 400W mercury lamp illumination 2s, obtains polyacrylic acid oligomer；
(3), weigh 10 parts of polyacrylic acid oligomer, 0.4 part of Sodium Polyacrylate (Zhengzhou Zhi Yuan chemical products Co., Ltd,
Legal numbering：CAS [9003-04-7], solid content >=96%, low polymer≤5%, other embodiments source are identical), 16 part third
Olefin(e) acid, 3 parts of hydroxy-ethyl acrylates, 4 parts of isobutyl acrylates, 12 parts of Hexyl 2-propenoates, 14 parts of propyl acrylates, 0.5 part of poly- second
Glycol (750) dimethylacrylate (Dongguan Yong Zheng Chemical Co., Ltd.s), 13 parts of polyacrylate oligomers, 23 parts of allyl oxygen
Base hydroxy propylene sodium sulfonate, 19 parts of polyglycereol (Sen Di bio tech ltd of Shenzhen, Natrulon H-10, other embodiments sources
It is identical), 2 parts of polyacrylamides (the popular edible chemical inc in Zibo, cation, CPAM, other embodiments source phases
Together), 1 part of polyethylene glycol (Jiangsu Hai'an Petrochemical Plant, PEG20000), 26 part of 5% (wt.%) potassium chloride are water-soluble
Liquid, 0.8 part of double (2,4,6- trimethylbenzoyls)-phenyl phosphine oxide, (Shangrao City thinks nanmu resin to be had 0.8 part of rosin resinoid
Limit company, water-white rosin resin), 0.1 part of ethoxyquin trimethylolpropane trimethacrylate, 0.6 part of Vitamin K3,5 parts of gas phases
Silica (Degussa, AEROSIL 200, other embodiments source are identical) is added in reactor, mixing speed 95r/
Min, stirring reaction 0.5h under the conditions of 27 DEG C of maintenance system temperature, through 400W mercury lamp illumination 2s, mould release membrance table is coated in by material
Face, through 2000W mercury lamp illumination 7s, that is, obtain medical acrylate conducting resinl.
Embodiment 2
A kind of medical acrylate conducting resinl, its preparation method comprise the following steps：
(1) 10 parts of ethyl acrylates, 0.5 part of n-butyl acrylate, 1 part of Isooctyl acrylate monomer, 0.8 part of acrylic acid, are weighed
Isobutyl ester, 2 parts of Hexyl 2-propenoates, 0.04 part of double (2,4,6- trimethylbenzoyl)-phenyl phosphine oxide are added in reactor,
Mixing speed is 90r/min, stirring reaction 0.1h under the conditions of 25 DEG C of maintenance system temperature, through 100W mercury lamp illumination 8s, is gathered
Acrylate oligomer；
(2) 10 parts of acrylic acid, 0.03 part of 1- hydroxycyclohexyl phenyl ketone, 1 part of hydroxy-ethyl acrylate, 0.2 part of first, are weighed
Base hydroxypropyl acrylate, 0.1 part of PAA, 1.2 parts of hydroxypropyl acrylates are added in reactor, mixing speed 100r/
Min, stirring reaction 0.1h under the conditions of 25 DEG C of maintenance system temperature, through 400W mercury lamp illumination 12s, obtains polyacrylic acid oligomer；
(3), weigh 10 parts of polyacrylic acid oligomer, 0.3 part of Sodium Polyacrylate, 9 parts of acrylic acid, 3 parts of hydroxy-ethyl acrylates,
2 parts of ethyl acrylates, 7 parts of Isooctyl acrylate monomers, 9 parts of propyl acrylates, 0.1 part of polyethylene glycol (550) dimethylacrylate
(Dongguan Yong Zheng Chemical Co., Ltd.s), 5 parts of polyacrylate oligomers, 12 parts of kayexalate (beautiful Sheng chemical industry in Shouguang City
Co., Ltd, LS8547-74, other embodiments source are identical), 11 parts of polyglycereol, 1 part of polyacrylamide, 0.5 part of poly- second two
Alcohol, 17 part of 4% (wt.%) potassium chloride solution, 0.4 part of double (2,4,6- trimethylbenzoyls)-phenyl phosphine oxide, 0.4 part
Gum dammar (Zhengzhou Di Ke chemical products Co., Ltd, Indonesia superfine), 0.05 part of ethoxyquin tetramethylol methane tetraacrylate,
0.1 part of Vitamin K3,2 parts of aerosils are added in reactor, mixing speed 80r/min, maintenance system temperature 25
Stirring reaction 0.2h under the conditions of DEG C, through 400W mercury lamp illumination 6s, material is coated in mould release membrance surface, through 1000W mercury lamp illumination
20s, that is, obtain medical acrylate conducting resinl.
Embodiment 3
A kind of medical acrylate conducting resinl, its preparation method comprise the following steps：
(1) 10 parts of ethyl acrylates, 3 parts of n-butyl acrylates, 5 parts of Isooctyl acrylate monomers, 2 parts of i-butyls, are weighed
Ester, 6 parts of Hexyl 2-propenoates, 0.09 part of 1- hydroxycyclohexyl phenyl ketone are added in reactor, mixing speed 120r/min,
Stirring reaction 0.5h under the conditions of 30 DEG C of maintenance system temperature, through 1000W mercury lamp illumination 1s, obtain polyacrylate oligomer；
(2) 10 parts of acrylic acid, 0.1 part of double (2,4,6- trimethylbenzoyls)-phenyl phosphine oxide, 7 parts of acrylic acid, are weighed
Hydroxyl ethyl ester, 1.3 parts of hydroxy propyl methacrylates, 0.6 part of PAA, 3.2 parts of hydroxypropyl acrylates are added in reactor, are stirred
It is 130r/min to mix speed, stirring reaction 0.5h under the conditions of 30 DEG C of maintenance system temperature, through 1000W mercury lamp illumination 2s, is gathered
Acrylic acid oligomer；
(3) 10 parts of polyacrylic acid oligomer, 0.9 part of Sodium Polyacrylate, 12 parts of acrylic acid, 14 parts of acrylic acid hydroxyl second, are weighed
Ester, 8 parts of ethyl acrylates, 15 parts of Isooctyl acrylate monomers, 20 parts of propyl acrylates, 1 part of polyethylene glycol (400) dimethacrylate
Ester (Dongguan Yong Zheng Chemical Co., Ltd.s), 18 parts of polyacrylate oligomers, 33 parts of moist type non-ionic reaction emulsifying agent SM-
JR-3,27 parts of polyglycereol, 6 parts of polyacrylamides, 4 parts of polyethylene glycol, 47 part of 7% (wt.%) potassium chloride solution, 1.5 parts of 1-
Hydroxycyclohexyl phenyl ketone, 3 parts of rosin resinoids (Shangrao City Si Nan resins Co., Ltd, water-white rosin resin), 0.3 part of second
Oxidation trimethylolpropane trimethacrylate, 2 parts of Vitamin K3s, 16 parts of aerosils are added in reactor, stirring speed
Spend for 100r/min, stirring reaction 0.8h under the conditions of 30 DEG C of maintenance system temperature, through 1000W mercury lamp illumination 1s, material is coated
On mould release membrance surface, through 3000W mercury lamp illumination 3s, that is, medical acrylate conducting resinl is obtained.
Embodiment 4
A kind of medical acrylate conducting resinl, its preparation method comprise the following steps：
(1) 10 parts of ethyl acrylates, 1 part of n-butyl acrylate, 3 parts of Isooctyl acrylate monomers, 1 part of i-butyl, are weighed
Ester, 4 parts of Hexyl 2-propenoates, 0.06 part of 1- hydroxycyclohexyl phenyl ketone are added in reactor, mixing speed 100r/min,
Stirring reaction 0.3h under the conditions of 28 DEG C of maintenance system temperature, through 400W mercury lamp illumination 3s, obtain polyacrylate oligomer；
(2) 10 parts of acrylic acid, 0.06 part of 1- hydroxycyclohexyl phenyl ketone, 3 parts of hydroxy-ethyl acrylates, 0.9 part of first, are weighed
Base hydroxypropyl acrylate, 0.4 part of PAA, 2 parts of hydroxypropyl acrylates are added in reactor, mixing speed 110r/
Min, stirring reaction 0.3h under the conditions of 29 DEG C of maintenance system temperature, through 500W mercury lamp illumination 5s, obtains polyacrylic acid oligomer；
(3) 10 parts of polyacrylic acid oligomer, 0.7 part of Sodium Polyacrylate, 5 parts of acrylic acid, 15 parts of acrylic acid hydroxyl second, are weighed
Ester, 10 parts of ethyl acrylates, 10 parts of isobutyl acrylates, 15 parts of Hexyl 2-propenoates, 0.7 part of polyethylene glycol (1000) dimethyl propylene
Olefin(e) acid ester (Dongguan Yong Zheng Chemical Co., Ltd.s), 10 parts of polyacrylate oligomers, 18 parts of allyloxy hydroxy propylene sodium sulfonates, 19
Part polyglycereol, 5 parts of polyacrylamides, 2 parts of polyethylene glycol, 23 part of 7% (wt.%) sodium-chloride water solution, 1 part of double (2,4,6- tri-
Methyl benzoyl)-phenyl phosphine oxide, 2 parts of gum dammars (Zhengzhou Di Ke chemical products Co., Ltd, Indonesia are superfine), 0.1 part
Ethoxyquin tetramethylol methane tetraacrylate, 1 part of Vitamin K3,9 parts of aerosils are added in reactor, and mixing speed is
90r/min, stirring reaction 0.7h under the conditions of 26 DEG C of maintenance system temperature, through 600W mercury lamp illumination 4s, by material coated in release
Film surface, through 1000W mercury lamp illumination 16s, that is, obtain medical acrylate conducting resinl.
Embodiment 5
A kind of medical acrylate conducting resinl, its preparation method comprise the following steps：
(1) it is different that 10 parts of ethyl acrylates, 1 part of n-butyl acrylate, 4 parts of Isooctyl acrylate monomers, 1.5 parts of acrylic acid, are weighed
Butyl ester, 4 parts of Hexyl 2-propenoates, 0.07 part of 1- hydroxycyclohexyl phenyl ketone are added in reactor, mixing speed 95r/
Min, stirring reaction 0.4h under the conditions of 28 DEG C of maintenance system temperature, through 500W mercury lamp illumination 5s, obtains polyacrylate oligomer；
(2) 10 parts of acrylic acid, 0.08 part of benzoin dimethylether, 3 parts of hydroxy-ethyl acrylates, 0.8 part of methacrylic acid, are weighed
Hydroxypropyl acrylate, 0.4 part of PAA, 1.9 parts of hydroxypropyl acrylates are added in reactor, mixing speed 115r/min, are maintained
Stirring reaction 0.3h under the conditions of 28 DEG C of system temperature, through 700W mercury lamp illumination 4s, obtain polyacrylic acid oligomer；
(3) 10 parts of polyacrylic acid oligomer, 0.5 part of Sodium Polyacrylate, 6 parts of acrylic acid, 13 parts of acrylic acid hydroxypropyls, are weighed
Ester, 5 parts of ethyl acrylates, 12 parts of isobutyl acrylates, 16 parts of Isooctyl acrylate monomers, 0.6 part of polyethylene glycol (750) dimethyl propylene
Olefin(e) acid ester (Dongguan Yong Zheng Chemical Co., Ltd.s), 13 parts of polyacrylate oligomers, 26 parts of kayexalates, 21 parts it is poly- sweet
Oil, 3 parts of polyacrylamides, 2.3 parts of polyethylene glycol, 28 part of 9% (wt.%) sodium-chloride water solution, 1.2 parts of benzoin dimethylethers,
1.8 parts of Petropols (Puyang Hengfeng petrochemical industry Co., Ltd, C5 hydrogenated petroleum resins), 0.1 part of propylene of diethylene glycol two
Acid esters, 0.8 part of Vitamin K3,7 parts of aerosils are added in reactor, mixing speed 93r/min, maintenance system temperature
Stirring reaction 0.5h under the conditions of 29 DEG C of degree, through 600W mercury lamp illumination 3s, is coated in mould release membrance surface, through 1000W mercury lamps by material
Illumination 16s, that is, obtain medical acrylate conducting resinl.
Embodiment 6
A kind of medical acrylate conducting resinl, its preparation method comprise the following steps：
(1) 10 parts of ethyl acrylates, 2.3 parts of n-butyl acrylates, 3 parts of Isooctyl acrylate monomers, 1.5 parts of acrylic acid, are weighed
Isobutyl ester, 4 parts of Hexyl 2-propenoates, 0.06 part of benzoin dimethylether are added in reactor, mixing speed 115r/min, are maintained
Stirring reaction 0.3h under the conditions of 27 DEG C of system temperature, through 900W mercury lamp illumination 2s, obtain polyacrylate oligomer；
(2) 10 parts of acrylic acid, 0.07 part of benzoin dimethylether, 4 parts of hydroxy-ethyl acrylates, 1.1 parts of methacrylic acids, are weighed
Hydroxypropyl acrylate, 0.3 part of PAA, 2.7 parts of hydroxypropyl acrylates are added in reactor, mixing speed 120r/min, are maintained
Stirring reaction 0.3h under the conditions of 26 DEG C of system temperature, through 700W mercury lamp illumination 4s, obtain polyacrylic acid oligomer；
(3) 10 parts of polyacrylic acid oligomer, 0.6 part of Sodium Polyacrylate, 15 parts of acrylic acid, 4 parts of acrylic acid hydroxypropyls, are weighed
Ester, 9 parts of ethyl acrylates, 10 parts of butyl acrylates, 6 parts of isobutyl acrylates, 0.6 part of polyethylene glycol (600) dimethyl allene
Acid esters (Dongguan Yong Zheng Chemical Co., Ltd.s), 9 parts of polyacrylate oligomers, 31 parts of moist type non-ionic reaction emulsifying agents
SM-JR-3,23 parts of polyglycereol, 2 parts of polyacrylamides, 3.1 parts of polyethylene glycol, 43 part of 7% (wt.%) aqueous ammonium chloride solution, 0.6
Part benzoin dimethylether, 2.7 parts of coumarone-indene resins (Zibo Ning Song Chemical Co., Ltd.s, 12# Petropols), 0.25 part of season
Penta tetra-acrylate, 0.6 part of Vitamin K3,11 parts of aerosils are added in reactor, mixing speed 95r/
Min, stirring reaction 0.5h under the conditions of 28 DEG C of maintenance system temperature, through 800W mercury lamp illumination 2s, mould release membrance table is coated in by material
Face, through 3000W mercury lamp illumination 5s, that is, obtain medical acrylate conducting resinl.
Embodiment 7
A kind of medical acrylate conducting resinl, its preparation method comprise the following steps：
(1) 10 parts of ethyl acrylates, 2.3 parts of n-butyl acrylates, 4 parts of Isooctyl acrylate monomers, 1.9 parts of acrylic acid, are weighed
Isobutyl ester, 3 parts of Hexyl 2-propenoates, 0.07 part of diaryl group iodized salt are added in reactor, mixing speed 105r/min, are maintained
Stirring reaction 0.4h under the conditions of 28 DEG C of system temperature, through 700W mercury lamp illumination 3s, obtain polyacrylate oligomer；
(2) 10 parts of acrylic acid, 0.06 part of triaryl salt compounded of iodine, 5 parts of hydroxy-ethyl acrylates, 0.8 part of methacrylic acid, are weighed
Hydroxypropyl acrylate, 0.3 part of PAA, 2.2 parts of hydroxypropyl acrylates are added in reactor, mixing speed 123r/min, are maintained
Stirring reaction 0.3h under the conditions of 28 DEG C of system temperature, through 800W mercury lamp illumination 4s, obtain polyacrylic acid oligomer；
(3) 10 parts of polyacrylic acid oligomer, 0.6 part of Sodium Polyacrylate, 12 parts of acrylic acid, 6 parts of acrylic acid hydroxypropyls, are weighed
Ester, 7 parts of ethyl acrylates, 13 parts of butyl acrylates, 16 parts of isobutyl acrylates, 0.4 part of polyethylene glycol (750) dimethyl allene
Acid esters (Dongguan Yong Zheng Chemical Co., Ltd.s), 15 parts of polyacrylate oligomers, 26 parts of allyloxy hydroxy propylene sodium sulfonates, 18 parts
Polyglycereol, 3 parts of polyacrylamides, 2.4 parts of polyethylene glycol, 40 part of 6% (wt.%) aqueous ammonium chloride solution, 1.1 parts of alkyl iodides
Salt, 1.7 parts of polyterpene resinoids (get Sai Chemical trades Co., Ltd of Jiangyin City, T30), 0.15 part of diethylene glycol diacrylate
Ester, 0.8 part of Vitamin K3,9 parts of aerosils are added in reactor, mixing speed 96r/min, maintenance system temperature
Stirring reaction 0.5h under the conditions of 27 DEG C, through 600W mercury lamp illumination 3s, material is coated in mould release membrance surface, through 2000W mercury lamp light
According to 8s, that is, obtain medical acrylate conducting resinl.
Embodiment 8
A kind of medical acrylate conducting resinl, its preparation method comprise the following steps：
(1) 10 parts of ethyl acrylates, 1.8 parts of n-butyl acrylates, 2.5 parts of Isooctyl acrylate monomers, 1.2 parts of propylene, are weighed
Sour isobutyl ester, 3.5 parts of Hexyl 2-propenoates, 0.08 part of alkyl salt compounded of iodine are added in reactor, mixing speed 100r/min, dimension
Stirring reaction 0.3h under the conditions of 28 DEG C of system temperature is held, through 200W mercury lamp illumination 6s, obtains polyacrylate oligomer；
(2) 10 parts of acrylic acid, 0.06 part of isopropylbenzene cyclopentadienyl iron hexafluorophosphate, 4 parts of hydroxy-ethyl acrylates, 0.9 part of first, are weighed
Base hydroxypropyl acrylate, 0.4 part of PAA, 2.5 parts of hydroxypropyl acrylates are added in reactor, mixing speed 125r/
Min, stirring reaction 0.3h under the conditions of 28 DEG C of maintenance system temperature, through 800W mercury lamp illumination 6s, obtains polyacrylic acid oligomer；
(3), weigh 10 parts of polyacrylic acid oligomer, 0.7 part of Sodium Polyacrylate, 6 parts of acrylic acid, 9 parts of hydroxy-ethyl acrylates,
3 parts of hydroxypropyl acrylates, 6 parts of ethyl acrylates, 23 parts of butyl acrylates, 0.7 part of polyethylene glycol (400) dimethylacrylate
(Dongguan Yong Zheng Chemical Co., Ltd.s), 12 parts of polyacrylate oligomers, 26 parts of kayexalates, 23 parts of polyglycereol, 3 parts
Polyacrylamide, 3.1 parts of polyethylene glycol, 28 part of 10% (wt.%) aqueous ammonium chloride solution, 0.8 part of alkyl salt compounded of iodine, 2.1 parts it is poly-
Terpenoid resin (get Sai Chemical trades Co., Ltd of Jiangyin City, T30), 0.25 part of tetramethylol methane tetraacrylate, 0.9 part of dimension life
Plain K3,14 parts of aerosils are added in reactor, mixing speed 95r/min, under the conditions of 26 DEG C of maintenance system temperature
Stirring reaction 0.7h, through 500W mercury lamp illumination 3s, material is coated in mould release membrance surface, through 2000W mercury lamp illumination 9s, that is, obtained
Medical acrylate conducting resinl.
Reference examples 1
In this reference examples, polyacrylic acid oligomer is not added, and other components and preparation method are same as Example 1.
Reference examples 2
In this reference examples, polyacrylate oligomer is not added, other components and preparation method are same as Example 1.
Reference examples 3
In this reference examples, polyacrylamide is not added, other components and preparation method are same as Example 1.
Reference examples 4
In this reference examples, tackifier is not added, other components and preparation method are same as Example 1.
Reference examples 5
In this reference examples, surfactant is not added, other components and preparation method are same as Example 1.
Reference examples 6
In this reference examples, polyethylene glycol dimethacrylate, other components and preparation method and the phase of embodiment 1 are not added
Together.
Reference examples 7
In this reference examples, water-borne acrylic type monomer is not added, and other components and preparation method are same as Example 1.
Reference examples 8
In this reference examples, oiliness acrylic monomer is not added, and other components and preparation method are same as Example 1.
Reference examples 9
In this reference examples, Sodium Polyacrylate is not added, other components and preparation method are same as Example 1.
The performance of medical acrylate conducting resinl made from embodiment 1~8 and reference examples 1~9 is tested, test side
Method is as follows, and test result sees below Tables 1 and 2.
Tack is tested by GB/T 4852-2002 standards；Viscosity is held to be surveyed by GB/T 2792-2014 standards
Examination；Water-retaining property is tested by NY/T 886-2016 standards；Mould proof property is tested by GB/T 24128-2009 standards；It is raw
Thing compatibility presses ISO10993-10:2010 standards are tested；Electrical property is detected with electrical property test instrument.
The performance parameter of medical acrylate conducting resinl made from the embodiment 1~8 of table 1
The performance parameter of medical acrylate conducting resinl made from the reference examples 1~9 of table 2
Claims (9)
- A kind of 1. medical acrylate conducting resinl, it is characterised in that：Its raw material components includes：10 parts of polyacrylic acid oligomer, gather 0.3~0.9 part of PAA, 12~26 parts of water-borne acrylic type monomer, 18~43 parts of oiliness acrylic monomer, polyethylene glycol 0.1~1 part of dimethylacrylate, 5~18 parts of polyacrylate oligomer, 12~33 parts of surfactant, polyglycereol 11~ 27 parts, 1~6 part of polyacrylamide, 0.5~4 part of polyethylene glycol, 17~47 parts of salting liquid, 0.4~1.5 part of light trigger, increasing stick 2~16 parts of 0.4~3 part of agent, 0.05~0.3 part of crosslinking agent, 0.1~2 part of Vitamin K3 and aerosil, the number For mass fraction；Polyacrylic acid oligomer is 10 by mass ratio：(0.03~0.1)：(1~7)：(0.2~1.3)：(0.1~0.6)：(1.2 ~3.2) acrylic acid, light trigger, hydroxy-ethyl acrylate, hydroxy propyl methacrylate, PAA and hydroxypropyl acrylate Reaction is made,Polyacrylate oligomer is 10 by mass ratio：0.5~3：1~5：0.8~2：2~6：0.04~0.09 acrylic acid second Ester, n-butyl acrylate, Isooctyl acrylate monomer, isobutyl acrylate, Hexyl 2-propenoate and light trigger reaction are made.
- 2. medical acrylate conducting resinl according to claim 1, it is characterised in that：Water-borne acrylic type monomer is propylene At least one of acid, hydroxy-ethyl acrylate or hydroxypropyl acrylate；Oiliness acrylic monomer is ethyl acrylate, acrylic acid At least one of butyl ester, isobutyl acrylate, Isooctyl acrylate monomer, Hexyl 2-propenoate or propyl acrylate.
- 3. medical acrylate conducting resinl according to claim 1 or claim 2, it is characterised in that：Glycol dimethacrylates The molecular weight of polyethylene glycol is 400~1000 in ester；Tackifier is rosin resinoid, polyterpene resinoid, gum dammar, oil At least one of resin or coumarone-indene resin.
- 4. medical acrylate conducting resinl according to claim 1 or claim 2, it is characterised in that：Crosslinking agent is the hydroxyl first of ethoxyquin three Base propane triacrylate, ethoxyquin tetramethylol methane tetraacrylate, diethylene glycol diacrylate or pentaerythrite tetrapropylene At least one of acid esters.
- 5. medical acrylate conducting resinl according to claim 1 or claim 2, it is characterised in that：Light trigger is 1- hydroxy cyclohexylphenyls Base phenyl ketone, double (2,4,6- trimethylbenzoyls)-phenyl phosphine oxides, benzoin dimethylether, diaryl group iodized salt, three virtues At least one of base salt compounded of iodine, alkyl salt compounded of iodine or isopropylbenzene cyclopentadienyl iron hexafluorophosphate.
- 6. medical acrylate conducting resinl according to claim 1 or claim 2, it is characterised in that：Salting liquid be potassium chloride solution, At least one of sodium-chloride water solution or aqueous ammonium chloride solution, the mass concentration of salting liquid is 5-10%wt；Surfactant For in allyloxy hydroxy propylene sodium sulfonate, moist type non-ionic reaction emulsifying agent SM-JR-3 or kayexalate extremely Few one kind.
- 7. the preparation method of the medical acrylate conducting resinl described in claim 1-6 any one, it is characterised in that：By poly- third Olefin(e) acid oligomer, Sodium Polyacrylate, water-borne acrylic type monomer, oiliness acrylic monomer, glycol dimethacrylates Ester, polyacrylate oligomer, surfactant, polyglycereol, polyacrylamide, polyethylene glycol, salting liquid, light trigger, increasing Glutinous agent, crosslinking agent, Vitamin K3 and aerosil, low whipping speed is 80~100r/min, temperature is 25~30 DEG C Under the conditions of, 0.2~0.8h is reacted, then through 400~1000W mercury lamp 1~6s of illumination, resulting material is coated in mould release membrance table Face, through 1000~3000W mercury lamp 3~20s of illumination, that is, obtain medical acrylate conducting resinl.
- 8. the preparation method of medical acrylate conducting resinl according to claim 7, it is characterised in that：Polyacrylate is low The preparation method of polymers is：By ethyl acrylate, n-butyl acrylate, Isooctyl acrylate monomer, isobutyl acrylate, acrylic acid oneself Ester and light trigger, under conditions of low whipping speed is 90~120r/min, temperature is 25~30 DEG C, 0.1~0.5h is reacted, so By 100~1000W mercury lamp 1~8s of illumination, polyacrylate oligomer is produced.
- 9. the preparation method of the medical acrylate conducting resinl according to claim 7 or 8, it is characterised in that：Polyacrylic acid The preparation method of oligomer is：By acrylic acid, light trigger, hydroxy-ethyl acrylate, hydroxy propyl methacrylate, PAA and Hydroxypropyl acrylate, under the conditions of low whipping speed is 100~130r/min, temperature is 25~30 DEG C, 0.1~0.5h is reacted, so By 400~1000W mercury lamp 2~12s of illumination, polyacrylic acid oligomer is produced.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107955549A (en) * | 2017-11-29 | 2018-04-24 | 广西众昌树脂有限公司 | Medical pressure sensitive adhesive |
| CN109233733A (en) * | 2018-07-03 | 2019-01-18 | 南宁珀源能源材料有限公司 | The one-component boiling glue and preparation method thereof of easy boiling degumming |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1158745A (en) * | 1997-03-18 | 1997-09-10 | 浙江大学 | Production process of medical pressure-sensing conducting resin |
| CN1192352A (en) * | 1998-03-06 | 1998-09-09 | 周永强 | Disposable ECG electrode with pre-placed electric conduction paste and prepn. technology thereof |
| CN101238189A (en) * | 2005-08-04 | 2008-08-06 | 3M创新有限公司 | Conductive adhesives and biomedical articles including same |
| EP1760133B1 (en) * | 2004-05-19 | 2011-09-28 | Bridgestone Corporation | Adhesive agent composition and adhesive film for electronic component |
| CN102898970A (en) * | 2012-11-02 | 2013-01-30 | 绍兴振德医用敷料有限公司 | Method for preparing ultraviolet light polymerization environment-friendly antibacterial acrylic ester medical pressure sensitive adhesive product |
| CN105219317A (en) * | 2015-11-12 | 2016-01-06 | 四川厚生天佐药业有限公司 | A kind of medical polyacrylate pressure-sensitive adhesive of environmental protection sticks agent |
-
2017
- 2017-07-18 CN CN201710585080.5A patent/CN107400464A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1158745A (en) * | 1997-03-18 | 1997-09-10 | 浙江大学 | Production process of medical pressure-sensing conducting resin |
| CN1192352A (en) * | 1998-03-06 | 1998-09-09 | 周永强 | Disposable ECG electrode with pre-placed electric conduction paste and prepn. technology thereof |
| EP1760133B1 (en) * | 2004-05-19 | 2011-09-28 | Bridgestone Corporation | Adhesive agent composition and adhesive film for electronic component |
| CN101238189A (en) * | 2005-08-04 | 2008-08-06 | 3M创新有限公司 | Conductive adhesives and biomedical articles including same |
| CN102898970A (en) * | 2012-11-02 | 2013-01-30 | 绍兴振德医用敷料有限公司 | Method for preparing ultraviolet light polymerization environment-friendly antibacterial acrylic ester medical pressure sensitive adhesive product |
| CN105219317A (en) * | 2015-11-12 | 2016-01-06 | 四川厚生天佐药业有限公司 | A kind of medical polyacrylate pressure-sensitive adhesive of environmental protection sticks agent |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107955549A (en) * | 2017-11-29 | 2018-04-24 | 广西众昌树脂有限公司 | Medical pressure sensitive adhesive |
| CN109233733A (en) * | 2018-07-03 | 2019-01-18 | 南宁珀源能源材料有限公司 | The one-component boiling glue and preparation method thereof of easy boiling degumming |
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