CN107399940A - A kind of baking-free lightweight insulating brick and preparation method thereof - Google Patents

A kind of baking-free lightweight insulating brick and preparation method thereof Download PDF

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Publication number
CN107399940A
CN107399940A CN201610331129.XA CN201610331129A CN107399940A CN 107399940 A CN107399940 A CN 107399940A CN 201610331129 A CN201610331129 A CN 201610331129A CN 107399940 A CN107399940 A CN 107399940A
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CN
China
Prior art keywords
baking
insulating brick
waste material
cement
mineral wool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610331129.XA
Other languages
Chinese (zh)
Inventor
马光宇
王向锋
徐鹏飞
刘常鹏
王忠润
李卫东
张天赋
孙守斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Angang Steel Co Ltd
Original Assignee
Angang Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Angang Steel Co Ltd filed Critical Angang Steel Co Ltd
Priority to CN201610331129.XA priority Critical patent/CN107399940A/en
Publication of CN107399940A publication Critical patent/CN107399940A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses a kind of baking-free lightweight insulating brick and preparation method thereof, insulating brick includes the mineral wool waste material that mass percent is 30~70%, 10~35% cement, 0~22% flyash, 5~10% water.Preparation method includes:Dispensing, prepare mineral wool waste material, cement, flyash, water in proportion;Stirring, is first put into mineral wool waste material and cement, flyash, is then proportionally added into water and is stirred 10~20min and obtains compound;Base, compound is obtained into adobe through vibrating forming;Maintenance, baking-free lightweight insulating brick is obtained after the maintenance of adobe normal temperature.Mineral wool can be produced waste material and chopped fiber and be made non-burning brick by the present invention, and small investment, technique is simple, and unit weight is small, good heat insulating, and sound absorption properties good, production cost is low.

Description

A kind of baking-free lightweight insulating brick and preparation method thereof
Technical field
It is especially a kind of to prepare baking-free lightweight guarantor with mineral wool slag ball the present invention relates to a kind of construction material and preparation method thereof Warm brick and preparation method thereof.
Background technology
Molten blast furnace slag is one of principal by product of blast furnace, while is also the chief component of steel factory waste residue.It is logical Often, molten blast furnace slag per ton contains (126~188) × 104KJ sensible heat, equivalent to the energy of 30~40kg heavy oil, Er Qieqi With higher temperature, about 1450~1600 DEG C, belong to the residual heat resources of high-quality, there is very high recycling to be worth.Return It will be that enterprise reduces production cost to receive this part sensible heat, create economic benefit.
At present, domestic and international blast furnace cinder is more based on water quenching, although there is minor heat can be by the form of remaining hot water Reclaimed, but most of energy can not all realize recovery, cause huge energy waste.It is and molten state blast furnace slag is directly raw It is that an extraordinary blast furnace cinder comprehensively utilizes mode to produce as high value added products such as mineral wools, and it can not only realize blast furnace slag height The direct utilization of quality waste heat, and the high added value comprehensive utilization of blast furnace slag can be realized, it is China's smelter in recent years One important development focus.However, blast furnace slag production mineral wool product will necessarily generating unit be divided into fine poor chopped fiber flying chip, Contaminated fiber flying chip etc. near fiber powder and production line including dust pelletizing system recovery, also have in addition not into the slag ball of fibre Deng, because it is inorganic lightweight material, pack compression difficult, transport difficult, stockpiling or landfill after be difficult in natural environment Resolution, causes obvious secondary pollution.And rejoin mineral cotton smelter not only operation difficulty is big, and significantly affect mineral wool production Efficiency and product quality, processing cost substantially increase.Therefore, the processing of mineral wool production discarded object is as the great of mineral wool industry Problem.Because mineral wool fiber has the characteristics that anti-corrosion, insulation, tensile strength are high, if insulating brick raw material will be used as not only to disappear A large amount of mineral wools of receiving produce accessory substances, and can realize the harmless treatment of mineral wool waste material, and economic benefit is obvious.
The Patents of insulating brick are prepared with mineral wool fiber flying chip both at home and abroad and document is not found, it is discarded with blast furnace slag etc. Thing prepares the related patent of insulating brick and document is relatively more, as Chinese Patent Application No. is 201210542011.3, entitled《One Kind Superfine slag powder baking-free brick and its production method》Patent of invention, its main contents is:It include mass percent be 15~ 25% slag micropowder, 35~45% slag, 8~15% flyash, 20~25% lime stone, 10~15% water, Each ingredient percent sum is not more than 100%.Described production method includes dispensing, stirring, base, maintenance process.Should Cement during invention replaces tradition non-burning brick using slag micropowder is used as cementing agent, reduces non-burning brick production cost, and slag adds The features such as entering to reduce the use of the non-burning brick aggregate of tradition.And for example Chinese Patent Application No. be 200810014015.8, it is entitled《One Kind steel scoria unburned brick》Patent of invention, its main contents is:Its raw material includes Steel-slag Sand, steel-making slag powder, blast furnace slag, lime.System Making the method for the steel scoria unburned brick is, adds water to stir load weighted raw material, compressing to brick machine, then through maintenance, Finished product steel scoria unburned brick is obtained after ageing.Both the above is non-burning brick to have the problems such as big unit weight, poor thermal insulation property, it is difficult to is building Thing agent structure is built as building main material by laying bricks or stones to use, hence it is evident that limit the application of product, economic benefit is poor.
In a word, in the prior art mineral wool fiber prepare baking-free lightweight insulating brick correlation technique it is less, and in the prior art The problems such as big unit weight, poor thermal insulation property, high production cost be present in insulating brick.
The content of the invention
The present invention provides a kind of baking-free lightweight insulating brick and preparation method thereof, overcomes the shortcomings of the prior art, can incite somebody to action Mineral wool produces waste material and chopped fiber and is made non-burning brick, and small investment, technique is simple, and unit weight is small, good heat insulating, sound absorption properties good, raw It is low to produce cost.
In order to solve the above problems, the present invention uses following technical scheme:
A kind of baking-free lightweight insulating brick, it includes the mineral wool waste material that mass percent is 30~70%, 10~35% water Mud, 0~22% flyash, 5~10% water.
The mineral wool waste material is slag wool fiber or rock wool fibers containing certain slag ball, its shot content >=50%.
The mineral wool waste material is by broken, fibre length≤15mm, slag spherolite footpath≤3mm.
The cement is 32.5 grades of portland slag cements.
The flyash sieves by removal of impurities, to ensure that wherein the debris such as comprising metal wire, grass roots, granularity are not below 1mm.
A kind of preparation method of baking-free lightweight insulating brick, including dispensing, stirring, base, maintenance process, are specifically included:
Dispensing, prepare mineral wool waste material, cement, flyash, water in proportion;
Stirring, is first put into mineral wool waste material and cement, flyash, is then proportionally added into water and is stirred 10~20min and obtains To compound;
Base, compound is obtained into adobe through vibrating forming;
Maintenance, baking-free lightweight insulating brick is obtained after the maintenance of adobe normal temperature.
During natural curing, fetch water 3~5 times, maintenance can dispatch from the factory for 5~18 days.
The thermal conductivity factor of the insulating brick is 0.050~0.070W/mK.
The acoustic absorptivity of the insulating brick is 2.10~2.50.
The unit weight of the insulating brick is 850~1150g/cm3
The present invention has the advantages that compared with prior art:First, realize mineral wool waste residue, the innoxious of fiber of giving up Processing, solves the problems, such as the secondary pollution of mineral wool waste material;Second, the insulating brick technique that mineral wool waste residue, useless fiber are produced is simple, throw Money is few, and cost is low, and application is wide;Third, the good heat insulating of insulating brick, sound absorption properties good, unit weight is small, service life length etc.. Therefore, the present invention has obvious economic benefit and environmental benefit, and in industry slag directly produces mineral wool product and uses field There are obvious economic benefit and popularizing value.
Embodiment
Embodiment 1
A kind of baking-free lightweight insulating brick, it include mass percent be 65% mineral wool waste material (including 35% slag Ball, 30% slag wool fiber), 15% portland slag cement, 14% flyash, 6% water.The mineral wool waste material warp Cross broken, average fiber length 14mm, slag spherolite footpath 3mm.The cement is 32.5 grades of portland slag cements.The flyash Raw material passes through impurity removal process, and granularity is 100 μm.
The preparation method of insulating brick includes dispensing, stirring, base, maintenance process, specifically includes:1) dispensing, it is accurate in proportion Standby mineral wool waste material, cement, flyash, water;2) stir, be first put into mineral wool waste material and cement, flyash, then add in proportion Enter water and be stirred 14min to obtain compound;3) base, compound is obtained into adobe through vibrating forming;4) conserve, adobe normal temperature Baking-free lightweight insulating brick is obtained after maintenance.
During natural curing, fetch water 4 times, maintenance can obtain finished product in 12 days.
After testing, the performance of the insulating brick is as follows:
Embodiment 2
A kind of baking-free lightweight insulating brick, it include mass percent be 55% mineral wool waste material (include 32% slag ball, 23% slag wool fiber), 15.5% portland slag cement, 20% flyash, 9.5% water.The mineral wool waste material By broken, average fiber length 12mm, slag spherolite footpath 2.8mm.The cement is 32.5 grades of portland slag cements.The powder Coal ash raw material passes through impurity removal process, and granularity is 80 μm.
The preparation method of insulating brick includes dispensing, stirring, base, maintenance process, specifically includes:1) dispensing, it is accurate in proportion Standby mineral wool waste, cement, flyash, water;2) stir, be first put into mineral wool waste material and cement, flyash, then press than Example addition water is stirred 15min and obtains compound;3) base, compound is obtained into adobe through vibrating forming;4) conserve, adobe Baking-free lightweight insulating brick is obtained after normal temperature maintenance.
During natural curing, fetch water 5 times, maintenance can obtain finished product in 14 days.
After testing, the performance of the insulating brick is as follows:
Embodiment 3
A kind of baking-free lightweight insulating brick, it include mass percent be 59% mineral wool waste material (include 34% slag ball, 25% rock wool fibers), 16.2% portland slag cement, 15% flyash, 9.8% water.The rock wool waste material warp Cross broken, average fiber length 11.5mm, slag spherolite footpath 2.6mm.The cement is 32.5 grades of portland slag cements.The powder Coal ash raw material passes through impurity removal process, and granularity is 75 μm.
The preparation method of insulating brick includes dispensing, stirring, base, maintenance process, specifically includes:1) dispensing, it is accurate in proportion Standby rock wool waste material, cement, flyash, water;2) stir, be first put into rock wool waste material and cement, flyash, be then proportionally added into water It is stirred 18min and obtains compound;3) base, compound is obtained into adobe through vibrating forming;4) conserve, the maintenance of adobe normal temperature After obtain baking-free lightweight insulating brick.
During natural curing, fetch water 5 times, maintenance can obtain finished product in 15 days.
After testing, the performance of the insulating brick is as follows:
Embodiment 4
A kind of baking-free lightweight insulating brick, it include mass percent be 52% mineral wool waste material (include 31% slag ball, 21% rock wool fibers), 20.6% portland slag cement, 18% flyash, 9.4% water.The rock wool waste material warp Cross broken, average fiber length 11.9mm, slag spherolite footpath 2.0mm.The cement is 32.5 grades of portland slag cements.The powder Coal ash raw material passes through impurity removal process, and granularity is 79 μm.
The preparation method of insulating brick includes dispensing, stirring, base, maintenance process, specifically includes:1) dispensing, it is accurate in proportion Standby rock wool waste material, cement, flyash, water;2) stir, be first put into rock wool waste material and cement, flyash, be then proportionally added into water It is stirred 19min and obtains compound;3) base, compound is obtained into adobe through vibrating forming;4) conserve, the maintenance of adobe normal temperature After obtain baking-free lightweight insulating brick.
During natural curing, fetch water 4 times, maintenance can obtain finished product in 16 days.
After testing, the performance of the insulating brick is as follows:
Embodiment 5
A kind of baking-free lightweight insulating brick, it include mass percent be 55% mineral wool waste material (include 33% slag ball, 22% rock wool fibers), 35% portland slag cement, 10% water.For the rock wool waste material by broken, fiber is averagely long Spend 11.5mm, slag spherolite footpath 2.6mm.The cement is 32.5 grades of portland slag cements.The powdered coal ash is by removal of impurities Technique, granularity are 77 μm.
The preparation method of insulating brick includes dispensing, stirring, base, maintenance process, specifically includes:1) dispensing, it is accurate in proportion Standby rock wool waste material, cement, water;2) stir, be first put into rock wool waste material and cement, be then proportionally added into water and be stirred 20min Obtain compound;3) base, compound is obtained into adobe through vibrating forming;4) conserve, obtained after the maintenance of adobe normal temperature unburned light Vacuum brick.
During natural curing, fetch water 5 times, maintenance can obtain finished product in 15 days.
After testing, the performance of the insulating brick is as follows:

Claims (7)

  1. A kind of 1. baking-free lightweight insulating brick, it is characterised in that including mass percent be 30~70% mineral wool waste material, 10~ 35% cement, 0~22% flyash, 5~10% water.
  2. 2. baking-free lightweight insulating brick according to claim 1, it is characterised in that the mineral wool waste material is to contain certain slag ball Slag wool fiber or rock wool fibers, its shot content >=50%.
  3. 3. baking-free lightweight insulating brick according to claim 1, it is characterised in that the mineral wool waste material is by broken, fiber length Degree≤15mm, slag spherolite footpath≤3mm.
  4. 4. baking-free lightweight insulating brick according to claim 1, it is characterised in that the cement is 32.5 grades of slag portlands Cement.
  5. 5. baking-free lightweight insulating brick according to claim 1, it is characterised in that the flyash sieves by removal of impurities, to protect Wherein comprising metal wire, grass roots debris, granularity are not below 1mm to card.
  6. A kind of 6. preparation method of baking-free lightweight insulating brick for described in any one of Claims 1 to 5, it is characterised in that including Dispensing, stirring, base, maintenance process, it is specially:
    Dispensing, prepare mineral wool waste material, cement, flyash, water in proportion;
    Stirring, is first put into mineral wool waste material and cement, flyash, is then proportionally added into water and is stirred 10~20min and is mixed Close material;
    Base, compound is obtained into adobe through vibrating forming;
    Maintenance, baking-free lightweight insulating brick is obtained after the maintenance of adobe normal temperature.
  7. 7. the preparation method of baking-free lightweight insulating brick according to claim 6, it is characterised in that during natural curing, Fetch water 3~5 times, maintenance can dispatch from the factory for 5~18 days.
CN201610331129.XA 2016-05-18 2016-05-18 A kind of baking-free lightweight insulating brick and preparation method thereof Pending CN107399940A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108341678A (en) * 2018-03-04 2018-07-31 李嘉顺 A kind of low cost Green environmental-protection building light cellular partition board and preparation method thereof
CN110092628A (en) * 2018-01-27 2019-08-06 山东华美建材有限公司 A kind of environment-friendly composite material wall body brick and preparation method thereof
CN112225508A (en) * 2020-10-20 2021-01-15 上海握算实业有限公司 Rock wool waste regenerated cement foam board and preparation method thereof
CN112876150A (en) * 2021-03-01 2021-06-01 广东前景建筑科技有限公司 Fire-resistant heat-insulation ceramsite brick and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101857400A (en) * 2010-04-22 2010-10-13 连来才 Lightweight insulating brick and production process thereof
CN103043977A (en) * 2012-12-14 2013-04-17 昆明钢铁控股有限公司 Superfine slag powder baking-free brick and production method thereof
CN103232201A (en) * 2013-05-10 2013-08-07 高修增 Baking-free brick for buildings

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101857400A (en) * 2010-04-22 2010-10-13 连来才 Lightweight insulating brick and production process thereof
CN103043977A (en) * 2012-12-14 2013-04-17 昆明钢铁控股有限公司 Superfine slag powder baking-free brick and production method thereof
CN103232201A (en) * 2013-05-10 2013-08-07 高修增 Baking-free brick for buildings

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110092628A (en) * 2018-01-27 2019-08-06 山东华美建材有限公司 A kind of environment-friendly composite material wall body brick and preparation method thereof
CN108341678A (en) * 2018-03-04 2018-07-31 李嘉顺 A kind of low cost Green environmental-protection building light cellular partition board and preparation method thereof
CN112225508A (en) * 2020-10-20 2021-01-15 上海握算实业有限公司 Rock wool waste regenerated cement foam board and preparation method thereof
CN112876150A (en) * 2021-03-01 2021-06-01 广东前景建筑科技有限公司 Fire-resistant heat-insulation ceramsite brick and preparation process thereof

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