CN107399787A - A kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium - Google Patents
A kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium Download PDFInfo
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- CN107399787A CN107399787A CN201710793437.9A CN201710793437A CN107399787A CN 107399787 A CN107399787 A CN 107399787A CN 201710793437 A CN201710793437 A CN 201710793437A CN 107399787 A CN107399787 A CN 107399787A
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- Prior art keywords
- settling tank
- tank
- magnetic valve
- adsorption tank
- jute
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/286—Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/22—Chromium or chromium compounds, e.g. chromates
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention discloses a kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium, including adsorption tank, settling tank, store up slag bath and clear water reserviors, adsorption tank, settling tank and clear water reserviors are provided with liquid level gauge, and adsorption tank, settling tank and clear water reserviors are sequentially connected by pipeline, and magnetic valve and water pump are respectively equipped with pipeline.The upper end of adsorption tank is provided with acid-base accommodation room and jute powder room, and inside is provided with agitator, and side wall is provided with pH on-line detectors.The bottom of cylindrical settling tank is additionally provided with turbination screen pack.Storage slag bath positioned at settling tank lower end connects with settling tank filtering net lower openings.Clear water reserviors are provided with online chromium detector.Microcomputer control system connection magnetic valve, water pump, agitator, pH on-line detectors and online chromium detector, and control magnetic valve, water pump and agitator work.The present apparatus has that treatment effeciency is high, can continuous production, automaticity is high and advantages of simple structure and simple, is adapted to large-scale promotion application.
Description
(1) technical field
The present invention relates to field of waste water treatment, more particularly to a kind of wastewater treatment using jute powder adsorbing hexavalent chromium to fill
Put.
(2) background technology
Chromyl waste water is mainly derived from the productions such as metallurgy, intermetallic composite coating, plating, paint, printing and dyeing and chromate production
Industry, Cr VI can enter human body by food, and be enriched with vivo, and enrichment to a certain extent, can cause Itai-itai diseases, heredity base
Because of defect and cancer etc., thus Cr VI has been listed in one of 8 kinds of maximum chemical substances of harm to the human body, while is also state
One of 3 kinds of generally acknowledged carcinogenic metal objects of border, thus the Cr VI in waste water have to pass through processing it is up to standard after can discharge.
At present, the conventional processing method of Cr VI mainly has coagulant sedimentation, ion-exchange and electroosmose process in waste water
Deng.Coagulant sedimentation technical maturity, application time length, but treatment effeciency is low, and easily trigger secondary pollution;At ion-exchange
Positive effect, but complex process are managed, ion exchange resin price is high, causes cost height;Electroosmose process needs to consume big energy
And dialyser, cost are higher.
Jute be Tiliaceae Corchorus annual herb plant, be that quantity is enriched, it is cheap, wide material sources can be again
Production-goods source.The blade of long fruit jute and it is tender slightly on histocyte in rich in the polysaccharose substance such as pectin, these polysaccharose substances
In rich in-OH and-NH2Deng group, under certain pH, there is very strong chelation to Cr VI, be a kind of natural chela
Mixture.
However, the existing device that heavy metal in waste water is adsorbed using jute, if Jiang Ping is in Publication No.
A kind of water treatment facilities that heavy metal lead is adsorbed using tossa disclosed in CN203513320U, has automaticity
Low, labor intensity is big, can not continuous production, the processing time length shortcoming such as low with treatment effeciency, be not suitable for large-scale promotion application.
(3) content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium,
The device can utilize the Cr VI in cheap jute powder efficient absorption waste water, have simple in construction, automaticity height,
The advantages that treatment effeciency is high, continuous production, and investment is small and easy to use.
The technical scheme is that:
A kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium, it is characterised in that including adsorption tank, settling tank,
Slag bath and clear water reserviors are stored up, the adsorption tank, is sequentially connected by pipeline between settling tank and clear water reserviors, is respectively provided with the pipeline
There are magnetic valve and water pump.So, using magnetic valve and water pump, waste water can by the pipeline successively adsorbing hexavalent chromium in adsorption tank,
Settled in settling tank, then it is filtered after, water after processing reaches clear water reserviors.
The upper portion side wall and lower sides of the adsorption tank, settling tank and clear water reserviors are respectively arranged with liquid level gauge.So, when
When liquid level reaches the liquid level gauge of upper portion side wall, inlet pipeline charging pump is stopped, when liquid level reaches the liquid level gauge of lower sides
When, the water pump on outlet conduit is stopped, and then liquid level in control container.
Adsorbent is jute powder in the adsorption tank, and the upper end of the adsorption tank is provided with acid-base accommodation room and jute powder
Room, the acid-base accommodation room and jute powder room are connected by straight pipeline with the adsorption tank respectively, are set on the straight pipeline
Magnetic valve is equipped with, the side wall of the adsorption tank is additionally provided with pH on-line detectors.So, pH value in adsorption tank can be monitored in real time,
And the pH value in room and solenoid valve control adsorption tank is reconciled by soda acid, reaction is carried out under more excellent environment.
The adsorption tank is internally provided with agitator.So, the Cr VI in jute powder and waste water can be contacted more fully,
Be advantageous to improve adsorption efficiency, reduce adsorption time.
The settling tank is cylinder, and the bottom of the settling tank is additionally provided with screen pack, and the screen pack is in inverted cone
Shape, the top of the screen pack and the side wall sealing of the settling tank are fixed, and opening, the sedimentation are arranged at the bottom of the screen pack
The bottom surface in pond it is corresponding be provided with opening, the bottom of the screen pack and the bottom surface of the settling tank seal in opening
Fixed, the delivery port of the settling tank is located under screen pack.So, cylindrical settling tank can avoid producing sedimentation dead angle,
When the pump working on settling tank outlet conduit, the jute powder of adsorbing hexavalent chromium is deposited on screen pack, the water after processing from
Screen pack mesopore is flowed through, and clear water reserviors are reached through water pump.
It is described heavy by being arranged at that the storage slag bath is located at the lower end of the settling tank, the storage slag bath and the settling tank
The straight pipeline connection of pond bottom surface opening is dropped, magnetic valve is provided with the straight pipeline.So, when magnetic valve is opened
When, the jute powder for being deposited on adsorbing hexavalent chromium on turbination screen pack enters storage slag bath under gravity.Store up slag bath
It can be connected with vavuum pump, promote jute powder to enter storage slag bath.
Online chromium detector is provided with the clear water reserviors.So, can be after the processing of monitoring in real time in water in line chromium detector
Content of 6-valence Cr ions.
The clear water reserviors are connected with the adsorption tank by pipeline, and magnetic valve and water pump are provided with the pipeline.So,
When the chromium content that online chromium detector detects is not up to standard, water in clear water reserviors is reflowable to be carried out at absorption again to adsorption tank
Reason.
The magnetic valve, water pump, agitator, liquid level gauge, pH on-line detectors and online chromium detector are and microcomputer
Control system is connected, and the magnetic valve, water pump and agitator are controlled by the microcomputer control system.So, can lead to
Microcomputer control system control magnetic valve, water pump and agitator are crossed, realizes the switch of magnetic valve, water pump and agitator, and then
Automatic progress pH regulations, automatic stirring, automatic feeding water and water outlet are realized, automatic cleaning deposition chromium slag enters storage slag bath etc. and operated,
Automaticity improves, and reduces labor intensity, and realize continuous production.
The jute powder is crushed after drying and is made for the blade and tender tip of long fruit jute.So, obtained jute powder is inhaled
Attached more efficient, adsorption effect is more preferable.
Screen pipe is provided with the inlet pipeline of the adsorption tank.So, when agitator stirs in adsorption tank, can avoid
Jute powder in adsorption tank is lost in, and ensures higher adsorption efficiency and adsorption effect.
The pH value of the adsorption tank is 5-7.So, be advantageous to the Cr VI in jute powder absorption waste water, improve absorption effect
Rate and adsorption effect.
The adsorption time of the adsorption tank is 25-35 minutes.So, jute powder has in more sufficient time absorption waste water
Cr VI, ensure adsorption effect.
The sedimentation time of the settling tank is 15-25 minutes.So, on the one hand to be adsorbed with the jute powder of Cr VI by
Gradually it is deposited in settling tank on the screen pack of turbination, on the other hand jute powder can be made further to adsorb the sexavalence in waste water
Chromium, further improve adsorption effect.
Compared to prior art, the advantages and positive effects of the present invention are:Battery valve, water pump, agitator, pH are examined online
Survey instrument and online chromium detector is connected with microcomputer control system, and magnetic valve, water pump and agitator are by microcomputer control
System control processed, automaticity is high, and labor intensity is low, easy to use;In wastewater treatment process, without shutting down, the company of can be achieved
Continuous production, improves treatment effeciency;The pH value of adsorption tank is automatically adjusted, improves treatment effeciency and effect;With online chromium detector,
Chromium concn in monitoring water in real time, ensures that the water chromium concn of discharge is up to standard;Adsorbent is made using cheap jute powder, improves jute
Added value, be adapted to large-scale promotion.
(4) illustrate
Fig. 1 is the structural representation of wastewater treatment equipment provided by the invention.
In figure:1- adsorption tanks, 11- acid-base accommodations room, 12- jute powder room, 13- screen pipes, 14-pH on-line detectors, 15-
Agitator, 2- settling tanks, 21- screen packs, 3- storage slag baths, 4- clear water reserviors, the online chromium detectors of 41-, 51- water pumps one, 52- water pumps
Two, 53- water pump three, 54- water pumps four, 55- water pumps five, 61- magnetic valves one, 62- magnetic valves two, 63- magnetic valves three, 64- electromagnetism
Valve four, 65- magnetic valves five, 66- magnetic valves six, 67- magnetic valves seven, 68- magnetic valves eight, 71- liquid level gauges one, 72- liquid level gauges two,
73- liquid level gauges three, 74- liquid level gauges four, 75- liquid level gauges five, 76- liquid level gauges six.
(5) embodiment
The present invention is described in further detail below in conjunction with the accompanying drawings.
As described in Figure 1, the present invention provides a kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium, including adsorption tank
1, settling tank 2, slag bath 3 and clear water reserviors 4 are stored up, water pump 1 and magnetic valve 1 are disposed with the inlet channel of adsorption tank 1,
Screen pipe 13 is additionally provided with the inlet channel of adsorption tank 1, the upper end of adsorption tank 1 is respectively arranged with acid-base accommodation room 11 and jute
Powder room 12, acid-base accommodation room 11 and jute powder room 12 are connected by straight pipeline with adsorption tank 1 respectively, are set respectively on straight pipeline
Magnetic valve 6 66 and magnetic valve 7 67 are equipped with, for controlling acid-base modifier and adsorbent jute powder to add adsorption tank 1 respectively, is inhaled
Agitator 15 is additionally provided with inside attached pond 1, the upper portion side wall and lower sides of adsorption tank 1 are respectively arranged with liquid level gauge 1 and liquid
Position meter 2 72, for controlling liquid level in adsorption tank, the side wall of adsorption tank 1 is additionally provided with pH on-line detectors 14.
Adsorption tank 1 is connected with settling tank 2 by pipeline, and magnetic valve 2 62 and water pump 2 52 are disposed with pipeline.It is heavy
The upper portion side wall and lower sides for dropping pond 2 are respectively arranged with liquid level gauge 3 73 and liquid level gauge 4 74, for liquid in control settlement pond
Position height.Settling tank 2 is cylinder, and the bottom of settling tank 2 is additionally provided with screen pack 21, and screen pack 21 is in turbination, filtering
The top of net 21 and the side wall sealing of settling tank 2 are fixed, and opening arranged at the bottom of screen pack 21, and the bottom surface of settling tank 2 is corresponding
Be provided with opening, the bottom of screen pack 21 seals in opening with the bottom surface of settling tank 2 and fixed.Slag bath 3 is stored up positioned at sedimentation
The lower end in pond 2, storage slag bath 3 are connected with settling tank 2 by being arranged at the straight pipeline of the bottom surface opening of settling tank 2, described straight
Magnetic valve 8 68 is provided with shape pipeline.
Settling tank 2 is connected with clear water reserviors 4 by pipeline, and magnetic valve 3 63 and water pump three are disposed with the pipeline
53.The upper portion side wall and lower sides of clear water reserviors 4 are respectively arranged with liquid level gauge 5 75 and liquid level gauge 6 76.The side wall of clear water reserviors 4
Online chromium detector 41 is provided with, for monitoring the concentration of Cr VI in clear water reserviors in real time.Clear water reserviors 4 and adsorption tank 1 pass through pipe
Road is connected, and water pump 4 54 and magnetic valve 4 64 are provided with the pipeline.Water pump five is additionally provided with the outlet conduit of clear water reserviors 4
55 and magnetic valve 5 65.
Above-mentioned liquid level gauge 1 is to liquid level gauge 6 76, and pH on-line detectors 14 and online chromium detector 41 are and microcomputer
Control system (not shown) connects, magnetic valve 1 to magnetic valve 8 68, water pump 1 to water pump 5 55, and agitator 15 is equal
It is connected with microcomputer control system, and is controlled by microcomputer control system.
Sorbent used jute powder is crushed after drying and is made for the blade and tender tip of long fruit jute in the present embodiment.
A kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium provided by the invention, before startup, all magnetic valves,
Water pump and agitator are in off working state.After wastewater treatment equipment starts, magnetic valve 1 is opened, and water pump 1 works,
Waste water enters adsorption tank 1 by chimney filter 13, and when liquid level reaches liquid level gauge 1, magnetic valve 1 is closed, and water pump 1 stops
Work, agitator 15 are started working, and magnetic valve 7 67 is opened, and adsorbent jute powder enters adsorption tank 1, close magnetic valve 7 67,
PH on-line detectors 14 detect wastewater pH, and send numerical value to microcomputer control system, microcomputer control system control
Magnetic valve 6 66 opens or closes, and it is 5 to keep wastewater pH in adsorption tank 1.Stirring and adsorbing time of the jute powder in adsorption tank 1 is
30 minutes.After arrival time, magnetic valve 2 62 is opened, and water pump 2 52 works, the powder of jute containing adsorbing hexavalent chromium in adsorption tank 1
Waste water enters settling tank 2, when liquid level reaches liquid level arrival liquid level gauge 3 73 in liquid level gauge 2 72 or settling tank in adsorption tank, electricity
Magnet valve 2 62 is closed, and water pump 2 52 and agitator 15 are stopped, and the waste water of the powder of jute containing adsorbing hexavalent chromium sinks in settling tank 2
Drop 20 minutes.At the same time, waste water and jute powder can be entered back into adsorption tank 1, is stirred absorption, realizes continuous production.When
In settling tank 2 after sedimentation time arrival, magnetic valve 3 63 is opened, and water pump 3 53 works, the jute powder deposition of adsorbing hexavalent chromium
On screen pack 21, the water after processing, through the hole of screen pack 21, clear water reserviors 4 are reached through magnetic valve 3 63 and water pump 3 53.
When liquid level reaches liquid level arrival liquid level gauge 5 75 in liquid level gauge 4 74 or clear water reserviors 4 in settling tank, magnetic valve 3 63 is closed, water
Pump 3 53 is stopped.Now, magnetic valve 8 68 is opened, and the jute powder for being deposited on adsorbing hexavalent chromium on screen pack 21 is made in gravity
Enter storage slag bath 3 with lower, close magnetic valve 8 68 afterwards.Meanwhile online chromium detector 41 detects Cr VI in clear water reserviors 4 in real time
Concentration, and by detection numerical value send to microcomputer control system, when hexavalent chromium concentration is up to standard, magnetic valve 5 65 open,
Water pump 5 55 is worked, and the water after being handled in clear water reserviors 4 is discharged through outlet conduit, when liquid level reaches liquid level gauge 6 76, magnetic valve five
65 close, and water pump 5 55 is stopped;When hexavalent chromium concentration is not up to standard, the powder of jute containing adsorbing hexavalent chromium in pond 1 to be adsorbed
Waste water enters after settling tank 2, and magnetic valve 4 64 is opened, and water pump 4 54 works, and the water in clear water reserviors 4 is back to by chimney filter 13
Adsorption tank 1, when liquid level reaches that liquid level reaches liquid level gauge 1 in liquid level gauge 6 76 or adsorption tank 1 in clear water reserviors 4, magnetic valve 4 64
Close, water pump 4 54 is stopped, and reusing jute powder into the water not up to standard in adsorption tank 1 is adsorbed, sedimentation, directly
It is up to standard to hexavalent chromium concentration.Above-mentioned all magnetic valves, water pump and agitator can be controlled by microcomputer control system, automatically
Change degree is high, and treatment effeciency is high.Storing up the chromium slag in slag bath 3 can smelt or the methods of electronation by waste liqouor through incinerating, and create
Bigger value.
The above enumerates for the specific embodiment of the present invention, should for the equipment and structure of wherein not detailed description
When being interpreted as taking the existing common apparatus in this area and universal method to be practiced.
The above embodiment of the present invention is only to illustrate that technical solution of the present invention is used simultaneously, only the row of technical solution of the present invention
Lift, the technical scheme and its protection domain being not intended to limit the invention.Using equivalent technologies mean, equivalent apparatus etc. to this hair
The improvement of technical scheme disclosed in bright claims and specification is considered to be without departing from claims of the present invention
And the scope disclosed in specification.
Claims (6)
1. a kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium, it is characterised in that including adsorption tank, settling tank, storage
Slag bath and clear water reserviors, the adsorption tank, are sequentially connected between settling tank and clear water reserviors by pipeline, are provided with the pipeline
Magnetic valve and water pump, the adsorption tank, the upper portion side wall and lower sides of settling tank and clear water reserviors are respectively arranged with liquid level gauge;
Adsorbent is jute powder in the adsorption tank, and the upper end of the adsorption tank is provided with acid-base accommodation room and jute powder room, institute
State acid-base accommodation room and jute powder room to be connected with the adsorption tank by straight pipeline respectively, electricity is provided with the straight pipeline
Magnet valve, the side wall of the adsorption tank are additionally provided with pH on-line detectors, and the adsorption tank is internally provided with agitator;
The settling tank is cylinder, and the bottom of the settling tank is additionally provided with screen pack, and the screen pack is in turbination, institute
State the top of screen pack to fix with the side wall sealing of the settling tank, opening is arranged at the bottom of the screen pack, the settling tank
Bottom surface it is corresponding be provided with opening, the bottom of the screen pack and the bottom surface of the settling tank are solid in opening sealing
Fixed, the delivery port of the settling tank is located under screen pack;
The storage slag bath is located at the lower end of the settling tank, and the storage slag bath and the settling tank are by being arranged at the settling tank
The straight pipeline of bottom surface opening is connected, and magnetic valve is provided with the straight pipeline;
Online chromium detector is provided with the clear water reserviors, the clear water reserviors are connected with the adsorption tank by pipeline, the pipe
Magnetic valve and water pump are provided with road;
The magnetic valve, water pump, agitator, liquid level gauge, pH on-line detectors and online chromium detector control with microcomputer
System is connected, and the magnetic valve, water pump and agitator are controlled by the microcomputer control system.
2. the wastewater treatment equipment according to claim 1 using jute powder adsorbing hexavalent chromium, it is characterised in that the Huang
Numb powder is crushed after drying and is made for the blade and tender tip of long fruit jute.
3. the wastewater treatment equipment according to claim 2 using jute powder adsorbing hexavalent chromium, it is characterised in that the suction
Screen pipe is provided with the inlet pipeline in attached pond.
4. the wastewater treatment equipment according to claim 3 using jute powder adsorbing hexavalent chromium, it is characterised in that the suction
The pH value in attached pond is 5-7.
5. the wastewater treatment equipment according to claim 4 using jute powder adsorbing hexavalent chromium, it is characterised in that the suction
The adsorption time in attached pond is 25-35 minutes.
6. the wastewater treatment equipment according to claim 5 using jute powder adsorbing hexavalent chromium, it is characterised in that described heavy
The sedimentation time for dropping pond is 15-25 minutes.
Priority Applications (1)
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CN201710793437.9A CN107399787A (en) | 2017-09-05 | 2017-09-05 | A kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710793437.9A CN107399787A (en) | 2017-09-05 | 2017-09-05 | A kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium |
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Publication Number | Publication Date |
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CN107399787A true CN107399787A (en) | 2017-11-28 |
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CN201710793437.9A Withdrawn CN107399787A (en) | 2017-09-05 | 2017-09-05 | A kind of wastewater treatment equipment using jute powder adsorbing hexavalent chromium |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109231586A (en) * | 2018-11-19 | 2019-01-18 | 四川中哲新材料科技有限公司 | A kind of electrolytic manganese metal waste discharge processing system |
-
2017
- 2017-09-05 CN CN201710793437.9A patent/CN107399787A/en not_active Withdrawn
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109231586A (en) * | 2018-11-19 | 2019-01-18 | 四川中哲新材料科技有限公司 | A kind of electrolytic manganese metal waste discharge processing system |
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Application publication date: 20171128 |