CN1073933C - Composite anti-corrosion material - Google Patents
Composite anti-corrosion material Download PDFInfo
- Publication number
- CN1073933C CN1073933C CN98111157A CN98111157A CN1073933C CN 1073933 C CN1073933 C CN 1073933C CN 98111157 A CN98111157 A CN 98111157A CN 98111157 A CN98111157 A CN 98111157A CN 1073933 C CN1073933 C CN 1073933C
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- CN
- China
- Prior art keywords
- resin
- layer
- resin layer
- unsaturated
- corrosion material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The present invention discloses a composite anticorrosive material which is a glass fiber reinforced plastic material formed by compounding fiberglass fabric and resin layers. The present invention is characterized in that one layer or more than one layer of the resin layers has the mode of a graphite resin layer which is a preservative layer made by mixing unsaturated resin, graphite powder and a solidifying agent. The present invention has the advantages of good acidproof performance and good alkali-proof performance; the composite anticorrosion material can resist the high temperature of 120 DEG C, and can be made into various containers such as anticorrosive storing cisterns, tanks, evaporators, pipelines, etc.; the made containers have the advantages of strong heat transmission coefficient and high compressive resistance.
Description
The present invention relates to a kind of anti-corrosion material.
Containers such as storage tank, vaporizer, pipeline is anticorrosion in the prior art, generally adopts simple glass steel or graphite liner etc., and it is acidproof, alkaline-resisting, resistance to high temperature is undesirable.
The object of the present invention is to provide a kind of composite anti-corrosion material with good acidproof, alkaline-resisting, resistance to high temperature.
Technical solution of the present invention is:
A kind of composite anti-corrosion material, it is the glass fibre reinforced plastic material that is composited by glass cloth and resin layer, the difference of itself and prior art is: the one or more layers employing graphite resin layer in the resin layer, the graphite resin layer is the preservative layer that is mixed by unsaturated resin, plumbago and curing agent.
The weight proportion of unsaturated resin and plumbago is 1: 0.6～0.8 in the graphite resin layer, and the amount of curing agent adds in the ratio of using the per kilogram unsaturated resin to add 25～80ml.Unsaturated resin adopts 199 or 191 polyester unsaturated resins.Curing agent adopts MEK cobalt green or benzene sulfonyl chloride.
The present invention has good acidproof, alkaline resistance properties, and the high temperature of 120 ℃ of abilities, can be made into containers such as various anticorrosion storage tanks, jar, vaporizer, pipeline, and the container heat-transfer coefficient of making is strong, compression resistance is high, is a kind of desirable novel anti-corrosion material.
The invention will be further described below in conjunction with embodiment:
Embodiment 1:
Unsaturated resin and the plumbago weight proportion by 1: 0.6 is mixed, and in using the per kilogram unsaturated resin to add the ratio adding curing agent of 30ml, make the graphite resin preservative, unsaturated resin adopts 191 polyester unsaturated resins, and curing agent adopts benzene sulfonyl chloride; According to shape, the size of required making container, spread layer of glass fiber fabric earlier on mould then, brush one deck resin layer repaves layer of glass fiber fabric, brushes one deck resin layer again, so repeatedly, generally about 25 layers, decides on the pressurized situation.Pipeline in this way, as stated above, winding pipeline is made.191 polyester resin adopt Jiangsu and positive chemical industry (group) company is that produce and positive board product, are a kind of translucent goods.
Embodiment 2:
Unsaturated resin and the plumbago weight proportion by 1: 0.7 is mixed, and in using the per kilogram unsaturated resin to add the ratio adding curing agent of 60ml, make the graphite resin preservative, unsaturated resin adopts 199 polyester unsaturated resins, and curing agent adopts the MEK cobalt green; According to shape, the size of required making container, spread layer of glass fiber fabric earlier on mould then, brush one deck resin layer repaves layer of glass fiber fabric, brushes one deck resin layer again, so repeatedly, generally about 25 layers, decides on the pressurized situation.Pipeline in this way, as stated above, winding pipeline is made.199 polyester resin adopt Jiangsu and positive chemical industry (group) company is that produce and positive board product, are a kind of yellowish transparent articles.
Embodiment 3:
Unsaturated resin and the plumbago weight proportion by 1: 0.8 is mixed, and in using the per kilogram unsaturated resin to add the ratio adding curing agent of 75ml, make the graphite resin preservative, unsaturated resin adopts 191 polyester not steep and resin, and curing agent adopts benzene sulfonyl chloride; According to shape, the size of required making container, spread layer of glass fiber fabric earlier on mould then, brush one deck resin layer repaves layer of glass fiber fabric, brushes one deck resin layer again, so repeatedly, generally about 25 layers, decides on the pressurized situation.Pipeline in this way, as stated above, winding pipeline is made.191 polyester resin adopt Jiangsu and positive chemical industry (group) company is that produce and positive board product, are a kind of translucent goods.
Claims (4)
1, a kind of composite anti-corrosion material, it is the glass fibre reinforced plastic material that is composited by glass cloth and resin layer, it is characterized in that: the one or more layers employing graphite resin layer in the resin layer, the graphite resin layer is the preservative layer that is mixed by unsaturated resin, plumbago and curing agent.
2, composite anti-corrosion material according to claim 1 is characterized in that: the weight proportion of unsaturated resin and plumbago is 1: 0.6～0.8 in the graphite resin layer, and the amount of curing agent adds in the ratio of using the per kilogram unsaturated resin to add 25～80ml.
3, composite anti-corrosion material according to claim 1 and 2 is characterized in that: unsaturated resin adopts 199 or 191 polyester unsaturated resins.
4, composite anti-corrosion material according to claim 1 and 2 is characterized in that: curing agent adopts MEK cobalt green or benzene sulfonyl chloride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98111157A CN1073933C (en) | 1998-02-25 | 1998-02-25 | Composite anti-corrosion material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98111157A CN1073933C (en) | 1998-02-25 | 1998-02-25 | Composite anti-corrosion material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1198383A CN1198383A (en) | 1998-11-11 |
| CN1073933C true CN1073933C (en) | 2001-10-31 |
Family
ID=5221156
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98111157A Expired - Fee Related CN1073933C (en) | 1998-02-25 | 1998-02-25 | Composite anti-corrosion material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1073933C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103884213A (en) * | 2014-03-01 | 2014-06-25 | 瑞冬集团有限公司 | Corrosion-resistant shell and tube heat exchanger |
| CN106863938B (en) * | 2015-12-11 | 2019-07-23 | 深圳光启空间技术有限公司 | Glass reinforced plastic, preparation method and aerostatics gondola |
| CN115403982A (en) * | 2022-09-06 | 2022-11-29 | 江苏城乡建设职业学院 | Graphite tube, tube type heat exchanger and preparation method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD282201A5 (en) * | 1989-04-14 | 1990-09-05 | Sbk Magdeburg Veb | METHOD FOR PRODUCING PVC-GUP COMPOSITE MATERIALS, ESPECIALLY FOR COMPOSITE CONTAINERS |
| JPH04243185A (en) * | 1991-01-17 | 1992-08-31 | Kanegafuchi Chem Ind Co Ltd | Laminated board for printed circuit |
| CN1070205A (en) * | 1992-09-02 | 1993-03-24 | 北京东城紫光塑料电器厂 | High impact-resistant, anti-electrostatic unsaturated polyester composite and method for making and application |
-
1998
- 1998-02-25 CN CN98111157A patent/CN1073933C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD282201A5 (en) * | 1989-04-14 | 1990-09-05 | Sbk Magdeburg Veb | METHOD FOR PRODUCING PVC-GUP COMPOSITE MATERIALS, ESPECIALLY FOR COMPOSITE CONTAINERS |
| JPH04243185A (en) * | 1991-01-17 | 1992-08-31 | Kanegafuchi Chem Ind Co Ltd | Laminated board for printed circuit |
| CN1070205A (en) * | 1992-09-02 | 1993-03-24 | 北京东城紫光塑料电器厂 | High impact-resistant, anti-electrostatic unsaturated polyester composite and method for making and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1198383A (en) | 1998-11-11 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |