CN107385203B - Method for preparing sintered ore by using thermal state converter slag as binder phase - Google Patents

Method for preparing sintered ore by using thermal state converter slag as binder phase Download PDF

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CN107385203B
CN107385203B CN201710742160.7A CN201710742160A CN107385203B CN 107385203 B CN107385203 B CN 107385203B CN 201710742160 A CN201710742160 A CN 201710742160A CN 107385203 B CN107385203 B CN 107385203B
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sinter
ferrous material
vessel slag
hot
slag
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CN107385203A (en
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李金莲
廖相巍
唐复平
王亮
韩子文
任伟
张伟
张立国
李晓伟
刘祥
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Angang Steel Co Ltd
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Angang Steel Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/16Sintering; Agglomerating

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  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
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  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention relates to a method for preparing sintered ore by using thermal converter slag as a binder phase, which comprises the following steps: 1) calculating ingredients; 2) preheating; 3) paving materials for the first time; 4) pouring and covering; 5) paving the material for the second time; 6) compacting and sintering; 7) cooling; 8) crushing and screening; the invention uses the high-temperature thermal converter slag as a binding phase to bind the iron-containing raw material to prepare the sinter without using solid fuel and flux, can fully recover the waste heat and calcium resources of the high-temperature thermal converter slag, reduce the environmental pollution and reduce the production cost of the sinter.

Description

A method of sinter is prepared using hot vessel slag for Binder Phase
Technical field
The present invention relates to metallurgical technology field more particularly to it is a kind of using hot vessel slag be Binder Phase prepare sinter Method.
Background technique
Vessel slag is the industrial solid wastes generated in a kind of convertor steelmaking process.1 ton of steel of every production want by-product 0.1~ 0.13 ton of vessel slag, temperature is relatively high, reaches 1300 DEG C~1450 DEG C or so, heat content also very abundant, vessel slag per ton About contain (1.26~1.88) × 106The sensible heat of kJ is equivalent to the heat of 45~60kg standard coal generation.Wherein also contain 15% Therefore~25% metallic iron (MFe) and a large amount of beneficial element calcium, magnesium and silicon etc. are increased to vessel slag heat and physical resources Recycling, become reduce steel mill's smelting cost main means.Currently, vessel slag main methods are by hot converter Slag carry out it is cooling after by being crushed, sieve repeatedly, magnetic separation, be used after extracting metal therein, usually handle again Vessel slag afterwards is for ground backfill, urban road laying or for making cement, water purification agent and steel slag fertilizer etc..This processing method Making the sensible heat of vessel slag can not recycle, and cause the huge waste of the energy.
Sinter mainly uses Iron Ore Powder, flux and solid fuel to be prepared at present, under the conditions of exhausting, solid fuel Burning makes Iron Ore Powder and flux part high temperature melting generate other unfused Iron Ore Powders of liquid phase bonding.Traditional sintering process is deposited In following problem: 1) needing the fixed carbon with addition of about 3%~5% in sintering process, need to consume a large amount of coal resources;2) by Fossil fuel has been used in sintering process, produces a large amount of generation SO2、NOX、COXEtc. atmosphere pollutions;3) need to consume calcium, Magnesium resource coheres the needs of Iron Ore Powder to meet;4) formation efficiency is not high.
Application No. is the Chinese patents of CN200780047831.2 to disclose a kind of " side returned mine using corona treatment Method and device " is returned mine by using plasma fusing and cohesion come the bonding that makes to return mine, but since plasma temperature is excessively high, It is capable of the heat of 10000 DEG C or higher high temperature, is easy to produce ion vaporized state, temperature control is uneven, and it is It returns mine suitable for processing, fine iron ore cannot be handled.
Summary of the invention
The present invention provides a kind of methods for preparing sinter using hot vessel slag for Binder Phase, fire without using solid It is that Binder Phase to bond iron-bearing material prepares sinter with the hot vessel slag of high temperature under conditions of material and flux, it can be abundant The waste heat and calcium resource for recycling the hot vessel slag of high temperature, reduce environmental pollution, and reduce sinter production cost.
In order to achieve the above object, the present invention is implemented with the following technical solutions:
A method of sinter being prepared for Binder Phase using hot vessel slag, is included the following steps:
1) burdening calculation: based on mass fraction, by following component content in prepared sinter or parameter be limitation because Element carries out proportion calculating to hot vessel slag and ferrous material;TFe 40%~65%, CaO/SiO2=1.5~4.0, CaO+ MgO/SiO2+Al2O3Range be=1.75~4.20, P2O5≤ 0.2%;
2) the pre-heat treatment: the pre-heat treatment is carried out to ferrous material using the high-temperature flue gas of cooling sinter, removes chalybeate Free water and molecular water in material, by ferrous material preheating temperature to 200~1000 DEG C;
3) first time stone: in the ferrous material spreading to container after the pre-heat treatment, smooth charge level, first time spreading Ferrous material thickness of feed layer is 20~50mm;
4) pour and cover: the hot vessel slag of high temperature is uniformly poured be layed onto it is smooth after ferrous material surface, hot converter slag charge Layer is with a thickness of 5~10mm;
5) second of stone: on the ferrous material spreading after the pre-heat treatment to hot converter slag material layer, smooth charge level, The ferrous material thickness of feed layer of secondary spreading is 50~100mm;
6) compacting sintering: pressure treatment is carried out to sinter bed using press machine, pressure limit is 10t~80t;And pressure maintaining 5~10min is to bond bonding iron-bearing material sinter is made with hot vessel slag;
7) cooling: the sinter after compacting being cooled to 200 DEG C or less using cold wind;
8) crushing and screening: sinter after cooling is by broken crusher machine, then sieves through grade sieve, finally obtains finished product Sinter.
Mass percent of the state vessel slag in sinter is 15%~60%.
The ferrous material is magnetic iron ore, bloodstone, limonite, siderite, BF return fines, sinter return fine, metallurgical dust sludge In a kind and two or more any combination.
The granularmetric composition of the ferrous material is that 1-3mm accounts for 50% or more total amount quality.
The granularmetric composition of the ferrous material is that 1~3mm accounts for 50% or more total amount quality.
The temperature range of the hot vessel slag is 1300~1600 DEG C, and R coefficient of stabilization is 95% or more.
Compared with prior art, the beneficial effects of the present invention are:
Present invention combination vessel slag and sintering ore production technology reapective features, using calcium oxide resource in vessel slag as Binder Phase directly bonds ferrous material and prepares sinter, and the waste heat of vessel slag is not only utilized, and take full advantage of wherein iron, Calcium resource reduces vessel slag environmental pollution, while having saved carbon resource used in sintering, prevents sintering process to atmosphere Ironmaking and STEELMAKING PRODUCTION old is greatly lowered in environmental pollution, opens a calcium, magnesium resource resource is followed inside iron and steel enterprise The new route that ring utilizes.
Detailed description of the invention
Fig. 1 is a kind of process flow of method for preparing sinter for Binder Phase using hot vessel slag of the present invention Figure.
Specific embodiment
Specific embodiments of the present invention will be further explained with reference to the accompanying drawing:
As shown in Figure 1, a kind of method for preparing sinter using hot vessel slag for Binder Phase of the present invention, including such as Lower step:
1) burdening calculation: based on mass fraction, by following component content in prepared sinter or parameter be limitation because Element carries out proportion calculating to hot vessel slag and ferrous material;TFe 40%~65%, CaO/SiO2=1.5~4.0, CaO+ MgO/SiO2+Al2O3Range be=1.75~4.20, P2O5≤ 0.2%;
2) the pre-heat treatment: the pre-heat treatment is carried out to ferrous material using the high-temperature flue gas of cooling sinter, removes chalybeate Free water and molecular water in material, by ferrous material preheating temperature to 200~1000 DEG C;
3) first time stone: in the ferrous material spreading to container after the pre-heat treatment, smooth charge level, first time spreading Ferrous material thickness of feed layer is 20~50mm;
4) pour and cover: the hot vessel slag of high temperature is uniformly poured be layed onto it is smooth after ferrous material surface, hot converter slag charge Layer is with a thickness of 5~10mm;
5) second of stone: on the ferrous material spreading after the pre-heat treatment to hot converter slag material layer, smooth charge level, The ferrous material thickness of feed layer of secondary spreading is 50~100mm;
6) compacting sintering: pressure treatment is carried out to sinter bed using press machine, pressure limit is 10t~80t;And pressure maintaining 5~10min is to bond bonding iron-bearing material sinter is made with hot vessel slag;
7) cooling: the sinter after compacting being cooled to 200 DEG C or less using cold wind;
8) crushing and screening: sinter after cooling is by broken crusher machine, then sieves through grade sieve, finally obtains finished product Sinter.
Mass percent of the state vessel slag in sinter is 15%~60%.
The ferrous material is magnetic iron ore, bloodstone, limonite, siderite, BF return fines, sinter return fine, metallurgical dust sludge In a kind and two or more any combination.
The granularmetric composition of the ferrous material is that 1-3mm accounts for 50% or more total amount quality.
The granularmetric composition of the ferrous material is that 1~3mm accounts for 50% or more total amount quality.
The temperature range of the hot vessel slag is 1300~1600 DEG C, and R coefficient of stabilization is 95% or more.
Following embodiment is implemented under the premise of the technical scheme of the present invention, gives detailed embodiment and tool The operating process of body, but protection scope of the present invention is not limited to following embodiments.Method therefor is such as without spy in following embodiments Not mentionleting alone bright is conventional method.
[embodiment 1]
It is limiting factor to hot vessel slag and ferrous material by following component content in prepared sinter or parameter Proportion calculating is carried out, hot vessel slag mass percent in sinter is 20%, it calculates and weighs ferrous material, ferrous material Granularmetric composition is that 1~3mm accounts for total amount quality 60%, and the temperature of hot vessel slag is 1500 DEG C, R (CaO/SiO2)=2.91.
The pre-heat treatment is carried out to ferrous material using the high-temperature flue gas of cooling sinter, in evaporation heating ferrous material from By water and molecular water, by ferrous material preheating temperature to 700 DEG C or so;Again ferrous material spreading after the pre-heat treatment to container It is interior, while smooth surface of material, the thickness of feed layer of first time spreading ferrous material are 20mm;Hot vessel slag high temperature is uniform Pour be layed onto it is smooth after the ferrous material bed of material on, the thickness of feed layer of hot vessel slag is 5mm;Again the chalybeate after the pre-heat treatment Expect on spreading to the bed of material of hot vessel slag, while smooth surface of material, the ferrous material thickness of feed layer of second of spreading are 50mm。
Pressure treatment, pressure 10t are carried out using press machine;Sinter is made after pressure maintaining 5min;It will be compacted using cold wind Sinter afterwards is cooled to 200 DEG C hereinafter, sinter after cooling passes through broken crusher machine, then sieves through grade sieve, finally Obtain the finished product sinter of certain particle size grade.The chemical component and performance of finished product sinter are shown in Table 1, table 2 respectively.
[embodiment 2]
It is limiting factor to hot vessel slag and ferrous material by following component content in prepared sinter or parameter Proportion calculating is carried out, hot vessel slag mass percent in sinter is 30%, it calculates and weighs ferrous material, ferrous material Granularmetric composition is that 1~3mm accounts for total amount quality 65%, and the temperature of hot vessel slag is 1400 DEG C, R (CaO/SiO2)=2.60.
The pre-heat treatment is carried out to ferrous material using the high-temperature flue gas of cooling sinter, in evaporation heating ferrous material from By water and molecular water, by ferrous material preheating temperature to 500 DEG C or so;Again ferrous material spreading after the pre-heat treatment to container It is interior, while smooth surface of material, the thickness of feed layer of first time spreading ferrous material are 50mm;Hot vessel slag high temperature is uniform Pour be layed onto it is smooth after the ferrous material bed of material on, the thickness of feed layer of hot vessel slag is 10mm;Again the iron content after the pre-heat treatment On material spreading to the bed of material of hot vessel slag, while smooth surface of material, the ferrous material thickness of feed layer of second of spreading are 100mm。
Pressure treatment, pressure 80t are carried out using press machine;Sinter is made after pressure maintaining 10min;It will be compacted using cold wind Sinter afterwards is cooled to 200 DEG C hereinafter, sinter after cooling passes through broken crusher machine, then sieves through grade sieve, finally Obtain the finished product sinter of certain particle size grade.The chemical component and performance of finished product sinter are shown in Table 1, table 2 respectively.
[embodiment 3]
It is limiting factor to hot vessel slag and ferrous material by following component content in prepared sinter or parameter Proportion calculating is carried out, hot vessel slag mass percent in sinter is 40%, it calculates and weighs ferrous material, ferrous material Granularmetric composition is that 1~3mm accounts for total amount quality 70%, and the temperature of hot vessel slag is 1600 DEG C, R (CaO/SiO2)=3.91.
The pre-heat treatment is carried out to ferrous material using the high-temperature flue gas of cooling sinter, in evaporation heating ferrous material from By water and molecular water, by ferrous material preheating temperature to 300 DEG C or so;Again ferrous material spreading after the pre-heat treatment to container It is interior, while smooth surface of material, the thickness of feed layer of first time spreading ferrous material are 50mm;Hot vessel slag high temperature is uniform Pour be layed onto it is smooth after the ferrous material bed of material on, the thickness of feed layer of hot vessel slag is 5mm;Again the chalybeate after the pre-heat treatment Expect on spreading to the bed of material of hot vessel slag, while smooth surface of material, the ferrous material thickness of feed layer of second of spreading are 80mm。
Pressure treatment, pressure 50t are carried out using press machine;Sinter is made after pressure maintaining 5min;It will be compacted using cold wind Sinter afterwards is cooled to 200 DEG C hereinafter, sinter after cooling passes through broken crusher machine, then sieves through grade sieve, finally Obtain the finished product sinter of certain particle size grade.The chemical component and performance of finished product sinter are shown in Table 1, table 2 respectively.
1 sinter chemical composition % of table
Embodiment TFe FeO MnO P2O5 R(CaO/SiO2)
Embodiment 1 57.60 48.44 0.28 0.16 2.31
Embodiment 2 53.13 44.65 0.42 0.18 2.50
Embodiment 3 48.56 40.83 0.56 0.19 2.63
2 sinter high temperature metallurgical properties of table
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (5)

1. a kind of method for preparing sinter using hot vessel slag for Binder Phase, which comprises the steps of:
1) burdening calculation: being limiting factor pair by following component content in prepared sinter or parameter based on mass fraction Hot vessel slag and ferrous material carry out proportion calculating;TFe 40%~65%, CaO/SiO2=1.5~4.0, CaO+MgO/ SiO2+Al2O3Range be=1.75~4.20, P2O5≤ 0.2%;Mass percent of the hot vessel slag in sinter be 15%~60%;
2) the pre-heat treatment: the pre-heat treatment is carried out to ferrous material using the high-temperature flue gas of cooling sinter, is removed in ferrous material Free water and molecular water, by ferrous material preheating temperature to 200~1000 DEG C;
3) first time stone: in the ferrous material spreading to container after the pre-heat treatment, smooth charge level, the iron content of first time spreading Material thickness of feed layer is 20~50mm;
4) pour and cover: the hot vessel slag of high temperature is uniformly poured be layed onto it is smooth after ferrous material surface, hot converter slag material layer is thick Degree is 5~10mm;
5) second of stone: on the ferrous material spreading after the pre-heat treatment to hot converter slag material layer, smooth charge level, second The ferrous material thickness of feed layer of spreading is 50~100mm;
6) compacting sintering: pressure treatment is carried out to sinter bed using press machine, pressure limit is 10t~80t;And pressure maintaining 5~ 10min is to bond bonding iron-bearing material sinter is made with hot vessel slag;
7) cooling: the sinter after compacting being cooled to 200 DEG C or less using cold wind;
8) crushing and screening: sinter after cooling is by broken crusher machine, then sieves through grade sieve, finally obtains finished product sintering Mine.
2. a kind of method for preparing sinter using hot vessel slag for Binder Phase according to claim 1, feature exist In, the ferrous material be magnetic iron ore, bloodstone, limonite, siderite, BF return fines, sinter return fine, 1 in metallurgical dust sludge Kind and two or more any combination.
3. a kind of method for preparing sinter using hot vessel slag for Binder Phase according to claim 1, feature exist In the granularmetric composition of the ferrous material is that 1-3mm accounts for 50% or more total amount quality.
4. a kind of method for preparing sinter using hot vessel slag for Binder Phase according to claim 1, feature exist In the granularmetric composition of the ferrous material is that 1~3mm accounts for 50% or more total amount quality.
5. a kind of method for preparing sinter using hot vessel slag for Binder Phase according to claim 1, feature exist In the temperature range of the hot vessel slag is 1300~1600 DEG C, and R coefficient of stabilization is 95% or more.
CN201710742160.7A 2017-08-25 2017-08-25 Method for preparing sintered ore by using thermal state converter slag as binder phase Active CN107385203B (en)

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CN110273065B (en) * 2018-03-14 2021-05-14 宝山钢铁股份有限公司 Iron ore microwave sintering method

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JPS5272307A (en) * 1975-12-15 1977-06-16 Okura Akimitsu Process for production of sintered ore making use of converter slag
JPS5457403A (en) * 1977-10-17 1979-05-09 Yoshizawa Sekkai Kogyo Kk Production of ore lump
JPH09279260A (en) * 1996-04-16 1997-10-28 Nippon Steel Corp Method for agglomerating iron ore
JPH10314799A (en) * 1997-05-20 1998-12-02 Kawasaki Steel Corp Method for treating oil bearing sludge having high iron content
CN101831539B (en) * 2010-05-20 2012-11-28 牛庆君 Method for producing artificial rich iron ore from copper smelting waste slag by using new sintering technology
CN103045857B (en) * 2012-12-28 2014-12-31 柳州钢铁股份有限公司 Production method for sintering converter granulated slag to produce blast-furnace smelting sintered ore
JP6020832B2 (en) * 2013-12-12 2016-11-02 Jfeスチール株式会社 Sintering raw material manufacturing method

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