CN107385139A - A kind of smelting process of high-carbon steel - Google Patents

A kind of smelting process of high-carbon steel Download PDF

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Publication number
CN107385139A
CN107385139A CN201710635258.2A CN201710635258A CN107385139A CN 107385139 A CN107385139 A CN 107385139A CN 201710635258 A CN201710635258 A CN 201710635258A CN 107385139 A CN107385139 A CN 107385139A
Authority
CN
China
Prior art keywords
carbon
molten steel
steel
refining
carburetting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710635258.2A
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Chinese (zh)
Inventor
安强
汤伟
曾凡政
杨俊�
何航
徐吉尤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Valin Xiangtan Iron and Steel Co Ltd
Hunan Hualing Xiangtan Iron and Steel Co Ltd
Original Assignee
Hunan Hualing Xiangtan Iron and Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Hualing Xiangtan Iron and Steel Co Ltd filed Critical Hunan Hualing Xiangtan Iron and Steel Co Ltd
Priority to CN201710635258.2A priority Critical patent/CN107385139A/en
Publication of CN107385139A publication Critical patent/CN107385139A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/30Regulating or controlling the blowing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • B22D11/18Controlling or regulating processes or operations for pouring
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/072Treatment with gases
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum

Abstract

A kind of smelting process of high-carbon steel, processing step include:(1)It is 0.10% ~ 0.20% to bessemerize carbon content in terminal point control molten steel, and carbon content of the converter tapping process in molten steel adds suitable ferrosilicon, ferromanganese or manganese-silicon and carry out deoxidation alloying to molten steel;(2)The weak argon gas stirring of the big tank of tapping process, converter tapping process and refining, which are smelted, adjusts carbon to use low nitrogen carburant carburetting, and external refining L stoves F adjusts carbon amounts at 0.03%~0.05%, using carbon line carburetting;(3)CAS and LF refining process are stirred using weak argon gas, LF stove transmission process molten steel all standing operation;(4)Casting process controls big tank automatic jet and middle Baogang's liquid level to add insulation material all standing to operate.The present invention uses the low nitrogen carburant carburetting of novel low-cost, while by smelting process technique adjustment, not entering VD/RH applications of vacuum, nitrogen content reaches 25~40ppm on strand or material, can reduce production cost.

Description

A kind of smelting process of high-carbon steel
Technical field
The invention belongs to method for making steel, is a kind of smelting process of high-carbon steel.
Background technology
The smelting of traditional high-carbon Series Steel, harmful element is typically removed by converter Strong oxdiative, tapping process and refined Cheng Qiang deoxidations, and carburetting is carried out using carburant.Because conventional carburant nitrogen content is higher, tyre bead steel, cord steel and bearing Steel etc. needs to carry out vacuumize process into VD/RH to nitrogen high request steel grade, reaches the requirement of drop nitrogen, and production cost is higher.
Conventional carburant mainly has petroleum coke and calcining coal, and carburant nitrogen content is respectively 0.50% and 0.32% or so, and This two kinds of carburant prices are higher.It is minimum to need carburetting due to high-carbon steel such as tyre bead steel, cord steel, SWRH82B and bearing steels 0.60%, each about nitrogen pick-up 33ppm and 22ppm.Such as the pure graphite carburant that the enterprise such as Baosteel uses(Carbon content more than 99%), nitrogen Content is relatively low, but the market price is higher, is unfavorable for the control of production cost.Control nitrogen type carburant has the structure of class graphite, its Burn-off rate is significantly higher than conventional petroleum Jiao carburant and calcining coal carburant, and carbon absorption rate is stable, and process is connected more Efficiently, the more traditional carburant of its cost low 10%~15%, to realizing that efficient, the inexpensive smelting of variety steel has clear superiority. Simultaneously by the control technology of external refining LF stoves and continuous casting protective casting, can be achieved not entering VD/RH applications of vacuum smelting control Technology.Therefore high-carbon steel smelting technique provides technology for the production of high-carbon steel low-cost high-efficiency control nitrogen and ensured.
The content of the invention
It is an object of the invention to provide a kind of smelting process of high-carbon steel, by bessemerizing the control of terminal, using low The control technology of the low nitrogen type carburetting material carburetting of cost, external refining stove and continuous casting protective casting, it is high to reach high-carbon steel low cost The purpose of effect control nitrogen production.
Technical scheme:
A kind of smelting process of high-carbon steel, processing step include:
(1)It is 0.10% ~ 0.20% to bessemerize carbon content in terminal point control molten steel, and carbon of the converter tapping process in molten steel contains Amount adds suitable ferrosilicon, ferromanganese or manganese-silicon and carries out deoxidation alloying to molten steel.
(2)The weak argon gas stirring of the big tank of tapping process, converter tapping process and refining are smelted and adjust carbon to be increased using low nitrogen carburant Carbon, external refining L stoves F adjusts carbon amounts at 0.03%~0.05%, using carbon line carburetting.
(3)CAS and LF refining process are stirred using weak argon gas, LF stove transmission process molten steel all standing operation.
(4)Casting process controls big tank automatic jet and middle Baogang's liquid level to add insulation material all standing to operate.
Advantages of the present invention:By bessemerizing the control of terminal, tapping process uses low nitrogen carburant carburetting, and refining is led to Cross weak argon gas stirring, LF stove transmission process molten steel all standing operation inhales nitrogen caused by reducing secondary oxidation and do not enter VD/RH vacuum Processing, and the control of continuous casting protection pouring, strand nitrogen content can control below 40ppm, realize high-carbon steel low-cost high-efficiency Control the purpose of nitrogen production.
Embodiment
Embodiment one:The smelting of TQ72A steel
Stove molten iron first carries out molten iron pretreatment, and molten steel sulfur content [S]=0.010% after processing, temperature=1282 DEG C, molten iron enters converter Before slag must be taken off totally.Converter smelting adds molten iron and steel scrap, 81 tons of molten iron, 7.7 tons of steel scrap.Converter terminal control [C]= 0.11%, tapping process adds ferromanganese (FeMn) and ferrosilicon(FeSi), and the big tank bottom of tapping process blows weak argon gas stirring, and add 0.64 ton of low-carbon carburant carburetting.
Molten steel enters CAS and LF slag making and the weak argon gas stirring of transmission process, and transmission process molten steel all standing operation, steel Water calls in continuous casting, molten steel automatic jet, and middle Baogang's liquid level adds insulation material all standing to operate, and strand takes gas sample to detect nitrogen content For 32ppm, testing result reaches requirement.
Embodiment two:The smelting of LX72A steel
Enter stove molten iron and first carry out molten iron pretreatment, molten steel sulfur content [S]=0.010% after processing, temperature=1286 DEG C, molten iron enter turn Stokehold must take off slag totally.Converter smelting adds molten iron and steel scrap, 82.7 tons of molten iron, 7.25 tons of steel scrap.Converter terminal controls [C]=0.15%, tapping process add ferromanganese (FeMn) and ferrosilicon(FeSi), and the big tank bottom of tapping process blows weak argon gas stirring, and Add 0.55 ton of low-carbon carburant carburetting.
Molten steel enters CAS and LF slag making and the weak argon gas stirring of transmission process, and transmission process molten steel all standing operation, steel Water calls in continuous casting, molten steel automatic jet, and middle Baogang's liquid level adds insulation material all standing to operate, and strand takes gas sample to detect nitrogen content For 28ppm, testing result reaches requirement.

Claims (1)

1. a kind of smelting process of high-carbon steel, processing step include:
(1)It is 0.10% ~ 0.20% to bessemerize carbon content in terminal point control molten steel, and carbon of the converter tapping process in molten steel contains Amount adds suitable ferrosilicon, ferromanganese or manganese-silicon and carries out deoxidation alloying to molten steel;
(2)The weak argon gas stirring of the big tank of tapping process, converter tapping process and refining are smelted and adjust carbon to use low nitrogen carburant carburetting, stove Outer refining L stoves F adjusts carbon amounts at 0.03%~0.05%, using carbon line carburetting;
CAS and LF refining process are stirred using weak argon gas, LF stove transmission process molten steel all standing operation;
Casting process controls big tank automatic jet and middle Baogang's liquid level to add insulation material all standing to operate.
CN201710635258.2A 2017-07-30 2017-07-30 A kind of smelting process of high-carbon steel Pending CN107385139A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710635258.2A CN107385139A (en) 2017-07-30 2017-07-30 A kind of smelting process of high-carbon steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710635258.2A CN107385139A (en) 2017-07-30 2017-07-30 A kind of smelting process of high-carbon steel

Publications (1)

Publication Number Publication Date
CN107385139A true CN107385139A (en) 2017-11-24

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710635258.2A Pending CN107385139A (en) 2017-07-30 2017-07-30 A kind of smelting process of high-carbon steel

Country Status (1)

Country Link
CN (1) CN107385139A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108251598A (en) * 2018-01-12 2018-07-06 唐山钢铁集团有限责任公司 A kind of carburetting control nitrogen production process of middle carbon high-alloy steel
CN113088628A (en) * 2021-03-31 2021-07-09 山东钢铁股份有限公司 LF refining method of low-carbon steel
CN114908282A (en) * 2022-05-31 2022-08-16 本钢板材股份有限公司 Production process for controlling oxygen and nitrogen content of SWRH42B carbon steel hot-rolled wire rod
WO2023151228A1 (en) * 2022-02-10 2023-08-17 张家港荣盛特钢有限公司 Method for controlling brittle inclusions of tire cord steel

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60234916A (en) * 1984-05-08 1985-11-21 Nisshin Steel Co Ltd Manufacture of stainless steel containing low nitrogen
CN104004881A (en) * 2014-06-13 2014-08-27 常州东大中天钢铁研究院有限公司 Method for controlling nitrogen content in process of producing aluminium deoxidation high-carbon steel
CN104498805A (en) * 2014-12-29 2015-04-08 首钢总公司 Production method of high-carbon low-nitrogen steel for strand wires
CN106399632A (en) * 2016-09-09 2017-02-15 武汉钢铁股份有限公司 High-carbon steel recarburization method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60234916A (en) * 1984-05-08 1985-11-21 Nisshin Steel Co Ltd Manufacture of stainless steel containing low nitrogen
CN104004881A (en) * 2014-06-13 2014-08-27 常州东大中天钢铁研究院有限公司 Method for controlling nitrogen content in process of producing aluminium deoxidation high-carbon steel
CN104498805A (en) * 2014-12-29 2015-04-08 首钢总公司 Production method of high-carbon low-nitrogen steel for strand wires
CN106399632A (en) * 2016-09-09 2017-02-15 武汉钢铁股份有限公司 High-carbon steel recarburization method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108251598A (en) * 2018-01-12 2018-07-06 唐山钢铁集团有限责任公司 A kind of carburetting control nitrogen production process of middle carbon high-alloy steel
CN108251598B (en) * 2018-01-12 2020-05-05 唐山钢铁集团有限责任公司 Carbon increasing and nitrogen controlling production method of medium-carbon high-alloy steel
CN113088628A (en) * 2021-03-31 2021-07-09 山东钢铁股份有限公司 LF refining method of low-carbon steel
WO2023151228A1 (en) * 2022-02-10 2023-08-17 张家港荣盛特钢有限公司 Method for controlling brittle inclusions of tire cord steel
CN114908282A (en) * 2022-05-31 2022-08-16 本钢板材股份有限公司 Production process for controlling oxygen and nitrogen content of SWRH42B carbon steel hot-rolled wire rod

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Application publication date: 20171124