CN107384317A - A kind of anti-freeze type foam dedusting agent - Google Patents

A kind of anti-freeze type foam dedusting agent Download PDF

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Publication number
CN107384317A
CN107384317A CN201710531173.XA CN201710531173A CN107384317A CN 107384317 A CN107384317 A CN 107384317A CN 201710531173 A CN201710531173 A CN 201710531173A CN 107384317 A CN107384317 A CN 107384317A
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CN
China
Prior art keywords
water
cyclodextrin
dust
freeze type
foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710531173.XA
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Chinese (zh)
Inventor
钟华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Tianshun Environmental Protection Equipment Ltd By Share Ltd
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Anhui Tianshun Environmental Protection Equipment Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Anhui Tianshun Environmental Protection Equipment Ltd By Share Ltd filed Critical Anhui Tianshun Environmental Protection Equipment Ltd By Share Ltd
Priority to CN201710531173.XA priority Critical patent/CN107384317A/en
Publication of CN107384317A publication Critical patent/CN107384317A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/22Materials not provided for elsewhere for dust-laying or dust-absorbing

Abstract

The invention provides a kind of anti-freeze type foam dedusting agent, it is made by following raw material:Double (2 second hexyl) sodium sulfo-succinates, cetylpyridinium chloride, gamma-cyclodextrin, 3 sulfopropyl etradecyldimethylamine glycine betaines, Dodecyl Polyoxyethylene Ether phosphate, Mono Isopropylamine, xanthans, calgon, guaiacol, lignin, natrium nitrosum, surplus is water.The synergy that the present invention passes through each formula so that foaming capacity is strong, and foam stability is high.Foaming capacity is stronger, and the gas release of unit mass depositing dust agent solution is bigger, and liquid film surface area is bigger, and dust-laying effect is better and efficiency is higher.The present invention is nontoxic, tasteless, to human body and environmentally friendly, non-secondary pollution.Dissolubility of the present invention is good, within a short period of time with regard to that can be configured to foam solution uniform, that property is stable after being mixed with water.

Description

A kind of anti-freeze type foam dedusting agent
Technical field
The present invention relates to a kind of anti-freeze type foam dedusting agent.
Background technology
A large amount of dust can be all produced in each process of mineral mining, seriously pollutes working environment.According to surveying and determination, in dust The decentralization proportion of respirable dust is very big, and operation will suck a large amount of dust to worker in such circumstances, cause worker to suffer from Pneumoconiosis.The dust suppression that China mine mainly uses at present has spray sprinkler, dust removal by ventilation and cleaner dedusting etc..Spraying Dedusting of sprinkling water is simple and easy but relatively low to the efficiency of dust collection of respirable dust;It can well be trapped and exhaled using high-effective dust-removing equipment Absorption dust, but big energy consumption, fragile, investment height be present, the problems such as dirt Sealing Arrangement need to be taken out in these cleaners.Therefore, need Explore more preferable dust removal method.
The country such as the former Soviet Union, the U.S., Canada is widely used physical chemistry to improve the efficiency of dust collection of respirable dust Dedusting, i.e. wetting agent dedusting and foam dust-removing.Because foam dust-removing has, simple in construction, water consumption is few, respirable dust is removed The features such as dirt efficiency high, be used widely abroad, and have developed a variety of foam dedusting agents (abbreviation foaming agent) formula and The structure type of foam maker (abbreviation foam maker), achieves good dust removing effects.
Foam dedusting agent operation principle is that foaming agent mixes in proportion with water, and a large amount of high expansion foams are produced by foam maker The drop of shape, it is sprayed onto in dirt source or air.When foam solution is sprayed onto ore or material heap, void-free foams are caused to cover With blocking dirt source, dust is set to moisten and suppress;When foam solution is ejected into dust laden air, then substantial amounts of foam particle is formed Group, its cumulative volume and the gross area are very big, greatly increase the contact surface and adhesive force of spray film and grit, improve the dedusting effect of water smoke Fruit.Its dust removal mechanism includes:Intercept, adhere to, moistening, settling etc., all dust to be met with foam can be almost trapped, it is especially right Respirable dust has stronger cohesion ability, and water consumption is few.
The content of the invention
The present invention provides a kind of anti-freeze type foam dedusting agent, has foaming capacity strong, changes the moistening of dust rapidly Property two aspects effect, and also worked in the case of temperature is relatively low.
A kind of anti-freeze type foam dedusting agent, it is made by following percentage by weight raw material:Double (2- second hexyl) sulfo-succinic acids Sodium 2.6%, cetylpyridinium chloride 0.5%, gamma-cyclodextrin 1.7%, 3- sulfopropyl etradecyldimethylamines glycine betaine 1.8%, ten Glycol polyoxyethylene ether phosphate 1.4%, Mono Isopropylamine 0.5%, xanthans 0.9%, calgon 1.7%, guaiacol 0.8%, Lignin 1.5%, natrium nitrosum 0.6-1%, surplus are water.
2nd, a kind of anti-freeze type foam dedusting agent according to claim 1, it is characterised in that by following percentage by weight Raw material is made:Double (2- second hexyl) sodium sulfo-succinates 2.5%, cetylpyridinium chloride 0.8%, gamma-cyclodextrin 1.6%, 3- Sulfopropyl etradecyldimethylamine glycine betaine 2.1%, Dodecyl Polyoxyethylene Ether phosphate 1.6%, Mono Isopropylamine 0.3%, xanthans 1.1%th, calgon 1.9%, guaiacol 0.8%, lignin 1.4%, natrium nitrosum 0.9%, surplus are water.
Further, it is made by following percentage by weight raw material:Double (2- second hexyl) sodium sulfo-succinates 3%, dodecyl chloride Change pyridine 0.4%, gamma-cyclodextrin 1.4-2%, 3- sulfopropyl etradecyldimethylamine glycine betaine 2.2%, Dodecyl Polyoxyethylene Ether phosphorus Hydrochlorate 1.4%, Mono Isopropylamine 0.5%, xanthans 1.5%, calgon 1.7%, guaiacol 0.6%, lignin 1.8%, nitrous Sour sodium 0.9%, surplus are water.
Further, it is made by following percentage by weight raw material:Double (2- second hexyl) sodium sulfo-succinates 2.8%, dodecyl Pyridinium chloride 0.6%, gamma-cyclodextrin 1.8%, 3- sulfopropyl etradecyldimethylamines glycine betaine 2%, Dodecyl Polyoxyethylene Ether phosphoric acid Salt 1.5%, Mono Isopropylamine 0.6%, xanthans 1.2%, calgon 1.8%, guaiacol 0.9%, lignin 1.4%, nitrous acid Sodium 1%, surplus are water.
Cyclodextrin molecular has the hollow cylinder three-dimensional ring structure tapered slightly, in its empty structure, outer upper end (Larger open end)It is made up of C2 and C3 secondary hydroxyl, lower end(Smaller opening end)It is made up of C6 primary hydroxyl, there is hydrophily, It is more by adding foam caused by gamma-cyclodextrin.3- sulfopropyl etradecyldimethylamines glycine betaine, lauryl alcohol polyoxy second Alkene ether phosphate is the foaming agent of the foam concentrate, and as a kind of nonionic surfactant, the foaming agent has frothing percentage The characteristics of high, caused foam uniform and smooth and stability are high.Guaiacol, Mono Isopropylamine, xanthans make caused foam Uniform and smooth and there is high stability.Natrium nitrosum uses as antifreezing agent, prevents from failing at low ambient temperatures.
The synergy that the present invention passes through each formula so that foaming capacity is strong, and foam stability is high.Foaming capacity is stronger, The gas release of unit mass depositing dust agent solution is bigger, and liquid film surface area is bigger, and dust-laying effect is better and efficiency is higher.Nothing of the present invention Poison, it is tasteless, to human body and environmentally friendly, non-secondary pollution.Dissolubility of the present invention is good, within a short period of time with regard to energy after being mixed with water It is configured to foam solution uniform, that property is stable.
Embodiment
Embodiment 1
A kind of anti-freeze type foam dedusting agent, it is made by following percentage by weight raw material:Double (2- second hexyl) sodium sulfo-succinates 2.5%th, cetylpyridinium chloride 0.8%, gamma-cyclodextrin 1.6%, 3- sulfopropyl etradecyldimethylamines glycine betaine 2.1%, 12 Alcohol polyoxyethylene ether phosphate 1.6%, Mono Isopropylamine 0.3%, xanthans 1.1%, calgon 1.9%, guaiacol 0.8%, wood Quality 1.4%, natrium nitrosum 0.9%, surplus are water.
Embodiment 2
A kind of anti-freeze type foam dedusting agent, it is made by following percentage by weight raw material:Double (2- second hexyl) sodium sulfo-succinates 3%, Cetylpyridinium chloride 0.4%, gamma-cyclodextrin 1.4-2%, 3- sulfopropyl etradecyldimethylamine glycine betaine 2.2%, lauryl alcohol gather Oxygen ethene ether phosphate 1.4%, Mono Isopropylamine 0.5%, xanthans 1.5%, calgon 1.7%, guaiacol 0.6%, lignin 1.8%th, natrium nitrosum 0.9%, surplus are water.
Embodiment 3
A kind of anti-freeze type foam dedusting agent, it is made by following percentage by weight raw material:Double (2- second hexyl) sodium sulfo-succinates 2.8%th, cetylpyridinium chloride 0.6%, gamma-cyclodextrin 1.8%, 3- sulfopropyl etradecyldimethylamines glycine betaine 2%, lauryl alcohol It is polyoxyethylene ether phosphate 1.5%, Mono Isopropylamine 0.6%, xanthans 1.2%, calgon 1.8%, guaiacol 0.9%, wooden Element 1.4%, natrium nitrosum 1%, surplus is water.
When prepared by above-mentioned dedusting agent, each raw material is mixed, you can.
Experiment:
Anti-freeze type foam dedusting agent obtained by selection example 1-3 is tested in the face of excavation operation everywhere in certain colliery.
The result of embodiment 1 is as shown in Table 1.
The result of embodiment 2 is as shown in Table 2.
The result of embodiment 3 is as shown in Table 3.
Traditional depositing dust result is as shown in Table 4.
Table one
Table two
Table three
Table four
The dust-laying effect of the embodiment of the present invention is substantially better than traditional depositing dust processing it can be seen from above table.
All above-mentioned this intellectual properties of primarily implementation, the not this new product of implementation of setting limitation other forms And/or new method.Those skilled in the art will utilize this important information, the above modification, to realize similar execution feelings Condition.But all modifications or transformation belong to the right of reservation based on new product of the present invention.
The above described is only a preferred embodiment of the present invention, being not the limitation for making other forms to the present invention, appoint What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc. Imitate embodiment.But it is every without departing from technical solution of the present invention content, the technical spirit according to the present invention is to above example institute Any simple modification, equivalent variations and the remodeling made, still fall within the protection domain of technical solution of the present invention.

Claims (4)

1. a kind of anti-freeze type foam dedusting agent, it is characterised in that be made by following percentage by weight raw material:Double (2- second hexyl) sulphurs Base sodium succinate 2.6%, cetylpyridinium chloride 0.5%, gamma-cyclodextrin 1.7%, 3- sulfopropyl etradecyldimethylamine glycine betaines 1.8%th, Dodecyl Polyoxyethylene Ether phosphate 1.4%, Mono Isopropylamine 0.5%, xanthans 0.9%, calgon 1.7%, guaiaci lignum Phenol 0.8%, lignin 1.5%, natrium nitrosum 0.6-1%, surplus are water.
2. a kind of anti-freeze type foam dedusting agent according to claim 1, it is characterised in that by following percentage by weight raw material It is made:Double (2- second hexyl) sodium sulfo-succinates 2.5%, cetylpyridinium chloride 0.8%, gamma-cyclodextrin 1.6%, 3- sulphurs third Base etradecyldimethylamine glycine betaine 2.1%, Dodecyl Polyoxyethylene Ether phosphate 1.6%, Mono Isopropylamine 0.3%, xanthans 1.1%, Calgon 1.9%, guaiacol 0.8%, lignin 1.4%, natrium nitrosum 0.9%, surplus are water.
3. a kind of anti-freeze type foam dedusting agent according to claim 1, it is characterised in that by following percentage by weight raw material It is made:Double (2- second hexyl) sodium sulfo-succinates 3%, cetylpyridinium chloride 0.4%, gamma-cyclodextrin 1.4-2%, 3- sulphur third Base etradecyldimethylamine glycine betaine 2.2%, Dodecyl Polyoxyethylene Ether phosphate 1.4%, Mono Isopropylamine 0.5%, xanthans 1.5%, Calgon 1.7%, guaiacol 0.6%, lignin 1.8%, natrium nitrosum 0.9%, surplus are water.
4. a kind of anti-freeze type foam dedusting agent according to claim 1, it is characterised in that by following percentage by weight raw material It is made:Double (2- second hexyl) sodium sulfo-succinates 2.8%, cetylpyridinium chloride 0.6%, gamma-cyclodextrin 1.8%, 3- sulphurs third Base etradecyldimethylamine glycine betaine 2%, Dodecyl Polyoxyethylene Ether phosphate 1.5%, Mono Isopropylamine 0.6%, xanthans 1.2%, six Sodium metaphosphate 1.8%, guaiacol 0.9%, lignin 1.4%, natrium nitrosum 1%, surplus are water.
CN201710531173.XA 2017-07-03 2017-07-03 A kind of anti-freeze type foam dedusting agent Pending CN107384317A (en)

Priority Applications (1)

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CN201710531173.XA CN107384317A (en) 2017-07-03 2017-07-03 A kind of anti-freeze type foam dedusting agent

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103114439A (en) * 2013-01-24 2013-05-22 量子高科(中国)生物股份有限公司 Non-woven fabric with biological regulation function and preparation method thereof
CN104531075A (en) * 2015-01-15 2015-04-22 山东科技大学 Mining dust removal foam generating agent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103114439A (en) * 2013-01-24 2013-05-22 量子高科(中国)生物股份有限公司 Non-woven fabric with biological regulation function and preparation method thereof
CN104531075A (en) * 2015-01-15 2015-04-22 山东科技大学 Mining dust removal foam generating agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
徐忠等: "《功能性变性淀粉》", 30 April 2010, 中国轻工业出版社 *

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