CN107384158A - A kind of insulating coating for high-tension switch cabinet - Google Patents

A kind of insulating coating for high-tension switch cabinet Download PDF

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Publication number
CN107384158A
CN107384158A CN201710646460.5A CN201710646460A CN107384158A CN 107384158 A CN107384158 A CN 107384158A CN 201710646460 A CN201710646460 A CN 201710646460A CN 107384158 A CN107384158 A CN 107384158A
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CN
China
Prior art keywords
parts
oil
modified alkyd
insulating coating
alkyd resin
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710646460.5A
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Chinese (zh)
Inventor
王铮
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Wuxi Yongxing Metal Hose Co Ltd
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Wuxi Yongxing Metal Hose Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Wuxi Yongxing Metal Hose Co Ltd filed Critical Wuxi Yongxing Metal Hose Co Ltd
Priority to CN201710646460.5A priority Critical patent/CN107384158A/en
Publication of CN107384158A publication Critical patent/CN107384158A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a kind of insulating coating for high-tension switch cabinet.The insulating coating includes the following component counted in parts by weight:150 220 parts of nitrocotton, 340 570 parts of oil-modified alkyd resin, 120 180 parts of dimethyl terephthalate (DMT), 24 58 parts of zinc oxide, 150 230 parts of amino resins, 18 parts of drier, 20 47 parts of 604 epoxy resin, 10 42 parts of titanium dioxide, 10 24 parts of solid levelling agent, 15 parts of dispersant, 0.1 0.8 parts of organic silicone oil, 1 10 parts of auxiliary agent, 12 32 parts of vulcanizing agent;The oil-modified alkyd resin is made up of castor oil, ethanedioic acid, hydrophilic macromolecular compounds and water.Insulating coating of the present invention has preferable adhesive force, weatherability and arc resistance, is suitable for the coating as high-tension switch cabinet, effectively prevent the safety of electric arc influence cabinet caused by short circuit.

Description

A kind of insulating coating for high-tension switch cabinet
Technical field
The invention belongs to electrical equipment manufacturing technology field, and in particular to a kind of insulating coating for high-tension switch cabinet.
Background technology
High-tension switch cabinet refers to be used for play break-make, control in power system generating, transmission of electricity, distribution, electric energy conversion and consumption Or the effect such as protection, high-tension switch cabinet are opened by electric equipment products of the voltage class in 3.6-550kV, high voltage isolator is made in ground connection Pass, high voltage load switch, high pressure automatic reclosing and sectionaliser, high-voltage actuating mechanism, high voltage explosion-proof power distribution device and high-voltage switch gear Several major classes such as cabinet.
Application number 201010593984.0, entitled electric insulation coating layer, coat system and method.Specifically, a kind of electricity is exhausted Edge coating, for minimizing the conductance of metal substrate, the electric insulation coating layer includes:Component of polymer, it is by monomer forerunner Body is formed;And powdered ingredients, its essence are dispersed in the component of polymer.The powder present in the electric insulation coating layer The amount of composition is:For the electric insulation coating layer of every 100 parts of weight, the weight from about 5 parts to about 80 parts.Arrived about when at about -50 DEG C 500 DEG C when being exposed to about 100V to about 330V, the electric insulation coating layer does not fail substantially.The dielectric strength of the electric insulation coating layer At least per the voltsalternating of mil about 2000.But powdered ingredients easily come off, cause insulating coating unbalanced.
Application number 201310726543.7, title include metal for a kind of Corona roller and preparation method thereof, the Corona roller Roller and the coating being coated on metal roller, wherein, the coating is made up of polysiloxane composition, the polysiloxanes group Compound includes polysiloxanes 40-60%, white carbon 20-40%, diatomite 5-20%, silica flour 2-8%, vulcanizing agent 1-5%, anti- Electrostatic agent 1-4%.Corona roller provided by the invention has fabulous electrical insulating property, arc resistance, Inverter fed motor and anti-flammability, has Preferable corona effects, reverse side corona will not be produced, the most satisfied requirement of client can be reached.With silicone materials under long term high temperature It is poor for coating adhesion, have much room for improvement.
The content of the invention
It is an object of the invention to provide a kind of insulating coating for high-tension switch cabinet, the coating adhesion is strong, dries It hurry up, are-tight property is good.
A kind of insulating coating for high-tension switch cabinet, including the following component counted in parts by weight:Nitrocotton 150-220 Part, oil-modified alkyd resin 340-570 parts, dimethyl terephthalate (DMT) 120-180 parts, zinc oxide 24-58 parts, amino resins It is 150-230 parts, drier 1-8 parts, 604 epoxy resin 20-47 parts, titanium dioxide 10-42 parts, solid levelling agent 10-24 parts, scattered Agent 1-5 parts, organic silicone oil 0.1-0.8 parts, auxiliary agent 1-10 parts, vulcanizing agent 12-32 parts;The oil-modified alkyd resin is by castor-oil plant Oil, ethanedioic acid, hydrophilic macromolecular compounds and water composition.
It is as improved, the above-mentioned insulating coating for high-tension switch cabinet, including the following component counted in parts by weight: 200 parts of nitrocotton, 420 parts of oil-modified alkyd resin, 158 parts of dimethyl terephthalate (DMT), 45 parts of zinc oxide, amino resins 201 Part, 4 parts of drier, 28 parts of 604 epoxy resin, 28 parts of titanium dioxide, 17 parts of solid levelling agent, 4 parts of dispersant, organic silicone oil 0.5 Part, 4 parts of auxiliary agent, 25 parts of vulcanizing agent.
It is that castor oil accounts for the 12-40% of oil-modified alkyd resin dry weight in the oil-modified alkyd resin as improved, The ethanedioic acid accounts for the 10-20% of oil-modified alkyd resin dry weight, and the hydrophilic macromolecular compounds account for oil-modified alkyd tree The 2-10% of fat dry weight.
It is that the hydrophilic macromolecular compounds are the condensation product of acrylic acid and glycerine as improved.
It is that the vulcanizing agent is double-(2,4- dichlorobenzoperoxide) as improved.
Alkyd resin viscosity is high, must could be dissolved with aromatic hydrocarbon solvent.The alkyd resin is made paint and uses spraying or dip-coating, Do not have to preferably brush.At room temperature can autoxidation dry, it is soft general towards property from dry functional, there is good glossiness, protect Light colour retention, weatherability, rate of drying are very fast.Oil-modified alkyd resin after modification can be able to height from dryness, be advantageous to Coating rapid-curing cutback.
It is specifically, existing by nitrocotton, oil-modified alkyd resin, dimethyl terephthalate (DMT), amino resins, 604 asphalt mixtures modified by epoxy resin In fat, titanium dioxide input reactor, 300-500 DEG C is heated to, reacts 10-20min, then add zinc oxide, drier, efflux of solids Flat agent, dispersant, organic silicone oil, auxiliary agent and vulcanizing agent, it is ultrasonically treated insulating coating after 10-15min.
Beneficial effect:
Compared with prior art, insulating coating of the present invention has preferable adhesive force, weatherability and arc resistance, is adapted to use In the coating as high-tension switch cabinet, the safety of electric arc influence cabinet caused by short circuit effectively prevent.
Embodiment
The present invention is further described in detail below by specific embodiment.
Embodiment 1
A kind of insulating coating for high-tension switch cabinet, including the following component counted in parts by weight:150 parts of nitrocotton, 340 parts of oil-modified alkyd resin, 120 parts of dimethyl terephthalate (DMT), 24 parts of zinc oxide, 150 parts of amino resins, 1 part of drier, 604 20 parts of epoxy resin, 10 parts of titanium dioxide, 10 parts of solid levelling agent, 1 part of dispersant, 0.1 part of organic silicone oil, 1 part of auxiliary agent, sulphur 12 parts of agent;The oil-modified alkyd resin is made up of castor oil, ethanedioic acid, hydrophilic macromolecular compounds and water.
Wherein, castor oil accounts for the 12% of oil-modified alkyd resin dry weight in the oil-modified alkyd resin, the ethanedioic acid The 10% of oil-modified alkyd resin dry weight is accounted for, the hydrophilic macromolecular compounds account for the 2% of oil-modified alkyd resin dry weight.
The hydrophilic macromolecular compounds are the condensation product of acrylic acid and glycerine.
The vulcanizing agent is double-(2,4- dichlorobenzoperoxide).
Embodiment 2
A kind of insulating coating for high-tension switch cabinet, including the following component counted in parts by weight:200 parts of nitrocotton, 420 parts of oil-modified alkyd resin, 158 parts of dimethyl terephthalate (DMT), 45 parts of zinc oxide, 201 parts of amino resins, 4 parts of drier, 604 28 parts of epoxy resin, 28 parts of titanium dioxide, 17 parts of solid levelling agent, 4 parts of dispersant, 0.5 part of organic silicone oil, 4 parts of auxiliary agent, sulphur 25 parts of agent.
Wherein, castor oil accounts for the 24% of oil-modified alkyd resin dry weight in the oil-modified alkyd resin, the ethanedioic acid The 14% of oil-modified alkyd resin dry weight is accounted for, the hydrophilic macromolecular compounds account for the 8% of oil-modified alkyd resin dry weight.
The hydrophilic macromolecular compounds are the condensation product of acrylic acid and glycerine.
The vulcanizing agent is double-(2,4- dichlorobenzoperoxide).
Embodiment 3
A kind of insulating coating for high-tension switch cabinet, including the following component counted in parts by weight:220 parts of nitrocotton, 570 parts of oil-modified alkyd resin, 180 parts of dimethyl terephthalate (DMT), 58 parts of zinc oxide, 230 parts of amino resins, 8 parts of drier, 604 47 parts of epoxy resin, 42 parts of titanium dioxide, 24 parts of solid levelling agent, 5 parts of dispersant, 0.8 part of organic silicone oil, 10 parts of auxiliary agent, sulphur 32 parts of agent;The oil-modified alkyd resin is made up of castor oil, ethanedioic acid, hydrophilic macromolecular compounds and water.
Wherein, castor oil accounts for the 40% of oil-modified alkyd resin dry weight in the oil-modified alkyd resin, the ethanedioic acid The 20% of oil-modified alkyd resin dry weight is accounted for, the hydrophilic macromolecular compounds account for the 10% of oil-modified alkyd resin dry weight.
The hydrophilic macromolecular compounds are the condensation product of acrylic acid and glycerine.
The vulcanizing agent is double-(2,4- dichlorobenzoperoxide).
Are-tight property is used for evaluating insulating materials its insulating properties after arcing.
Comparative example
A kind of insulating coating for high-tension switch cabinet, including the following component counted in parts by weight:200 parts of nitrocotton, 420 parts of alkyd resin, 158 parts of dimethyl terephthalate (DMT), 45 parts of zinc oxide, 201 parts of amino resins, 4 parts of drier, 604 rings 28 parts of oxygen tree fat, 28 parts of titanium dioxide, 17 parts of solid levelling agent, 4 parts of dispersant, 0.5 part of organic silicone oil, 4 parts of auxiliary agent, vulcanizing agent 25 Part.
Wherein, ethanedioic acid described in the alkyd resin accounts for the 14% of oil-modified alkyd resin dry weight, and the hydrophily is high Molecular compound accounts for the 8% of oil-modified alkyd resin dry weight.
The hydrophilic macromolecular compounds are the condensation product of acrylic acid and glycerine,.
The vulcanizing agent is double-(2,4- dichlorobenzoperoxide).
Embodiment 1-3 and comparative example 1 insulating coating are detected, the data obtained is as shown in the table.
In addition, the invention is not restricted to above-mentioned embodiment, as long as in without departing from the scope of the present invention, can take various Mode implements the present invention.

Claims (5)

1. a kind of insulating coating for high-tension switch cabinet, it is characterised in that including the following component counted in parts by weight:Nitrification Cotton 150-220 parts, oil-modified alkyd resin 340-570 parts, dimethyl terephthalate (DMT) 120-180 parts, zinc oxide 24-58 parts, Amino resins 150-230 parts, drier 1-8 parts, 604 epoxy resin 20-47 parts, titanium dioxide 10-42 parts, solid levelling agent 10- 24 parts, dispersant 1-5 parts, organic silicone oil 0.1-0.8 parts, auxiliary agent 1-10 parts, vulcanizing agent 12-32 parts;The oil-modified alkyd tree Fat is made up of castor oil, ethanedioic acid, hydrophilic macromolecular compounds and water.
2. a kind of insulating coating for high-tension switch cabinet according to claim 1, it is characterised in that including below by weight Measure the component of number meter:200 parts of nitrocotton, 420 parts of oil-modified alkyd resin, 158 parts of dimethyl terephthalate (DMT), zinc oxide 45 Part, 201 parts of amino resins, 4 parts of drier, 28 parts of 604 epoxy resin, 28 parts of titanium dioxide, 17 parts of solid levelling agent, dispersant 4 Part, 0.5 part of organic silicone oil, 4 parts of auxiliary agent, 25 parts of vulcanizing agent.
A kind of 3. insulating coating for high-tension switch cabinet according to claim 1, it is characterised in that the modified alcohol of oil Castor oil accounts for the 12-40% of oil-modified alkyd resin dry weight in acid resin, and the ethanedioic acid accounts for oil-modified alkyd resin dry weight 10-20%, the hydrophilic macromolecular compounds account for the 2-10% of oil-modified alkyd resin dry weight.
4. according to a kind of insulating coating for high-tension switch cabinet described in claim 1,2 or 3, it is characterised in that the parent Aqueous high molecular compound is the condensation product of acrylic acid and glycerine.
A kind of 5. insulating coating for high-tension switch cabinet according to claim 1 or 2, it is characterised in that the vulcanization Agent is double-(2,4- dichlorobenzoperoxide).
CN201710646460.5A 2017-07-31 2017-07-31 A kind of insulating coating for high-tension switch cabinet Pending CN107384158A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710646460.5A CN107384158A (en) 2017-07-31 2017-07-31 A kind of insulating coating for high-tension switch cabinet

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Application Number Priority Date Filing Date Title
CN201710646460.5A CN107384158A (en) 2017-07-31 2017-07-31 A kind of insulating coating for high-tension switch cabinet

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CN107384158A true CN107384158A (en) 2017-11-24

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110093603A (en) * 2019-03-27 2019-08-06 广东求精电气有限公司 A kind of coating method of high-tension switch cabinet metal base

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030195292A1 (en) * 2002-04-12 2003-10-16 Thauming Kuo Waterborne acrylate-functionalized alkyd coating compositions
CN105622909A (en) * 2016-03-01 2016-06-01 湖南沃特邦恩新材料有限公司 Preparation method and application of waterborne alkyd resin

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030195292A1 (en) * 2002-04-12 2003-10-16 Thauming Kuo Waterborne acrylate-functionalized alkyd coating compositions
CN105622909A (en) * 2016-03-01 2016-06-01 湖南沃特邦恩新材料有限公司 Preparation method and application of waterborne alkyd resin

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110093603A (en) * 2019-03-27 2019-08-06 广东求精电气有限公司 A kind of coating method of high-tension switch cabinet metal base

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Application publication date: 20171124

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