CN107384020A - A kind of oil base ink for engineering blueprint printing and preparation method thereof - Google Patents
A kind of oil base ink for engineering blueprint printing and preparation method thereof Download PDFInfo
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- CN107384020A CN107384020A CN201710784739.XA CN201710784739A CN107384020A CN 107384020 A CN107384020 A CN 107384020A CN 201710784739 A CN201710784739 A CN 201710784739A CN 107384020 A CN107384020 A CN 107384020A
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- oil base
- base ink
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- paliogen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of oil base ink for engineering blueprint printing and preparation method thereof, belong to digital ink-jet technical field.The oil base ink includes following component by mass percentage：Alkane solvent 60~80%, volatilization prevention auxiliary agent 5~20%, dispersant 3~15%, levelling agent 0.1~1%, pigment 3~20%.The preparation method of the present invention is as follows：Other components by more than in addition to pigments are put into dispersion cylinder successively, and stirring 20min is until material is uniform；Pigment is slowly added under stirring, disperses 30~60min after the completion of batch mixing until well mixed；Scattered mixed liquor is ground to particle diameter D50 and is less than 150nm, the mixed liquor after grinding is subjected to centrifugation decontamination, filters and produces.Oil base ink obtained by the present invention is applied to sharp keen clear, fast light, water-fast, the resistance to wiping of finished product blueprint word lines obtained in engineering blueprint printing, can fully meet use demand, final product quality is excellent.
Description
Technical field
The present invention relates to digital ink-jet technical field, and in particular to it is a kind of for engineering blueprint printing oil base ink and its
Preparation method.
Background technology
Engineering blueprint drawing is in the R ＆ D design work in the fields such as machinery, building using quite extensive, engineering blueprint figure
Paper is during the storage of archives, the advantages of having the holding time long, and can avoid drawing by illegal modifications.
The conventional fabrication method of engineering blueprint is mainly diazol imaging method, and about invention is in early stage in 19th century, gradual quilt afterwards
It is widely used, turn into technique the most frequently used during blueprint.Diazol imaging method is made drawing and dark line is showed in white background
Bar, its operating process are as follows：1st, photosensitizer：Paper is carried out with the mixture of diazol (being used to dyestuff manufacture), reactant and acid
Photosensitizer, wherein the effect of acid is to prevent from reacting between diazol and reactant；2nd, expose：Translucent artwork is placed in
It is exposed above light-sensitive paper, the diazol of photosensitive part is because illumination decomposes, the compound in unexposed region during exposure
Do not decompose；3rd, develop：After exposure, then with ammonia or ammoniacal liquor developer is made, acid is neutralized so that remaining diazol can be with
Reactant combines to form blue dyes.Thus it has been made and artwork size identical copy.Though diazol imaging method is extensive
Use, but complex process be present, fabrication cycle length, the problem of definition is not high.With development in science and technology, the indigo plant of traditional diazol
Figure makes gradually to be substituted by laser blueprint printing technique.In order to adapt to the development of laser blueprint printing technique, people develop
Various ink powders applied to laser blueprint engineering machine.But use ink powder general as the consumptive material that laser blueprint prints
It is to supply to use in the form of toner cartridge, it is with high costs, after single toner cartridge has used, it is difficult to recycle, substantial amounts of resource can be caused
Waste and environmental pollution；In addition, toner cartridge size is directly connected to price, that is to say, that its bigger cost of toner cartridge size is more
Height, current existing blueprint ink powder maximum can only print No. 0 drawing, it is impossible to meet bigger engineering blueprint printing wide cut demand.
The content of the invention
For overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of oil base for engineering blueprint printing
Ink and preparation method thereof, the finished product blueprint word lines that the oil base ink of the present invention is applied to obtain in engineering blueprint printing
Sharp keen clear, fast light, water-fast, resistance to wiping, can fully meet use demand, final product quality is excellent.
To solve the above problems, the technical solution adopted in the present invention is as follows：
A kind of oil base ink for engineering blueprint printing, it includes following component by mass percentage：
As the preferred embodiment of the present invention, oil base ink of the invention includes following group by mass percentage
Point：
In being formulated above, alkane solvent is the main body being entirely formulated, and is closed for adjusting ink viscosity, having oil base ink
Suitable permeating volatile speed, while be also the decentralized medium of pigment.Preferably, the alkane solvent is nonane, certain herbaceous plants with big flowers alkane, 11
Alkane, dodecane, tridecane, the tetradecane, pentadecane, hexadecane, heptadecane, octadecane, nonadecane, eicosane, 200# solvent naphthas
In one kind or any two or more combination.
Volatilization prevention solvent be mainly used in preventing ink volatilization is too fast, cause in standby dry head and make printing broken string,
Slack problem.Preferably, the volatilization prevention auxiliary agent is preferably methyl ethyl ketoxime.
Dispersant can be such that pigment stabilizer is homogeneously dispersed in medium, can ensure granules of pigments in the ink shelf-life
All the time nano-scale particle is in, it is not anti-thick, do not flocculate.Preferably, the dispersant is preferably German Byk Chemie GmbH
BYK21222, Disuper S25, Anshan brightness rainbow new material chemical industry of Shanghai Core New Materials Technology Co., Ltd.'s production of production
HP1059, HP1060, HP1062, HP1064, HP1082, Lu Borun additive Co., Ltd production of Co., Ltd's production
One kind or any two or more combination in 909.
Levelling agent is used for the surface tension for adjusting ink, makes print procedure smooth stable, image is sharp keen clear.Preferably,
The levelling agent is one or any two in BYK333, BYK307, BYK378 of the production of German Byk Chemie GmbH
The combination of the kind above.
Pigment is the colouring agent in ink, and it assigns the different color of ink and met customer need, and is used in formula
Pigment belongs to high durable pigment, and not only bright-colored, tinting strength, tinting power is excellent, and fast light water-fast, is fully able to meet engineer's blue
The requirement of figure.Preferably, the pigment is that call number is PB60, PB15:6、PB15:3、PB15:2、PB15:1 blue pigment,
Call number is PR122 red pigment, and the violet pigment of call number PV19, PV23, call number is PBK7 black pigment.
As the preferred embodiment of the present invention, the model of the pigment is preferably：The production of BASF joint-stock company
Paliogen L6360、Paliogen L6385、Paliogen L6480、Paliogen L6495F、Heliogen L6700F、
Heliogen L6870、Heliogen L6900、Irgalite Blue GLO、Irgalite Blue GLVO；Clariant chemical industry
PINK E, the E5B02 of Co., Ltd's production；ML, ME of Cabot Co., Ltd of U.S. production.
Present invention also offers a kind of preparation method of the oil base ink for engineering blueprint printing, it includes following step
Suddenly：
1) other components by more than in addition to pigments are put into dispersion cylinder successively, and 20min is stirred under 200~500r/min
Until material is uniform；
2) pigment is slowly added under 200r/min stirring, it is 800~1200r/ to adjust rotating speed after the completion of batch mixing
Min disperses 30~60min until well mixed；
3) scattered mixed liquor is delivered to sand mill it is ground to particle diameter D50 and be less than 150nm, by the mixed liquor after grinding
It is delivered in centrifuge and carries out centrifugation decontamination, is then filtered, produced with 0.5 μm of filter paper.
As the preferred embodiment of the present invention, the design parameter of centrifugation is arranged in the step 3)：Flow 20~
50L/h, rotating speed are 5000~20000r/min.
Compared with prior art, the beneficial effects of the present invention are：
Oil base ink set of the present invention for engineering blueprint printing is reasonable in design, and preparation method is simple, application
, can not only be complete in sharp keen clear, fast light, water-fast, the resistance to wiping of finished product blueprint word lines obtained in engineering blueprint printing
Meet use demand, the printout good quality of engineering blueprint, and be advantageous to extend the archives preservation time of engineering blueprint.
Compared to traditional diazol imaging method, oil base ink process of the invention is simple, fabrication cycle is short, eliminates traditional handicraft
Links, operating efficiency is drastically increased, materials environmental protection, pollution will not be produced during production or use, and beat
It is high to print definition；Printed compared to existing ink powder toner cartridge, cost is cheap, and the substantial amounts of wasting of resources and environment will not be caused dirty
Dye, while sharp keen clearly printing effect is ensured, printing wide cut is unrestricted, can meet work more than No. 0 paper well
Journey blueprint prints wide cut demand.
Brief description of the drawings
Fig. 1 is that the engineering blueprint of embodiment 1 of the present invention prints pattern；
Fig. 2 is that the engineering blueprint of embodiment 2 of the present invention prints pattern；
Fig. 3 is that the engineering blueprint of embodiment 3 of the present invention prints pattern；
Fig. 4 is that the engineering blueprint of embodiment 4 of the present invention prints pattern；
Fig. 5 is that the engineering blueprint of comparative example of the present invention prints pattern.
Embodiment
The present invention is described in further detail with reference to embodiment.
A kind of oil base ink for engineering blueprint printing, it includes following component by mass percentage：
Wherein, alkane solvent is nonane, certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, the tetradecane, pentadecane, hexadecane, ten
Seven alkane, octadecane, nonadecane, eicosane, one kind in 200# solvent naphthas or any two or more combination.Volatilization prevention auxiliary agent is excellent
Elect methyl ethyl ketoxime as.Dispersant is preferably the BYK21222 of German Byk Chemie GmbH's production, Shanghai core new material section
Skill Co., Ltd production Disuper S25, Anshan Hui Hong new materials Chemical Co., Ltd. production HP1059, HP1060,
One kind or any two or more group in the 909 of HP1062, HP1064, HP1082, Lu Borun additive Co., Ltd production
Close.Levelling agent is one or any two kinds in BYK333, BYK307, BYK378 of the production of German Byk Chemie GmbH
Combination above.Pigment is that call number is PB60, PB15:6、PB15:3、PB15:2、PB15:1 blue pigment, call number are
PR122 red pigment, the violet pigment of call number PV19, PV23, call number are PBK7 black pigment.Preferably, face
The concrete model of material is：Paliogen L6360, Paliogen L6385, the Paliogen of BASF joint-stock company production
L6480、Paliogen L6495F、Heliogen L6700F、Heliogen L6870、Heliogen L6900、Irgalite
Blue GLO、Irgalite Blue GLVO；PINK E, the E5B02 of Clariant Chemical Co., Ltd. production；U.S.'s Cabot is public
Take charge of ML, ME of production.
The preparation method of oil base ink of the present invention comprises the following steps：
1) other components by more than in addition to pigments are put into dispersion cylinder successively, and 20min is stirred under 200~500r/min
Until material is uniform；
2) pigment is slowly added under 200r/min stirring, it is 800~1200r/ to adjust rotating speed after the completion of batch mixing
Min disperses 30~60min until well mixed；
3) scattered mixed liquor is delivered to sand mill it is ground to particle diameter D50 and be less than 150nm, by the mixed liquor after grinding
It is delivered in centrifuge and carries out centrifugation decontamination, the design parameter of centrifugation is arranged to：20~50L/h of flow, rotating speed be 5000~
20000r/min, then filtered, produced with 0.5 μm of filter paper.
Embodiment 1：
A kind of oil base ink for engineering blueprint printing, it includes following each component by mass percentage：
The preparation method of the oil base ink is as follows：
Other components by more than in addition to pigment Paliogen L6360 are put into dispersion cylinder successively, and adjustment rotating speed is
500r/min, stirring 20min are until material is uniform；Pigment Paliogen is slowly added under 200r/min stirring
L6360, it is that 1200r/min disperses 45min until well mixed that rotating speed is adjusted after the completion of batch mixing；Scattered mixed liquor is conveyed
Particle diameter D50 is ground to sand mill and is less than 150nm, and the mixed liquor after grinding is delivered in centrifuge and carries out centrifugation decontamination,
The design parameter of centrifugation is arranged to：Flow 35L/h, rotating speed 12000r/min, then filtered, produced with 0.5 μm of filter paper.
Embodiment 2：
A kind of oil base ink for engineering blueprint printing, it includes following each component by mass percentage：
The preparation method of the oil base ink is as follows：
Other components by more than in addition to pigment Paliogen L6360 are put into dispersion cylinder successively, and adjustment rotating speed is
200r/min, stirring 20min are until material is uniform；Pigment Paliogen is slowly added under 200r/min stirring
L6360, it is that 800r/min disperses 30min until well mixed that rotating speed is adjusted after the completion of batch mixing；Scattered mixed liquor is conveyed
Particle diameter D50 is ground to sand mill and is less than 150nm, and the mixed liquor after grinding is delivered in centrifuge and carries out centrifugation decontamination,
The design parameter of centrifugation is arranged to：Flow 40L/h, rotating speed 15000r/min, then filtered, produced with 0.5 μm of filter paper.
Embodiment 3：
A kind of oil base ink for engineering blueprint printing, it includes following each component by mass percentage：
The preparation method of the oil base ink is as follows：
Other components by more than in addition to pigment Paliogen L6360 are put into dispersion cylinder successively, and adjustment rotating speed is
400r/min, stirring 20min are until material is uniform；Pigment Paliogen is slowly added under 200r/min stirring
L6360, it is that 1000r/min disperses 50min until well mixed that rotating speed is adjusted after the completion of batch mixing；Scattered mixed liquor is conveyed
Particle diameter D50 is ground to sand mill and is less than 150nm, and the mixed liquor after grinding is delivered in centrifuge and carries out centrifugation decontamination,
The design parameter of centrifugation is arranged to：Flow 50L/h, rotating speed 20000r/min, then filtered, produced with 0.5 μm of filter paper.
Embodiment 4：
A kind of oil base ink for engineering blueprint printing, it includes following each component by mass percentage：
The preparation method of the oil base ink is as follows：
Other components by more than in addition to pigment Paliogen L6360 are put into dispersion cylinder successively, and adjustment rotating speed is
300r/min, stirring 20min are until material is uniform；Pigment Paliogen is slowly added under 200r/min stirring
L6360, it is that 900r/min disperses 50min until well mixed that rotating speed is adjusted after the completion of batch mixing；Scattered mixed liquor is conveyed
Particle diameter D50 is ground to sand mill and is less than 150nm, and the mixed liquor after grinding is delivered in centrifuge and carries out centrifugation decontamination,
The design parameter of centrifugation is arranged to：Flow 20L/h, rotating speed 5000r/min, then filtered, produced with 0.5 μm of filter paper.
Compliance test result：
In order to verify the beneficial effect of oil base ink of the present invention, viscosity, tension force are carried out to the oil base ink of embodiment 1~4
Tested etc. ink performance, engineering blueprint print performance is carried out to having a competition using the oil base ink of embodiment 1~4 and common ink powder
Test, as a result as shown in table 1, Fig. 1~Fig. 5.
As shown in Table 1, product stability of the present invention is excellent, can not only fully meet the use demand of engineering blueprint, beat
It is printed as that quality is excellent, and is advantageous to extend the archives preservation time of engineering blueprint；And for more traditional printing technology, effect
Rate is greatly improved, while also has more excellent printing definition, water resistance, light resistance, resistance to wiping, can be very
Meet the printing requirement of engineering blueprint well, in addition using the more environmentally-friendly energy-conservation of digital ink-jet technique fabrication blueprint, this hair
Bright described oil base ink has excellent market promotion prospect in engineering blueprint printing field.
The oil base ink of table 1 contrasts with common ink powder print performance
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this,
The change and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed scope.
Claims (10)
- A kind of 1. oil base ink for engineering blueprint printing, it is characterised in that：Including following component by mass percentage：
- 2. oil base ink according to claim 1, it is characterised in that：Including following component by mass percentage：
- 3. oil base ink according to claim 1 or 2, it is characterised in that：The alkane solvent is nonane, certain herbaceous plants with big flowers alkane, 11 Alkane, dodecane, tridecane, the tetradecane, pentadecane, hexadecane, heptadecane, octadecane, nonadecane, eicosane, 200# solvent naphthas In one kind or any two or more combination.
- 4. oil base ink according to claim 1 or 2, it is characterised in that：The volatilization prevention auxiliary agent is preferably methyl ethyl ketoxime.
- 5. oil base ink according to claim 1 or 2, it is characterised in that：The dispersant be preferably BYK21222, Disuper S25, one kind in HP1059, HP1060, HP1062, HP1064, HP1082, Lu Borun 909 or it is any two kinds with On combination.
- 6. oil base ink according to claim 1 or 2, it is characterised in that：The levelling agent be BYK333, BYK307, One or any two or more combination in BYK378.
- 7. oil base ink according to claim 1 or 2, it is characterised in that：The pigment is that call number is PB60, PB15: 6、PB15:3、PB15:2、PB15:1 blue pigment, call number are PR122 red pigment, call number PV19, PV23 Violet pigment, call number are PBK7 black pigment.
- 8. oil base ink according to claim 7, it is characterised in that：The model of the pigment is preferably：BASF share Company production Paliogen L6360, Paliogen L6385, Paliogen L6480, Paliogen L6495F, Heliogen L6700F、Heliogen L6870、Heliogen L6900、Irgalite Blue GLO、Irgalite Blue GLVO；PINK E, the E5B02 of Clariant Chemical Co., Ltd. production；ML, ME of Cabot Co., Ltd of U.S. production.
- A kind of 9. preparation method of oil base ink for engineering blueprint printing, it is characterised in that：Comprise the following steps：1) other components in addition to pigments are put into dispersion cylinder successively by more than, stir 20min under 200~500r/min until Material is uniform；2) pigment is slowly added under rotating speed 200r/min stirring, it is 800~1200r/ to adjust rotating speed after the completion of batch mixing Min disperses 30~60min until well mixed；3) scattered mixed liquor is delivered to sand mill it is ground to particle diameter D50 and be less than 150nm, the mixed liquor after grinding is conveyed Centrifugation decontamination is carried out into centrifuge, is then filtered, produced with 0.5 μm of filter paper.
- 10. preparation method according to claim 9, it is characterised in that：The design parameter of centrifugation is set in the step 3) For：20~50L/h of flow, rotating speed are 5000~20000r/min.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710784739.XA CN107384020A (en) | 2017-09-04 | 2017-09-04 | A kind of oil base ink for engineering blueprint printing and preparation method thereof |
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| CN201710784739.XA CN107384020A (en) | 2017-09-04 | 2017-09-04 | A kind of oil base ink for engineering blueprint printing and preparation method thereof |
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| CN107384020A true CN107384020A (en) | 2017-11-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710784739.XA Pending CN107384020A (en) | 2017-09-04 | 2017-09-04 | A kind of oil base ink for engineering blueprint printing and preparation method thereof |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1310748A (en) * | 1999-05-20 | 2001-08-29 | 阪田油墨株式会社 | Oil-based ink for ink-jet recording |
-
2017
- 2017-09-04 CN CN201710784739.XA patent/CN107384020A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1310748A (en) * | 1999-05-20 | 2001-08-29 | 阪田油墨株式会社 | Oil-based ink for ink-jet recording |
Non-Patent Citations (2)
| Title |
|---|
| 凌云星等: "《油墨技术手册 （上）》", 31 May 2009 * |
| 藏广州: "《凹版印刷技术分册 上册》", 30 November 2003, 安徽音像出版社 * |
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Application publication date: 20171124 |