CN107383821A - For manufacturing material covered in battery bag and preparation method thereof - Google Patents

For manufacturing material covered in battery bag and preparation method thereof Download PDF

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Publication number
CN107383821A
CN107383821A CN201710583820.1A CN201710583820A CN107383821A CN 107383821 A CN107383821 A CN 107383821A CN 201710583820 A CN201710583820 A CN 201710583820A CN 107383821 A CN107383821 A CN 107383821A
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CN
China
Prior art keywords
weight
parts
battery bag
covered
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710583820.1A
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Chinese (zh)
Inventor
陈朝
周战全
公茂利
彭飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Leeg Automotive Lightweight Technology Development Co Ltd
Original Assignee
Hebei Leeg Automotive Lightweight Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hebei Leeg Automotive Lightweight Technology Development Co Ltd filed Critical Hebei Leeg Automotive Lightweight Technology Development Co Ltd
Priority to CN201710583820.1A priority Critical patent/CN107383821A/en
Publication of CN107383821A publication Critical patent/CN107383821A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/06Unsaturated polyesters
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/147Lids or covers
    • H01M50/155Lids or covers characterised by the material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of for manufacturing material covered in battery bag and preparation method thereof, preparing the formula composition of the material includes the parts by weight of resin material 345, the parts by weight of initiator 6, the parts by weight of wetting dispersing agent 5, the parts by weight of releasing agent 12, the parts by weight of polymerization inhibitor 0.5, the parts by weight of filler 600, the parts by weight of thickener 9.1, the parts by weight of reinforcing material 326.Preparing the method for the material includes batch mixing, prepares the steps such as sheet material, thickening.Material provided by the present invention has many advantages, such as density is small, corrosion-resistant, fire resistance is good; traditional sheet metal component is substituted to be used for manufacturing covering in battery bag; the lightweight covered in battery bag can be realized, improves the efficiency of electric automobile, finally realizes energy-saving and emission-reduction, the target of environmental protection.

Description

For manufacturing material covered in battery bag and preparation method thereof
Technical field
The present invention relates to a kind of new material, and in particular to a kind of to can be used in manufacturing the material covered in battery bag and its preparation Method.
Background technology
Explosive growth is presented in China's new-energy automobile in 2015, annual production 37.9 ten thousand, increases by 3.5 times on a year-on-year basis, China Also the developing market of the maximum new-energy automobile in the whole world is turned into.In the coming five years whole nation, new-energy automobile will be possessed up to 5,000,000 Under the expection of the policy goals of amount, it is contemplated that new-energy automobile yield will keep about 40% year compound increasing before to the year two thousand twenty Speed, continue the high growth impetus.
New-energy automobile is mainly electric automobile at present, and the maximum part of electric automobile most critical, shared component is exactly electricity Pond, it may be said that the development of new-energy automobile is the development of battery in fact.But the development of battery runs into bottleneck at this stage, it is difficult to Mitigate its component in a short time, and lid quality is also larger in the battery bag based on sheet metal component, the loss of weight of such battery bag is just aobvious It is particularly important.
The content of the invention
It is used to manufacturing the upper lid of battery bag it is an object of the invention to provide a kind of new material, it is the intensity of the material, fire-retardant The properties such as property, water imbibition can compare favourably with sheet metal component, and quality is but well below sheet metal component.
To achieve these goals, following technical scheme is inventor provided.
For manufacturing the material covered in battery bag, the formula composition of the material is:The parts by weight of resin material 345, trigger The parts by weight of agent 6, the parts by weight of wetting dispersing agent 5, the parts by weight of releasing agent 12, the parts by weight of polymerization inhibitor 0.5, the parts by weight of filler 600, thickening The parts by weight of agent 9.1, the parts by weight of reinforcing material 326.
Preferably, above-mentioned to be used to manufacture the material covered in battery bag, the resin material is unsaturated polyester resin, polyethers The mixture of sulphone resin and polyvinyl acetate;The initiator is peroxidized t-butyl perbenzoate, the wetting dispersing agent is BYK-W9010, the releasing agent are BYK-P9080, the polymerization inhibitor is 1,4-benzoquinone, the filler is aluminium hydroxide and calcium carbonate Mixture, the thickener be magnesia, the reinforcing material be glass fibre.
It is further preferred that above-mentioned be used to manufacture the material covered in battery bag, the formula composition of the material is:It is unsaturated The parts by weight of polyester resin 220, the parts by weight of polyethersulfone resin 100 and the parts by weight of polyvinyl acetate 25, the tertiary fourth of perbenzoic acid The parts by weight of ester 6, the BYK-W9010 of 5 parts by weight, the BYK-P9080 of 12 parts by weight, the parts by weight of 1,4-benzoquinone 0.5, aluminium hydroxide 500 Parts by weight, the parts by weight of calcium carbonate 100, the parts by weight of magnesia 9.1, the parts by weight of glass fibre 326.
Above-mentioned to be used to manufacture the material covered in battery bag, the particle diameter of the aluminium hydroxide is preferably 1200 mesh.
Above-mentioned to be used to manufacture the material covered in battery bag, the particle diameter of the magnesia is preferably 600 mesh.
Above-mentioned to be used to manufacture the material covered in battery bag, the glass fibre is preferably alkali-free glass fibre.
The present invention additionally provides the preparation method for manufacturing the material covered in battery bag simultaneously, and operating procedure includes:
A. each material is weighed according to the formula of material composition;
B. will be stirred successively in the resin material weighed, polymerization inhibitor, initiator input mixing container, speed of agitator is 600r/min, mixing time are followed successively by 10min, 2min, 3min;Put into wetting dispersing agent simultaneously again and releasing agent be stirred, Speed of agitator is 600r/min, mixing time 5min;Then it is 100r/min to adjust speed of agitator, puts into filler, waits filler After all mixing, then speed of agitator is adjusted to 600r/min, stirs 20min, obtain resin system;
C. resin system step b obtained stands 2 hours, then will be surplus in the resin system after standing and formula composition Excess material is put into SMC sheet machine and sheet material is prepared;
D. the obtained sheet materials of step c are placed in 35 DEG C -40 DEG C of thermostatic chamber, place 24-48 hours, that is, obtain finished material.
Wetting dispersing agent BYK-W9010 of the present invention, described releasing agent BYK-W9080 are German Bi Ke chemistry The BYK series auxiliary agents of Co., Ltd's production.
Covered in traditional metal plate battery bag, design thickness is generally 1.0mm or so, uses new material provided by the present invention Covered in manufacture battery bag, when design thickness is 2.5mm, the intensity covered in battery bag is suitable with the intensity of metal plate material, but weight Alleviate 42.3%(The density of DC04 steel is 7.8g/cm3, and the density of new material is 1.8g/cm3), and the inside of noise is hindered Buddhist nun, the collision performance of resistance to wisp are superior to metal plate material.Moreover, material provided by the present invention also has well fire-retardant Performance, flame retardant rating have reached VO levels.
Therefore, new material provided by the present invention is used for the upper lid for manufacturing battery bag, can substantially mitigate what is covered in battery bag Weight, the lightweight covered in battery bag is realized, so that the weight of battery substantially reduces, make the car body weight of electric automobile Reduce, improve its efficiency, preferably realize energy-saving and emission-reduction, the effect of environmental protection.
Brief description of the drawings
Fig. 1 is the production procedure covered described in the flow sheet of new material described in embodiment 1 and embodiment 2 in battery bag Figure.
Embodiment
Content of the present invention is further described in detail with reference to specific embodiment.
The production of 1 new material of the present invention of embodiment
The implication of each symbol is in table 1:
UPR:Unsaturated polyester resin
PES:Polyethersulfone resin
PVAc:Polyvinyl acetate
TBPB:Peroxidized t-butyl perbenzoate
BQ:1,4-benzoquinone
Al(OH)3:Aluminium hydroxide
CaCO3:Calcium carbonate
MgO:Magnesia
GF:Glass fibre, it is fine from the P204-4800 alkali-free glasss of Owens Corning Composites's production Dimension.
New material production process:
1.1 batch mixing(Resin system)
1.1.1 according to the formula in table 1, various materials are weighed successively(In addition to thickener and reinforcing material);
1.1.2 the resin 1, resin 2, resin 3 of weighing are put into mixing container by induction system, high-speed stirred(600r/ min)10min(Batch mixing 1);
1.1.3 the polymerization inhibitor of weighing is launched to mixing container high speed and stirred(600r/min)2min(Batch mixing 2);
1.1.4 the initiator of weighing is launched to mixing container high speed and stirred(600r/min)3min(Batch mixing 3);
Stirred 1.1.5 the wetting dispersing agent of weighing and releasing agent are launched to mixing container high speed(600r/min)5min(It is mixed Material 4);
1.1.6 speed of agitator is transferred to 100r/min, the filler 1 of weighing and filler 2 is put into mixing container by induction system In, wait filler to be fully immersed into after resin mixes, then speed of agitator is adjusted to 600r/min, stir 20min(Batch mixing 5);
1.2 sheet production
1.2.1 by above-mentioned resin system, 2 hours are stood, preparation starts to produce sheet material;
1.2.2, the control system parameter of SMC sheet unit is set, resin system content is adjusted to 74.3%, content of glass fiber 25% is adjusted to, amount of thickener is adjusted to 0.7%;
1.2.3, resin system and thickener are pumped into the mixing system of SMC sheet unit by metering respectively, carry out mixture (" batch mixing 6 ");
1.2.4 by " 1.2.3 " " batch mixing 6 " respectively enters the A grooves of SMC sheet unit by conveyance conduit(Groove above)And B Groove(Following groove), the bottom of A, B groove lays PE films respectively in advance;
1.2.5 continuous glass fibre is uniformly cut into 25.4mm glass fibers by the yarn cutting system of SMC sheet unit Dimension, and uniformly fall on by B grooves and sticked " on the PE films of batch mixing 6 ";
1.2.6 units for sheet material is started, lower PE thin-film unreelings, after resin scraper under B grooves, film is uniformly coated certain thickness The batch mixing 6 of degree, when it is by fibre-collecting zone, the glass fibre sedimentation for being cut into certain length carries glass fibers thereon The PE films of dimension, in Dilvar zone and the upper Film laminated of the same manner coating batch mixing 6, and sufficiently to the sufficient dipping of glass;
1.2.7 the semi-finished product " 1.2.6 " obtained are cased it by the winding system of SMC sheet unit;
1.2.8 " 1.2.7 " obtained semi-finished product are transported to temperature control in 35 DEG C -40 DEG C of thermostatic chamber, carry out thickening 24- 48 hours, that is, obtain new material finished product.
The production covered in the battery bag of embodiment 2
Preparation before 2.1 productions
2.1.1 installing a mold on SMC press, it is 135 DEG C that mould is set into temperature, and SMC press pressures are arranged to 1500MN, Dwell time is 240s;
2.1.2 prepare the new material that embodiment 1 obtains, remove the debris such as mould upper and lower surface remnants flashes, defective material;
2.2 compacting
Laid after green wood media sheet is removed into PE thickness onto mould, start press, it is suppressed, SMC press itself enters Row heat-insulation pressure keeping;
2.3 product stripping
When heat-insulation pressure keeping terminates, SMC press automated backhauls, after mould is opened, startup ejection button ejects product, treats product After completely disengaging mould, product is taken out from mould, is placed on setting tooling;
2.4 post processing
Product overlap is polished off, forbidding colliding with scratches product, and product edge must not also there are the bad phenomenons such as sawtooth, obtain battery bag Upper lid finished product.
The test of lid performance in the battery bag of embodiment 3
Inventor is detected to the performance covered in the battery bag that is prepared according to embodiment method, as a result as shown in table 2.
Table 2
In summary, the advantage covered in the battery bag of new material manufacture provided by the present invention is:
1. lid has excellent corrosion resistance in battery bag, without carrying out the surface treatment such as anti-corrosion, spray painting.
2. the specific strength covered in battery bag is higher than former sheet metal component.
3. the flame retardant rating covered in battery bag can reach VO levels.
4. the lightweight covered in battery bag is realized, in light weight 42.3% compared with sheet metal component.
5. lid has good insulating properties in battery bag, it is pre-processed in high humidity, DC1000V, insulaion resistance >=500M Ω 。

Claims (7)

1. for manufacturing the material covered in battery bag, it is characterised in that the formula of the material, which forms, is:The weight of resin material 345 Measure part, the parts by weight of initiator 6, the parts by weight of wetting dispersing agent 5, the parts by weight of releasing agent 12, the parts by weight of polymerization inhibitor 0.5, the weight of filler 600 Measure part, the parts by weight of thickener 9.1, the parts by weight of reinforcing material 326.
2. according to claim 1 be used to manufacture the material covered in battery bag, it is characterised in that the resin material is not The mixture of saturated polyester resin, polyethersulfone resin and polyvinyl acetate;The initiator be peroxidized t-butyl perbenzoate, The wetting dispersing agent is BYK-W9010, the releasing agent is BYK-P9080, the polymerization inhibitor is 1,4-benzoquinone, the filler is The mixture of aluminium hydroxide and calcium carbonate, the thickener are magnesia, the reinforcing material is glass fibre.
3. according to claim 1 be used to manufacture the material covered in battery bag, it is characterised in that the formula group of the material Turn into:The parts by weight of unsaturated polyester resin 220, the parts by weight of polyethersulfone resin 100 and the parts by weight of polyvinyl acetate 25, peroxidating The parts by weight of t-butyl perbenzoate 6, the BYK-W9010 of 5 parts by weight, the BYK-P9080 of 12 parts by weight, the parts by weight of 1,4-benzoquinone 0.5, hydrogen The parts by weight of aluminum oxide 500, the parts by weight of calcium carbonate 100, the parts by weight of magnesia 9.1, the parts by weight of glass fibre 326.
4. being used for according to Claims 2 or 3 manufactures the material that is covered in battery bag, it is characterised in that the aluminium hydroxide Particle diameter be 1200 mesh.
5. being used for according to Claims 2 or 3 manufactures the material that is covered in battery bag, it is characterised in that the magnesia Particle diameter is 600 mesh.
6. being used for according to Claims 2 or 3 manufactures the material that is covered in battery bag, it is characterised in that the glass fibre For alkali-free glass fibre.
7. the preparation method as claimed in claim 1 for being used to manufacture the material covered in battery bag, it is characterised in that operating procedure Including:
A. the formula composition of material weighs each material according to claim 1;
B. will be stirred successively in the resin material weighed, polymerization inhibitor, initiator input mixing container, speed of agitator is 600r/min, mixing time are followed successively by 10min, 2min, 3min;Put into wetting dispersing agent simultaneously again and releasing agent be stirred, Speed of agitator is 600r/min, mixing time 5min;Then it is 100r/min to adjust speed of agitator, puts into filler, waits filler After all mixing, then speed of agitator is adjusted to 600r/min, stirs 20min, obtain resin system;
C. resin system step b obtained stands 2 hours, then will be surplus in the resin system after standing and formula composition Excess material is put into SMC sheet machine and sheet material is prepared;
D. the obtained sheet materials of step c are placed in 35 DEG C -40 DEG C of thermostatic chamber, place 24-48 hours, that is, obtain finished material.
CN201710583820.1A 2017-07-18 2017-07-18 For manufacturing material covered in battery bag and preparation method thereof Pending CN107383821A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710583820.1A CN107383821A (en) 2017-07-18 2017-07-18 For manufacturing material covered in battery bag and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710583820.1A CN107383821A (en) 2017-07-18 2017-07-18 For manufacturing material covered in battery bag and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107383821A true CN107383821A (en) 2017-11-24

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Country Status (1)

Country Link
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343407A (en) * 2008-08-22 2009-01-14 常熟东南塑料有限公司 Halogen-free flame-proof unsaturated polyester molding compound
CN101514254A (en) * 2009-03-09 2009-08-26 北京中铁长龙新型复合材料有限公司 Sheet molding compound with high flame resistance, low smoke and non-toxic and preparation method thereof
CN102558804A (en) * 2012-02-14 2012-07-11 上海耀华大中新材料有限公司 Black low-flow-mark polyester molding compound and preparation method thereof
CN104212127A (en) * 2014-09-10 2014-12-17 江苏恒神纤维材料有限公司 Low-temperature cured prepreg of mould used at high temperature
CN206098471U (en) * 2016-09-19 2017-04-12 宁德时代新能源科技股份有限公司 Power battery wraps upper cover structure

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343407A (en) * 2008-08-22 2009-01-14 常熟东南塑料有限公司 Halogen-free flame-proof unsaturated polyester molding compound
CN101514254A (en) * 2009-03-09 2009-08-26 北京中铁长龙新型复合材料有限公司 Sheet molding compound with high flame resistance, low smoke and non-toxic and preparation method thereof
CN102558804A (en) * 2012-02-14 2012-07-11 上海耀华大中新材料有限公司 Black low-flow-mark polyester molding compound and preparation method thereof
CN104212127A (en) * 2014-09-10 2014-12-17 江苏恒神纤维材料有限公司 Low-temperature cured prepreg of mould used at high temperature
CN206098471U (en) * 2016-09-19 2017-04-12 宁德时代新能源科技股份有限公司 Power battery wraps upper cover structure

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄家康等: "《复合材料成型技术》", 31 January 1999 *

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