CN107383706A - A kind of PVC cable sheath material and preparation method thereof - Google Patents
A kind of PVC cable sheath material and preparation method thereof Download PDFInfo
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- CN107383706A CN107383706A CN201710829107.0A CN201710829107A CN107383706A CN 107383706 A CN107383706 A CN 107383706A CN 201710829107 A CN201710829107 A CN 201710829107A CN 107383706 A CN107383706 A CN 107383706A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses a kind of PVC cable sheath material, is made up of the raw material of following weight parts：50 60 parts of polyvinyl chloride resin, 5 10 parts of natural rubber, 5 10 parts of butadiene rubber, 5 10 parts of polyethylene, 14 parts of gas-phase silica, 12 parts of glass fibre, 25 parts of graphene, 1.5 3 parts of impact modifier, 5 10 parts of nanometer titanium dioxide titanium valve, 14 parts of heat stabilizer, 48 parts of plasticizer, 46 parts of accelerator, 25 parts of barium monoxide, 35 parts of coupling agent, 48 parts of calcium oxide, 5 15 parts of perlite, 5 10 parts of lubricant, 36 parts of Diammonium phosphate (DAP), 36 parts of Firebrake ZB.CABLE MATERIALS of the present invention is using polyvinyl chloride resin as major ingredient, coordinate other auxiliary materials, without to heavy metals such as the harmful lead, cadmium, sexivalent chromium of human and environment, mercury, meet requirement of the standard to environmental protection, safety and environmental protection, so that wearability, machining property are good, cutting facilitates effortless, and diamagnetic performance, water resistance, resistance to elevated temperatures, resistance to chemical corrosion are all lifted than common cable material, biodegradation period is short, production cost is low, and economic value is high, and prospect is very wide.
Description
Technical field
The present invention relates to CABLE MATERIALS technical field, specifically a kind of PVC cable sheath material and preparation method thereof.
Background technology
PVC cable material is the resin based on polyvinyl chloride, addition stabilizer, dioctyl phthalate, O-phthalic
The sour inorganic filler such as plasticizer and calcium carbonate such as two isodecyl esters, DOTP, trioctyl trimellitate (TOTM), auxiliary agent
With the additive such as lubricant, the particle mediated extrusion by mixture and prepared.
Because of the stabilizer used, the additive such as plasticizer and various fillers is different and different in terms of environmental protection.One
As be detection method with ROHS or REACH and standard to weigh.It is divided into environmental protection and non-environmental protection PVC cable material.Environment-friendly cable material,
That is after CABLE MATERIALS is successfully prepared, tested with ROHS or REACH detection method and standard in ICP test equipments, institute
There are the banned substances such as content of beary metal in material composition, DEHP, nonyl phenol, polybrominated biphenyl and controlled substance etc., it is impossible to contain
Or within certain component.Because the standard and requirement of each country are different, corresponding environmental protection standard and it is different.Measuring unit one
As measured with ppm.The stabilizer of environment-friendly cable material is usually to use calcium zinc stabilizer.Meet the PVC cable material of REACH standards
Plasticizer above all can not be made using DEHP16 kinds material.Non-environmental protection CABLE MATERIALS non-environmental protection CABLE MATERIALS typically uses lead salt
To make stabilizer, because it contains the heavy metals such as heavy metal lead, chromium, cadmium, mercury, barium, environment and human health can be caused greatly to damage
Evil, and limited or prohibit the use of by increasing country.
The content of the invention
It is an object of the invention to provide a kind of PVC cable sheath material and preparation method thereof, to solve above-mentioned background technology
The problem of middle proposition.
To achieve the above object, the present invention provides following technical scheme：
A kind of PVC cable sheath material of the present invention, is made up of the raw material of following weight parts：
Polyvinyl chloride resin 50-60 parts, natural rubber 5-10 parts, butadiene rubber 5-10 parts, polyethylene 5-10 parts, gas-phase silica
1-4 parts, glass fibre 1-2 parts, graphene 2-5 parts, impact modifier 1.5-3 parts, nanometer titanium dioxide titanium valve 5-10 parts, thermostabilization
Agent 1-4 parts, plasticizer 4-8 parts, accelerator 4-6 parts, barium monoxide 2-5 parts, coupling agent 3-5 parts, calcium oxide 4-8 parts, perlite 5-
15 parts, lubricant 5-10 parts, Diammonium phosphate (DAP) 3-6 parts, Firebrake ZB 3-6 parts.
A kind of PVC cable sheath material, it is made up of the raw material of following weight parts：
50 parts of polyvinyl chloride resin, 5 parts of natural rubber, 5 parts of butadiene rubber, 5 parts of polyethylene, 1 part of gas-phase silica, glass fibre 1
Part, 2 parts of graphene, 1.5 parts of impact modifier, 5 parts of nanometer titanium dioxide titanium valve, 1 part of heat stabilizer, 4 parts of plasticizer, accelerator 4
Part, 2 parts of barium monoxide, 3 parts of coupling agent, 4 parts of calcium oxide, 5 parts of perlite, 5 parts of lubricant, 3 parts of Diammonium phosphate (DAP), 3 parts of Firebrake ZB.
A kind of PVC cable sheath material, it is made up of the raw material of following weight parts：
60 parts of polyvinyl chloride resin, 10 parts of natural rubber, 10 parts of butadiene rubber, 10 parts of polyethylene, 4 parts of gas-phase silica, glass fibers
2 parts of dimension, 5 parts of graphene, 3 parts of impact modifier, 10 parts of nanometer titanium dioxide titanium valve, 4 parts of heat stabilizer, 8 parts of plasticizer, accelerator
6 parts, 5 parts of barium monoxide, 5 parts of coupling agent, 8 parts of calcium oxide, 15 parts of perlite, 10 parts of lubricant, 6 parts of Diammonium phosphate (DAP), Firebrake ZB 6
Part.
A kind of PVC cable sheath material, it is made up of the raw material of following weight parts：
55 parts of polyvinyl chloride resin, 8 parts of natural rubber, 8 parts of butadiene rubber, 8 parts of polyethylene, 3 parts of gas-phase silica, glass fibre
1.5 parts, 3.5 parts of graphene, 2 parts of impact modifier, 7 parts of nanometer titanium dioxide titanium valve, 2.5 parts of heat stabilizer, 6 parts of plasticizer, promote
Enter 5 parts of agent, 3.5 parts of barium monoxide, 4 parts of coupling agent, 6 parts of calcium oxide, 10 parts of perlite, 8 parts of lubricant, 4.5 parts of Diammonium phosphate (DAP), boron
Sour 4.5 parts of zinc.
The plasticizer is citrate.
The accelerator is accelerator M.
A kind of preparation method of described PVC cable sheath material, comprises the following steps：
(1) by the polyvinyl chloride resin of above-mentioned parts by weight, natural rubber, butadiene rubber, polyethylene, gas-phase silica, glass fibers
Dimension, graphene, nanometer titanium dioxide titanium valve, perlite and lubricant are put into mixer stirring 40-50 minutes, and while stirring
It is heated, heating-up temperature is 90-100 DEG C, 30 minutes heat times, obtains batch mixing A；
(2) impact modifier, heat stabilizer, plasticizer, accelerator, barium monoxide, coupling agent, oxidation are added into batch mixing A
Calcium, Diammonium phosphate (DAP), Firebrake ZB, 50-70 minutes are again stirring for, batch mixing is put at reducing mechanism internal comminution after the completion of stirring
Reason, grinding time are 60 minutes, obtain finished product.
Compared with prior art, the beneficial effects of the invention are as follows：
CABLE MATERIALS of the present invention coordinates other auxiliary materials using polyvinyl chloride resin as major ingredient, without there is larger infringement to human and environment
The heavy metals such as lead, cadmium, sexivalent chromium, mercury, meet requirement of the standard to environmental protection, safety and environmental protection so that wearability, machining property
Well, cutting facilitates effortless, and diamagnetic performance, water resistance, resistance to elevated temperatures, resistance to chemical corrosion all compare common cable
Material is obviously improved, and biodegradation period is short, and production cost is low, and economic value is high, and prospect is very wide.There is material selection conjunction simultaneously
The advantages that reason, fire-retardant, low smoke and zero halogen, long service life, there is emergency case, caused material to human body, natural environment without
Evil, the mechanical strength of cable cover(ing) can be effectively improved, prevent its situation for occurring being broken in use, extend cable
Service life.The control that the preparation method of the present invention passes through rational charging sequence and technological parameter so that final products
Performance is guaranteed, and preparation method is simple, easy to operate.
Embodiment
With reference to specific embodiment, the present invention is further illustrated.
Embodiment 1
A kind of PVC cable sheath material, it is made up of the raw material of following weight parts：
50 parts of polyvinyl chloride resin, 5 parts of natural rubber, 5 parts of butadiene rubber, 5 parts of polyethylene, 1 part of gas-phase silica, glass fibre 1
Part, 2 parts of graphene, 1.5 parts of impact modifier, 5 parts of nanometer titanium dioxide titanium valve, 1 part of heat stabilizer, 4 parts of plasticizer, accelerator 4
Part, 2 parts of barium monoxide, 3 parts of coupling agent, 4 parts of calcium oxide, 5 parts of perlite, 5 parts of lubricant, 3 parts of Diammonium phosphate (DAP), 3 parts of Firebrake ZB.
The plasticizer is citrate.
The accelerator is accelerator M.
A kind of preparation method of described PVC cable sheath material, comprises the following steps：
(1) by the polyvinyl chloride resin of above-mentioned parts by weight, natural rubber, butadiene rubber, polyethylene, gas-phase silica, glass fibers
Dimension, graphene, nanometer titanium dioxide titanium valve, perlite and lubricant be put into mixer stir 40 minutes, and stirring while pair
It is heated, and heating-up temperature is 90 DEG C, 30 minutes heat times, obtains batch mixing A；
(2) impact modifier, heat stabilizer, plasticizer, accelerator, barium monoxide, coupling agent, oxidation are added into batch mixing A
Calcium, Diammonium phosphate (DAP), Firebrake ZB, it is again stirring for 50 minutes, batch mixing is put into the processing of reducing mechanism internal comminution, powder after the completion of stirring
The broken time is 60 minutes, obtains finished product.
Embodiment 2
A kind of PVC cable sheath material, it is made up of the raw material of following weight parts：
60 parts of polyvinyl chloride resin, 10 parts of natural rubber, 10 parts of butadiene rubber, 10 parts of polyethylene, 4 parts of gas-phase silica, glass fibers
2 parts of dimension, 5 parts of graphene, 3 parts of impact modifier, 10 parts of nanometer titanium dioxide titanium valve, 4 parts of heat stabilizer, 8 parts of plasticizer, accelerator
6 parts, 5 parts of barium monoxide, 5 parts of coupling agent, 8 parts of calcium oxide, 15 parts of perlite, 10 parts of lubricant, 6 parts of Diammonium phosphate (DAP), Firebrake ZB 6
Part.
The plasticizer is citrate.
The accelerator is accelerator M.
A kind of preparation method of described PVC cable sheath material, comprises the following steps：
(1) by the polyvinyl chloride resin of above-mentioned parts by weight, natural rubber, butadiene rubber, polyethylene, gas-phase silica, glass fibers
Dimension, graphene, nanometer titanium dioxide titanium valve, perlite and lubricant be put into mixer stir 50 minutes, and stirring while pair
It is heated, and heating-up temperature is 100 DEG C, 30 minutes heat times, obtains batch mixing A；
(2) impact modifier, heat stabilizer, plasticizer, accelerator, barium monoxide, coupling agent, oxidation are added into batch mixing A
Calcium, Diammonium phosphate (DAP), Firebrake ZB, it is again stirring for 70 minutes, batch mixing is put into the processing of reducing mechanism internal comminution, powder after the completion of stirring
The broken time is 60 minutes, obtains finished product.
Embodiment 3
A kind of PVC cable sheath material, it is made up of the raw material of following weight parts：
55 parts of polyvinyl chloride resin, 8 parts of natural rubber, 8 parts of butadiene rubber, 8 parts of polyethylene, 3 parts of gas-phase silica, glass fibre
1.5 parts, 3.5 parts of graphene, 2 parts of impact modifier, 7 parts of nanometer titanium dioxide titanium valve, 2.5 parts of heat stabilizer, 6 parts of plasticizer, promote
Enter 5 parts of agent, 3.5 parts of barium monoxide, 4 parts of coupling agent, 6 parts of calcium oxide, 10 parts of perlite, 8 parts of lubricant, 4.5 parts of Diammonium phosphate (DAP), boron
Sour 4.5 parts of zinc.
The plasticizer is citrate.
The accelerator is accelerator M.
A kind of preparation method of described PVC cable sheath material, comprises the following steps：
(1) by the polyvinyl chloride resin of above-mentioned parts by weight, natural rubber, butadiene rubber, polyethylene, gas-phase silica, glass fibers
Dimension, graphene, nanometer titanium dioxide titanium valve, perlite and lubricant be put into mixer stir 45 minutes, and stirring while pair
It is heated, and heating-up temperature is 90-1005 DEG C, 30 minutes heat times, obtains batch mixing A；
(2) impact modifier, heat stabilizer, plasticizer, accelerator, barium monoxide, coupling agent, oxidation are added into batch mixing A
Calcium, Diammonium phosphate (DAP), Firebrake ZB, it is again stirring for 60 minutes, batch mixing is put into the processing of reducing mechanism internal comminution, powder after the completion of stirring
The broken time is 60 minutes, obtains finished product.
Detect example
According to GB/T528-1998 testing example 1-3 tensile strength (MPa), according to GB/T2406-1993 standard
Oxygen index (OI) is tested, highest work temperature is tested according to GB12666.5 standard testing flame retardant rating, and according to GB/T2423-2001
Degree, concrete outcome see the table below 1.
From the point of view of embodiment, cable jacket material provided by the invention has that excellent tensile property, smoke density be small, oxygen index (OI)
Height, and the protective cover material has good resistance to elevated temperatures, improves the service life of cable.
Claims (7)
1. a kind of PVC cable sheath material, it is characterised in that be made up of the raw material of following weight parts：
Polyvinyl chloride resin 50-60 parts, natural rubber 5-10 parts, butadiene rubber 5-10 parts, polyethylene 5-10 parts, gas-phase silica 1-4
Part, glass fibre 1-2 parts, graphene 2-5 parts, impact modifier 1.5-3 parts, nanometer titanium dioxide titanium valve 5-10 parts, heat stabilizer
1-4 parts, plasticizer 4-8 parts, accelerator 4-6 parts, barium monoxide 2-5 parts, coupling agent 3-5 parts, calcium oxide 4-8 parts, perlite 5-15
Part, lubricant 5-10 parts, Diammonium phosphate (DAP) 3-6 parts, Firebrake ZB 3-6 parts.
2. a kind of PVC cable sheath material according to claim 1, it is characterised in that be made up of the raw material of following weight parts：
50 parts of polyvinyl chloride resin, 5 parts of natural rubber, 5 parts of butadiene rubber, 5 parts of polyethylene, 1 part of gas-phase silica, 1 part of glass fibre,
2 parts of graphene, 1.5 parts of impact modifier, 5 parts of nanometer titanium dioxide titanium valve, 1 part of heat stabilizer, 4 parts of plasticizer, 4 parts of accelerator,
2 parts of barium monoxide, 3 parts of coupling agent, 4 parts of calcium oxide, 5 parts of perlite, 5 parts of lubricant, 3 parts of Diammonium phosphate (DAP), 3 parts of Firebrake ZB.
3. a kind of PVC cable sheath material according to claim 1, it is characterised in that be made up of the raw material of following weight parts：
60 parts of polyvinyl chloride resin, 10 parts of natural rubber, 10 parts of butadiene rubber, 10 parts of polyethylene, 4 parts of gas-phase silica, glass fibre 2
Part, 5 parts of graphene, 3 parts of impact modifier, 10 parts of nanometer titanium dioxide titanium valve, 4 parts of heat stabilizer, 8 parts of plasticizer, accelerator 6
Part, 5 parts of barium monoxide, 5 parts of coupling agent, 8 parts of calcium oxide, 15 parts of perlite, 10 parts of lubricant, 6 parts of Diammonium phosphate (DAP), 6 parts of Firebrake ZB.
4. a kind of PVC cable sheath material according to claim 1, it is characterised in that be made up of the raw material of following weight parts：
55 parts of polyvinyl chloride resin, 8 parts of natural rubber, 8 parts of butadiene rubber, 8 parts of polyethylene, 3 parts of gas-phase silica, glass fibre 1.5
Part, 3.5 parts of graphene, 2 parts of impact modifier, 7 parts of nanometer titanium dioxide titanium valve, 2.5 parts of heat stabilizer, 6 parts of plasticizer, accelerator
5 parts, 3.5 parts of barium monoxide, 4 parts of coupling agent, 6 parts of calcium oxide, 10 parts of perlite, 8 parts of lubricant, 4.5 parts of Diammonium phosphate (DAP), Firebrake ZB
4.5 part.
5. a kind of PVC cable sheath material according to claim 1, it is characterised in that the plasticizer is citrate.
6. a kind of PVC cable sheath material according to claim 1, it is characterised in that the accelerator is vulcanization accelerator
M。
7. a kind of PVC cable sheath material described in claim any one of 1-6 is prepared with the following method, its feature exists
In comprising the following steps：
(1) by the polyvinyl chloride resin of above-mentioned parts by weight, natural rubber, butadiene rubber, polyethylene, gas-phase silica, glass fibre, stone
Black alkene, nanometer titanium dioxide titanium valve, perlite and lubricant are put into mixer stirring 40-50 minutes, and to it while stirring
Heated, heating-up temperature is 90-100 DEG C, 30 minutes heat times, obtains batch mixing A；
(2) impact modifier, heat stabilizer, plasticizer, accelerator, barium monoxide, coupling agent, calcium oxide, phosphorus are added into batch mixing A
Sour two ammoniums, Firebrake ZB, are again stirring for 50-70 minutes, and batch mixing is put into the processing of reducing mechanism internal comminution after the completion of stirring, crushed
Time is 60 minutes, obtains finished product.
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| CN201710829107.0A CN107383706A (en) | 2017-09-14 | 2017-09-14 | A kind of PVC cable sheath material and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276696A (en) * | 2017-12-31 | 2018-07-13 | 安徽天星电缆科技有限公司 | A kind of robot cable special-purpose polychloroethylene composite material |
| CN108424553A (en) * | 2018-04-16 | 2018-08-21 | 山东迪龙电缆有限公司 | A kind of Halogen house cable raw material |
| CN109251386A (en) * | 2018-07-02 | 2019-01-22 | 广东安普智信电气有限公司 | The resistance to fire proofing of shock resistance, preparation method and the application in cable protection pipe |
| CN109337231A (en) * | 2018-08-27 | 2019-02-15 | 芜湖市元奎新材料科技有限公司 | A kind of graphene flame-retardant shielded cable material and preparation method thereof |
| CN110511455A (en) * | 2019-08-05 | 2019-11-29 | 晶锋集团股份有限公司 | A kind of heat-proof macromolecule CABLE MATERIALS and preparation method thereof |
| CN110791044A (en) * | 2019-12-11 | 2020-02-14 | 安徽实友电力金具有限公司 | Preparation method of marine corrosion-resistant flame-retardant cable insulating material |
| CN112071490A (en) * | 2020-09-10 | 2020-12-11 | 湖南金缆电工科技有限责任公司 | High-temperature-resistant flame-retardant cable and manufacturing method thereof |
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| CN106496878A (en) * | 2016-11-24 | 2017-03-15 | 安徽意力电缆有限公司 | A kind of environment-friendly PVC CABLE MATERIALS |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276696A (en) * | 2017-12-31 | 2018-07-13 | 安徽天星电缆科技有限公司 | A kind of robot cable special-purpose polychloroethylene composite material |
| CN108424553A (en) * | 2018-04-16 | 2018-08-21 | 山东迪龙电缆有限公司 | A kind of Halogen house cable raw material |
| CN109251386A (en) * | 2018-07-02 | 2019-01-22 | 广东安普智信电气有限公司 | The resistance to fire proofing of shock resistance, preparation method and the application in cable protection pipe |
| CN109337231A (en) * | 2018-08-27 | 2019-02-15 | 芜湖市元奎新材料科技有限公司 | A kind of graphene flame-retardant shielded cable material and preparation method thereof |
| CN110511455A (en) * | 2019-08-05 | 2019-11-29 | 晶锋集团股份有限公司 | A kind of heat-proof macromolecule CABLE MATERIALS and preparation method thereof |
| CN110791044A (en) * | 2019-12-11 | 2020-02-14 | 安徽实友电力金具有限公司 | Preparation method of marine corrosion-resistant flame-retardant cable insulating material |
| CN112071490A (en) * | 2020-09-10 | 2020-12-11 | 湖南金缆电工科技有限责任公司 | High-temperature-resistant flame-retardant cable and manufacturing method thereof |
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Application publication date: 20171124 |