CN107383447A - A kind of anti-aging cable jacket material - Google Patents
A kind of anti-aging cable jacket material Download PDFInfo
- Publication number
- CN107383447A CN107383447A CN201710708713.7A CN201710708713A CN107383447A CN 107383447 A CN107383447 A CN 107383447A CN 201710708713 A CN201710708713 A CN 201710708713A CN 107383447 A CN107383447 A CN 107383447A
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- parts
- rubber
- aging
- light stabilizer
- cable jacket
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of anti-aging cable jacket material, its raw material includes by weight：80 100 parts of natural rubber,50 60 parts of butadiene-styrene rubber,15 20 parts of nitrile rubber,15 30 parts of CSM,20 30 parts of Corvic,5 18 parts of aluminum plating glass microballon,6 12 parts of barium mahogany sulfonate,28 parts of calcium sulfate crystal whiskers powder,12 25 parts of carbon black,5 10 parts of zinc oxide,5 10 parts of sulphur,8 15 parts of N isopropyl N` diphenyl-para-phenylene diamines,4 10 parts of 2 naphthylamines of N phenyl,5 10 parts of titanium dioxide,4 12 parts of phenyl salicylate,58 parts of ultra-violet absorber UV P,6 12 parts of ultra-violet absorber UV O,540 5 10 parts of light stabilizer GW,544 5 10 parts of light stabilizer GW,20 30 parts of filler,13 parts of plasticizer.The present invention is cooperated with properly mixed natural rubber, butadiene-styrene rubber, nitrile rubber, CSM and Corvic, then is aided with other each raw materials, finished product is had stronger resistant to thermal aging, resist oxygen aging and anti-light aging performance.
Description
Technical field
The present invention relates to electrical equipment technical field, more particularly to a kind of anti-aging cable jacket material.
Background technology
With developing rapidly for economy, electric wire is widely used in industry-by-industry, field.
Cable, typically by several or similar rope that several groups of wires (every group at least two) are twisted cable, often
Mutually insulated between group wire, and be often twisted into around a center, whole outside is surrounded by the cable cover(ing) of high-insulation.Cable
With interior energization, the feature of external insulation.
The ageing resistace of existing cable is poor, easily deforms, damages after long-time use, gradually loses using work(
Can, in order to slow down above-mentioned aging phenomenon, improve resistance of the cable in external environment, increase the service life of cable jacket material into
For the current technical issues that need to address.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of anti-aging cable jacket material, and it has stronger heat resistanceheat resistant
Aging, resist oxygen aging and anti-light aging performance.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of anti-aging cable jacket material, its raw material include by weight：Natural rubber 80-100 parts, butadiene-styrene rubber 50-
60 parts, nitrile rubber 15-20 parts, CSM 15-30 parts, Corvic 20-30 parts, aluminum plating glass microballon
5-18 parts, barium mahogany sulfonate 6-12 parts, calcium sulfate crystal whiskers powder 2-8 parts, carbon black 12-25 parts, zinc oxide 5-10 parts, sulphur 5-10
Part, N- isopropyl-N`- diphenyl-para-phenylene diamine 8-15 parts, N- phenyl-2-naphthylamine 4-10 parts, titanium dioxide 5-10 parts, salicylic acid benzene
Ester 4-12 parts, Ultraviolet Absorber UV-P 5-8 parts, ultra-violet absorber UV-O 6-12 parts, light stabilizer GW-540 5-10
Part, light stabilizer GW-544 5-10 parts, filler 20-30 parts, plasticizer 1-3 parts.
Preferably, its raw material includes by weight：90 parts of natural rubber, 50 parts of butadiene-styrene rubber, 15 parts of nitrile rubber, chlorine sulphur
Change 30 parts of polyethylene rubber, 25 parts of Corvic, 15 parts of aluminum plating glass microballon, 10 parts of barium mahogany sulfonate, calcium sulfate crystal whiskers
5 parts of powder, 20 parts of carbon black, 7 parts of zinc oxide, 8 parts of sulphur, 12 parts of N- isopropyl-N`- diphenyl-para-phenylene diamines, N- phenyl-2-naphthylamines 8
Part, 8 parts of titanium dioxide, 8 parts of phenyl salicylate, 7 parts of Ultraviolet Absorber UV-P, 10 parts of ultra-violet absorber UV-O, light is steady
Determine 8 parts of agent GW-540,5 parts of light stabilizer GW-544,25 parts of filler, 2 parts of plasticizer.
Wherein, the filler is one kind in lignin and plant ash or combination.
Wherein, the plasticizer is one kind in epoxy aliphatic acid methyl ester and chlorinated paraffin.
Beneficial effects of the present invention：The present invention is with properly mixed natural rubber, butadiene-styrene rubber, nitrile rubber, chlorosulfonation
Polyethylene rubber and Corvic cooperate, then are aided with other each raw materials, finished product had stronger resistant to thermal aging, resisted
Oxygen aging and anti-light aging performance, in raw material, aluminum plating glass microballon, barium mahogany sulfonate, calcium sulfate crystal whiskers powder, carbon black, zinc oxide,
The mutual cooperation of titanium dioxide and sulphur enhances the thermal ageing resistant performance of product, wherein carbon black, and zinc oxide and titanium dioxide are also
As photomask agent；N- isopropyl-N`- diphenyl-para-phenylene diamines, the mutual cooperation of N- phenyl-2-naphthylamines enhance the antioxygen of product
Ageing properties；Phenyl salicylate, Ultraviolet Absorber UV-P, ultra-violet absorber UV-O, light stabilizer GW-540, light stabilizer
GW-544 mutual cooperation enhances the anti-light aging performance of product.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of anti-aging cable jacket material, its raw material include by weight：90 parts of natural rubber, 50 parts of butadiene-styrene rubber, fourth
15 parts of nitrile rubber, 30 parts of CSM, 25 parts of Corvic, 15 parts of aluminum plating glass microballon, barium mahogany sulfonate
10 parts, 5 parts of calcium sulfate crystal whiskers powder, 20 parts of carbon black, 7 parts of zinc oxide, 8 parts of sulphur, 12 parts of N- isopropyl-N`- diphenyl-para-phenylene diamines,
8 parts of N- phenyl-2-naphthylamines, 8 parts of titanium dioxide, 8 parts of phenyl salicylate, 7 parts of Ultraviolet Absorber UV-P, ultra-violet absorber
8 parts of 10 parts of UV-O, light stabilizer GW-540,5 parts of light stabilizer GW-544,25 parts of filler, 2 parts of plasticizer.
Embodiment 2
A kind of anti-aging cable jacket material, its raw material include by weight：100 parts of natural rubber, 50 parts of butadiene-styrene rubber, fourth
15 parts of nitrile rubber, 15 parts of CSM, 20 parts of Corvic, 5 parts of aluminum plating glass microballon, barium mahogany sulfonate 10
Part, 2 parts of calcium sulfate crystal whiskers powder, 25 parts of carbon black, 6 parts of zinc oxide, 6 parts of sulphur, 9 parts of N- isopropyl-N`- diphenyl-para-phenylene diamines, N-
5 parts of phenyl-2-naphthylamine, 6 parts of titanium dioxide, 5 parts of phenyl salicylate, 6 parts of Ultraviolet Absorber UV-P, ultra-violet absorber UV-
6 parts of 7 parts of O, light stabilizer GW-540,6 parts of light stabilizer GW-544,25 parts of filler, 3 parts of plasticizer.
Embodiment 3
A kind of anti-aging cable jacket material, its raw material include by weight：80 parts of natural rubber, 58 parts of butadiene-styrene rubber, fourth
20 parts of nitrile rubber, 25 parts of CSM, 28 parts of Corvic, 13 parts of aluminum plating glass microballon, barium mahogany sulfonate
12 parts, 7 parts of calcium sulfate crystal whiskers powder, 25 parts of carbon black, 5 parts of zinc oxide, 8 parts of sulphur, 9 parts of N- isopropyl-N`- diphenyl-para-phenylene diamines,
5 parts of N- phenyl-2-naphthylamines, 6 parts of titanium dioxide, 6 parts of phenyl salicylate, 5 parts of Ultraviolet Absorber UV-P, ultra-violet absorber
9 parts of 10 parts of UV-O, light stabilizer GW-540,6 parts of light stabilizer GW-544,20 parts of filler, 1 part of plasticizer.
Embodiment 4
A kind of anti-aging cable jacket material, its raw material include by weight：95 parts of natural rubber, 60 parts of butadiene-styrene rubber, fourth
20 parts of nitrile rubber, 18 parts of CSM, 28 parts of Corvic, 17 parts of aluminum plating glass microballon, barium mahogany sulfonate
11 parts, 7 parts of calcium sulfate crystal whiskers powder, 24 parts of carbon black, 9 parts of zinc oxide, 9 parts of sulphur, 14 parts of N- isopropyl-N`- diphenyl-para-phenylene diamines,
9 parts of N- phenyl-2-naphthylamines, 9 parts of titanium dioxide, 11 parts of phenyl salicylate, 6 parts of Ultraviolet Absorber UV-P, ultra-violet absorber
6 parts of 6 parts of UV-O, light stabilizer GW-540,6 parts of light stabilizer GW-544,25 parts of filler, 3 parts of plasticizer.
Embodiment 5
A kind of anti-aging cable jacket material, its raw material include by weight：80 parts of natural rubber, 55 parts of butadiene-styrene rubber, fourth
17 parts of nitrile rubber, 17 parts of CSM, 27 parts of Corvic, 18 parts of aluminum plating glass microballon, barium mahogany sulfonate
12 parts, 5 parts of calcium sulfate crystal whiskers powder, 11 parts of carbon black, 9 parts of zinc oxide, 8 parts of sulphur, 12 parts of N- isopropyl-N`- diphenyl-para-phenylene diamines,
5 parts of N- phenyl-2-naphthylamines, 6 parts of titanium dioxide, 8 parts of phenyl salicylate, 6 parts of Ultraviolet Absorber UV-P, ultra-violet absorber
8 parts of 10 parts of UV-O, light stabilizer GW-540,6 parts of light stabilizer GW-544,22 parts of filler, 2 parts of plasticizer.
Embodiment 6
A kind of anti-aging cable jacket material, its raw material include by weight：100 parts of natural rubber, 55 parts of butadiene-styrene rubber, fourth
16 parts of nitrile rubber, 28 parts of CSM, 28 parts of Corvic, 15 parts of aluminum plating glass microballon, barium mahogany sulfonate 8
Part, 5 parts of calcium sulfate crystal whiskers powder, 25 parts of carbon black, 8 parts of zinc oxide, 6 parts of sulphur, 10 parts of N- isopropyl-N`- diphenyl-para-phenylene diamines, N-
5 parts of phenyl-2-naphthylamine, 5 parts of titanium dioxide, 5 parts of phenyl salicylate, 5 parts of Ultraviolet Absorber UV-P, ultra-violet absorber UV-
5 parts of 7 parts of O, light stabilizer GW-540,5 parts of light stabilizer GW-544,30 parts of filler, 3 parts of plasticizer.
Performance test is carried out to a kind of anti-aging cable jacket material material of the present invention, test result is as follows：
(1) the performance test results before aging：
| Tensile strength/MPa | It is broken rate elongation/% | |
| Common cable protective cover material | 12.8 | 39.7 |
| Cable jacket material of the present invention | 17.6 | 88.5 |
(2) the performance test results after heat, light, oxygen aging：
| Tensile strength/MPa | It is broken rate elongation/% | |
| Common cable protective cover material | 8.4 | 27.2 |
| Cable jacket material of the present invention | 15.1 | 77.6 |
In above-described embodiment 1-6, the present invention is with properly mixed natural rubber, butadiene-styrene rubber, nitrile rubber, chlorosulfonation
Polyethylene rubber and Corvic cooperate, then are aided with other each raw materials, finished product had stronger resistant to thermal aging, resisted
Oxygen aging and anti-light aging performance, in raw material, aluminum plating glass microballon, barium mahogany sulfonate, calcium sulfate crystal whiskers powder, carbon black, zinc oxide,
The mutual cooperation of titanium dioxide and sulphur enhances the thermal ageing resistant performance of product, wherein carbon black, and zinc oxide and titanium dioxide are also
As photomask agent；N- isopropyl-N`- diphenyl-para-phenylene diamines, the mutual cooperation of N- phenyl-2-naphthylamines enhance the antioxygen of product
Ageing properties；Phenyl salicylate, Ultraviolet Absorber UV-P, ultra-violet absorber UV-O, light stabilizer GW-540, light stabilizer
GW-544 mutual cooperation enhances the anti-light aging performance of product.
The general principle and principal character of the present invention has been shown and described above.It should be understood by those skilled in the art that
The present invention is not limited to the above embodiments, merely illustrating the principles of the invention described in above-described embodiment and specification,
Without departing from the spirit and scope, various changes and modifications of the present invention are possible, and these changes and improvements all fall
Enter in scope of the claimed invention.The scope of the present invention is defined by the appended claims and its equivalents.
Claims (4)
1. a kind of anti-aging cable jacket material, it is characterised in that its raw material includes by weight：Natural rubber 80-100 parts, fourth
Benzene rubber 50-60 parts, nitrile rubber 15-20 parts, CSM 15-30 parts, Corvic 20-30 parts, plating
Lead glass microballon 5-18 parts, barium mahogany sulfonate 6-12 parts, calcium sulfate crystal whiskers powder 2-8 parts, carbon black 12-25 parts, zinc oxide 5-10 parts,
Sulphur 5-10 parts, N- isopropyl-N`- diphenyl-para-phenylene diamine 8-15 parts, N- phenyl-2-naphthylamine 4-10 parts, titanium dioxide 5-10 parts,
Phenyl salicylate 4-12 parts, Ultraviolet Absorber UV-P 5-8 parts, ultra-violet absorber UV-O 6-12 parts, light stabilizer GW-
5405-10 parts, light stabilizer GW-5445-10 parts, filler 20-30 parts, plasticizer 1-3 parts.
A kind of 2. anti-aging cable jacket material according to claim 1, it is characterised in that：Its raw material includes by weight：
90 parts of natural rubber, 50 parts of butadiene-styrene rubber, 15 parts of nitrile rubber, 30 parts of CSM, 25 parts of Corvic,
15 parts of aluminum plating glass microballon, 10 parts of barium mahogany sulfonate, 5 parts of calcium sulfate crystal whiskers powder, 20 parts of carbon black, 7 parts of zinc oxide, 8 parts of sulphur, N-
12 parts of isopropyl-N`- diphenyl-para-phenylene diamines, 8 parts of N- phenyl-2-naphthylamines, 8 parts of titanium dioxide, 8 parts of phenyl salicylate, ultraviolet
7 parts of absorbent UV-P, ultra-violet absorber UV-O10 parts, light stabilizer GW-5408 parts, light stabilizer GW-5445 parts, filling
25 parts of agent, 2 parts of plasticizer.
A kind of 3. anti-aging cable jacket material according to claim 1 or 2, it is characterised in that：The filler is wooden
One kind or combination in element and plant ash.
A kind of 4. anti-aging cable jacket material according to claim 1 or 2, it is characterised in that：The plasticizer is epoxy
One kind in fatty acid methyl ester and chlorinated paraffin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710708713.7A CN107383447A (en) | 2017-08-17 | 2017-08-17 | A kind of anti-aging cable jacket material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710708713.7A CN107383447A (en) | 2017-08-17 | 2017-08-17 | A kind of anti-aging cable jacket material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107383447A true CN107383447A (en) | 2017-11-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710708713.7A Pending CN107383447A (en) | 2017-08-17 | 2017-08-17 | A kind of anti-aging cable jacket material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868383A (en) * | 2017-11-25 | 2018-04-03 | 蚌埠申徽彩色印刷包装有限公司 | The preparation method of water proof type corrugated board core material |
| CN109054121A (en) * | 2018-08-09 | 2018-12-21 | 安徽中宏线缆有限公司 | A kind of power cable oil resistant high fire-retardance native rubber composite material |
| CN113871076A (en) * | 2021-10-15 | 2021-12-31 | 四川省新都美河线缆厂 | Super low temperature resistant soft type cable |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102222542A (en) * | 2011-05-05 | 2011-10-19 | 常州鸿泽澜线缆有限公司 | Composite material cable core |
| CN105778228A (en) * | 2016-04-13 | 2016-07-20 | 安徽埃克森科技集团有限公司 | Anti-abrasion composite cable material with enhanced tensile strength and preparing method thereof |
| CN106479007A (en) * | 2016-10-25 | 2017-03-08 | 姹や寒 | A kind of wearable environment protection type power cable sheath material |
-
2017
- 2017-08-17 CN CN201710708713.7A patent/CN107383447A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102222542A (en) * | 2011-05-05 | 2011-10-19 | 常州鸿泽澜线缆有限公司 | Composite material cable core |
| CN105778228A (en) * | 2016-04-13 | 2016-07-20 | 安徽埃克森科技集团有限公司 | Anti-abrasion composite cable material with enhanced tensile strength and preparing method thereof |
| CN106479007A (en) * | 2016-10-25 | 2017-03-08 | 姹や寒 | A kind of wearable environment protection type power cable sheath material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868383A (en) * | 2017-11-25 | 2018-04-03 | 蚌埠申徽彩色印刷包装有限公司 | The preparation method of water proof type corrugated board core material |
| CN109054121A (en) * | 2018-08-09 | 2018-12-21 | 安徽中宏线缆有限公司 | A kind of power cable oil resistant high fire-retardance native rubber composite material |
| CN113871076A (en) * | 2021-10-15 | 2021-12-31 | 四川省新都美河线缆厂 | Super low temperature resistant soft type cable |
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