CN107382277A - A kind of superfine composite modified agstone of concrete microdilatancy - Google Patents

A kind of superfine composite modified agstone of concrete microdilatancy Download PDF

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Publication number
CN107382277A
CN107382277A CN201710700778.7A CN201710700778A CN107382277A CN 107382277 A CN107382277 A CN 107382277A CN 201710700778 A CN201710700778 A CN 201710700778A CN 107382277 A CN107382277 A CN 107382277A
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CN
China
Prior art keywords
agstone
modified
concrete
composite modified
superfine composite
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710700778.7A
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Chinese (zh)
Inventor
张建强
姜建松
柴天红
刘桂平
习海平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangxi Building Materials Scientific Research & Design Institute
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Jiangxi Building Materials Scientific Research & Design Institute
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Publication date
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Priority to CN201710700778.7A priority Critical patent/CN107382277A/en
Publication of CN107382277A publication Critical patent/CN107382277A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/10Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
    • C04B38/103Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam the foaming being obtained by the introduction of a gas other than untreated air, e.g. nitrogen
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • C04B40/0042Powdery mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602Making the green bodies or pre-forms by moulding
    • C04B2235/6021Extrusion moulding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

A kind of superfine composite modified agstone of concrete microdilatancy, include the raw material of following parts by weight, lime stone chip is 75 90, and silicon ash is 36, and it is 10 20 to wait outer flyash, and lithium slag is 10 20;The material modified mode mixed in addition is excited to mix, the percentage by weight that each modified excitation material accounts for above-mentioned superfine composite modified agstone total amount is, desulfurated plaster is 2% 4%, and triethanolamine is 0.03% 0.05%, maltodextrin is 0.05% 0.15%, and sulphate aluminium cement is 2% 6%.The present invention lime stone chip, silicon ash, etc. that functional form modification excitation material is added in outer flyash, lithium slag is dual modified through superfine grinding and chemi-excitation, not only contribute to the raising of early stage and later stage activity, microdilatancy function is made it have simultaneously, enhances the anti-crack ability of concrete;The powder fluidity of superfine composite modified agstone is improved, makes it easier to gas conveying, and is not easy empty arch caking.

Description

A kind of superfine composite modified agstone of concrete microdilatancy
Technical field
The present invention relates to concrete field, is exactly a kind of superfine composite modified lime stone of concrete microdilatancy Powder.
Background technology
China is currently under infrastructure construction peak period, and construction scale is huge, and building structure is with armored concrete knot Configuration formula is main body.The trend of Chinese commodity concrete in recent years is to keep annual production to be accounted at 2,400,000,000 tons or so substantially according to statistics More than half of the world, although cement concrete industry is completely in the superfluous state of supply structure, mineral admixture is simultaneously There is no production capacity surplus.Due to the domestic steel and iron industry also industrial waste residue resource such as serious production capacity surplus, flyash, slag distribution not Uniformly, yield is reduced year by year, and the high activated admixture such as slag, flyash quantum of output is actually being reduced year by year, and the country is permitted The conventional concrete mineral admixture in more areas has been extremely short raw material.Agstone is to produce lime stone rubble and machine Fine sand caused by sandstone processed and aggregate chips are raw material, the fine powder obtained by further grinding process, because having in concrete Good diminishing and filing effect and be concerned and apply.Research in recent years, it was demonstrated that agstone can be used as concrete mineral The part of admixture is applied in concrete, can supplement the deficiency of flyash supply, but in current practical engineering application In, also have limestone micropowder gas conveying effect is poor, easily empty arch caking and activity are stored in concrete mixing plant canister Exponential quantity is low, the problem of bleeding, shrinkage cracking easily occurs in concrete in incorporation concrete.
The content of the invention
It is an object of the invention to provide a kind of superfine composite modified agstone of concrete microdilatancy, the agstone gas Body conveying effect is good, and it is not in that empty arch lumps and as concrete mineral admixture to be stored in concrete mixing plant canister Activity index value height be present, be avoided that the problem of bleeding, shrinkage cracking occurs in concrete.
The superfine composite modified agstone of concrete microdilatancy of the present invention, include the raw material of following parts by weight, lime Stone chip is 75-90, silicon ash 3-6, and it is 10-20 to wait outer flyash, and lithium slag is 10-20;Excite the material modified side mixed in addition Formula mixes, and the percentage by weight that each modified excitation material accounts for above-mentioned superfine composite modified agstone total amount is that desulfurated plaster is 2%-4%, triethanolamine 0.03%-0.05%, maltodextrin 0.05%-0.15%, sulphate aluminium cement 2%-6%.
Described lime stone chip maximum particle diameter is less than 2%, MB values no more than 2.36mm, clay content and is less than 0.50, calcium carbonate Content is more than 90%;The silicon ash encryption stage, activity are not less than 105%;The outer flyash of the grade, loss on ignition are not more than 8%;It is described Lithium slag, 28d activity indexs value are not more than 8% not less than 95%, sulfur trioxide content.
The preparation method of the superfine composite modified agstone of concrete microdilatancy of the present invention:By lime stone chip, lithium Slag, etc. outer flyash, silicon ash and excite material modified by proportioning, use tumbling ball mill(Maximum pan feeding particle diameter is less than 5mm) Under conditions of rotating speed is 48r/min, intergrinding 20-40min, the superfine composite modified agstone of microdilatancy is then obtained.
The concrete of the present invention is removed with the superfine composite modified agstone Specifications of microdilatancy meets GB/ Outside T30190-2013, its Blain specific surface is controlled in 600-700m2/ kg, angle of repose are less than or equal to 30 degree;Mix modified lime The limited expansion rate that the cement mortar 28d activity indexs value of stone flour is more than or equal to 85%, 28d cement mortars is not less than 0.003%.
The present invention the superfine composite modified agstone of concrete microdilatancy, lime stone chip, silicon ash, etc. outer fine coal It is dual modified by mechanical force superfine grinding and chemi-excitation that functional form modification excitation material is added in ash, lithium slag, not only favorably In the raising of early stage and later stage activity, while microdilatancy function is made it have, enhance the anti-crack ability of concrete;It is obviously improved The powder fluidity of superfine composite modified agstone, gas conveying is made it easier to, and be not easy empty arch caking;Mixed in concrete The workability of concrete can be significantly improved by entering superfine composite modified agstone, make concrete be not easy to isolate bleeding.In the product Substantial amounts of industrial residue is make use of, reduces pollution of the industrial residue to environment, while second class powered coal ash or replacement can be substituted completely Part miberal powder, research on maximum utilized quantity is up to the 40% of binder materials, and product price is low compared with market second class powered coal ash, has significant society Meeting, environment and economic benefit.
Embodiment
Embodiment 1:
A kind of superfine composite modified agstone of concrete microdilatancy, in parts by weight, by 77 parts of lime stone chips, 3 parts of silicon Ash, the outer flyash such as 10 parts, 10 parts of lithium slags and modified exciting agent insert intergrinding 30min in tumbling ball mill, produce To the superfine composite modified agstone of microdilatancy type.Wherein modified exciting agent is by weight percentage(Account for compound lime stone flour quality Percentage)Meter, by 2% desulfurated plaster, 0.04% triethanolamine, 0.05% maltodextrin and 4% aluminium sulfate water Mud forms.
Embodiment 2:
A kind of superfine composite modified agstone of concrete microdilatancy, in parts by weight, by 85 parts of lime stone chips, 6 parts of silicon Ash, the outer flyash such as 5 parts, 4 parts of lithium slags and modified exciting agent insert intergrinding 35min in tumbling ball mill, that is, obtain The superfine composite modified agstone of microdilatancy type.Wherein modified exciting agent is by weight percentage(Account for compound lime stone flour quality Percentage)Meter, by 4% desulfurated plaster, 0.08% maltodextrin, 0.06% triethanolamine and 6% sulphate aluminium cement Composition.
Above-described embodiment 1 and 2 is respectively applied in cement mortar and C30 concrete, with reference to GB/T30190《Lime stone Powder concrete》、GB23439《Cement expansive material》And JGJ55-2011《Design of common concrete proportioning code》Etc. standard, The related performance indicators for mixing the composite modified agstone cement mortar of above two and concrete are have detected respectively, are as a result seen respectively Tables 1 and 2:
Table 1 mixes the correlated performance of the superfine composite modified agstone cement mortar of microdilatancy
Embodiment Fluidity ratio 28d activity indexs 28d limited expansion rates
1 104 85% 0.03%
2 102 87% 0.05%
Table 2 mixes the correlated performance of the superfine composite modified agstone C30 concrete of microdilatancy
Concrete Species Water Mud/ kg Coal Ash/ kg Ore deposit Powder/ kg Common stone Powder/kg It is composite modified Stone flour/kg It is glutinous It is poly- Property Protect Water Property 7d is strong Degree/ MPa 28d is strong Degree/MPa 28d limitations are swollen Swollen rate/%
Benchmark group 220 70 60 0 0 It is good It is good 21.5 34.3 -
Contrast groups 220 0 60 70 0 Difference Difference 20.1 32.2 -
Embodiment 1 220 0 60 0 70 It is excellent It is excellent 23.6 36.8 -0.001
Embodiment 2 220 0 60 0 70 It is excellent It is excellent 25.4 38.2 0.002

Claims (2)

1. a kind of superfine composite modified agstone of concrete microdilatancy, include the raw material of following parts by weight, lime stone chip For 75-90, silicon ash 3-6, it is 10-20 to wait outer flyash, and lithium slag is 10-20;The material modified mode mixed in addition is excited to mix, The percentage by weight that each modified excitation material accounts for above-mentioned superfine composite modified agstone total amount is, desulfurated plaster 2%-4%, three Monoethanolamine is 0.03%-0.05%, maltodextrin 0.05%-0.15%, sulphate aluminium cement 2%-6%.
2. lime stone chip maximum particle diameter described in is less than 2%, MB values and contained less than 0.50, calcium carbonate no more than 2.36mm, clay content Amount is more than 90%;The silicon ash encryption stage, activity are not less than 105%;The outer flyash of the grade, loss on ignition are not more than 8%;The lithium Slag, 28d activity indexs value are not more than 8% not less than 95%, sulfur trioxide content.
CN201710700778.7A 2017-08-16 2017-08-16 A kind of superfine composite modified agstone of concrete microdilatancy Pending CN107382277A (en)

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Application Number Priority Date Filing Date Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110128043A (en) * 2019-05-27 2019-08-16 中建材中岩科技有限公司 A kind of sub-micron active mixed material and preparation method thereof
CN110563369A (en) * 2019-09-23 2019-12-13 中铁四局集团有限公司 Modified limestone powder, preparation method thereof and concrete
CN111196697A (en) * 2020-01-14 2020-05-26 重庆砼磊混凝土有限公司 Preparation method of superfine composite modified limestone chip concrete
CN112079589A (en) * 2020-09-15 2020-12-15 中建西部建设西南有限公司 Modified lithium slag complex mineral admixture and preparation and application thereof
CN113417662A (en) * 2021-08-06 2021-09-21 广东水电二局股份有限公司 Tunnel excavation supporting method
CN115583812A (en) * 2022-10-08 2023-01-10 江西申洪新型材料有限公司 Composite modified bentonite and application thereof in concrete preparation

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110128043A (en) * 2019-05-27 2019-08-16 中建材中岩科技有限公司 A kind of sub-micron active mixed material and preparation method thereof
CN110563369A (en) * 2019-09-23 2019-12-13 中铁四局集团有限公司 Modified limestone powder, preparation method thereof and concrete
CN110563369B (en) * 2019-09-23 2021-07-30 中铁四局集团有限公司 Modified limestone powder, preparation method thereof and concrete
CN111196697A (en) * 2020-01-14 2020-05-26 重庆砼磊混凝土有限公司 Preparation method of superfine composite modified limestone chip concrete
CN112079589A (en) * 2020-09-15 2020-12-15 中建西部建设西南有限公司 Modified lithium slag complex mineral admixture and preparation and application thereof
CN113417662A (en) * 2021-08-06 2021-09-21 广东水电二局股份有限公司 Tunnel excavation supporting method
CN115583812A (en) * 2022-10-08 2023-01-10 江西申洪新型材料有限公司 Composite modified bentonite and application thereof in concrete preparation
CN115583812B (en) * 2022-10-08 2024-01-23 江西申洪新型材料有限公司 Composite modified bentonite and application thereof in preparing concrete

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