CN107382057A - A kind of corrosion-resistant glass and preparation method thereof - Google Patents

A kind of corrosion-resistant glass and preparation method thereof Download PDF

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Publication number
CN107382057A
CN107382057A CN201710617744.1A CN201710617744A CN107382057A CN 107382057 A CN107382057 A CN 107382057A CN 201710617744 A CN201710617744 A CN 201710617744A CN 107382057 A CN107382057 A CN 107382057A
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CN
China
Prior art keywords
parts
dosage
glass
cullet
corrosion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710617744.1A
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Chinese (zh)
Inventor
肖华章
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Huarui Glass Co Ltd
Original Assignee
Chongqing Huarui Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chongqing Huarui Glass Co Ltd filed Critical Chongqing Huarui Glass Co Ltd
Priority to CN201710617744.1A priority Critical patent/CN107382057A/en
Publication of CN107382057A publication Critical patent/CN107382057A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/02Other methods of shaping glass by casting molten glass, e.g. injection moulding
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/02Pretreated ingredients
    • C03C1/024Chemical treatment of cullet or glass fibres
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/20Compositions for glass with special properties for chemical resistant glass

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of corrosion-resistant glass and preparation method thereof, it is made up of the raw material of following mass fraction:The dosage of quartz sand is 80 100 parts, the dosage of soda ash is 25 32 parts, the dosage of lime stone is 1.5 2.5 parts, the dosage of plant ash is 0.07 0.15 parts, and the dosage of sodium nitrate is 0.01 0.03 parts, and the dosage of saltcake is 0.02 0.04 parts, the dosage of cullet is 0.8 1.2 parts, the advantages of glass obtained by the preparation method of the present invention has corrosion resistance, and stability is good, and service life is long.

Description

A kind of corrosion-resistant glass and preparation method thereof
Technical field
The present invention relates to a kind of corrosion-resistant glass and preparation method thereof.
Background technology
Glass be fused together by silica and other chemical substances formed (main production raw material is:Soda ash, stone Lime stone, quartz).Contiguous network structure is formed in melting, viscosity, which gradually increases and hardened, in cooling procedure causes what it was crystallized Silicates nonmetallic materials.It is widely used in building, for every wind printing opacity, belonging to mixture.Separately some gold have been mixed into it The oxide or salt of category and show the coloured glass of color, and pass through physics or chemistry method made from tempering glass Glass etc., is widely used in building, for every wind printing opacity.
Glass contacts with the external world, is influenceed by natural cause, exposes to the weather for a long time, causes glass to corrode, it is difficult to meet people To the demand of its general performance.
The content of the invention
In view of the drawbacks described above of prior art, it is an object of the invention to provide a kind of corrosion-resistant glass and its making side Method, there is corrosion resistance, and stability is good, service life length.
The purpose of the present invention realized by such technical scheme, a kind of corrosion-resistant glass, by following mass fraction Raw material composition:The dosage of quartz sand is 80-100 parts, and the dosage of soda ash is 25-32 parts, and the dosage of lime stone is 1.5-2.5 Part, the dosage of plant ash is 0.07-0.15 parts, and the dosage of sodium nitrate is 0.01-0.03 parts, and the dosage of saltcake is 0.02-0.04 Part, the dosage of cullet is 0.8-1.2 parts.
Further, the cullet remove out impurity, and the cullet are clear glass, and every cullet volume is less than 1m3
Further, mixed after being soaked 0.5 hour in the cullet immersion hydrofluoric acid solution after filtration and washing with the raw material Close.
Further, the raw material composition:The dosage of quartz sand is 80 parts, and the dosage of soda ash is 29 parts, the dosage of lime stone For 2 parts, the dosage of plant ash is 0.1 part, and the dosage of sodium nitrate is 0.02 part, and the dosage of saltcake is 0.03 part, the use of cullet Measure as 1 part.
A kind of preparation method of corrosion-resistant glass, comprises the following steps:
The first step:Take quartz sand 80-100 parts, soda ash 25-32 parts, lime stone 1.5-2.5 parts, plant ash 0.07-0.15 Part, sodium nitrate 0.01-0.03 parts, saltcake 0.02-0.04 parts, cullet 0.8-1.2 parts are well mixed;
Second step:The mixture of upper step is put into smelting furnace, pressure 100-200Mpa, 500-1000 degrees Celsius of temperature, 1-2 Hour, carry out melting;
3rd step:The bath of glass that top is obtained is poured into prepared mould, is annealed to the demoulding of normal temperature rear mold naturally, is obtained Glass.
Further, annealing is that glass is placed into lucifuge and ventilation naturally in the 3rd step.
Further, glass will be obtained in the 3rd step should be polished and rounding.
By adopting the above-described technical solution, the present invention has the advantage that:Permanence and corrosion-resistant can be produced Glass, and service life grow, preparation method is simple, low manufacture cost.
Other advantages, target and the feature of the present invention will be illustrated in the following description to a certain extent, and And to a certain extent, based on will be apparent to those skilled in the art to investigating hereafter, Huo Zheke To be instructed from the practice of the present invention.The target and other advantages of the present invention can be wanted by following specification and right Book is sought to realize and obtain.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1:
A kind of corrosion-resistant glass, is made up of the raw material of following mass fraction:The dosage of quartz sand is 80 parts, the dosage of soda ash For 29 parts, the dosage of lime stone is 2 parts, and the dosage of plant ash is 0.1 part, and the dosage of sodium nitrate is 0.02 part, the dosage of saltcake For 0.03 part, the dosage of cullet is 1 part.
The cullet remove out impurity, and the cullet are clear glass, every cullet volume 0.5m3
Mixed after being soaked 0.5 hour in the cullet immersion hydrofluoric acid solution after filtration and washing with the raw material.
A kind of preparation method of corrosion-resistant glass, comprises the following steps:
The first step:Take 80 parts of quartz sand, 29 parts of soda ash, 2 parts of lime stone, 0.1 part of plant ash, 0.02 part of sodium nitrate, saltcake 0.03 part, 1 part of cullet are well mixed;
Second step:The mixture of upper step is put into smelting furnace, pressure 150Mpa, 800 degrees Celsius of temperature, 1.5 hours, carried out Melting;
3rd step:The bath of glass that top is obtained is poured into prepared mould, is annealed to the demoulding of normal temperature rear mold naturally, is obtained Glass.
Annealing is that glass is placed into lucifuge and ventilation naturally in 3rd step.
Glass will be obtained in 3rd step should be polished and rounding.
Embodiment 2
A kind of corrosion-resistant glass, is made up of the raw material of following mass fraction:The dosage of quartz sand is 90 parts, the dosage of soda ash For 25 parts, the dosage of lime stone is 1.5 parts, and the dosage of plant ash is 0.07 part, and the dosage of sodium nitrate is 0.01 part, the use of saltcake Measure as 0.02 part, the dosage of cullet is 0.8 part.
The cullet remove out impurity, and the cullet are clear glass, every cullet volume 0.5m3
Mixed after being soaked 0.5 hour in the cullet immersion hydrofluoric acid solution after filtration and washing with the raw material.
A kind of preparation method of corrosion-resistant glass, comprises the following steps:
The first step:Take 90 parts of quartz sand, 25 parts of soda ash, 1.5 parts of lime stone, 0.07 part of plant ash, 0.01 part of sodium nitrate, awns 0.02 part of nitre, 0.8 part of cullet are well mixed;
Second step:The mixture of upper step is put into smelting furnace, pressure 100Mpa, 500 degrees Celsius of temperature, 1 hour, melted Refining;
3rd step:The bath of glass that top is obtained is poured into prepared mould, is annealed to the demoulding of normal temperature rear mold naturally, is obtained Glass.
Annealing is that glass is placed into lucifuge and ventilation naturally in 3rd step.
Glass will be obtained in 3rd step should be polished and rounding.
Embodiment 3
A kind of corrosion-resistant glass, is made up of the raw material of following mass fraction:The dosage of quartz sand is 100 parts, the use of soda ash Measure as 32 parts, the dosage of lime stone is 2.5 parts, and the dosage of plant ash is 0.15 part, and the dosage of sodium nitrate is 0.03 part, saltcake Dosage is 0.04 part, and the dosage of cullet is 1.2 parts.
The cullet remove out impurity, and the cullet are clear glass, every cullet volume 0.5m3
Mixed after being soaked 0.5 hour in the cullet immersion hydrofluoric acid solution after filtration and washing with the raw material.
A kind of preparation method of corrosion-resistant glass, comprises the following steps:
The first step:Take 100 parts of quartz sand, 32 parts of soda ash, 2.5 parts of lime stone, 0.15 part of plant ash, 0.03 part of sodium nitrate, 0.04 part of saltcake, 1.2 parts of cullet are well mixed;
Second step:The mixture of upper step is put into smelting furnace, pressure 200Mpa, 1000 degrees Celsius of temperature, 2 hours, carried out Melting;
3rd step:The bath of glass that top is obtained is poured into prepared mould, is annealed to the demoulding of normal temperature rear mold naturally, is obtained Glass.
Annealing is that glass is placed into lucifuge and ventilation naturally in 3rd step.
Glass will be obtained in 3rd step should be polished and rounding.
The glass that the present embodiment 1 obtains has decay resistance and stably, service life length.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention Art scheme is modified or equivalent substitution, and without departing from the objective and scope of the technical program, it all should cover in the present invention Right among.

Claims (7)

  1. A kind of 1. corrosion-resistant glass, it is characterised in that:It is made up of the raw material of following mass fraction:The dosage of quartz sand is 80-100 Part, the dosage of soda ash is 25-32 parts, and the dosage of lime stone is 1.5-2.5 parts, and the dosage of plant ash is 0.07-0.15 parts, nitric acid The dosage of sodium is 0.01-0.03 parts, and the dosage of saltcake is 0.02-0.04 parts, and the dosage of cullet is 0.8-1.2 parts.
  2. 2. corrosion-resistant glass as claimed in claim 1, it is characterised in that:The cullet remove out impurity, and the cullet are Clear glass, every cullet volume are less than 1m3
  3. 3. corrosion-resistant glass as claimed in claim 1, it is characterised in that:The cullet immerse in hydrofluoric acid solution and soaked Mixed after 0.5 hour after filtration and washing with the raw material.
  4. 4. corrosion-resistant glass as claimed in claim 1, it is characterised in that:The raw material composition:The dosage of quartz sand is 80 parts, The dosage of soda ash is 29 parts, and the dosage of lime stone is 2 parts, and the dosage of plant ash is 0.1 part, and the dosage of sodium nitrate is 0.02 part, The dosage of saltcake is 0.03 part, and the dosage of cullet is 1 part.
  5. A kind of 5. preparation method of corrosion-resistant glass, it is characterised in that:Comprise the following steps:
    The first step:Take quartz sand 80-100 parts, soda ash 25-32 parts, lime stone 1.5-2.5 parts, plant ash 0.07-0.15 parts, nitre Sour sodium 0.01-0.03 parts, saltcake 0.02-0.04 parts, cullet 0.8-1.2 parts are well mixed;
    Second step:The mixture of upper step is put into smelting furnace, pressure 100-200Mpa, 500-1000 degrees Celsius of temperature, 1-2 is small When, carry out melting;
    3rd step:The bath of glass that top is obtained is poured into prepared mould, is annealed to the demoulding of normal temperature rear mold naturally, is obtained glass Glass.
  6. 6. the preparation method of corrosion-resistant glass as claimed in claim 5, it is characterised in that:Annealing is naturally in 3rd step Glass is placed into lucifuge and ventilation.
  7. 7. the preparation method of corrosion-resistant glass as claimed in claim 5, it is characterised in that:Glass will be obtained in 3rd step It should be polished and rounding.
CN201710617744.1A 2017-07-26 2017-07-26 A kind of corrosion-resistant glass and preparation method thereof Pending CN107382057A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710617744.1A CN107382057A (en) 2017-07-26 2017-07-26 A kind of corrosion-resistant glass and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710617744.1A CN107382057A (en) 2017-07-26 2017-07-26 A kind of corrosion-resistant glass and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107382057A true CN107382057A (en) 2017-11-24

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CN201710617744.1A Pending CN107382057A (en) 2017-07-26 2017-07-26 A kind of corrosion-resistant glass and preparation method thereof

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CN (1) CN107382057A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110577362A (en) * 2019-10-21 2019-12-17 徐州宏华玻璃科技有限公司 Formula of more environment-friendly toughened glass

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105000804A (en) * 2015-08-05 2015-10-28 芜湖新利德玻璃制品有限公司 Corrosion-resisting glass and preparation method thereof
CN105060711A (en) * 2015-08-04 2015-11-18 芜湖新利德玻璃制品有限公司 High-strength glass and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105060711A (en) * 2015-08-04 2015-11-18 芜湖新利德玻璃制品有限公司 High-strength glass and preparation method thereof
CN105000804A (en) * 2015-08-05 2015-10-28 芜湖新利德玻璃制品有限公司 Corrosion-resisting glass and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110577362A (en) * 2019-10-21 2019-12-17 徐州宏华玻璃科技有限公司 Formula of more environment-friendly toughened glass

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Application publication date: 20171124