CN107381944A - A kind of mine water shunting advanced treatment apparatus and its processing method - Google Patents
A kind of mine water shunting advanced treatment apparatus and its processing method Download PDFInfo
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- CN107381944A CN107381944A CN201710648223.2A CN201710648223A CN107381944A CN 107381944 A CN107381944 A CN 107381944A CN 201710648223 A CN201710648223 A CN 201710648223A CN 107381944 A CN107381944 A CN 107381944A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/38—Treatment of water, waste water, or sewage by centrifugal separation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
- C02F2201/007—Modular design
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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Abstract
A kind of mine water shunts advanced treatment apparatus, including preliminary Rose Box, centrifugal sedimentation system, water storage transferring box, four-way magnet-controlled valve and data acquisition control system, the bottom of preliminary Rose Box obstructs mechanism for natural water plant, the top of preliminary Rose Box is sieve mechanism, the bottom of preliminary Rose Box is connected by the first water pipe with the water inlet of centrifugal sedimentation system, and the first water pipe is provided with the first valve and the first water pump；The present invention realizes the depth shunting multistep treatment of mine water, silt, coal dust and oil body material in mine water can be filtered out, heavy metal ion, sulfate radical and sulfite ion in mine water, nitrate anion and nitrite ion can be filtered off by microbiological treatment, handling process is finely perfect, heavy-metal ion removal is handled using different microorganism fungus kinds, effluent quality is good, water resource sub-prime improves treatment effeciency using utilization rate, shunting processing is improved.
Description
Technical field
The invention belongs to coal mine operation equipment technical field, and in particular to a kind of mine water shunts advanced treatment apparatus
And its processing method.
Background technology
Water is Source of life, and water resource is the guarantee of human society happy life.China's water resources ownership per capita only has
The a quarter of world's water resources ownership per capita, one of 13 Ge Pin lands that abounds in rivers and lakes in the world are classified as by the United Nations.86, the whole nation is state-owned
Water shortage accounts for 71% in emphasis coal field, serious water shortage up to 40%, shortage of water resources problem seriously governs mining production and coal
Charcoal industrial expansion and the daily life for affecting coal workers.
Coal field mine water is unprocessed and arbitrarily discharges, and brings obvious environmental pollution, therefore by mine water deeply
Recycling is carried out after processing and has become urgent problem to be solved in production.The deep treatment method of China's mine water at present
There are solid-liquid isolation method, neutralisation, chemical agent flocculence, Ecological Disposal method, molecule membrane filter technique etc., but treating mine drainage type be present
The problems such as single, equipment and technological process are complicated, processing equipment and operating cost are high.
The content of the invention
The present invention is in order to solve weak point of the prior art, there is provided at a kind of depth shunting multistage for realizing mine water
Reason, silt, coal dust and oil body material in mine water can be filtered out, can be filtered off by microbiological treatment in mine water
The mine water shunting advanced treating dress of heavy metal ion, sulfate radical and sulfite ion, nitrate anion and nitrite ion
Put and its processing method.
In order to solve the above technical problems, the present invention adopts the following technical scheme that：A kind of mine water shunts advanced treatment apparatus,
Including preliminary Rose Box, centrifugal sedimentation system, water storage transferring box, four-way magnet-controlled valve and data acquisition control system, preliminary mistake
The bottom of filter box is that natural water plant obstructs mechanism, and the top of preliminary Rose Box is sieve mechanism, the bottom of preliminary Rose Box
Portion is connected by the first water pipe with the water inlet of centrifugal sedimentation system, and the first water pipe is provided with the first valve and the first water pump, from
The delivery port of heart sedimenting system is connected by aqueduct with water storage transferring box, and aqueduct is provided with the second valve, water storage transferring box
Be connected by the second water pipe with the water inlet of four-way magnet-controlled valve, on the second water pipe along water (flow) direction be sequentially provided with oil water separator,
Water monitor, the 3rd valve and the second water pump；Data acquisition control system by data wire respectively with water monitor and four
Logical magnet-controlled valve connection；
First delivery port of four-way magnet-controlled valve is connected with sulfate reducing bacteria flocculation system by the 3rd water pipe, on the 3rd water pipe
Provided with the 4th valve；Second delivery port of four-way magnet-controlled valve is connected with denitrifying bacteria nitrogen converting system by the 4th water pipe,
4th water pipe is provided with the 5th valve；3rd delivery port of four-way magnet-controlled valve is connected with methanogen by the 5th water pipe and degraded
System, the 5th water pipe are provided with the 6th valve；Sulfate reducing bacteria flocculation system is turned by the 6th water pipe and denitrifying bacteria nitrogen
System connection is changed, the 6th water pipe is provided with the 3rd water pump and the 7th valve, and denitrifying bacteria nitrogen converting system passes through the 7th water pipe
It is connected with methanogen degeneration system, the 7th water pipe is provided with the 4th water pump and the 8th valve；Sulfate reducing bacteria flocculation system
It is connected by the 12nd water pipe with methanogen degeneration system, the 12nd water pipe is provided with the 8th water pump and the 14th valve；
Methanogen degeneration system is connected with first class purification cistern by the 8th water pipe, the 8th water pipe be provided with the 5th water pump and
9th valve, first class purification cistern are connected with secondary purification cistern by the 9th water pipe, along water (flow) direction on the 9th water pipe
It is sequentially provided with the tenth valve, ultrafiltration membrane system and the 11st valve；
Sulfate reducing bacteria flocculation system is connected by the tenth water pipe with first class purification cistern, and the tenth water pipe is provided with the 6th water
Pump and the 12nd valve, denitrifying bacteria nitrogen converting system are connected by the 11st water pipe with first class purification cistern, and the 11st
Water pipe is provided with the 7th water pump and the 13rd valve.
The structure phase of sulfate reducing bacteria flocculation system, denitrifying bacteria nitrogen converting system and methanogen degeneration system
Together, including isothermal reaction tank, middle part is provided with biofilm ball in isothermal reaction tank, and the outer layer of biofilm ball is nylon wire, biofilm ball it is interior
Portion is activated carbon granule；The filter screen positioned at the top of biofilm ball is provided with isothermal reaction tank, the top of isothermal reaction tank is provided with glass
Glass top cover, glass roof are provided with vent valve, pressure sensor；The tank wall of isothermal reaction tank is provided with pH sensors and pH
Adjust mouth；
It is micro- that sulfate reducing bacteria is accommodated on activated carbon granule wherein in the isothermal reaction tank of sulfate reducing bacteria flocculation system
Biology, hair nitrobacteria microorganism is accommodated on the activated carbon granule in the isothermal reaction tank of denitrifying bacteria nitrogen converting system,
Methanogen microorganism is accommodated on activated carbon granule in the isothermal reaction tank of methanogen degeneration system.
A kind of processing method of mine water shunting advanced treatment apparatus, comprises the following steps：
（1）Pending mine water is passed into the top of preliminary Rose Box, sieve mechanism by the silt in mine water and
Coal dust is filtered out, and the mine water after filtering is flowed into the natural water plant barrier mechanism of preliminary filtering lower box part, natural water plant
Obstruct in-house water plant on the one hand further to adsorb the silt in mine water and coal dust, on the other hand can also adsorb
Heavy metal ion, sulfate radical, sulfite ion, nitrate ion, nitrite ion and the oil of mine water inside points；
（2）Then the first valve is opened, starts the first water pump, the first water pump takes out the mine water after the processing in preliminary Rose Box
Enter into centrifugal sedimentation system, start centrifugal sedimentation system, centrifugal sedimentation system carries out centrifugal sedimentation, further mistake to mine water
Filter out the silt in mine water；
（3）After centrifugal sedimentation, the second valve is opened, mine water is flowed into water storage transferring box by aqueduct in centrifugal sedimentation system,
Mine water, which flows into, carries out secondary precipitation in water storage transferring box；
（4）Remove the lubricant component in mine water：Open the 3rd valve, start the second water pump, the second water pump is by water storage transferring box
Interior mine water is pumped into the second water pipe, wherein the oil water separator on the second water pipe filters off the oil body in mine water；
（5）Then water monitor detects to the water quality in the second water pipe, detect mine water in heavy metal, sulfate radical from
Whether son, sulfite ion, the concentration of nitrate ion and nitrite ion exceeded, and water monitor will detect
Data simultaneously make corresponding finger by data line transfer to data acquisition control system, data acquisition control system analyze data
Order, then makes corresponding processing according to instruction.
When the concentration over-standard for the heavy metal that water monitor detects, when other detection projects meet standard, data acquisition
Control system sends instruction, opens the 3rd delivery port of four-way magnet-controlled valve, the step（5）The middle processing made according to instruction
Step, including：Mine water enters the 5th water pipe by the 3rd delivery port of four-way magnet-controlled valve, then opens the on the 5th water pipe
Six valves, mine water enter in the isothermal reaction tank of methanogen degeneration system, and the constant temperature for adjusting methanogen degeneration system is anti-
Answer the temperature and pH in tank so that methanogen microorganism of the temperature in 35 DEG C, pH 7, methanogen degeneration system according to
Flourish is needed to absorb heavy metal ion, and the isothermal reaction tank of methanogen degeneration system is then observed by glass roof
Interior mine water, after mine water covers filter screen, start the 5th water pump, and open the 9th valve, the tenth valve and the 11st
Valve, mine water are pumped into first class purification cistern by the 5th water pump, and first class purification cistern carries out disinfection and adjusted to mine water
Its pH, then mine water after ultrafiltration membrane system filters enter secondary purification cistern in.
The sulfate ion and ion concentration of inferior sulfate radical detected when water monitor is exceeded, and other detection projects meet
During standard, data acquisition control system sends instruction, opens first delivery port of four-way magnet-controlled valve, the step（5）Middle
The processing step made according to instruction, including：Mine water enters the 3rd water pipe by first delivery port of four-way magnet-controlled valve, then beats
The 4th valve on the 3rd water pipe is opened, mine water enters in the isothermal reaction tank of sulfate reducing bacteria flocculation system, adjusts sulfuric acid
Temperature and pH in the isothermal reaction tank of salt reducing bacteria flocculation system so that temperature at 35 DEG C, pH 7, wad a quilt with cotton by sulfate reducing bacteria
Sulfate reduction bacteria microorganism in solidifying system is with SO4 2-、SO3 2-For electron acceptor, using organic matter as carbon source and electron donor, most
Hydrogen sulfide is produced eventually, and the mine water in the isothermal reaction tank of sulfate reducing bacteria flocculation system is then observed by glass roof,
After mine water covers filter screen, start the 6th water pump, and open the 12nd valve, the tenth valve and the 11st valve, mine
Water is pumped into first class purification cistern by the 6th water pump, and first class purification cistern carries out disinfection to mine water and adjusts its pH, then
Mine water enters in secondary purification cistern after ultrafiltration membrane system filters.
When the nitrate ion and nitrous acid acid ion concentration over-standard that water monitor detects, other detection project symbols
During standardization, data acquisition control system sends instruction, opens second delivery port of four-way magnet-controlled valve, the step（5）In
The processing step made according to instruction, including：Mine water enters the 4th water pipe by second delivery port of four-way magnet-controlled valve, then
The 5th valve on the 4th water pipe is opened, mine water enters in the isothermal reaction tank of denitrifying bacteria nitrogen converting system, and adjustment is anti-
Temperature and pH in the isothermal reaction tank of nitrobacteria nitrogen converting system so that temperature is at 30 DEG C, pH 7, denitrifying bacteria nitrogen
Nitrate ion and nitrite ion are converted into nitrogen by the hair nitrobacteria microorganism in converting system, then pass through glass
Mine water in the isothermal reaction tank of top cover observation hair nitrobacteria microorganism, after mine water covers filter screen, starts the 7th water
Pump, and the 13rd valve, the tenth valve and the 11st valve are opened, mine water is pumped into first class purification water storage by the 7th water pump
Pond, first class purification cistern carry out disinfection to mine water and adjust its pH, and then mine water filters laggard by ultrafiltration membrane system
Enter in secondary purification cistern.
When heavy metal, sulfate ion and the ion concentration of inferior sulfate radical that water monitor detects are exceeded, and nitrate anion
When ion and nitrous acid acid ion concentration meet standard, data collecting system sends instruction, opens the first of four-way magnet-controlled valve
Individual delivery port, the step（5）The middle processing step made according to instruction, including：Mine water is by first of four-way magnet-controlled valve
Delivery port enters the 3rd water pipe, then opens the 4th valve on the 3rd water pipe, and mine water enters sulfate reducing bacteria flocculation system
In the isothermal reaction tank of system, temperature and pH in the isothermal reaction tank of sulfate reducing bacteria flocculation system are adjusted so that temperature exists
35 DEG C, pH 7, the sulfate reduction bacteria microorganism in sulfate reducing bacteria flocculation system is with SO4 2-、SO3 2-For electron acceptor, with
Organic matter is carbon source and electron donor, finally produces hydrogen sulfide, then observes sulfate reducing bacteria flocculation system by glass roof
Mine water in the isothermal reaction tank of system, after mine water covers filter screen, start the 8th water pump, and open the 14th valve, ore deposit
Well water is pumped into by the 8th water pump in the isothermal reaction tank of methanogen degeneration system, and the constant temperature for adjusting methanogen degeneration system is anti-
Answer the temperature and pH in tank so that methanogen microorganism of the temperature in 35 DEG C, pH 7, methanogen degeneration system according to
Flourish is needed to absorb heavy metal ion, and the isothermal reaction tank of methanogen degeneration system is then observed by glass roof
Interior mine water, after mine water covers filter screen, start the 5th water pump, and open the 9th valve, the tenth valve and the 11st
Valve, mine water are pumped into first class purification cistern by the 5th water pump, and first class purification cistern carries out disinfection and adjusted to mine water
Its pH, then mine water after ultrafiltration membrane system filters enter secondary purification cistern in.
When heavy metal, nitrate ion and the nitrous acid acid ion concentration over-standard that water monitor detects, and sulfuric acid
When radical ion and ion concentration of inferior sulfate radical meet standard, data collecting system sends instruction, opens the second of four-way magnet-controlled valve
Individual delivery port, the step（5）The middle processing step made according to instruction, including：Mine water is by second of four-way magnet-controlled valve
Delivery port enters the 4th water pipe, then opens the 5th valve on the 4th water pipe, and mine water enters denitrifying bacteria nitrogen conversion system
In the isothermal reaction tank of system, temperature and pH in the isothermal reaction tank of denitrifying bacteria nitrogen converting system are adjusted so that temperature exists
30 DEG C, pH 7, hair nitrobacteria microorganism in denitrifying bacteria nitrogen converting system is by nitrate ion and nitrite ion
Nitrogen is converted into, the mine water in the isothermal reaction tank of hair nitrobacteria microorganism is then observed by glass roof, works as mine
After water covers filter screen, start the 4th water pump, and open the 8th valve, mine water is pumped into methanogen degeneration system by the 4th water pump
Isothermal reaction tank in, adjust the temperature and pH in the isothermal reaction tank of methanogen degeneration system so that temperature is at 35 DEG C, pH
For 7, the methanogen microorganism in methanogen degeneration system needs to absorb heavy metal ion according to flourish, then leads to
The mine water crossed in the isothermal reaction tank of glass roof observation methanogen degeneration system, after mine water covers filter screen, start
5th water pump, and the 9th valve, the tenth valve and the 11st valve are opened, mine water is pumped into first class purification by the 5th water pump and stored
Pond, first class purification cistern carry out disinfection to mine water and adjust its pH, and then mine water is after ultrafiltration membrane system filters
Into in secondary purification cistern.
When water monitor detects sulfate ion, ion concentration of inferior sulfate radical, nitrate ion and nitrous acid acid group
Ion concentration is exceeded, and when heavy metal meets standard, data collecting system sends instruction, and open four-way magnet-controlled valve first goes out
The mouth of a river, the step（5）The middle processing step made according to instruction, including：Mine water by four-way magnet-controlled valve first water outlet
Mouth enters the 3rd water pipe, then opens the 4th valve on the 3rd water pipe, and mine water enters sulfate reducing bacteria flocculation system
In isothermal reaction tank, adjust sulfate reducing bacteria flocculation system isothermal reaction tank in temperature and pH so that temperature at 35 DEG C,
PH is 7, and the sulfate reduction bacteria microorganism in sulfate reducing bacteria flocculation system is with SO4 2-、SO3 2-For electron acceptor, with organic
Thing is carbon source and electron donor, finally produces hydrogen sulfide, then observes sulfate reducing bacteria flocculation system by glass roof
Mine water in isothermal reaction tank, after mine water covers filter screen, start the 3rd water pump, and open the 7th valve, mine water quilt
4th water pump is pumped into the isothermal reaction tank of denitrifying bacteria nitrogen converting system, adjusts the constant temperature of denitrifying bacteria nitrogen converting system
Temperature and pH in retort so that hair nitrobacteria of the temperature in 30 DEG C, pH 7, denitrifying bacteria nitrogen converting system is micro-
Nitrate ion and nitrite ion are converted into nitrogen by biology, then observe hair nitrobacteria microorganism by glass roof
Isothermal reaction tank in mine water, after mine water covers filter screen, start the 7th water pump, and open the 13rd valve, the tenth
Valve and the 11st valve, mine water are pumped into first class purification cistern by the 7th water pump, and first class purification cistern is to mine water
Carry out disinfection and adjust its pH, then mine water enters in secondary purification cistern after ultrafiltration membrane system filters.
When water monitor detects heavy metal, sulfate ion, sulfite ion, nitrate ion and nitrous acid
When the concentration of radical ion is exceeded, data collecting system sends instruction, opens first delivery port of four-way magnet-controlled valve, the step
Suddenly（5）The middle processing step made according to instruction, including：Mine water enters the 3rd water by first delivery port of four-way magnet-controlled valve
Pipe, the 4th valve on the 3rd water pipe is then opened, mine water enters in the isothermal reaction tank of sulfate reducing bacteria flocculation system,
Adjust the temperature and pH in the isothermal reaction tank of sulfate reducing bacteria flocculation system so that temperature is at 35 DEG C, pH 7, sulfate
Sulfate reduction bacteria microorganism in reducing bacteria flocculation system is with SO4 2-、SO3 2-For electron acceptor, using organic matter as carbon source and electricity
Sub- donor, hydrogen sulfide is finally produced, in the isothermal reaction tank that sulfate reducing bacteria flocculation system is then observed by glass roof
Mine water, after mine water covers filter screen, start the 3rd water pump, and open the 7th valve, mine water is pumped into by the 4th water pump
In the isothermal reaction tank of denitrifying bacteria nitrogen converting system, the temperature in the isothermal reaction tank of denitrifying bacteria nitrogen converting system is adjusted
Degree and pH so that hair nitrobacteria microorganism of the temperature in 30 DEG C, pH 7, denitrifying bacteria nitrogen converting system is by nitrate anion
Ion and nitrite ion are converted into nitrogen, and the isothermal reaction tank of hair nitrobacteria microorganism is then observed by glass roof
Interior mine water, after mine water covers filter screen, start the 4th water pump, and open the 8th valve, mine water is taken out by the 4th water pump
Enter in the isothermal reaction tank of methanogen degeneration system, adjust methanogen degeneration system isothermal reaction tank in temperature and
PH so that methanogen microorganism of the temperature in 35 DEG C, pH 7, methanogen degeneration system according to flourish need by
Heavy metal ion is absorbed, and the mine water in the isothermal reaction tank of methanogen degeneration system is then observed by glass roof, when
After mine water covers filter screen, start the 5th water pump, and open the 9th valve, the tenth valve and the 11st valve, mine water quilt
5th water pump is pumped into first class purification cistern, and first class purification cistern carries out disinfection to mine water and adjusts its pH, then mine
Water enters in secondary purification cistern after ultrafiltration membrane system filters.
Above-mentioned technical proposal is used, the invention has the advantages that：Pending mine water flows through successively in the present invention
Stood in box screens coarse filtration system, natural water plant baffle system, centrifugal sedimentation system, water storage case；Remove silt, coal dust etc.
Impurity；The water outlet of station case, flows through oil water separator in water storage；Removal mixes oil component；The water outlet of oil water separator, flows through water quality
Monitor, data collection and control system, four-way magnet-controlled valve, realize that shunting is handled；The shunting water outlet of four-way magnet-controlled valve, according to water
The difference of matter has respectively entered sulfate reducing bacteria flocculation system, denitrifying bacteria nitrogen converting system, methanogen degeneration system
Carry out biological treatment；Heavy-metal ion removal, nitrate nitrogen, nitrite nitrogen etc.；After microbiological treatment, from methane phase degeneration system
Water outlet, flow through first class purification water cistern and carry out disinfection, adjust pH, the purposes such as coal washing water, mining area landscape water can be used as, flowed through
Ultrafiltration membrane system, into secondary purification water cistern, as purposes such as mining area domestic waters.It is perfect because handling process is fine,
Heavy-metal ion removal is handled using different microorganism fungus kinds, effluent quality is good, and water resource sub-prime utilizes and improves utilization rate,
Shunting processing improves treatment effeciency.
Brief description of the drawings
Fig. 1 is the structural representation of mine water shunting advanced treatment apparatus in the present invention；
Fig. 2 is sulfate reducing bacteria flocculation system in the present invention, denitrifying bacteria nitrogen converting system and methanogen degeneration system
Connection diagram.
Embodiment
As depicted in figs. 1 and 2, a kind of mine water of the invention shunting advanced treatment apparatus, including preliminary Rose Box, centrifugation
Sedimenting system 1, water storage transferring box 2, four-way magnet-controlled valve 3 and data acquisition control system 4, the bottom of preliminary Rose Box is natural
Water plant obstructs mechanism 5, and natural water plant barrier mechanism 5 is planted in the aquatic plants such as the hornwort of preliminary Rose Box bottom for some
Thing, preliminary Rose Box can be made up of glass, the photosynthesis of water plant is beneficial to this, the top of preliminary Rose Box is screen cloth
Coarse filtration mechanism 6, sieve mechanism 6 include four layers of filter screen of setting side by side up and down, and the aperture of four layers of filter screen is gradual from top to bottom
Diminish, to reach the effect of the silt in preliminary filtering mine water, the bottom of preliminary Rose Box is heavy by the first water pipe 7 and centrifugation
The water inlet connection of drop system 1, the first water pipe 7 are provided with the first valve 8 and the first water pump 9, the delivery port of centrifugal sedimentation system 1
It is connected by aqueduct 10 with water storage transferring box 2, aqueduct 10 is provided with the second valve 11, and water storage transferring box 2 passes through the second water
Pipe 12 is connected with the water inlet of four-way magnet-controlled valve 3, and oil water separator 13, water quality are sequentially provided with along water (flow) direction on the second water pipe 12
Monitor 14, the 3rd valve 15 and the second water pump 16；Data acquisition control system 4 by data wire respectively with water monitor 14
Connected with four-way magnet-controlled valve 3；
First delivery port of four-way magnet-controlled valve 3 is connected with sulfate reducing bacteria flocculation system 17 by the 3rd water pipe 18, and the 3rd
Water pipe 18 is provided with the 4th valve 19；It is thin that second delivery port of four-way magnet-controlled valve 3 by the 4th water pipe 20 is connected with denitrification
Bacterium nitrogen converting system 21, the 4th water pipe 20 are provided with the 5th valve 22；3rd delivery port of four-way magnet-controlled valve 3 passes through the 5th water
Pipe 23 is connected with methanogen degeneration system 24, and the 5th water pipe 23 is provided with the 6th valve 25；Sulfate reducing bacteria flocculation system
17 are connected by the 6th water pipe 26 with denitrifying bacteria nitrogen converting system 21, and the 6th water pipe 26 is provided with the 3rd water pump 27 and the 7th
Valve 28, denitrifying bacteria nitrogen converting system 21 are connected by the 7th water pipe 29 with methanogen degeneration system 24, the 7th water pipe
29 are provided with the 4th water pump 30 and the 8th valve 31；Sulfate reducing bacteria flocculation system 17 passes through the 12nd water pipe 32 and methane phase
Bacterium degeneration system 24 connects, and the 12nd water pipe 32 is provided with the 8th water pump 33 and the 14th valve 34；
Methanogen degeneration system 24 is connected with first class purification cistern 36 by the 8th water pipe 35, in first class purification cistern 36
Can be carried out disinfection processing using chlorine to mine water, and the 8th water pipe 35 is provided with the 5th water pump 37 and the 9th valve 38, one-level
Purification cistern 36 is connected with secondary purification cistern 40 by the 9th water pipe 39, is set successively along water (flow) direction on the 9th water pipe 39
There are the tenth valve 41, the valve 43 of ultrafiltration membrane system 42 and the 11st, ultrafiltration membrane system 42 uses tube-type hollow fiber filter membrane, filter membrane
It is adopted as polyvinyl chloride；
Sulfate reducing bacteria flocculation system 17 is connected by the tenth water pipe 44 with first class purification cistern 36, is set on the tenth water pipe 44
There are the 6th water pump 45 and the 12nd valve 46, denitrifying bacteria nitrogen converting system 21 is stored by the 11st water pipe 47 with first class purification
Pond 36 connects, and the 11st water pipe 47 is provided with the 7th water pump 48 and the 13rd valve 49.
The knot of sulfate reducing bacteria flocculation system 17, denitrifying bacteria nitrogen converting system 21 and methanogen degeneration system 24
Structure is identical, including isothermal reaction tank 50, and middle part is provided with biofilm ball 51 in isothermal reaction tank 50, and the outer layer of biofilm ball 51 is nylon
Net, the inside of biofilm ball 51 is activated carbon granule；The filter screen 52 positioned at the top of biofilm ball 51 is provided with isothermal reaction tank 50, it is permanent
The top of warm retort 50 is provided with glass roof 53, and glass roof 53 is provided with vent valve 54, pressure sensor 55；Isothermal reaction
The tank wall of tank 50 is provided with pH sensors 56 and pH regulation mouths 57, and mouth 57 can be adjusted by pH into isothermal reaction tank 50
Soda acid chemical substance is added, to change the pH in isothermal reaction tank 50；
Sulfate reduction is accommodated on activated carbon granule wherein in the isothermal reaction tank 50 of sulfate reducing bacteria flocculation system 17
Bacteria microorganism, hair nitrobacteria is accommodated on the activated carbon granule in the isothermal reaction tank 50 of denitrifying bacteria nitrogen converting system 21
Microorganism, methanogen microorganism is accommodated on the activated carbon granule in the isothermal reaction tank 50 of methanogen degeneration system 24.
The processing method of the mine water shunting advanced treatment apparatus of the present invention, comprises the following steps：
（1）Pending mine water is passed into the top of preliminary Rose Box, sieve mechanism 6 by the silt in mine water and
Coal dust is filtered out, and the mine water after filtering is flowed into the natural water plant barrier mechanism 5 of preliminary filtering lower box part, natural water plant
Obstruct the water plant in mechanism 5 on the one hand further to adsorb the silt in mine water and coal dust, on the other hand can also inhale
Heavy metal ion, sulfate radical, sulfite ion, nitrate ion, nitrite ion and the oil of attached mine water inside points
Matter；
（2）Then open the first valve 8, start the first water pump 9, the first water pump 9 is by the mine after the processing in preliminary Rose Box
Water is pumped into centrifugal sedimentation system 1, starts centrifugal sedimentation system 1, and centrifugal sedimentation system 1 carries out centrifugal sedimentation to mine water,
Further filter out the silt in mine water；
（3）After centrifugal sedimentation, the second valve 11 is opened, mine water flows into water storage transfer by aqueduct 10 in centrifugal sedimentation system 1
In case 2, mine water, which flows into, carries out secondary precipitation in water storage transferring box 2；
（4）Remove the lubricant component in mine water：Open the 3rd valve 15, start the second water pump 16, the second water pump 16 is by water storage
Mine water in transferring box 2 is pumped into the second water pipe 12, wherein the oil water separator 13 on the second water pipe 12 is by mine water
Oil body filters off；
（5）Then water monitor 14 detects to the water quality in the second water pipe 12, detects heavy metal, sulfuric acid in mine water
Whether radical ion, sulfite ion, the concentration of nitrate ion and nitrite ion are exceeded, and water monitor 14 will be examined
The data measured simultaneously make phase by data line transfer to data acquisition control system 4, the analyze data of data acquisition control system 4
The instruction answered；
When the concentration over-standard of the heavy metal detected, when other detection projects meet standard, data acquisition control system 4 sends finger
Order, opens the 3rd delivery port of four-way magnet-controlled valve 3, and mine water enters the 5th water by the 3rd delivery port of four-way magnet-controlled valve 3
Pipe 23, then opens the 6th valve 25 on the 5th water pipe 23, and mine water enters the isothermal reaction of methanogen degeneration system 24
In tank 50, temperature and pH in the isothermal reaction tank 50 of adjustment methanogen degeneration system 24 so that temperature at 35 DEG C, pH 7,
Methanogen microorganism in methanogen degeneration system 24 needs to absorb heavy metal ion according to flourish, then passes through
Glass roof 53 observes the mine water in the isothermal reaction tank 50 of methanogen degeneration system 24, when mine water covers filter screen 52
Afterwards, start the 5th water pump 37, and open the 9th valve 38, the tenth valve 41 and the 11st valve 43, mine water is by the 5th water
Pump 37 is pumped into first class purification cistern 36, and first class purification cistern 36 carries out disinfection to mine water and adjusts its pH, then mine
Water enters in secondary purification cistern 40 after the filtering of ultrafiltration membrane system 42；
When the sulfate ion and ion concentration of inferior sulfate radical that detect are exceeded, when other detection projects meet standard, data are adopted
Collection control system 4 sends instruction, first delivery port of opening four-way magnet-controlled valve 3, and mine water is by first of four-way magnet-controlled valve 3
Delivery port enters the 3rd water pipe 18, then opens the 4th valve 19 on the 3rd water pipe 18, and mine water enters sulfate reducing bacteria
In the isothermal reaction tank 50 of flocculation system 17, temperature in the isothermal reaction tank 50 of adjustment sulfate reducing bacteria flocculation system 17 and
PH so that sulfate reduction bacteria microorganism of the temperature in 35 DEG C, pH 7, sulfate reducing bacteria flocculation system 17 is with SO4 2-、
SO3 2-For electron acceptor, using organic matter as carbon source and electron donor, hydrogen sulfide is finally produced, is then observed by glass roof 53
Mine water in the isothermal reaction tank 50 of sulfate reducing bacteria flocculation system 17, after mine water covers filter screen 52, start the 6th
Water pump 45, and open the 12nd valve 46, the tenth valve 41 and the 11st valve 43, mine water and be pumped into one by the 6th water pump 45
Level purification cistern 36, first class purification cistern 36 carries out disinfection to mine water and adjusts its pH, and then mine water passes through ultrafiltration
Membranous system 42 enters in secondary purification cistern 40 after filtering；
When the nitrate ion and nitrous acid acid ion concentration over-standard that detect, when other detection projects meet standard, data
Acquisition control system 4 sends instruction, opens second delivery port of four-way magnet-controlled valve 3, mine water is by the second of four-way magnet-controlled valve 3
Individual delivery port enters the 4th water pipe 20, then opens the 5th valve 22 on the 4th water pipe 20, and mine water enters denitrifying bacteria
In the isothermal reaction tank 50 of nitrogen converting system 21, the temperature in the isothermal reaction tank 50 of adjustment denitrifying bacteria nitrogen converting system 21
And pH so that hair nitrobacteria microorganism of the temperature in 30 DEG C, pH 7, denitrifying bacteria nitrogen converting system 21 is by nitrate anion
Ion and nitrite ion are converted into nitrogen, and the isothermal reaction of hair nitrobacteria microorganism is then observed by glass roof 53
Mine water in tank 50, after mine water covers filter screen 52, start the 7th water pump 48, and open the 13rd valve 49, the tenth valve
The 41 and the 11st valve 43 of door, mine water are pumped into first class purification cistern 36, first class purification cistern 36 by the 7th water pump 48
Mine water is carried out disinfection and adjusts its pH, then mine water enters secondary purification cistern after the filtering of ultrafiltration membrane system 42
In 40；
When the heavy metal, sulfate ion and ion concentration of inferior sulfate radical that detect are exceeded, and nitrate ion and nitrous acid acid
When ion concentration meets standard, data collecting system sends instruction, opens first delivery port of four-way magnet-controlled valve 3, mine
Water enters the 3rd water pipe 18 by first delivery port of four-way magnet-controlled valve 3, then opens the 4th valve 19 on the 3rd water pipe 18,
Mine water enters in the isothermal reaction tank 50 of sulfate reducing bacteria flocculation system 17, adjustment sulfate reducing bacteria flocculation system 17
Temperature and pH in isothermal reaction tank 50 so that sulfuric acid of the temperature in 35 DEG C, pH 7, sulfate reducing bacteria flocculation system 17
Salt reduces bacteria microorganism with SO4 2-、SO3 2-For electron acceptor, using organic matter as carbon source and electron donor, hydrogen sulfide is finally produced,
Then the mine water in the isothermal reaction tank 50 of sulfate reducing bacteria flocculation system 17 is observed by glass roof 53, works as mine water
After covering filter screen 52, start the 8th water pump 33, and open the 14th valve 34, mine water is pumped into methanogen by the 8th water pump 33
In the isothermal reaction tank 50 of degeneration system 24, temperature and pH in the isothermal reaction tank 50 of adjustment methanogen degeneration system 24,
So that methanogen microorganism of the temperature in 35 DEG C, pH 7, methanogen degeneration system 24 is needed weight according to flourish
Metal Ions Absorption, the mine in the isothermal reaction tank 50 of methanogen degeneration system 24 is then observed by glass roof 53
Water, after mine water covers filter screen 52, start the 5th water pump 37, and open the 9th valve 38, the tenth valve 41 and the 11st
Valve 43, mine water are pumped into first class purification cistern 36 by the 5th water pump 37, and first class purification cistern 36 disappears to mine water
Poison simultaneously adjusts its pH, and then mine water enters in secondary purification cistern 40 after the filtering of ultrafiltration membrane system 42；
When the heavy metal, nitrate ion and nitrous acid acid ion concentration over-standard that detect, and sulfate ion and sulfurous acid
When ion concentration meets standard, data collecting system sends instruction, opens second delivery port of four-way magnet-controlled valve 3, mine
Water enters the 4th water pipe 20 by second delivery port of four-way magnet-controlled valve 3, then opens the 5th valve 22 on the 4th water pipe 20,
Mine water enters in the isothermal reaction tank 50 of denitrifying bacteria nitrogen converting system 21, adjustment denitrifying bacteria nitrogen converting system 21
Temperature and pH in isothermal reaction tank 50 so that hair nitre of the temperature in 30 DEG C, pH 7, denitrifying bacteria nitrogen converting system 21
Change bacterial micro-organism and nitrate ion and nitrite ion are converted into nitrogen, hair nitrification is then observed by glass roof 53
Mine water in the isothermal reaction tank 50 of bacterial micro-organism, after mine water covers filter screen 52, start the 4th water pump 30, and open
8th valve 31, mine water are pumped into the isothermal reaction tank 50 of methanogen degeneration system 24 by the 4th water pump 30, adjustment production first
Temperature and pH in the isothermal reaction tank 50 of alkane bacterium degeneration system 24 so that at 35 DEG C, pH 7, methanogen is degraded is temperature
Methanogen microorganism in system 24 needs to absorb heavy metal ion according to flourish, is then observed by glass roof 53
Mine water in the isothermal reaction tank 50 of methanogen degeneration system 24, after mine water covers filter screen 52, start the 5th water pump
37, and open the 9th valve 38, the tenth valve 41 and the 11st valve 43, mine water and first class purification is pumped into by the 5th water pump 37
Cistern 36, first class purification cistern 36 carry out disinfection to mine water and adjust its pH, and then mine water passes through ultrafiltration membrane system
Enter after 42 filterings in secondary purification cistern 40；
When detecting sulfate ion, ion concentration of inferior sulfate radical, nitrate ion and nitrous acid acid ion concentration over-standard, and
When heavy metal meets standard, data collecting system sends instruction, opens first delivery port of four-way magnet-controlled valve 3, mine water by
First delivery port of four-way magnet-controlled valve 3 enters the 3rd water pipe 18, then opens the 4th valve 19 on the 3rd water pipe 18, mine
Water enters in the isothermal reaction tank 50 of sulfate reducing bacteria flocculation system 17, the constant temperature of adjustment sulfate reducing bacteria flocculation system 17
Temperature and pH in retort 50 so that sulfate of the temperature in 35 DEG C, pH 7, sulfate reducing bacteria flocculation system 17 is also
Opportunistic pathogen microorganism is with SO4 2-、SO3 2-For electron acceptor, using organic matter as carbon source and electron donor, hydrogen sulfide is finally produced, then
The mine water in the isothermal reaction tank 50 of sulfate reducing bacteria flocculation system 17 is observed by glass roof 53, when mine water covers
After filter screen 52, start the 3rd water pump 27, and open the 7th valve 28, mine water is pumped into denitrifying bacteria nitrogen by the 4th water pump 30 and turned
Change in the isothermal reaction tank 50 of system 21, temperature in the isothermal reaction tank 50 of adjustment denitrifying bacteria nitrogen converting system 21 and
PH so that hair nitrobacteria microorganism of the temperature in 30 DEG C, pH 7, denitrifying bacteria nitrogen converting system 21 by nitrate anion from
Son and nitrite ion are converted into nitrogen, and the isothermal reaction tank of hair nitrobacteria microorganism is then observed by glass roof 53
Mine water in 50, after mine water covers filter screen 52, start the 7th water pump 48, and open the 13rd valve 49, the tenth valve
41 and the 11st valve 43, mine water are pumped into first class purification cistern 36 by the 7th water pump 48, and first class purification cistern 36 is right
Mine water carries out disinfection and adjusts its pH, and then mine water enters secondary purification cistern 40 after the filtering of ultrafiltration membrane system 42
It is interior；
When the concentration for detecting heavy metal, sulfate ion, sulfite ion, nitrate ion and nitrite ion is equal
When exceeded, data collecting system sends instruction, opens first delivery port of four-way magnet-controlled valve 3, mine water is by four-way magnet-controlled valve 3
First delivery port enter the 3rd water pipe 18, then open the 4th valve 19 on the 3rd water pipe 18, mine water enters sulfuric acid
In the isothermal reaction tank 50 of salt reducing bacteria flocculation system 17, in the isothermal reaction tank 50 of adjustment sulfate reducing bacteria flocculation system 17
Temperature and pH so that sulfate reduction bacteria microorganism of the temperature in 35 DEG C, pH 7, sulfate reducing bacteria flocculation system 17
With SO4 2-、SO3 2-For electron acceptor, using organic matter as carbon source and electron donor, hydrogen sulfide is finally produced, then passes through glass roof
Lid 53 observes the mine water in the isothermal reaction tank 50 of sulfate reducing bacteria flocculation system 17, after mine water covers filter screen 52,
Start the 3rd water pump 27, and open the 7th valve 28, mine water is pumped into denitrifying bacteria nitrogen converting system 21 by the 4th water pump 30
Isothermal reaction tank 50 in, temperature and pH in the isothermal reaction tank 50 of adjustment denitrifying bacteria nitrogen converting system 21 so that temperature
Hair nitrobacteria microorganism in 30 DEG C, pH 7, denitrifying bacteria nitrogen converting system 21 is spent by nitrate ion and nitrous acid
Radical ion is converted into nitrogen, and the mine in the isothermal reaction tank 50 of hair nitrobacteria microorganism is then observed by glass roof 53
Water, after mine water covers filter screen 52, start the 4th water pump 30, and open the 8th valve 31, mine water is taken out by the 4th water pump 30
Enter in the isothermal reaction tank 50 of methanogen degeneration system 24, in the isothermal reaction tank 50 of adjustment methanogen degeneration system 24
Temperature and pH so that methanogen microorganism of the temperature in 35 DEG C, pH 7, methanogen degeneration system 24 gives birth to according to breeding
Length is needed to absorb heavy metal ion, and the isothermal reaction tank 50 of methanogen degeneration system 24 is then observed by glass roof 53
Interior mine water, after mine water covers filter screen 52, start the 5th water pump 37, and open the 9th valve 38, the tenth valve 41 with
And the 11st valve 43, mine water are pumped into first class purification cistern 36 by the 5th water pump 37, first class purification cistern 36 is to mine
Water carries out disinfection and adjusts its pH, and then mine water enters in secondary purification cistern 40 after the filtering of ultrafiltration membrane system 42.
The present embodiment is not that the shape to the present invention, material, structure etc. make any formal limitation, every according to this hair
Any simple modification, equivalent change and modification that bright technical spirit is made to above example, belongs to the technology of the present invention side
The protection domain of case.
Claims (10)
1. a kind of mine water shunts advanced treatment apparatus, it is characterised in that：Including preliminary Rose Box, centrifugal sedimentation system, water storage
Transferring box, four-way magnet-controlled valve and data acquisition control system, the bottom of preliminary Rose Box obstruct mechanism for natural water plant, just
The top of step Rose Box is sieve mechanism, and the bottom of preliminary Rose Box passes through the first water pipe and the water inlet of centrifugal sedimentation system
Mouth connection, the first water pipe are provided with the first valve and the first water pump, and the delivery port of centrifugal sedimentation system passes through aqueduct and water storage
Transferring box is connected, and aqueduct is provided with the second valve, and water storage transferring box is connected by the water inlet of the second water pipe and four-way magnet-controlled valve
Connect, oil water separator, water monitor, the 3rd valve and the second water pump are sequentially provided with along water (flow) direction on the second water pipe；Data
Acquisition control system is connected with water monitor and four-way magnet-controlled valve respectively by data wire；
First delivery port of four-way magnet-controlled valve is connected with sulfate reducing bacteria flocculation system by the 3rd water pipe, on the 3rd water pipe
Provided with the 4th valve；Second delivery port of four-way magnet-controlled valve is connected with denitrifying bacteria nitrogen converting system by the 4th water pipe,
4th water pipe is provided with the 5th valve；3rd delivery port of four-way magnet-controlled valve is connected with methanogen by the 5th water pipe and degraded
System, the 5th water pipe are provided with the 6th valve；Sulfate reducing bacteria flocculation system is turned by the 6th water pipe and denitrifying bacteria nitrogen
System connection is changed, the 6th water pipe is provided with the 3rd water pump and the 7th valve, and denitrifying bacteria nitrogen converting system passes through the 7th water pipe
It is connected with methanogen degeneration system, the 7th water pipe is provided with the 4th water pump and the 8th valve；Sulfate reducing bacteria flocculation system
It is connected by the 12nd water pipe with methanogen degeneration system, the 12nd water pipe is provided with the 8th water pump and the 14th valve；
Methanogen degeneration system is connected with first class purification cistern by the 8th water pipe, the 8th water pipe be provided with the 5th water pump and
9th valve, first class purification cistern are connected with secondary purification cistern by the 9th water pipe, along water (flow) direction on the 9th water pipe
It is sequentially provided with the tenth valve, ultrafiltration membrane system and the 11st valve；
Sulfate reducing bacteria flocculation system is connected by the tenth water pipe with first class purification cistern, and the tenth water pipe is provided with the 6th water
Pump and the 12nd valve, denitrifying bacteria nitrogen converting system are connected by the 11st water pipe with first class purification cistern, and the 11st
Water pipe is provided with the 7th water pump and the 13rd valve.
A kind of 2. mine water shunting advanced treatment apparatus according to claim 1, it is characterised in that：Sulfate reducing bacteria is wadded a quilt with cotton
Solidifying system, denitrifying bacteria nitrogen converting system are identical with the structure of methanogen degeneration system, including isothermal reaction tank, constant temperature are anti-
Middle part in tank is answered to be provided with biofilm ball, the outer layer of biofilm ball is nylon wire, and the inside of biofilm ball is activated carbon granule；Isothermal reaction tank
Interior to be provided with the filter screen positioned at the top of biofilm ball, the top of isothermal reaction tank is provided with glass roof, and glass roof, which is provided with, deflates
Valve, pressure sensor；The tank wall of isothermal reaction tank is provided with pH sensors and pH regulation mouths；
It is micro- that sulfate reducing bacteria is accommodated on activated carbon granule wherein in the isothermal reaction tank of sulfate reducing bacteria flocculation system
Biology, hair nitrobacteria microorganism is accommodated on the activated carbon granule in the isothermal reaction tank of denitrifying bacteria nitrogen converting system,
Methanogen microorganism is accommodated on activated carbon granule in the isothermal reaction tank of methanogen degeneration system.
A kind of 3. processing method of mine water shunting advanced treatment apparatus according to claim 2, it is characterised in that：Including
Following steps：
（1）Pending mine water is passed into the top of preliminary Rose Box, sieve mechanism by the silt in mine water and
Coal dust is filtered out, and the mine water after filtering is flowed into the natural water plant barrier mechanism of preliminary filtering lower box part, natural water plant
Obstruct in-house water plant on the one hand further to adsorb the silt in mine water and coal dust, on the other hand can also adsorb
Heavy metal ion, sulfate radical, sulfite ion, nitrate ion, nitrite ion and the oil of mine water inside points；
（2）Then the first valve is opened, starts the first water pump, the first water pump takes out the mine water after the processing in preliminary Rose Box
Enter into centrifugal sedimentation system, start centrifugal sedimentation system, centrifugal sedimentation system carries out centrifugal sedimentation, further mistake to mine water
Filter out the silt in mine water；
（3）After centrifugal sedimentation, the second valve is opened, mine water is flowed into water storage transferring box by aqueduct in centrifugal sedimentation system,
Mine water, which flows into, carries out secondary precipitation in water storage transferring box；
（4）Remove the lubricant component in mine water：Open the 3rd valve, start the second water pump, the second water pump is by water storage transferring box
Interior mine water is pumped into the second water pipe, wherein the oil water separator on the second water pipe filters off the oil body in mine water；
（5）Then water monitor detects to the water quality in the second water pipe, detect mine water in heavy metal, sulfate radical from
Whether son, sulfite ion, the concentration of nitrate ion and nitrite ion exceeded, and water monitor will detect
Data simultaneously make corresponding finger by data line transfer to data acquisition control system, data acquisition control system analyze data
Order, then makes corresponding processing according to instruction.
A kind of 4. processing method of mine water shunting advanced treatment apparatus according to claim 3, it is characterised in that：Work as water
The concentration over-standard for the heavy metal that matter monitor detects, when other detection projects meet standard, data acquisition control system is sent
Instruction, open the 3rd delivery port of four-way magnet-controlled valve, the step（5）The middle processing step made according to instruction, including：Ore deposit
Well water enters the 5th water pipe by the 3rd delivery port of four-way magnet-controlled valve, then opens the 6th valve on the 5th water pipe, mine
Water enters in the isothermal reaction tank of methanogen degeneration system, adjusts the temperature in the isothermal reaction tank of methanogen degeneration system
And pH so that methanogen microorganism of the temperature in 35 DEG C, pH 7, methanogen degeneration system is according to flourish needs
Heavy metal ion is absorbed, the mine water in the isothermal reaction tank of methanogen degeneration system is then observed by glass roof,
After mine water covers filter screen, start the 5th water pump, and open the 9th valve, the tenth valve and the 11st valve, mine water
First class purification cistern is pumped into by the 5th water pump, first class purification cistern carries out disinfection to mine water and adjusts its pH, then ore deposit
Well water enters in secondary purification cistern after ultrafiltration membrane system filters.
A kind of 5. processing method of mine water shunting advanced treatment apparatus according to claim 3, it is characterised in that：Work as water
The sulfate ion and ion concentration of inferior sulfate radical that matter monitor detects are exceeded, when other detection projects meet standard, data
Acquisition control system sends instruction, opens first delivery port of four-way magnet-controlled valve, the step（5）It is middle to be made according to instruction
Processing step, including：Mine water enters the 3rd water pipe by first delivery port of four-way magnet-controlled valve, then opens on the 3rd water pipe
The 4th valve, mine water enter sulfate reducing bacteria flocculation system isothermal reaction tank in, adjustment sulfate reducing bacteria flocculation
Temperature and pH in the isothermal reaction tank of system so that sulphur of the temperature in 35 DEG C, pH 7, sulfate reducing bacteria flocculation system
Hydrochlorate reduces bacteria microorganism with SO4 2-、SO3 2-It is final to produce vulcanization using organic matter as carbon source and electron donor for electron acceptor
Hydrogen, the mine water in the isothermal reaction tank of sulfate reducing bacteria flocculation system is then observed by glass roof, when mine water overflows
After screen pack, start the 6th water pump, and open the 12nd valve, the tenth valve and the 11st valve, mine water is by the 6th water
First class purification cistern is pumped into, first class purification cistern carries out disinfection to mine water and adjusts its pH, and then mine water passes through
Enter after ultrafiltration membrane system filtering in secondary purification cistern.
A kind of 6. processing method of mine water shunting advanced treatment apparatus according to claim 3, it is characterised in that：Work as water
The nitrate ion and nitrous acid acid ion concentration over-standard that matter monitor detects, when other detection projects meet standard, number
Instruction is sent according to acquisition control system, opens second delivery port of four-way magnet-controlled valve, the step（5）It is middle to be made according to instruction
Processing step, including：Mine water enters the 4th water pipe by second delivery port of four-way magnet-controlled valve, then opens the 4th water pipe
On the 5th valve, mine water enters in the isothermal reaction tank of denitrifying bacteria nitrogen converting system, and adjustment denitrifying bacteria nitrogen turns
The temperature and pH changed in the isothermal reaction tank of system so that temperature is in 30 DEG C, pH 7, denitrifying bacteria nitrogen converting system
Nitrate ion and nitrite ion are converted into nitrogen by hair nitrobacteria microorganism, then observe hair nitre by glass roof
Change the mine water in the isothermal reaction tank of bacterial micro-organism, after mine water covers filter screen, start the 7th water pump, and open the tenth
Three valves, the tenth valve and the 11st valve, mine water are pumped into first class purification cistern, first class purification water storage by the 7th water pump
Pond carries out disinfection to mine water and adjusts its pH, and then mine water enters secondary purification cistern after ultrafiltration membrane system filters
It is interior.
A kind of 7. processing method of mine water shunting advanced treatment apparatus according to claim 3, it is characterised in that：Work as water
Heavy metal, sulfate ion and the ion concentration of inferior sulfate radical that matter monitor detects are exceeded, and nitrate ion and nitrous acid
When acid ion concentration meets standard, data collecting system sends instruction, opens first delivery port of four-way magnet-controlled valve, described
Step（5）The middle processing step made according to instruction, including：Mine water enters the 3rd by first delivery port of four-way magnet-controlled valve
Water pipe, then opens the 4th valve on the 3rd water pipe, and mine water enters the isothermal reaction tank of sulfate reducing bacteria flocculation system
It is interior, adjust temperature and pH in the isothermal reaction tank of sulfate reducing bacteria flocculation system so that temperature is at 35 DEG C, pH 7, sulfuric acid
Sulfate reduction bacteria microorganism in salt reducing bacteria flocculation system is with SO4 2-、SO3 2-For electron acceptor, using organic matter as carbon source and
Electron donor, hydrogen sulfide is finally produced, the isothermal reaction tank of sulfate reducing bacteria flocculation system is then observed by glass roof
Interior mine water, after mine water covers filter screen, start the 8th water pump, and open the 14th valve, mine water is by the 8th water pump
Be pumped into methanogen degeneration system isothermal reaction tank in, adjust methanogen degeneration system isothermal reaction tank in temperature and
PH so that methanogen microorganism of the temperature in 35 DEG C, pH 7, methanogen degeneration system according to flourish need by
Heavy metal ion is absorbed, and the mine water in the isothermal reaction tank of methanogen degeneration system is then observed by glass roof, when
After mine water covers filter screen, start the 5th water pump, and open the 9th valve, the tenth valve and the 11st valve, mine water quilt
5th water pump is pumped into first class purification cistern, and first class purification cistern carries out disinfection to mine water and adjusts its pH, then mine
Water enters in secondary purification cistern after ultrafiltration membrane system filters.
A kind of 8. processing method of mine water shunting advanced treatment apparatus according to claim 3, it is characterised in that：Work as water
Heavy metal, nitrate ion and the nitrous acid acid ion concentration over-standard that matter monitor detects, and sulfate ion and sulfurous
When acid ion concentration meets standard, data collecting system sends instruction, opens second delivery port of four-way magnet-controlled valve, described
Step（5）The middle processing step made according to instruction, including：Mine water enters the 4th by second delivery port of four-way magnet-controlled valve
Water pipe, then opens the 5th valve on the 4th water pipe, and mine water enters the isothermal reaction tank of denitrifying bacteria nitrogen converting system
It is interior, adjust temperature and pH in the isothermal reaction tank of denitrifying bacteria nitrogen converting system so that temperature is at 30 DEG C, pH 7, anti-nitre
Nitrate ion and nitrite ion are converted into nitrogen by the hair nitrobacteria microorganism changed in bacterium nitrogen converting system, then
The mine water in the isothermal reaction tank of hair nitrobacteria microorganism is observed by glass roof, after mine water covers filter screen, is opened
Dynamic 4th water pump, and the 8th valve is opened, mine water is pumped into by the 4th water pump in the isothermal reaction tank of methanogen degeneration system,
Adjust the temperature and pH in the isothermal reaction tank of methanogen degeneration system so that at 35 DEG C, pH 7, methanogen drops temperature
Methanogen microorganism in solution system needs to absorb heavy metal ion according to flourish, is then observed by glass roof
Mine water in the isothermal reaction tank of methanogen degeneration system, after mine water covers filter screen, start the 5th water pump, and open
9th valve, the tenth valve and the 11st valve, mine water are pumped into first class purification cistern by the 5th water pump, and first class purification stores
Pond carries out disinfection to mine water and adjusts its pH, and then mine water enters secondary purification water storage after ultrafiltration membrane system filters
In pond.
A kind of 9. processing method of mine water shunting advanced treatment apparatus according to claim 3, it is characterised in that：Work as water
Matter monitor detects sulfate ion, ion concentration of inferior sulfate radical, nitrate ion and nitrous acid acid ion concentration over-standard,
And heavy metal is when meeting standard, data collecting system sends instruction, opens first delivery port of four-way magnet-controlled valve, the step
（5）The middle processing step made according to instruction, including：Mine water enters the 3rd water by first delivery port of four-way magnet-controlled valve
Pipe, the 4th valve on the 3rd water pipe is then opened, mine water enters in the isothermal reaction tank of sulfate reducing bacteria flocculation system,
Adjust the temperature and pH in the isothermal reaction tank of sulfate reducing bacteria flocculation system so that temperature is at 35 DEG C, pH 7, sulfate
Sulfate reduction bacteria microorganism in reducing bacteria flocculation system is with SO4 2-、SO3 2-For electron acceptor, using organic matter as carbon source and electricity
Sub- donor, hydrogen sulfide is finally produced, in the isothermal reaction tank that sulfate reducing bacteria flocculation system is then observed by glass roof
Mine water, after mine water covers filter screen, start the 3rd water pump, and open the 7th valve, mine water is pumped into by the 4th water pump
In the isothermal reaction tank of denitrifying bacteria nitrogen converting system, the temperature in the isothermal reaction tank of denitrifying bacteria nitrogen converting system is adjusted
Degree and pH so that hair nitrobacteria microorganism of the temperature in 30 DEG C, pH 7, denitrifying bacteria nitrogen converting system is by nitrate anion
Ion and nitrite ion are converted into nitrogen, and the isothermal reaction tank of hair nitrobacteria microorganism is then observed by glass roof
Interior mine water, after mine water covers filter screen, start the 7th water pump, and open the 13rd valve, the tenth valve and the tenth
One valve, mine water are pumped into first class purification cistern by the 7th water pump, and first class purification cistern carries out disinfection and adjusted to mine water
Its pH is saved, then mine water enters in secondary purification cistern after ultrafiltration membrane system filters.
A kind of 10. processing method of mine water shunting advanced treatment apparatus according to claim 3, it is characterised in that：When
Water monitor detects the dense of heavy metal, sulfate ion, sulfite ion, nitrate ion and nitrite ion
When degree is exceeded, data collecting system sends instruction, opens first delivery port of four-way magnet-controlled valve, the step（5）Middle
The processing step made according to instruction, including：Mine water enters the 3rd water pipe by first delivery port of four-way magnet-controlled valve, then beats
The 4th valve on the 3rd water pipe is opened, mine water enters in the isothermal reaction tank of sulfate reducing bacteria flocculation system, adjusts sulfuric acid
Temperature and pH in the isothermal reaction tank of salt reducing bacteria flocculation system so that temperature at 35 DEG C, pH 7, wad a quilt with cotton by sulfate reducing bacteria
Sulfate reduction bacteria microorganism in solidifying system is with SO4 2-、SO3 2-For electron acceptor, using organic matter as carbon source and electron donor, most
Hydrogen sulfide is produced eventually, and the mine water in the isothermal reaction tank of sulfate reducing bacteria flocculation system is then observed by glass roof,
After mine water covers filter screen, start the 3rd water pump, and open the 7th valve, mine water is pumped into denitrifying bacteria by the 4th water pump
In the isothermal reaction tank of nitrogen converting system, temperature and pH in the isothermal reaction tank of denitrifying bacteria nitrogen converting system are adjusted, is made
Hair nitrobacteria microorganism of the temperature in 30 DEG C, pH 7, denitrifying bacteria nitrogen converting system is obtained by nitrate ion and nitrous
Acid ion is converted into nitrogen, and the mine in the isothermal reaction tank of hair nitrobacteria microorganism is then observed by glass roof
Water, after mine water covers filter screen, start the 4th water pump, and open the 8th valve, mine water is pumped into methane phase by the 4th water pump
In the isothermal reaction tank of bacterium degeneration system, temperature and pH in the isothermal reaction tank of methanogen degeneration system are adjusted so that temperature
The methanogen microorganism spent in 35 DEG C, pH 7, methanogen degeneration system is needed heavy metal ion according to flourish
Absorb, the mine water in the isothermal reaction tank of methanogen degeneration system is then observed by glass roof, when mine water covers
After filter screen, start the 5th water pump, and open the 9th valve, the tenth valve and the 11st valve, mine water and taken out by the 5th water pump
Enter first class purification cistern, first class purification cistern carries out disinfection to mine water and adjusts its pH, and then mine water passes through ultrafiltration
Enter after membranous system filtering in secondary purification cistern.
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