CN107378303A - A kind of high intensity alternating-current resistance welding wire production method - Google Patents

A kind of high intensity alternating-current resistance welding wire production method Download PDF

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Publication number
CN107378303A
CN107378303A CN201710433129.5A CN201710433129A CN107378303A CN 107378303 A CN107378303 A CN 107378303A CN 201710433129 A CN201710433129 A CN 201710433129A CN 107378303 A CN107378303 A CN 107378303A
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CN
China
Prior art keywords
copper
continuous casting
equal
resistance welding
temperature
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Pending
Application number
CN201710433129.5A
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Chinese (zh)
Inventor
李文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhu State Bond Copper Co Ltd
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Wuhu State Bond Copper Co Ltd
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Application filed by Wuhu State Bond Copper Co Ltd filed Critical Wuhu State Bond Copper Co Ltd
Priority to CN201710433129.5A priority Critical patent/CN107378303A/en
Publication of CN107378303A publication Critical patent/CN107378303A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/302Cu as the principal constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding

Abstract

The invention discloses a kind of high intensity alternating-current resistance welding wire production method, include the raw copper and following steps of specific components:Step 1:Cast continuous casting copper bar;Step 2:Made annealing treatment;Step 3:It is heated to 430~450 DEG C and keeps the temperature range to carry out drawing processing, drawing copper wire is made;Step 4:Drawing copper wire is immersed in 250~260 DEG C of high temperature resistant silicone oil and then takes out cooling step five:Clean the high temperature resistant silicone oil on surface;Step 6:300~350 DEG C are heated to, then hot drawing copper wire is immersed into the transformer oil within 50 DEG C, until the temperature of drawing copper wire is down within 60 DEG C, then takes out and naturally cools to room temperature;Step 7:The transformer oil on surface is cleaned, carries out sizing polishing.Duty cycle of the invention is short, production cost is low and operation process is easily controllable, and high intensity alternating-current resistance welding wire is had preferable mechanical strength and welding performance.

Description

A kind of high intensity alternating-current resistance welding wire production method
Technical field
The present invention relates to a kind of resistance welding wire production method technical field, particularly a kind of high intensity alternating-current resistance welding wire life Production method.
Background technology
Alternating-current resistance welding wire is a kind of consumptive material applied on high frequency resistance welding machine, and its main making material is copper wire, is led to Often it is made up of continuous up-casting copper bar drawing.Because alternating-current resistance welding wire has thinner line footpath, therefore lead in the prior art Often need by the way that repeatedly cold drawing molding can be only achieved required line footpath repeatedly, not only duty cycle is long, production cost height but also Because process is cumbersome so that the operation process of alternating-current resistance welding wire cold drawing molding is difficult to control, therefore adds high-frequency resistance welding (HFRW) The quality control difficulty and inspection workload of silk cold drawing molding operation.
In addition, the alternating-current resistance welding wire that conventional method produces in the prior art has, efficiency is low, energy consumption is big, the production cycle The deficiencies of length, impurity content are high, line base surface is oxidizable and interior tissue is uneven;Due to alternating-current resistance welding wire impurity content Height, line base surface is oxidizable and interior tissue is uneven, easily causes the surface quality of alternating-current resistance welding wire poor so that high-frequency electrical Wire feed is not smooth enough in use for welding resistance silk, and the mobility and wellability during welding are poor, easily cause weld cracking, go out Existing incomplete fusion and the weld defect such as lack of penetration.
The content of the invention
For overcome the deficiencies in the prior art, the invention provides a kind of high intensity alternating-current resistance welding wire production method, makees The industry cycle is short, production cost is low and operation process is easily controllable, and high intensity alternating-current resistance welding wire is had preferably machinery Intensity and welding performance.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of high intensity alternating-current resistance welding wire production method, raw copper include the element of following mass percent:Copper 60.5%~ 63.5%, tin 3.5~5.5%, zinc 32.5~34.5%, and impurity of the total amount less than or equal to 0.5%, and the iron in impurity is less than or equal to 0.15%th, lead is less than or equal to 0.08%, antimony and is less than or equal to 0.005%, bismuth less than or equal to 0.002%, phosphorus less than or equal to 0.01%;And wrap Include following steps:
Step 1:Above-mentioned raw materials copper is melted and crystallized by continuous casting process and is cast as the circle that sectional area is 8~12 square centimeters Cylindricality continuous casting copper bar;
Step 2:Continuous casting copper rod bending packing to step 1 processing is coiled, is then fed into annealing furnace and is made annealing treatment;
Step 3:Continuous casting copper bar of the step 2 by annealing is unwind and aligned, is then being heated to 430~450 DEG C and keep the temperature range, carry out drawing processing, the diameter of continuous casting copper bar is reduced into 0.5~2.0 millimeter, drawing copper is made Silk;
Step 4:Drawing copper wire made from step 3 is immersed in high temperature resistant silicone oil, the temperature of high temperature resistant silicone oil remains 250 ~260 DEG C, drawing copper wire is then taken out from high temperature resistant silicone oil, is positioned in air and is cooled to room temperature;
Step 5:Drawing copper wire after step 4 is handled is sent into ultrasonic cleaning device, washes the high temperature resistant silicone oil on surface, Then rinsed with clear water, then low-temperature air-drying;
Step 6:Drawing copper wire after step 5 is cleaned is sent into closed glowing furnace, under inert gas shielding atmosphere, with every The speed of 10~50 DEG C of minute is heated to 300~350 DEG C, the transformer being then immersed into hot drawing copper wire within 50 DEG C In oil, until the temperature of drawing copper wire is down within 60 DEG C, then takes out and naturally cool to room temperature;
Step 7:Drawing copper wire after step 6 Quenching Treatment is sent into ultrasonic cleaning device, washes the transformer on surface Oil, then rinsed with clear water, then low-temperature air-drying;Then sizing polishing is carried out, that is, high intensity alternating-current resistance welding wire is made.
As the further improvement of above-mentioned technical proposal, in step 1, the melting temperature of above-mentioned raw materials copper for 1200~ 1220 DEG C, holding temperature of the copper liquid in continuous casting after melting is 1900~1200 DEG C, and the oxygen content melted in copper liquid is less than Equal to 10ppm, electrical conductivity is more than or equal to 100%IACS.
As the further improvement of above-mentioned technical proposal, in step 2, the method for annealing is:In inert gas shielding Under atmosphere, by continuous casting copper bar, constant-speed heating is warming up to 510~540 DEG C within the time of 2~3 hours, is then incubated 2 hours, so Cooled afterwards with the speed per minute for being less than or equal to 10 DEG C, gone until continuous casting copper bar is cold within 60 DEG C, then from annealing furnace Interior taking-up, natural cooling.
Compared with prior art, the beneficial effects of the invention are as follows:
A kind of high intensity alternating-current resistance welding wire production method provided by the present invention, duty cycle is short, production cost is low and makees Industry process is easily controllable, so as to advantageously reduce the quality control difficulty of alternating-current resistance welding wire machine-shaping operation and examine work Amount;The high intensity alternating-current resistance welding wire that the present invention processes has preferable mechanical strength so that alternating-current resistance welding wire was using Wire feed is smooth in journey, and the mobility and wellability during welding are preferable, and weld seam is not easy to crack, incomplete fusion and it is lack of penetration the defects of occur Probability is remarkably decreased.
Embodiment
The present invention is further described with reference to specific embodiment.
A kind of high intensity alternating-current resistance welding wire production method that the present embodiment is provided, raw copper include following quality percentage Several elements:Copper 60.5%~63.5%, tin 3.5~5.5%, zinc 32.5~34.5%, and total amount are less than or equal to 0.5% impurity, and Iron in impurity is less than or equal to 0.15%, lead and is less than or equal to 0.08%, antimony less than or equal to 0.005%, bismuth less than or equal to 0.002%, phosphorus Less than or equal to 0.01%;
And above-mentioned raw materials copper will also pass through following procedure of processing:
Step 1:Above-mentioned raw materials copper is melted and crystallized by continuous casting process and is cast as the circle that sectional area is 8~12 square centimeters Cylindricality continuous casting copper bar;Specifically, the melting temperature of above-mentioned raw materials copper is 1200~1220 DEG C, and copper liquid after melting is in continuous casting Holding temperature is 1900~1200 DEG C, and the oxygen content melted in copper liquid is less than or equal to 10ppm, and electrical conductivity is more than or equal to 100% IACS。
Step 2:Continuous casting copper rod bending packing to step 1 processing is coiled, is then fed into annealing furnace and carries out at annealing Reason;Specifically, the method for annealing is:Under inert gas shielding atmosphere, by continuous casting copper bar within the time of 2~3 hours Constant-speed heating is warming up to 510~540 DEG C, is then incubated 2 hours, is then dropped with the speed per minute for being less than or equal to 10 DEG C Temperature, go within 60 DEG C, then taken out out of annealing furnace, natural cooling until continuous casting copper bar is cold.
Step 3:Continuous casting copper bar of the step 2 by annealing is unwind and aligned, then be heated to 430~ 450 DEG C and the temperature range is kept, carry out drawing processing, the diameter of continuous casting copper bar is reduced into 0.5~2.0 millimeter, be made and draw Pull out copper wire.
Step 4:Drawing copper wire made from step 3 is immersed in high temperature resistant silicone oil, the temperature of high temperature resistant silicone oil is kept For 250~260 DEG C, drawing copper wire is then taken out from high temperature resistant silicone oil, is positioned in air and is cooled to room temperature.
Step 5:Drawing copper wire after step 4 is handled is sent into ultrasonic cleaning device, washes the high temperature resistant on surface Silicone oil, then rinsed with clear water, then low-temperature air-drying.
Step 6:Drawing copper wire after step 5 is cleaned is sent into closed glowing furnace, under inert gas shielding atmosphere, 300~350 DEG C are heated to 10~50 DEG C per minute of speed, the change then hot drawing copper wire being immersed within 50 DEG C In depressor oil, until the temperature of drawing copper wire is down within 60 DEG C, then takes out and naturally cool to room temperature.
Step 7:Drawing copper wire after step 6 Quenching Treatment is sent into ultrasonic cleaning device, washes the change on surface Depressor oil, is then rinsed with clear water, then low-temperature air-drying;Then sizing polishing is carried out, that is, high intensity alternating-current resistance welding wire is made.
A diameter of 2.0 millimeters prepared by a kind of high intensity alternating-current resistance welding wire production method that the present embodiment is provided High intensity alternating-current resistance welding wire tensile strength can reach 1000 MPa, and elongation is 15~20%, therefore is sent in use Silk is smooth;And weld when mobility and wellability it is preferable, weld seam is not easy to crack, incomplete fusion and it is lack of penetration the defects of occurrence probability It is remarkably decreased.
The preferable implementation to the present invention is illustrated above, and certainly, the present invention can also use and above-mentioned implementation The different form of mode, the equivalent conversion that those skilled in the art are made on the premise of without prejudice to spirit of the invention Or corresponding change, it should all belong in protection scope of the present invention.

Claims (3)

1. a kind of high intensity alternating-current resistance welding wire production method, it is characterised in that raw copper includes the member of following mass percent Element:Copper 60.5%~63.5%, tin 3.5~5.5%, zinc 32.5~34.5%, and total amount are less than or equal to 0.5% impurity, and in impurity Iron be less than or equal to 0.15%, lead be less than or equal to 0.08%, antimony be less than or equal to 0.005%, bismuth be less than or equal to 0.002%, phosphorus be less than etc. In 0.01%;And comprise the following steps:
Step 1:Above-mentioned raw materials copper is melted and crystallized by continuous casting process and is cast as the circle that sectional area is 8~12 square centimeters Cylindricality continuous casting copper bar;
Step 2:Continuous casting copper rod bending packing to step 1 processing is coiled, is then fed into annealing furnace and is made annealing treatment;
Step 3:Continuous casting copper bar of the step 2 by annealing is unwind and aligned, is then being heated to 430~450 DEG C and keep the temperature range, carry out drawing processing, the diameter of continuous casting copper bar is reduced into 0.5~2.0 millimeter, drawing copper is made Silk;
Step 4:Drawing copper wire made from step 3 is immersed in high temperature resistant silicone oil, the temperature of high temperature resistant silicone oil remains 250 ~260 DEG C, drawing copper wire is then taken out from high temperature resistant silicone oil, is positioned in air and is cooled to room temperature;
Step 5:Drawing copper wire after step 4 is handled is sent into ultrasonic cleaning device, washes the high temperature resistant silicone oil on surface, Then rinsed with clear water, then low-temperature air-drying;
Step 6:Drawing copper wire after step 5 is cleaned is sent into closed glowing furnace, under inert gas shielding atmosphere, with every The speed of 10~50 DEG C of minute is heated to 300~350 DEG C, the transformer being then immersed into hot drawing copper wire within 50 DEG C In oil, until the temperature of drawing copper wire is down within 60 DEG C, then takes out and naturally cool to room temperature;
Step 7:Drawing copper wire after step 6 Quenching Treatment is sent into ultrasonic cleaning device, washes the transformer on surface Oil, then rinsed with clear water, then low-temperature air-drying;Then sizing polishing is carried out, that is, high intensity alternating-current resistance welding wire is made.
A kind of 2. high intensity alternating-current resistance welding wire production method according to claim 1, it is characterised in that:In step 1, The melting temperature of above-mentioned raw materials copper is 1200~1220 DEG C, and holding temperature of the copper liquid in continuous casting after melting is 1900~1200 DEG C, and the oxygen content melted in copper liquid is less than or equal to 10ppm, electrical conductivity is more than or equal to 100%IACS.
A kind of 3. high intensity alternating-current resistance welding wire production method according to claim 1, it is characterised in that:In step 2, The method of annealing is:Under inert gas shielding atmosphere, by continuous casting copper bar within the time of 2~3 hours constant-speed heating liter Then temperature is incubated 2 hours, then cooled with the speed per minute for being less than or equal to 10 DEG C to 510~540 DEG C, until continuous casting Copper bar is cold to be gone within 60 DEG C, is then taken out out of annealing furnace, natural cooling.
CN201710433129.5A 2017-06-09 2017-06-09 A kind of high intensity alternating-current resistance welding wire production method Pending CN107378303A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS558375A (en) * 1978-07-06 1980-01-21 Takaharu Orita Production of brazing filler metal
CN102862003A (en) * 2012-10-08 2013-01-09 佛山市泓实机械制造有限公司 Silver-free copper based solder and preparation method thereof
CN102896438A (en) * 2012-10-22 2013-01-30 王志祥 Copper-zinc solder and preparation method thereof
CN102941417A (en) * 2012-11-14 2013-02-27 四川大西洋焊接材料股份有限公司 Tin bronze welding wire and preparation method thereof
CN103737197A (en) * 2013-10-17 2014-04-23 西安理工大学 Amorphous alloy brazing filler metal for welding TA series titanium and stainless steel and preparation method of amorphous alloy brazing filler metal
CN104439749A (en) * 2014-11-05 2015-03-25 安徽华众焊业有限公司 Special silver-free welding rod

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS558375A (en) * 1978-07-06 1980-01-21 Takaharu Orita Production of brazing filler metal
CN102862003A (en) * 2012-10-08 2013-01-09 佛山市泓实机械制造有限公司 Silver-free copper based solder and preparation method thereof
CN102896438A (en) * 2012-10-22 2013-01-30 王志祥 Copper-zinc solder and preparation method thereof
CN102941417A (en) * 2012-11-14 2013-02-27 四川大西洋焊接材料股份有限公司 Tin bronze welding wire and preparation method thereof
CN103737197A (en) * 2013-10-17 2014-04-23 西安理工大学 Amorphous alloy brazing filler metal for welding TA series titanium and stainless steel and preparation method of amorphous alloy brazing filler metal
CN104439749A (en) * 2014-11-05 2015-03-25 安徽华众焊业有限公司 Special silver-free welding rod

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Application publication date: 20171124