CN107377206A - A kind of closed circuit recycling technique of rotary kiln baking magnetic separation iron ore stone mine tailing - Google Patents

A kind of closed circuit recycling technique of rotary kiln baking magnetic separation iron ore stone mine tailing Download PDF

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Publication number
CN107377206A
CN107377206A CN201710562812.9A CN201710562812A CN107377206A CN 107377206 A CN107377206 A CN 107377206A CN 201710562812 A CN201710562812 A CN 201710562812A CN 107377206 A CN107377206 A CN 107377206A
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China
Prior art keywords
iron ore
rotary kiln
closed circuit
tailings
sections
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CN201710562812.9A
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Chinese (zh)
Inventor
展仁礼
王欣
郭忆
边立国
雷鹏飞
杏仲全
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Gansu Jiu Steel Group Hongxing Iron and Steel Co Ltd
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Gansu Jiu Steel Group Hongxing Iron and Steel Co Ltd
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Application filed by Gansu Jiu Steel Group Hongxing Iron and Steel Co Ltd filed Critical Gansu Jiu Steel Group Hongxing Iron and Steel Co Ltd
Priority to CN201710562812.9A priority Critical patent/CN107377206A/en
Publication of CN107377206A publication Critical patent/CN107377206A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/005Pretreatment specially adapted for magnetic separation
    • B03C1/015Pretreatment specially adapted for magnetic separation by chemical treatment imparting magnetic properties to the material to be separated, e.g. roasting, reduction, oxidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/02Magnetic separation acting directly on the substance being separated
    • B03C1/30Combinations with other devices, not otherwise provided for
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/02Roasting processes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The present invention proposes a kind of closed circuit recycling technique of rotary kiln baking magnetic separation iron ore stone mine tailing, step:1mm granulations are classified as to 15mm oxidation refractory iron ores using rotary kiln, + 1 ~ 5mm, + 5 ~ 15mm scopes carry out magnetizing roast respectively, roasted ore is cooled to normal temperature, it is useless that dry type pre-selection throwing is carried out to roasted ore using screw dry magnetic separator, throw useless rear roasted ore and carry out wet-milling wet separation, it is selected that three sections of wet types are carried out using weak magnetic separator, two sections, three sections of mine tailings are after magnetic separator is enriched with, it is enriched with mine tailing and one section of cleaner tailings, useless rear barren rock is thrown together to discharge by qualified tailings, Grade Control is below 8%, the filtered dehydration of concentrate after enrichment, break up, granulation returns to rotary kiln and carries out closed circuit magnetizing roast, three sections of selected rear concentrate are final qualified concentrate containing, grade reaches more than 60%.The technique pin realizes iron resource in online closed circuit recovery mine tailing, avoids feeding Tailings Dam secondary recovery from hanking the problem of this is high again.

Description

A kind of closed circuit recycling technique of rotary kiln baking magnetic separation iron ore stone mine tailing
Technical field
The invention belongs to iron ore dressing technical field, is related to a kind of closed circuit recovery of rotary kiln baking magnetic separation iron ore stone mine tailing Utilize technique.
Background technology
China's iron ore resource lean ore is more, magnetic ore deposit is few, and weak-magnetic iron ore accounts for more than the 70% of gross reserves, weak magnetic Iron ore is handled through magnetizing roast, after being changed into strongly magnetic mineral, can carry out magnetic separation, is obtained quality and is met sintered material requirement Iron ore concentrate.+ 15mm grades iron ore directly uses shaft furnace magnetizing roast, and -15mm grade iron ores are classified as -1mm granulations ,+1 ~ -5mm ,+5 ~ -15mm enter rotary kiln and carry out magnetizing roast respectively, because difficulty selects ferric oxide ore size fractionated to have different magnetization Baking property, roasting time, sintering temperature are different, and certain limit grade iron ore enters rotary kiln magnetizing roast, deposits unavoidably Roasting quality is uneven the problem of, that is, with the presence of rawore is burnt, tailings grade is caused to be up to 17 ~ 22%, metal recovery rate is only For 78% or so, and tailing dam is sent into the filtered dehydration of mine tailing, and secondary recovery is using needing to spend very big cost.
The content of the invention
The present invention is directed to certain size fraction ranges refractory iron ore rotary kiln magnetizing roast, and roasted ore quality is uneven, magnetic separation A kind of the problem of tailings grade is high, can recycle but be sent into tailing dam, and secondary recovery utilizes cost high, there is provided rotary kiln The closed circuit recycling technique of calcining magnetic separation iron ore tailings.
The technical solution adopted in the present invention is:A kind of closed circuit recycling work of rotary kiln baking magnetic separation iron ore stone mine tailing Skill, comprise the following steps:A. magnetizing roast is carried out to refractory iron ore using rotary kiln, roasted ore is cooled to normal temperature;
B. it is useless that dry type pre-selection throwing is carried out to roasted ore using screw dry magnetic separator, throws useless Grade Control below 8%;
C. throw it is useless after pre- concentrate selection successively by one section, two sections, three sections of weak magnetic wet grindings it is selected, be milled to -0.074mm and account for Than 70% or so, ore deposit is final qualified concentrate containing after the mill choosing of weak magnetic wet type, and grade reaches more than 60%;
D. two sections of weak magnetics are selected, three sections of weak magnetic essence mine tailings after magnetic separator is enriched with, mine tailing and one section of cleaner tailings after enrichment, throw it is useless Barren rock is together discharged by qualified tailings afterwards, and Iron Grade of Tailings is controlled below 8%;
E. the filtered dehydration of concentrate after being enriched with, drying is broken up, pelletize returns to the closed circuit magnetizing roast of rotary kiln progress, magnetic separation;
F. because for magnetic iron ore in continuous ore dressing, easily formation disk pack wraps up in phenomenon, influences the selected index of wet type, needs after roasting At each section it is selected before install demagnetization device additional, de- magnetic is carried out to previous stages of magnetic separation processing iron ore concentrate, selected created conditions for next section.
Oxidation refractory iron ore described in step A includes speculum iron, bloodstone, limonite, siderite and complicated symbiosis Iron ore, belong to weak-magnetic iron ore, need to after magnetizing roast can magnetic separation obtain high grade iron concentrate.
Refractory iron ore is crushed to -15mm, is then classified as -1mm ,+1 ~ -5mm ,+5 ~ -15mm, -1mm granulation, three Size fraction ranges enter kiln and carry out magnetizing roast respectively.Magnetizing roast respectively, certain size fraction ranges enter kiln roasting and roasted ore be present unavoidably The problem of quality is uneven, causes bis- sections, three sections tailings grades of step C to reach 17 ~ 20%, belong to unqualified mine tailing, there is recycling Value.
Roasted ore in step B, due to containing 10% or so country rock in raw ore, using screw dry magnetic separator to roasted ore It is useless to carry out dry type pre-selection throwing, throws waste product position by adjusting revolution speed of screw control, throws and give up Grade Control below 8%, reduce follow-up mill Ore deposit amount, reduce production cost.
Step D, bis- sections of weak magnetic cleaner tailings of E, three sections of weak magnetic cleaner tailings are enriched with concentrate after intensity magnetic separator enrichment processing Grade reaches 30% or so, and category burns pig iron ore, and the qualified iron ore concentrate of ability magnetic separation production grade more than 60%, rich after palpus is fired After the filtered dehydration of collection concentrate, drying are broken up, pelletize, return to rotary kiln and enter calcining magnetic separation process system, formation is closed circuit online Tailings recovery process.
The beneficial effects of the invention are as follows:According to the certain size fraction ranges iron ore rotary kiln magnetizing roast quality of refractory iron ore It is uneven, cause tailings grade height, metal recovery rate low, mine tailing, which has to recycle, is worth this feature, develops magnetic separation not Qualified tailings closed circuit recycling technique online, reduce mine tailing and be sent into the cost that tailing dam recycles again, improve money Source utilization rate.
Brief description of the drawings
Fig. 1 is the process chart of the present invention.
Embodiment
The oxidation refractory iron ore that embodiment uses derives from wine steel Orebody in Jingtieshan ore deposit.
- 15mm Orebody in Jingtieshan oxidation the refractory iron ore of wine steel grade 32% is subjected to following handle:
A. be classified as -1mm and pelletize ,+1 ~ -5mm ,+5 ~ -15mm enter kiln and carry out magnetizing roast respectively, roasted ore is cooled to often Temperature;
B. it is useless that dry type pre-selection throwing is carried out to roasted ore using screw dry magnetic separator, throws waste product position below 8%;Due to containing in raw ore There is 10% or so country rock, carry out dry type pre-selection throwing to roasted ore using screw dry magnetic separator and give up, by adjusting revolution speed of screw control Waste product position is thrown, useless Grade Control is thrown below 8%, reduces follow-up ore grinding amount, reduce production cost.
C. throw it is useless after pre- concentrate selection by three sections of weak magnetic wet types mill choosings, be milled to -0.074mm accountings 70% or so, three sections Concentrate is final qualified concentrate containing after selected, and grade reaches more than 60%;
D. the selected one section of tailings grade of weak magnetic is discharged below 8% by qualified tailings, two sections, three sections of tailings grades 17%, through high intensity magnetic separation After machine enrichment, tailings grade 10% is enriched with, is together discharged with one section of mine tailing, the useless rear barren rock of throwing by qualified tailings, total Iron Grade of Tailings Control is enriched with concentrate grade 30% below 9%, and filtered dehydration, drying are broken up, pelletized, and return to rotary kiln closed circuit recovery online Magnetizing roast, magnetic separation, it is final to obtain iron concentrate grade 60%, the index of metal recovery rate 88%.

Claims (3)

1. a kind of closed circuit recycling technique of rotary kiln baking magnetic separation iron ore stone mine tailing, comprises the following steps:A. rotary kiln is used Magnetizing roast is carried out to refractory iron ore, roasted ore is cooled to normal temperature;
B. it is useless that dry type pre-selection throwing is carried out to roasted ore using screw dry magnetic separator, throws useless Grade Control below 8%;
C. throw it is useless after pre- concentrate selection successively by one section, two sections, three sections of weak magnetic wet grindings it is selected, be milled to -0.074mm and account for Than 70% or so, ore deposit is final qualified concentrate containing after the mill choosing of weak magnetic wet type, and grade reaches more than 60%;
D. two sections of weak magnetics are selected, three sections of weak magnetic essence mine tailings after magnetic separator is enriched with, mine tailing and one section of cleaner tailings after enrichment, throw it is useless Barren rock is together discharged by qualified tailings afterwards, and Iron Grade of Tailings is controlled below 8%;
E. the filtered dehydration of concentrate after being enriched with, drying is broken up, pelletize returns to the closed circuit magnetizing roast of rotary kiln progress, magnetic separation;
F. because for magnetic iron ore in continuous ore dressing, easily formation disk pack wraps up in phenomenon, influences the selected index of wet type, needs after roasting At each section it is selected before install demagnetization device additional, de- magnetic is carried out to previous stages of magnetic separation processing iron ore concentrate, selected created conditions for next section.
2. the closed circuit recycling technique of rotary kiln baking magnetic separation iron ore stone mine tailing according to claim 1, it is characterized in that:Step Oxidation refractory iron ore described in rapid A includes speculum iron, bloodstone, limonite, siderite and complicated symbiotic iron ore stone.
3. the closed circuit recycling technique of rotary kiln baking magnetic separation iron ore stone mine tailing according to claim 1, it is characterized in that:It is difficult Iron ore is crushed to -15mm, is then classified as -1mm ,+1 ~ -5mm ,+5 ~ -15mm, -1mm granulation, three size fraction ranges point Do not enter kiln and carry out magnetizing roast.
CN201710562812.9A 2017-07-11 2017-07-11 A kind of closed circuit recycling technique of rotary kiln baking magnetic separation iron ore stone mine tailing Pending CN107377206A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108950179A (en) * 2018-06-15 2018-12-07 甘肃酒钢集团宏兴钢铁股份有限公司 A kind of refractory iron ore low temperature reduction with hydrogen magnetic roasting process
CN110714117A (en) * 2019-10-18 2020-01-21 甘肃酒钢集团宏兴钢铁股份有限公司 Intelligent pre-selection waste throwing-shaft furnace magnetizing roasting method for refractory iron ore
CN110787905A (en) * 2019-10-18 2020-02-14 甘肃酒钢集团宏兴钢铁股份有限公司 Magnetized roasting-intelligent pre-selection combined discarding method for weakly magnetic refractory iron ore
CN113789422A (en) * 2021-11-17 2021-12-14 唐山冀东装备工程股份有限公司 Tailing resource utilization method and system

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CN103468936A (en) * 2013-08-15 2013-12-25 甘肃酒钢集团宏兴钢铁股份有限公司 Difficult-separation iron ore tailing pelletizing rotary kiln magnetic roasting treatment technology
CN103657841A (en) * 2013-12-09 2014-03-26 攀钢集团矿业有限公司 Production method of vanadium-titanium-ferrum concentrate
CN103937961A (en) * 2014-04-15 2014-07-23 甘肃酒钢集团宏兴钢铁股份有限公司 Magnetization roasting treatment process for chromite rotary kiln
CN103949404A (en) * 2014-03-24 2014-07-30 甘肃酒钢集团宏兴钢铁股份有限公司 Refractory iron ore fines grading combined processing method
JP2014214338A (en) * 2013-04-24 2014-11-17 住友金属鉱山株式会社 Method for manufacturing hematite for iron manufacture
CN104437826A (en) * 2014-09-15 2015-03-25 中冶北方(大连)工程技术有限公司 Separation technology of specularite after reduction roasting
CN105233976A (en) * 2015-11-05 2016-01-13 鞍钢集团矿业公司 Tailing recovery process adopting preconcentration-roasting-regrinding and magnetic separation method

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CN102728457A (en) * 2012-06-15 2012-10-17 甘肃酒钢集团宏兴钢铁股份有限公司 Method of producing nickel-containing iron ore concentrate from siliceous iron oxide ores containing nickel
JP2014214338A (en) * 2013-04-24 2014-11-17 住友金属鉱山株式会社 Method for manufacturing hematite for iron manufacture
CN103468936A (en) * 2013-08-15 2013-12-25 甘肃酒钢集团宏兴钢铁股份有限公司 Difficult-separation iron ore tailing pelletizing rotary kiln magnetic roasting treatment technology
CN103657841A (en) * 2013-12-09 2014-03-26 攀钢集团矿业有限公司 Production method of vanadium-titanium-ferrum concentrate
CN103949404A (en) * 2014-03-24 2014-07-30 甘肃酒钢集团宏兴钢铁股份有限公司 Refractory iron ore fines grading combined processing method
CN103937961A (en) * 2014-04-15 2014-07-23 甘肃酒钢集团宏兴钢铁股份有限公司 Magnetization roasting treatment process for chromite rotary kiln
CN104437826A (en) * 2014-09-15 2015-03-25 中冶北方(大连)工程技术有限公司 Separation technology of specularite after reduction roasting
CN105233976A (en) * 2015-11-05 2016-01-13 鞍钢集团矿业公司 Tailing recovery process adopting preconcentration-roasting-regrinding and magnetic separation method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108950179A (en) * 2018-06-15 2018-12-07 甘肃酒钢集团宏兴钢铁股份有限公司 A kind of refractory iron ore low temperature reduction with hydrogen magnetic roasting process
CN108950179B (en) * 2018-06-15 2020-07-03 甘肃酒钢集团宏兴钢铁股份有限公司 Low-temperature hydrogen reduction magnetizing roasting process for refractory iron ore
CN110714117A (en) * 2019-10-18 2020-01-21 甘肃酒钢集团宏兴钢铁股份有限公司 Intelligent pre-selection waste throwing-shaft furnace magnetizing roasting method for refractory iron ore
CN110787905A (en) * 2019-10-18 2020-02-14 甘肃酒钢集团宏兴钢铁股份有限公司 Magnetized roasting-intelligent pre-selection combined discarding method for weakly magnetic refractory iron ore
CN113789422A (en) * 2021-11-17 2021-12-14 唐山冀东装备工程股份有限公司 Tailing resource utilization method and system

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Application publication date: 20171124

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