CN107376638A - Fermentation waste gas processing equipment and processing method - Google Patents

Fermentation waste gas processing equipment and processing method Download PDF

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Publication number
CN107376638A
CN107376638A CN201710848994.6A CN201710848994A CN107376638A CN 107376638 A CN107376638 A CN 107376638A CN 201710848994 A CN201710848994 A CN 201710848994A CN 107376638 A CN107376638 A CN 107376638A
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CN
China
Prior art keywords
waste gas
fermentation waste
gas processing
processing equipment
fermentation
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Pending
Application number
CN201710848994.6A
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Chinese (zh)
Inventor
屈庆瑾
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Chongqing Headroom Occupies Environmental Protection Technology Co Ltd
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Chongqing Headroom Occupies Environmental Protection Technology Co Ltd
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Priority to CN201710848994.6A priority Critical patent/CN107376638A/en
Publication of CN107376638A publication Critical patent/CN107376638A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20753Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biomedical Technology (AREA)
  • Toxicology (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention provides a kind of fermentation waste gas processing equipment and processing method, is related to technical field of waste gas treatment.A kind of fermentation waste gas processing equipment, including dehydrating unit, light processor, light processor is arranged to receive the fermentation waste gas after dehydrating unit is handled, light processor includes body, the ultraviolet light source for photodissociation fermentation waste gas and the filter screen for degradable fermented waste gas, and ultraviolet light source, filter screen are arranged at the inside of body.The equipment integrated design, convenient and flexible operation, there is preferable application prospect.A kind of fermentation waste gas processing system, including above-mentioned fermentation waste gas processing equipment and the control device for controlling fermentation waste gas processing equipment.The system automation controls, and saves manpower, reduces cost.

Description

Fermentation waste gas processing equipment and processing method
Technical field
The present invention relates to technical field of waste gas treatment, and more particularly to a kind of fermentation waste gas processing equipment and processing method.
Background technology
Because biofermentation product has curative effect high, toxicity is low, the features such as few side effects, with genetic engineering, cell Engineering, enzyme engineering, the modern biotechnology fast development that Fermentation Engineering is representative, biofermentation product is as investing in 2l centuries One of industry most active, with fastest developing speed.
In biofermentation article manufacturing process, general air dosage is very big, causes a large amount of untreated tail gas to be discharged into air, Partial fermentation metabolite overflows with the tail gas with water vapour, and produces some and have special unpleasant gas, due to discharge The scale of construction is generally large, and carbon dioxide, ammonia, the stench of fermentation and the moiety intermediate being mingled with its tail gas are along with a large amount of water vapours Constantly rise in atmosphere, form the special waste gas for being difficult to be handled with certain single plain mode.
Film filter, film filter separative efficiency are installed again after fermentation tank tail gas liquid separating apparatus by some external enterprises Height, but influenceed by fermentation exhaust sterilizing steam etc., membrane filtration service life is short, and maintenance cost is high;And for tail gas, pressure drop Resistance is big, so as to bring a series of problems.Really effective processing method is few both at home and abroad, lacks a thorough, economical rationality Scheme.
The content of the invention
It is an object of the invention to provide a kind of fermentation waste gas processing equipment, the equipment integrated design, spirit easy to operate It is living, there is preferable application prospect.
Another object of the present invention is to a kind of fermentation waste gas processing method, this method effectively handles fermentation waste gas, place Efficiency high is managed, realizes that fermentation waste gas is innoxious.
What embodiments of the invention were realized in:
A kind of fermentation waste gas processing equipment, including dehydrating unit, light processor, dehydrating unit connect with light processor Connect, light processor includes body, light schematic diagram illustrating and photocatalysis component, and light schematic diagram illustrating, photocatalysis component are arranged at body Inside.
Further, in preferred embodiments of the present invention, photocatalysis component is filter screen, and the matrix of filter screen is by nickel foam system Form.
Further, in preferred embodiments of the present invention, the matrix of filter screen is loaded with nano titanium oxide.
Further, in preferred embodiments of the present invention, the porosity of filter screen is more than 95%.
Further, in preferred embodiments of the present invention, fermentation waste gas processing equipment also includes inlet duct, spraying dress Put, sprayer unit is arranged between inlet duct and light processor.
Further, in preferred embodiments of the present invention, fermentation waste gas processing equipment also includes thermantidote, cold air dress Put and be connected with sprayer unit.
Fermentation waste gas processing equipment also includes the control device being connected with dehydrating unit, photocatalysis apparatus.
A kind of fermentation waste gas processing method, including:Fermentation waste gas is dehumidified using above-mentioned fermentation waste gas processing equipment, Light processing.
Further, in preferred embodiments of the present invention, the relative humidity of the fermentation waste gas after dehumidification treatments is 30 ~80%.
Further, in preferred embodiments of the present invention, also include before being dehumidified to fermentation waste gas:Regulation fermentation The pH value of waste gas is to 7~8.
The beneficial effect of the embodiment of the present invention is:
The present invention provides a kind of fermentation waste gas processing equipment, including dehydrating unit, light processor, light processor include Body, light schematic diagram illustrating and photocatalysis component.Light schematic diagram illustrating is ultraviolet source,.Photocatalysis component is made up of nickel foam, foam Ni has nano titanium oxide.
Fermentation waste gas processing equipment also includes sprayer unit, and fermentation waste gas is pre-processed before dehumidification treatments, improves Acid-base value, it is set to be more easy to oxidation processes.Control device makes fermentation waste gas processing equipment realize Automated condtrol so that fermentation waste gas Processing more precisely, rationally, saves manpower, reduces cost, reduces potential safety hazard.
A kind of fermentation waste gas processing method, acid-base value regulation is carried out to fermentation waste gas using above-mentioned fermentation waste gas processing equipment And dehumidification treatments, make the pH value of fermentation waste gas and relative humidity be beneficial to carry out light processing, improve light processing efficiency and effect.
Brief description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, below by embodiment it is required use it is attached Figure is briefly described, it will be appreciated that the following drawings illustrate only certain embodiments of the present invention, therefore be not construed as pair The restriction of scope, for those of ordinary skill in the art, on the premise of not paying creative work, can also be according to this A little accompanying drawings obtain other related accompanying drawings.
Fig. 1 is the structural representation for the fermentation waste gas processing equipment that the embodiment of the present invention 1 provides;
Fig. 2 is the structural representation for the fermentation waste gas processing equipment that the embodiment of the present invention 2 provides;
Fig. 3 is the structural representation for the fermentation waste gas processing equipment that the embodiment of the present invention 3 provides;
Fig. 4 is the structural representation for the fermentation waste gas processing system that the embodiment of the present invention 4 provides.
Icon:100- fermentation waste gas processing equipments;101- first passages;103- second channels;105- third channels;110- Inlet duct;120- dehydrating units;121- dehumidifiers;123- dewaterers;130- light processors;131- bodies;133- is ultraviolet Line source;135- filter screens;140- exhaust apparatus;200- fermentation waste gas processing equipments;210- blower fans;The processing of 300- fermentation waste gas is set It is standby;310- sprayer units;320- thermantidotes;400- fermentation waste gas processing systems;410- control devices.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention In accompanying drawing, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is Part of the embodiment of the present invention, rather than whole embodiments.The present invention implementation being generally described and illustrated herein in the accompanying drawings The component of example can be configured to arrange and design with a variety of.
Therefore, below the detailed description of the embodiments of the invention to providing in the accompanying drawings be not intended to limit it is claimed The scope of the present invention, but be merely representative of the present invention selected embodiment.It is common based on the embodiment in the present invention, this area The every other embodiment that technical staff is obtained under the premise of creative work is not made, belong to the model that the present invention protects Enclose.
It should be noted that:Similar label and letter represents similar terms in following accompanying drawing, therefore, once a certain Xiang Yi It is defined, then it further need not be defined and explained in subsequent accompanying drawing in individual accompanying drawing.
In the description of the invention, it is necessary to which explanation, the orientation or position relationship of the instruction such as term " interior ", " outer " are base In orientation shown in the drawings or position relationship, or the invention product using when the orientation usually put or position relationship, only It is to be described for the ease of description is of the invention with simplified, rather than the device or element of instruction or hint meaning must be with specifically Orientation, with specific azimuth configuration and operation, therefore be not considered as limiting the invention.
In addition, term " first ", " second ", " the 3rd " etc. are only used for distinguishing description, and it is not intended that instruction or hint Relative importance.
In the description of the invention, it is also necessary to explanation, unless otherwise clearly defined and limited, term " setting ", " connection " should be interpreted broadly, for example, it may be being fixedly connected or being detachably connected, or be integrally connected;Can be Mechanically connect or electrically connect.For the ordinary skill in the art, above-mentioned term can be understood with concrete condition Concrete meaning in the present invention.
Below in conjunction with the accompanying drawings, some embodiments of the present invention are elaborated.It is following in the case where not conflicting Feature in embodiment and embodiment can be mutually combined.
Embodiment 1
Fig. 1 is refer to, the present embodiment provides a kind of fermentation waste gas processing equipment 100, including inlet duct 110, dehumidifying dress 120, light processor 130 and exhaust apparatus 140 are put, inlet duct 110 is connected by first passage 101 with dehydrating unit 120, Dehydrating unit 120 is connected by second channel 103 with light processor 130, light processor 130 by third channel 105 with Exhaust apparatus 140 connects.Fermentation waste gas processing equipment 100 is according to design outline and size is actually needed, in the present embodiment, such as Fig. 1, fermentation waste gas processing equipment 100 are pyramidal structure.
Dehydrating unit 120 is used to remove the steam in discarding, and reduces the relative humidity of waste gas.In the present embodiment, remove Wet device 120 includes dehumidifier 121.Discarding for typically discharging has certain heat, and dehydrating unit 120 has resistance to elevated temperatures, Can normally it be dehumidified below 60 DEG C.In the present embodiment, dehumidifier 121 includes heat exchanger (not shown), compressor (figure Do not show), heat exchanger uses inner screw thread copper pipe, and fin uses titanium aluminium, and refrigerant is reconciled using the anti-high pressure of mixed type and formed. Dehumidifier 121 also includes display, for displays temperature and humidity.Because fermentation waste gas has corrosivity, dehydrating unit 120 has There is anti-corrosion function.Heat exchanger is made using stainless steel plate, and electric cabinet is using the closed electronic box processing of silica gel, and refrigeration accessory is by anti- Corruption processing, water accumulating disc are made of stainless steel.
In the present invention, dehydrating unit 120 cooperates with light processor 130 and fermentation waste gas is handled, and works as warp The relative humidity for crossing the fermentation waste gas of the processing of dehydrating unit 120 is 30~80%, and the effect of light processor 130 is more preferable, fermentation The degradation rate of waste gas is higher, the gas environmental sound of discharge.
The present invention is handled fermentation waste gas by the way of photodissociation composite photocatalyst, and the processing mode works well. Light processor 130 includes body 131, the ultraviolet light source 133 for photodissociation fermentation waste gas and for degradable fermented waste gas Filter screen 135, ultraviolet light source 133, filter screen 135 are arranged in body 131.
In the present embodiment, ultraviolet light source 133 is high energy quartz UV ultraviolet light sources 133.Ultraviolet light source 133 produces Electromagnetic wavelength light beam, it can make odorant molecular dissociation under the bombardment of light quantum largely taking and distribute.In the present embodiment, it is purple The wavelength of outer line source 133 is 150nm~250nm, is 185nm, 195nm, 200nm, 225nm preferably.
Oxygen and moisture in light processor 130 can produce largely in the presence of the light quantum of ultraviolet light source 133 Hydrogen in statu nascendi, reactive hydrogen and hydroxyl oxygen isoreactivity group, a part of fermentation waste gas and active group react, and is converted into titanium dioxide The innocuous substance such as carbon and water, discarded purpose is removed so as to reach.
Meanwhile the oxygen molecule that ultraviolet beam can be decomposed in air produces free oxygen, i.e. active oxygen, free oxygen and oxygen molecule With reference to generation ozone.Ozone has extremely strong oxygenolysis to organic matter due to its strong oxidizing property, make fermentation waste gas and Stench Degradation and Transformation is into low molecular compound, water and carbon dioxide.Due to the unstability of ozone, ozone and the organic fermentation of stench After waste gas effect, itself is faded away, and final discharge will not be had an impact under conditions of substantial equilibrium.
In order to increase the sphere of action of ultraviolet light source 133, in the present embodiment, the fluorescent tube of ultraviolet light source 133 is spiral shell Coil.
In the present embodiment, the photochemical catalyst of filter screen 135 is nano-scale anatase titanium dioxide.Received when ultraviolet lighting is mapped to When on rice titanium dioxide granule, electronics is excited by ultraviolet light, transits to conduction band and forms free electron, and a band is formed in valence band The hole of positive electricity, form electron-hole pair.Utilize the oxidation in caused hole and the reducing power of free electron, titanium dioxide Titanium and hydrone, the oxygen molecule of surface contact react, and produce the extremely strong free radical of oxidizing force.Free radical decomposing and fermenting waste gas In organic substance, the hydrogen in organic substance and carbon are resolved into water and carbon dioxide.
Specifically, the matrix of filter screen 135 is made by nickel foam, nano titanium oxide is loaded with matrix.Using bubble Foam nickel, due to its existing metallic nickel high temperature resistant, feature corrosion-resistant, chemical property is stable, has foam unique again as matrix Tridimensional network.On the one hand the structure can increase the contact area of titanium dioxide and fermentation waste gas, improve photocatalysis effect Rate, improve the degradation efficiency to fermentation waste gas.Preferably, the porosity of filter screen 135 is more than 95%, has filter screen 135 good Gas circulation and permeability, there is preferable photocatalysis efficiency.
Embodiment 2
Fig. 2 is refer to, the present embodiment provides a kind of fermentation waste gas processing equipment 200.
The difference of fermentation waste gas processing equipment 200 and fermentation waste gas processing equipment 100 essentially consists in:
Dehydrating unit 120 also includes dewaterer 123, and dewaterer 123 is connected with inlet duct 110, dehumidifier 121 respectively. Fermentation waste gas enters dewaterer 123 by inlet duct 110, by preliminary dewater treatment, is entering dehumidifier 121, is carrying out Vapour dehumidifying is further taken off, its relative humidity is reached standard value.The double dehydration of dewaterer 123 and dehumidifier 121 can ensure The effect on moisture extraction of fermentation waste gas so that relative humidity is more accurate, also reduces the live load to dehumidifier 121, and extension makes Use the time limit.
Fermentation waste gas processing equipment 200 also includes the blower fan 210 for being arranged at second channel 103, and control fermentation waste gas is being sent out Flowing velocity in ferment waste gas treatment equipment 200, and then control light decomposition and photocatalytic speed and effect.Prevent fermentation waste gas stream Dynamic ambiguity, influence overall degradation effect.In the present embodiment, blower fan 210 is axial flow blower, and it is not done in the present invention Limit.
Represented to simplify, non-mentioned position in the present embodiment, refer to corresponding contents in embodiment 1.
Embodiment 3
Fig. 3 is refer to, the present embodiment provides a kind of fermentation waste gas processing equipment 300.
The difference of fermentation waste gas processing equipment 300 and fermentation waste gas processing equipment 200 essentially consists in:
Fermentation waste gas processing equipment 300 includes being arranged at sprayer unit 310, the thermantidote 320 of first passage 101.Hair Ferment waste gas is generally acid or alkalescence, and its acid-base property can influence light decomposition, photocatalysis effect, while can also corrode at fermentation waste gas Manage equipment 300.Sprayer unit 310 sprays into alkali mist or acid mist according to the pH-value of fermentation waste gas, make the pH value of fermentation waste gas for 7~ 8.Because sprayer unit 310 connects with inlet duct 110, the fermentation waste gas vapor (steam) temperature being just passed through is higher, to spray effect and Sprayer unit 310 has certain influence.Thermantidote 320 conveys cold air into first passage 101 to strengthen the effect of atomization And carry out appropriate cooling.
Represented to simplify, non-mentioned position in the present embodiment, refer to corresponding contents in embodiment 2.
Embodiment 4
Fig. 4 is refer to, the present embodiment provides a kind of fermentation waste gas processing system 400.
The difference of fermentation waste gas processing system 400 and fermentation waste gas processing equipment 300 essentially consists in:
Fermentation waste gas processing system 400 includes being used for the control device 410 for controlling fermentation waste gas processing equipment 300.Control Device 410 realizes the automatic operating of fermentation waste gas processing equipment 300, at any time the operation of monitor fermentation waste gas treatment equipment 300, So that fermentation waste gas processing is more precisely, rationally, manpower is saved, reduces cost.
Represented to simplify, non-mentioned position in the present embodiment, refer to corresponding contents in embodiment 3.
Embodiments described above is part of the embodiment of the present invention, rather than whole embodiments.The reality of the present invention The detailed description for applying example is not intended to limit the scope of claimed invention, but is merely representative of the selected implementation of the present invention Example.Based on the embodiment in the present invention, what those of ordinary skill in the art were obtained under the premise of creative work is not made Every other embodiment, belongs to the scope of protection of the invention.

Claims (10)

  1. A kind of 1. fermentation waste gas processing equipment, it is characterised in that including dehydrating unit, light processor, the dehydrating unit with The light processor connection, the light processor include body, light schematic diagram illustrating and photocatalysis component, the light decomposition group Part, the photocatalysis component are arranged at the inside of the body.
  2. 2. fermentation waste gas processing equipment according to claim 1, it is characterised in that the photocatalysis component is filter screen, institute The matrix for stating filter screen is made by nickel foam.
  3. 3. fermentation waste gas processing equipment according to claim 2, it is characterised in that the matrix of the filter screen is loaded with nanometer Titanium dioxide.
  4. 4. fermentation waste gas processing equipment according to claim 3, it is characterised in that the porosity of the filter screen is more than 95%.
  5. 5. fermentation waste gas processing equipment according to claim 1, it is characterised in that the fermentation waste gas processing equipment is also wrapped Inlet duct, sprayer unit are included, the sprayer unit is arranged between the inlet duct and the light processor.
  6. 6. fermentation waste gas processing equipment according to claim 5, it is characterised in that the fermentation waste gas processing equipment is also wrapped Thermantidote is included, the thermantidote is connected with the sprayer unit.
  7. 7. fermentation waste gas processing equipment according to claim 1, it is characterised in that the fermentation waste gas processing equipment is also wrapped Include the control device being connected with the dehydrating unit, the photocatalysis apparatus.
  8. A kind of 8. fermentation waste gas processing method, it is characterised in that including:Using the fermentation as described in any one of claim 1 to 7 Waste gas treatment equipment is dehumidified to fermentation waste gas, light processing.
  9. 9. fermentation waste gas processing method according to claim 8, it is characterised in that the fermentation after dehumidification treatments is given up The relative humidity of gas is 30~80%.
  10. 10. fermentation waste gas processing method according to claim 9, it is characterised in that dehumidified to the fermentation waste gas Also include before:The pH value of the fermentation waste gas is adjusted to 7~8.
CN201710848994.6A 2017-09-19 2017-09-19 Fermentation waste gas processing equipment and processing method Pending CN107376638A (en)

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CN201710848994.6A CN107376638A (en) 2017-09-19 2017-09-19 Fermentation waste gas processing equipment and processing method

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Application Number Priority Date Filing Date Title
CN201710848994.6A CN107376638A (en) 2017-09-19 2017-09-19 Fermentation waste gas processing equipment and processing method

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CN107376638A true CN107376638A (en) 2017-11-24

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CN110627278A (en) * 2019-10-28 2019-12-31 河南心连心化学工业集团股份有限公司 Wastewater treatment device and process and preparation method of photocatalyst used by same
CN110627278B (en) * 2019-10-28 2023-11-03 河南心连心化学工业集团股份有限公司 Wastewater treatment device and process and preparation method of photocatalyst used by same

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