CN107372488A - A kind of preparation method of novel agrochemical auxiliary agent - Google Patents

A kind of preparation method of novel agrochemical auxiliary agent Download PDF

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Publication number
CN107372488A
CN107372488A CN201710789013.5A CN201710789013A CN107372488A CN 107372488 A CN107372488 A CN 107372488A CN 201710789013 A CN201710789013 A CN 201710789013A CN 107372488 A CN107372488 A CN 107372488A
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CN
China
Prior art keywords
parts
auxiliary agent
novel agrochemical
preparation
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710789013.5A
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Chinese (zh)
Inventor
唐志军
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NANTONG PAISIDI PESTICIDE CHEMICAL CO Ltd
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NANTONG PAISIDI PESTICIDE CHEMICAL CO Ltd
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Priority to CN201710789013.5A priority Critical patent/CN107372488A/en
Publication of CN107372488A publication Critical patent/CN107372488A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18Vapour or smoke emitting compositions with delayed or sustained release
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of preparation method of novel agrochemical auxiliary agent, the novel agrochemical auxiliary agent is made up of the component of following parts by weight:46 parts of 5 15 parts of vegetable oil, 20 40 parts of dry ice, 30 50 parts of light mineral oil, 15 parts of calcium dodecyl benzene sulfonate, 26 parts of lauryl sodium sulfate and antifreezing agent;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 1.7 2.1:1.The advantage of the invention is that:The preparation method of novel agrochemical auxiliary agent of the present invention, each component is to environment, harmless composition in formula, directly addition pesticide solution can produce haze effect, without adding harmful auxiliary agent such as benzene, dimethylbenzene, aniline, cyclohexanone again in production process, meet environmental protection, low-residual, degradable, non-harmful requirement, be particularly suitable for use in vegetables, fruit tree pest and disease damage preventing and treating on, also had broad application prospects in terms of biological pesticide is prepared.

Description

A kind of preparation method of novel agrochemical auxiliary agent
Technical field
The present invention relates to insecticides adjuvant field, more particularly to a kind of preparation method of novel agrochemical auxiliary agent.
Background technology
For the prevention and control of plant diseases, pest control of shaft-like crop, it is to apply the more extensive applications of pesticide in current production to spray and dust Method.But both approaches, decoction or medicinal powder poor adhesion, crop surface is sprayed at, is easily blown away or is rushed by wind or rainwater Walk, influence prevention effect.Thermal fog is that liquid or solid agricultural chemicals is dissolved in the system that certain specification is modulated into appropriate solvent Agent, micron-sized mist or cigarette are formed by fog machine during use, spray into air.Because smog is fine, can be delivered to by fog machine Far very high distance, and there is prolonged floating capacity, it is used for the prevention and control of plant diseases, pest control of the occasions such as forest, orchard, can rises To long-time desinsection, the effect of sterilization.As Chinese invention patent CN101120674A proposes a kind of rubber tree powdery mildew, anthrax The pesticide of disease, decoction is become the ejection that nebulizes using pulsed spray painting dispenser, suspend in atmosphere, can be to rubber tree white powder The effect that disease, anthracnose reach while prevented and treated.Chinese invention patent CN101773113A proposes one kind containing propiconazole and poisoned with poison Thermal fog of barnyard grass and preparation method thereof, the thermal fog support the use with hot mist machine, in, low stem plant prevention and control of plant diseases, pest control effect Fruit is good, and environmental pollution is small.
But thermal fog, because smog is fine, floating capacity is stronger, height is unmanageable, especially in shorter shaft-like work Thing, using certain limitation being present.It is inconvenient for operation and existing thermal fog sprinkling needs special hot mist machine.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of preparation method of novel agrochemical auxiliary agent, to solve above-mentioned technology Problem.
In order to solve the above technical problems, the technical scheme is that:A kind of preparation method of novel agrochemical auxiliary agent, it is created New point is:The novel agrochemical auxiliary agent is made up of the component of following parts by weight:It is vegetable oil 5-15 parts, dry ice 20-40 parts, light Matter mineral oil 30-50 parts, calcium dodecyl benzene sulfonate 1-5 parts, lauryl sodium sulfate 2-6 parts and antifreezing agent 4-6 parts;Wherein, The antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 1.7-2.1:1;The system Preparation Method is:First vegetable oil, dry ice, light mineral oil and antifreezing agent are well mixed, then add detergent alkylate sulphur After sour calcium and lauryl sodium sulfate stir, novel agrochemical auxiliary agent is obtained.
Further, the novel agrochemical auxiliary agent is made up of the component of following parts by weight:Vegetable oil 8-12 parts, dry ice 25-35 parts, light mineral oil 35-45 parts, calcium dodecyl benzene sulfonate 2-4 parts, lauryl sodium sulfate 3-5 parts and antifreezing agent 4.5-5.5 part;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 1.7-2.1:1。
Further, the novel agrochemical auxiliary agent is made up of the component of following parts by weight:10 parts of vegetable oil, dry ice 30 Part, 40 parts of light mineral oil, 3 parts of calcium dodecyl benzene sulfonate, 4 parts of lauryl sodium sulfate and 5 parts of antifreezing agent;Wherein, it is described Antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 1.7-2.1:1.
The advantage of the invention is that:The preparation method of novel agrochemical auxiliary agent of the present invention, in formula each component be to environment, Harmless composition, haze effect can be produced by directly adding pesticide solution, and benzene, diformazan need not be added again in production process Harmful auxiliary agent such as benzene, aniline, cyclohexanone, meets environmental protection, low-residual, degradable, non-harmful requirement, the vegetables that are particularly suitable for use in, In the preventing and treating of the pest and disease damage of fruit tree, also had broad application prospects in terms of biological pesticide is prepared.
Embodiment
The following examples can make professional and technical personnel that the present invention be more fully understood, but therefore not send out this It is bright to be limited among described scope of embodiments.
Embodiment 1
The preparation method of the present embodiment novel agrochemical auxiliary agent, the novel agrochemical auxiliary agent are made up of the component of following parts by weight: 5 parts of vegetable oil, 20 parts of dry ice, 30 parts of light mineral oil, 1 part of calcium dodecyl benzene sulfonate, 2 parts of lauryl sodium sulfate and antifreeze 4 parts of agent;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 1.7: 1;The preparation method is:First vegetable oil, dry ice, light mineral oil and antifreezing agent are well mixed, then add 12 After alkyl benzene calcium sulfonate and lauryl sodium sulfate stir, novel agrochemical auxiliary agent is obtained.
Embodiment 2
The preparation method of the present embodiment novel agrochemical auxiliary agent, the novel agrochemical auxiliary agent are made up of the component of following parts by weight: 5 parts of vegetable oil, 20 parts of dry ice, 30 parts of light mineral oil, 1 part of calcium dodecyl benzene sulfonate, 2 parts of lauryl sodium sulfate and antifreeze 4 parts of agent;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 2.1: 1;The preparation method is:First vegetable oil, dry ice, light mineral oil and antifreezing agent are well mixed, then add 12 After alkyl benzene calcium sulfonate and lauryl sodium sulfate stir, novel agrochemical auxiliary agent is obtained.
Embodiment 3
The preparation method of the present embodiment novel agrochemical auxiliary agent, the novel agrochemical auxiliary agent are made up of the component of following parts by weight: 5 parts of vegetable oil, 20 parts of dry ice, 30 parts of light mineral oil, 1 part of calcium dodecyl benzene sulfonate, 2 parts of lauryl sodium sulfate and antifreeze 4 parts of agent;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 1.9: 1;The preparation method is:First vegetable oil, dry ice, light mineral oil and antifreezing agent are well mixed, then add 12 After alkyl benzene calcium sulfonate and lauryl sodium sulfate stir, novel agrochemical auxiliary agent is obtained.
Embodiment 4
The preparation method of the present embodiment novel agrochemical auxiliary agent, the novel agrochemical auxiliary agent are made up of the component of following parts by weight: 15 parts of vegetable oil, 40 parts of dry ice, 50 parts of light mineral oil, 5 parts of calcium dodecyl benzene sulfonate, 6 parts of lauryl sodium sulfate and anti- Freeze 6 parts of agent;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 1.9:1;The preparation method is:First vegetable oil, dry ice, light mineral oil and antifreezing agent are well mixed, then added After calcium dodecyl benzene sulfonate and lauryl sodium sulfate stir, novel agrochemical auxiliary agent is obtained.
Embodiment 5
The preparation method of the present embodiment novel agrochemical auxiliary agent, the novel agrochemical auxiliary agent are made up of the component of following parts by weight: 8 parts of vegetable oil, 25 parts of dry ice, 35 parts of light mineral oil, 2 parts of calcium dodecyl benzene sulfonate, 3 parts of lauryl sodium sulfate and antifreeze 4.5 parts of agent;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 1.9:1;The preparation method is:First vegetable oil, dry ice, light mineral oil and antifreezing agent are well mixed, then added After calcium dodecyl benzene sulfonate and lauryl sodium sulfate stir, novel agrochemical auxiliary agent is obtained.
Embodiment 6
The preparation method of the present embodiment novel agrochemical auxiliary agent, the novel agrochemical auxiliary agent are made up of the component of following parts by weight: 12 parts of vegetable oil, 35 parts of dry ice, 45 parts of light mineral oil, 4 parts of calcium dodecyl benzene sulfonate, 5 parts of lauryl sodium sulfate and anti- Freeze 5.5 parts of agent;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 1.9:1;The preparation method is:First vegetable oil, dry ice, light mineral oil and antifreezing agent are well mixed, then added After calcium dodecyl benzene sulfonate and lauryl sodium sulfate stir, novel agrochemical auxiliary agent is obtained.
Embodiment 7
The preparation method of the present embodiment novel agrochemical auxiliary agent, the novel agrochemical auxiliary agent are made up of the component of following parts by weight: 10 parts of vegetable oil, 30 parts of dry ice, 40 parts of light mineral oil, 3 parts of calcium dodecyl benzene sulfonate, 4 parts of lauryl sodium sulfate and anti- Freeze 5 parts of agent;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and the mass ratio of ethylene glycol and propane diols is 1.9:1;The preparation method is:First vegetable oil, dry ice, light mineral oil and antifreezing agent are well mixed, then added After calcium dodecyl benzene sulfonate and lauryl sodium sulfate stir, novel agrochemical auxiliary agent is obtained.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The skill of the industry For art personnel it should be appreciated that the present invention is not limited to the above embodiments, described in above-described embodiment and specification is explanation The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and Its equivalent thereof.

Claims (3)

  1. A kind of 1. preparation method of novel agrochemical auxiliary agent, it is characterised in that:The novel agrochemical auxiliary agent is by following parts by weight Component forms:Vegetable oil 5-15 parts, dry ice 20-40 parts, light mineral oil 30-50 parts, calcium dodecyl benzene sulfonate 1-5 parts, ten Sodium dialkyl sulfate 2-6 parts and antifreezing agent 4-6 parts;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and second two The mass ratio of alcohol and propane diols is 1.7-2.1:1;The preparation method is:First by vegetable oil, dry ice, light mineral oil and antifreeze Agent is well mixed, and after then addition calcium dodecyl benzene sulfonate and lauryl sodium sulfate stir, is obtained new Type insecticides adjuvant.
  2. 2. the preparation method of novel agrochemical auxiliary agent according to claim 1, it is characterised in that:The novel agrochemical auxiliary agent is It is made up of the component of following parts by weight:Vegetable oil 8-12 parts, dry ice 25-35 parts, light mineral oil 35-45 parts, detergent alkylate Sulfoacid calcium 2-4 parts, lauryl sodium sulfate 3-5 parts and antifreezing agent 4.5-5.5 parts;Wherein, the antifreezing agent is ethylene glycol and third The mixture of glycol, and the mass ratio of ethylene glycol and propane diols is 1.7-2.1:1.
  3. 3. the preparation method of novel agrochemical auxiliary agent according to claim 1, it is characterised in that:The novel agrochemical auxiliary agent is It is made up of the component of following parts by weight:10 parts of vegetable oil, 30 parts of dry ice, 40 parts of light mineral oil, calcium dodecyl benzene sulfonate 3 5 parts of part, 4 parts of lauryl sodium sulfate and antifreezing agent;Wherein, the antifreezing agent is the mixture of ethylene glycol and propane diols, and second The mass ratio of glycol and propane diols is 1.7-2.1:1.
CN201710789013.5A 2017-09-05 2017-09-05 A kind of preparation method of novel agrochemical auxiliary agent Pending CN107372488A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104026124A (en) * 2014-06-09 2014-09-10 海南江河农药化工厂有限公司 Novel pesticide adjuvant and application thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104026124A (en) * 2014-06-09 2014-09-10 海南江河农药化工厂有限公司 Novel pesticide adjuvant and application thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘步林: "《农药剂型加工技术 第二版》", 31 October 1998, 化学工业出版社 *
徐汉虹: "《植物化学保护学 第四版》", 30 September 2007, 中国农业出版社 *

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Application publication date: 20171124