CN107366623A - A kind of corrosion-resistant chemical pump - Google Patents

A kind of corrosion-resistant chemical pump Download PDF

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Publication number
CN107366623A
CN107366623A CN201710551081.8A CN201710551081A CN107366623A CN 107366623 A CN107366623 A CN 107366623A CN 201710551081 A CN201710551081 A CN 201710551081A CN 107366623 A CN107366623 A CN 107366623A
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China
Prior art keywords
corrosion
resistant
chemical pump
ion beam
styrene
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Application number
CN201710551081.8A
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CN107366623B (en
Inventor
洪忠保
程志强
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Anhui Wolong Pump & Valve Co Ltd
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Anhui Wolong Pump & Valve Co Ltd
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Priority to CN201710551081.8A priority Critical patent/CN107366623B/en
Publication of CN107366623A publication Critical patent/CN107366623A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04DNON-POSITIVE-DISPLACEMENT PUMPS
    • F04D7/00Pumps adapted for handling specific fluids, e.g. by selection of specific materials for pumps or pump parts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04DNON-POSITIVE-DISPLACEMENT PUMPS
    • F04D29/00Details, component parts, or accessories
    • F04D29/02Selection of particular materials
    • F04D29/026Selection of particular materials especially adapted for liquid pumps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04DNON-POSITIVE-DISPLACEMENT PUMPS
    • F04D29/00Details, component parts, or accessories
    • F04D29/18Rotors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04DNON-POSITIVE-DISPLACEMENT PUMPS
    • F04D29/00Details, component parts, or accessories
    • F04D29/40Casings; Connections of working fluid
    • F04D29/406Casings; Connections of working fluid especially adapted for liquid pumps

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)

Abstract

The invention discloses a kind of corrosion-resistant chemical pump, is related to chemical industry pump technical field, and corrosion-resistant finishes is all covered with the pump housing and impeller, and the corrosion-resistant finishes is made up of styrene-acrylic emulsion base coating;The nano diatomite of the aluminium dihydrogen tripolyphosphate being doped using Bronsted acid and the processing of 1.5 1.8% intense pulsed ion beam containing its quality 2.1 2.3% in the styrene-acrylic emulsion base coating;A kind of corrosion-resistant chemical pump of the present invention, by coating corrosion-resistant finishes in the pump housing and impeller surface, the pump housing and impeller surface decay resistance can be significantly improved, improves service life, the average life span of the pump housing and impeller has been respectively increased 60% and 35% or so.

Description

A kind of corrosion-resistant chemical pump
Technical field
The invention belongs to chemical industry pump technical field, and in particular to a kind of corrosion-resistant chemical pump.
Background technology
Chemical pump is in chemical industry or petrochemical industry production, it is necessary in high temperature, low temperature, high pressure, inflammable, explosive, poisonous strong corruption Worked under erosion medium, higher to its performance requirement, chemical pump can also high inlet pressure, high viscosity, low discharge, high cavitation erosion bar again Worked under part, it is therefore, higher to the performance requirement of chemical pump, when the chemical pump manufacturing is carried out, it will usually in the pump housing One layer of corrosion resistant coating of upper coating, to protect the pump housing, and the impeller of chemical pump also needs to contact a large amount of corrosive substances, Equally surface corrosion resistance can be needed higher.
The content of the invention
The purpose of the present invention is to be directed to the problem of existing, there is provided a kind of corrosion-resistant chemical pump.
The present invention is achieved by the following technical solutions:
A kind of corrosion-resistant chemical pump, corrosion-resistant finishes is all covered with the pump housing and impeller, the corrosion-resistant finishes is by styrene-acrylic emulsion Base coating is made;The trimerization phosphorus being doped using Bronsted acid containing its quality 2.1-2.3% in the styrene-acrylic emulsion base coating The nano diatomite of acid dihydride aluminium and 1.5-1.8% intense pulsed ion beam processing.
Further, the corrosion-resistant finishes thickness is 80-100 μm.
Further, styrene-acrylic emulsion content accounts for the 40-60% of its gross mass in the styrene-acrylic emulsion base coating.
Further, the aluminium dihydrogen tripolyphosphate preparation method that the Bronsted acid is doped is:By tripolyphosphate dihydro Aluminium carries out attrition grinding, crosses 800-1000 mesh, then that aluminium dihydrogen tripolyphosphate is molten for 5.5-5.8% phosphoric acid with mass fraction Liquid presses 3-5g:50-80mL ratio uniform is admixed together, is heated to 60-70 DEG C, with 450r/min rotating speeds stir 2 hours, so After naturally cool to room temperature, stand 2-3 hours, then filter, using deionized water rinsing 1-2 times, be then dried to constant weight, i.e., Can.
Further, the nano diatomite preparation method of the intense pulsed ion beam processing is:Use ion energy for The intense pulsed ion beam for the ion beam mixing composition that 200keV, beam current density 120A/cm2, pulse width are 50ns is to receiving Rice diatomite carries out uniform treatment, processing time 5-8s, continuous processing 2 times, at intervals of 10-15s.
Further, the nano diatomite granularity is 55-60nm.
Further, described ion beam mixing is made up of following component by mass percentage:50%H+、50%C+
Further, the pump housing and impeller use for metal material.
By using protonic acid doping aluminium dihydrogen tripolyphosphate, proton can occur to aluminium dihydrogen tripolyphosphate surface atom Change reaction, generate excitation state polaron, carried out p-type doping, formed composite mixed system, changed aluminium dihydrogen tripolyphosphate table The physicochemical property in face, dispersiveness of the aluminium dihydrogen tripolyphosphate in coating can be significantly improved, promoted between coating molecule Interface compatibility, the mechanical property of coating is significantly improved, enhance the activity of coating, pass through the tripolyphosphate of protonic acid doping Aluminum dihydrogen more easily dissociates in paint coatings, and dissociation degree is high, dissociates the P come3O10 5-With extremely strong sequestering power, It can be reacted with the pump housing and impeller surface, form the complicated protection film based on tripolyphosphate compound, this complicated protection Film is insoluble in water, and hardness is high, and adhesive force is strong between the pump housing and impeller, can effectively prevent the generation of corrosion reaction, reach pole The effect of good antirust corrosion-proof, by protonic acid doping aluminium dihydrogen tripolyphosphate, enables to P=O and P-OH groups in the pump housing The position for being easiest to get rusty with impeller is occupied, using the teaching of the invention it is possible to provide outstanding inhibition protection effect, by being received with treated The bentonitic synergy of rice, phosphatization and passivation to a certain degree can occur with the pump housing and impeller surface, generation quality is more Good internal layer diaphragm, by the way that using nano-bentonite as skeletal support, the combination property of internal layer diaphragm can be significantly improved, especially It is decay resistance.
The present invention has advantages below compared with prior art:A kind of corrosion-resistant chemical pump of the present invention, by the pump housing and leaf Wheel surface coats corrosion-resistant finishes, can significantly improve the pump housing and impeller surface decay resistance, improves service life, the pump housing Average life span with impeller has been respectively increased 60% and 35% or so.
Embodiment
Embodiment 1
A kind of corrosion-resistant chemical pump, corrosion-resistant finishes is all covered with the pump housing and impeller, the corrosion-resistant finishes is by styrene-acrylic emulsion Base coating is made;The tripolyphosphate two being doped using Bronsted acid containing its quality 2.1% in the styrene-acrylic emulsion base coating Hydrogen aluminium and the nano diatomite of 1.5% intense pulsed ion beam processing.
Further, the corrosion-resistant finishes thickness is 80 μm.
Further, styrene-acrylic emulsion content accounts for the 40% of its gross mass in the styrene-acrylic emulsion base coating.
Further, the aluminium dihydrogen tripolyphosphate preparation method that the Bronsted acid is doped is:By tripolyphosphate dihydro Aluminium carries out attrition grinding, crosses 800 mesh, and aluminium dihydrogen tripolyphosphate and mass fraction then are pressed into 3g for 5.5% phosphoric acid solution: 50mL ratio uniform is admixed together, is heated to 60 DEG C, is stirred 2 hours with 450r/min rotating speeds, then naturally cools to room Temperature, 2 hours are stood, is then filtered, using deionized water rinsing 1 time, be then dried to constant weight, you can.
Further, the nano diatomite preparation method of the intense pulsed ion beam processing is:Use ion energy for The intense pulsed ion beam for the ion beam mixing composition that 200keV, beam current density 120A/cm2, pulse width are 50ns is to receiving Rice diatomite carries out uniform treatment, processing time 5s, continuous processing 2 times, at intervals of 10s.
Further, the nano diatomite granularity is 55nm.
Further, described ion beam mixing is made up of following component by mass percentage:50%H+、50%C+
Embodiment 2
A kind of corrosion-resistant chemical pump, corrosion-resistant finishes is all covered with the pump housing and impeller, the corrosion-resistant finishes is by styrene-acrylic emulsion Base coating is made;The tripolyphosphate two being doped using Bronsted acid containing its quality 2.3% in the styrene-acrylic emulsion base coating Hydrogen aluminium and the nano diatomite of 1.8% intense pulsed ion beam processing.
Further, the corrosion-resistant finishes thickness is 100 μm.
Further, styrene-acrylic emulsion content accounts for the 60% of its gross mass in the styrene-acrylic emulsion base coating.
Further, the aluminium dihydrogen tripolyphosphate preparation method that the Bronsted acid is doped is:By tripolyphosphate dihydro Aluminium carries out attrition grinding, crosses 1000 mesh, and aluminium dihydrogen tripolyphosphate and mass fraction then are pressed into 5g for 5.8% phosphoric acid solution: 80mL ratio uniform is admixed together, is heated to 70 DEG C, is stirred 2 hours with 450r/min rotating speeds, then naturally cools to room Temperature, 3 hours are stood, is then filtered, using deionized water rinsing 2 times, be then dried to constant weight, you can.
Further, the nano diatomite preparation method of the intense pulsed ion beam processing is:Use ion energy for The intense pulsed ion beam for the ion beam mixing composition that 200keV, beam current density 120A/cm2, pulse width are 50ns is to receiving Rice diatomite carries out uniform treatment, processing time 8s, continuous processing 2 times, at intervals of 10-15s.
Further, the nano diatomite granularity is 60nm.
Further, described ion beam mixing is made up of following component by mass percentage:50%H+、50%C+
Embodiment 3
A kind of corrosion-resistant chemical pump, corrosion-resistant finishes is all covered with the pump housing and impeller, the corrosion-resistant finishes is by styrene-acrylic emulsion Base coating is made;The tripolyphosphate two being doped using Bronsted acid containing its quality 2.2% in the styrene-acrylic emulsion base coating Hydrogen aluminium and the nano diatomite of 1.3% intense pulsed ion beam processing.
Further, the corrosion-resistant finishes thickness is 90 μm.
Further, styrene-acrylic emulsion content accounts for the 50% of its gross mass in the styrene-acrylic emulsion base coating.
Further, the aluminium dihydrogen tripolyphosphate preparation method that the Bronsted acid is doped is:By tripolyphosphate dihydro Aluminium carries out attrition grinding, crosses 900 mesh, and aluminium dihydrogen tripolyphosphate and mass fraction then are pressed into 4g for 5.7% phosphoric acid solution: 60mL ratio uniform is admixed together, is heated to 65 DEG C, is stirred 2 hours with 450r/min rotating speeds, then naturally cools to room Temperature, 2.5 hours are stood, is then filtered, using deionized water rinsing 1 time, be then dried to constant weight, you can.
Further, the nano diatomite preparation method of the intense pulsed ion beam processing is:Use ion energy for The intense pulsed ion beam for the ion beam mixing composition that 200keV, beam current density 120A/cm2, pulse width are 50ns is to receiving Rice diatomite carries out uniform treatment, processing time 6s, continuous processing 2 times, at intervals of 12s.
Further, the nano diatomite granularity is 58nm.
Further, described ion beam mixing is made up of following component by mass percentage:50%H+、50%C+
Comparative example 1:The trimerization phosphorus that styrene-acrylic emulsion base coating do not add Bronsted acid and be doped is differed only in embodiment 1 Acid dihydride aluminium.
Comparative example 2:Styrene-acrylic emulsion base coating, which is differed only in, with embodiment 1 does not add receiving for intense pulsed ion beam processing Rice diatomite.
Comparative example 3:Differed only in embodiment 1 in styrene-acrylic emulsion base coating using common untreated polyphosphoric acid dihydro Aluminium.
Comparative example 4:Differed only in embodiment 1 in styrene-acrylic emulsion base coating using common untreated nanometer diatom Soil.
Experiment:It is standby after the processing such as 200 mesh sand paper sanding and polishings by the steel disc that specification is 2cm × 1cm × 0.1cm, The coating prepared in embodiment and comparative example is uniformly applied on steel disc, then dried, coating layer thickness is 80 μm;
Resistance to neutral salt spray test(With reference to GB/T 1771-2007)Embodiment and comparative example steel disc are tested:
The salt spray resistance of the coating of table 1
336h 624h
Embodiment 1 It is unchanged It is unchanged
Embodiment 2 It is unchanged It is unchanged
Embodiment 3 It is unchanged It is unchanged
Comparative example 1 It is unchanged There is spot corrosion
Comparative example 2 There is spot corrosion -
Comparative example 3 There is spot corrosion Corrosion expands
Comparative example 4 It is unchanged There is spot corrosion
As can be seen from Table 1, do not use corrosion resistance raising effect of the polyphosphoric acid aluminum dihydrogen of protonic acid doping to coating general, Do not use plus the nano diatomite of intense pulsed ion beam processing also can a certain degree of rotproofness performance for reducing coating.

Claims (7)

1. a kind of corrosion-resistant chemical pump, it is characterised in that corrosion-resistant finishes, the corrosion-resistant painting are all covered with the pump housing and impeller Layer is made up of styrene-acrylic emulsion base coating;Carried out in the styrene-acrylic emulsion base coating containing its quality 2.1-2.3% using Bronsted acid The nano diatomite of the intense pulsed ion beam processing of the aluminium dihydrogen tripolyphosphate and 1.5-1.8% of doping.
2. a kind of corrosion-resistant chemical pump according to claim 1, it is characterised in that the corrosion-resistant finishes thickness is 80- 100μm。
A kind of 3. corrosion-resistant chemical pump according to claim 1, it is characterised in that phenylpropyl alcohol in the styrene-acrylic emulsion base coating Emulsion content accounts for the 40-60% of its gross mass.
A kind of 4. corrosion-resistant chemical pump according to claim 1, it is characterised in that the trimerization that the Bronsted acid is doped Aluminium dihydrogen phosphate preparation method is:Aluminium dihydrogen tripolyphosphate is subjected to attrition grinding, 800-1000 mesh is crossed, then by tripolyphosphate Aluminum dihydrogen presses 3-5g with the phosphoric acid solution that mass fraction is 5.5-5.8%:50-80mL ratio uniform is admixed together, is heated to 60-70 DEG C, stirred 2 hours with 450r/min rotating speeds, then naturally cool to room temperature, stood 2-3 hours, then filter, used Deionized water rinsing 1-2 times, is then dried to constant weight, you can.
5. a kind of corrosion-resistant chemical pump according to claim 1, it is characterised in that the intense pulsed ion beam processing Nano diatomite preparation method is:It for 200keV, beam current density 120A/cm2, pulse width is 50ns's to use ion energy The intense pulsed ion beam of ion beam mixing composition carries out uniform treatment, processing time 5-8s, continuous place to nano diatomite Reason 2 times, at intervals of 10-15s.
6. a kind of corrosion-resistant chemical pump according to claim 5, it is characterised in that the nano diatomite granularity is 55- 60nm。
7. a kind of corrosion-resistant chemical pump according to claim 5, it is characterised in that described ion beam mixing presses quality hundred Divide and be made up than meter of following component:50%H+、50%C+
CN201710551081.8A 2017-07-07 2017-07-07 A kind of corrosion-resistant chemical pump Active CN107366623B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109385149A (en) * 2018-09-06 2019-02-26 安徽腾龙泵阀制造有限公司 A kind of chemical pump pump valve component antirusting paint preparation method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51128698A (en) * 1975-05-02 1976-11-09 Teikoku Kako Kk The manufacturing process of the aluminum phosphate
CN2178292Y (en) * 1993-10-23 1994-09-28 许达人 High-temp. acid-proof corrosion resisting pump
CN102993841A (en) * 2012-10-15 2013-03-27 怀远县巨龙机械制造有限公司 Water-based flame-retardant antirust paint
CN103483937A (en) * 2013-09-26 2014-01-01 无锡阳工机械制造有限公司 Rust-proof paint
CN105017869A (en) * 2014-10-30 2015-11-04 合肥蓝天家具制造有限责任公司 Metal outer surface antirusting paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51128698A (en) * 1975-05-02 1976-11-09 Teikoku Kako Kk The manufacturing process of the aluminum phosphate
CN2178292Y (en) * 1993-10-23 1994-09-28 许达人 High-temp. acid-proof corrosion resisting pump
CN102993841A (en) * 2012-10-15 2013-03-27 怀远县巨龙机械制造有限公司 Water-based flame-retardant antirust paint
CN103483937A (en) * 2013-09-26 2014-01-01 无锡阳工机械制造有限公司 Rust-proof paint
CN105017869A (en) * 2014-10-30 2015-11-04 合肥蓝天家具制造有限责任公司 Metal outer surface antirusting paint

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109385149A (en) * 2018-09-06 2019-02-26 安徽腾龙泵阀制造有限公司 A kind of chemical pump pump valve component antirusting paint preparation method

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