CN107365609A - A kind of biomass barred body fuel with excellent resistive connection slag and preparation method thereof - Google Patents
A kind of biomass barred body fuel with excellent resistive connection slag and preparation method thereof Download PDFInfo
- Publication number
- CN107365609A CN107365609A CN201710574180.8A CN201710574180A CN107365609A CN 107365609 A CN107365609 A CN 107365609A CN 201710574180 A CN201710574180 A CN 201710574180A CN 107365609 A CN107365609 A CN 107365609A
- Authority
- CN
- China
- Prior art keywords
- parts
- barred body
- body fuel
- resistive connection
- well mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002893 slag Substances 0.000 title claims abstract description 48
- 239000002028 Biomass Substances 0.000 title claims abstract description 44
- 239000000446 fuel Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 238000002485 combustion reaction Methods 0.000 claims abstract description 39
- 239000002671 adjuvant Substances 0.000 claims abstract description 35
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- 239000010902 straw Substances 0.000 claims abstract description 31
- 239000000945 filler Substances 0.000 claims abstract description 28
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003245 coal Substances 0.000 claims abstract description 16
- 240000007594 Oryza sativa Species 0.000 claims abstract description 15
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 15
- 241000209140 Triticum Species 0.000 claims abstract description 15
- 235000021307 Triticum Nutrition 0.000 claims abstract description 15
- 239000000853 adhesive Substances 0.000 claims abstract description 15
- 230000001070 adhesive effect Effects 0.000 claims abstract description 15
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910001981 cobalt nitrate Inorganic materials 0.000 claims abstract description 15
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 15
- 235000009566 rice Nutrition 0.000 claims abstract description 15
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 229920000193 polymethacrylate Polymers 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims description 45
- 238000010792 warming Methods 0.000 claims description 37
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 238000010438 heat treatment Methods 0.000 claims description 22
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 20
- 229910052757 nitrogen Inorganic materials 0.000 claims description 18
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 16
- 239000012153 distilled water Substances 0.000 claims description 16
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 15
- 239000003153 chemical reaction reagent Substances 0.000 claims description 15
- 230000008878 coupling Effects 0.000 claims description 15
- 238000010168 coupling process Methods 0.000 claims description 15
- 238000005859 coupling reaction Methods 0.000 claims description 15
- 229910000077 silane Inorganic materials 0.000 claims description 15
- 238000012986 modification Methods 0.000 claims description 12
- 230000004048 modification Effects 0.000 claims description 12
- 238000005516 engineering process Methods 0.000 claims description 11
- -1 polypropylene Polymers 0.000 claims description 11
- 244000089742 Citrus aurantifolia Species 0.000 claims description 10
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 235000019738 Limestone Nutrition 0.000 claims description 10
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 10
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 10
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 10
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 10
- 229940043237 diethanolamine Drugs 0.000 claims description 10
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 10
- 239000004571 lime Substances 0.000 claims description 10
- 239000013049 sediment Substances 0.000 claims description 10
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 10
- UJDLUBDOCFXYBX-UHFFFAOYSA-N 2-butyl-2-phenylhexanoic acid Chemical compound CCCCC(CCCC)(C(O)=O)C1=CC=CC=C1 UJDLUBDOCFXYBX-UHFFFAOYSA-N 0.000 claims description 9
- 239000004743 Polypropylene Substances 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 235000019355 sepiolite Nutrition 0.000 claims description 9
- 239000001509 sodium citrate Substances 0.000 claims description 9
- 238000013019 agitation Methods 0.000 claims description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 8
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 8
- 239000006028 limestone Substances 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- 239000001508 potassium citrate Substances 0.000 claims description 8
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 8
- 235000011082 potassium citrates Nutrition 0.000 claims description 8
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 8
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 7
- 239000004113 Sepiolite Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 7
- 229910052624 sepiolite Inorganic materials 0.000 claims description 7
- 229920001661 Chitosan Polymers 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 229960002635 potassium citrate Drugs 0.000 claims description 6
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 150000001408 amides Chemical class 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000007667 floating Methods 0.000 claims description 5
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 238000000197 pyrolysis Methods 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 238000000967 suction filtration Methods 0.000 claims description 5
- 239000003610 charcoal Substances 0.000 claims description 4
- 239000002689 soil Substances 0.000 claims description 3
- 235000005979 Citrus limon Nutrition 0.000 claims description 2
- 244000131522 Citrus pyriformis Species 0.000 claims description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229920002472 Starch Polymers 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000008107 starch Substances 0.000 claims 1
- 235000019698 starch Nutrition 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000010304 firing Methods 0.000 abstract description 2
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 abstract 1
- 235000011083 sodium citrates Nutrition 0.000 description 7
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- 229910052746 lanthanum Inorganic materials 0.000 description 4
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 125000005909 ethyl alcohol group Chemical group 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- 241000206761 Bacillariophyta Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229960003975 potassium Drugs 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 241000208140 Acer Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical class C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/445—Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/442—Wood or forestry waste
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/10—Treating solid fuels to improve their combustion by using additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
- C10L2200/0272—Silicon containing compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
- C10L2200/029—Salts, such as carbonates, oxides, hydroxides, percompounds, e.g. peroxides, perborates, nitrates, nitrites, sulfates, and silicates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
- C10L2200/0295—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/04—Organic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Abstract
The invention discloses a kind of biomass barred body fuel with excellent resistive connection slag, its raw material includes by weight：40 60 parts of rice straw, 15 25 parts of wheat stalk, 36 parts of palm shell, 48 parts of sawmilling slag, 14 parts of Rape Straw, 26 parts of corncob, 28 parts of coal, 36 parts of lanthana, 25 parts of copper nitrate, 14 parts of cobalt nitrate, 39 parts of fluororesin, 25 parts of polymethacrylates, 36 parts of terephthaldehyde's base resin, 25 parts of silicones, 46 parts of NC Nitroncellulose, 570 48 parts of silane coupler KH, modified 36 parts of combustion adjuvant, 5 15 parts of modified filler, 48 parts of adhesive, 26 parts of sulphur-fixing agent, 35 parts of dedusting agent.The present invention also proposes a kind of preparation method of above-mentioned biomass barred body fuel with excellent resistive connection slag, and the biomass barred body fuel being prepared has excellent anti-slagging properties, easy firing and environmental protection.
Description
Technical field
The present invention relates to biomass fuel technical field, more particularly to a kind of biomass barred body combustion with excellent resistive connection slag
Material and preparation method thereof.
Background technology
The three big main energy sources that mankind nowadays use are oil, natural gas and coal, and they are all the non-renewable energy.
According to scholarly forecast, if will be respectively at 40 years, 60 years and 200 to the demand of the energy, these three energy by Economic Development speed
Exhausted in year.Therefore, substitute non-renewable energy resources using bioenergy has turned into the main flow of world today's energy field development.Closely
Several years, the development that bioenergy technology is advanced by leaps and bounds, but simultaneously, some shortcomings of bioenergy also gradually show.The
Generation bioenergy mainly uses fruit, for example, using the plants such as olive, soybean, sunflower, rape, numb maple grease come generation
For diesel oil, or utilize the plants such as corn, sugarcane, sweet potato refinement ethanol.Although the energy that this mode is refined belongs to renewable
The energy, and safety and environmental protection, but will cause grain and edible oil crisis due to refining bioenergy by grain oil product, the mankind's
Basic existence is affected.In view of the above-mentioned problems, the mankind are started with forest processing waste, stalk, moved by research and probe
Thing excrement etc. is as the material for refining bioenergy, such as with being fabricated to biomass after forest processing waste, stalk crushing and processing
Shaped fuel etc..
Therefore a kind of biomass barred body fuel with excellent resistive connection slag of exploitation is needed badly to solve the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of biomass rod with excellent resistive connection slag
Fluid fuel and preparation method thereof, the biomass barred body fuel being prepared have excellent anti-slagging properties, easy firing and environmental protection.
A kind of biomass barred body fuel with excellent resistive connection slag proposed by the present invention, its raw material include by weight：Water
Rice straw 40-60 parts, wheat stalk 15-25 parts, palm shell 3-6 parts, sawmilling slag 4-8 parts, Rape Straw 1-4 parts, corncob 2-6
Part, coal 2-8 parts, lanthana 3-6 parts, copper nitrate 2-5 parts, cobalt nitrate 1-4 parts, fluororesin 3-9 parts, polymethacrylates 2-
5 parts, terephthaldehyde base resin 3-6 parts, silicones 2-5 parts, NC Nitroncellulose 4-6 parts, Silane coupling reagent KH-570 4-8 parts, change
Property combustion adjuvant 3-6 parts, modified filler 5-15 parts, adhesive 4-8 parts, sulphur-fixing agent 2-6 parts, dedusting agent 3-5 parts.
Preferably, the raw material of modified combustion adjuvant includes by weight：Tetra-n-butyl titanate 5-15 parts, absolute ethyl alcohol 2-6 parts,
Diethanol amine 3-6 parts, distilled water 1-4 parts, stearic acid 2-5 parts, amide waxe 1-3 parts, dibutyl tin laurate 2-6 parts, poly- third
Alkene 4-8 parts, dibutyl carboxyl toluene 3-5 parts, diethylenetriamine 2-4 parts, diatomite 1-4 parts, sepiolite 2-5 parts, active lime
2-6 parts, lime stone 1-4 parts, copper sulphate 3-6 parts, iron chloride 2-5 parts, manganese oxide 4-8 parts, sodium citrate 2-6 parts, potassium citrate
3-6 parts, silane coupler KH-560 4-8 parts.
Preferably, the preparation method of modified combustion adjuvant, comprises the following steps：
S1, tetra-n-butyl titanate, absolute ethyl alcohol, diethanol amine and distilled water is well mixed, magnetic agitation obtains material
a；
S2, stearic acid, amide waxe, dibutyl tin laurate, polypropylene and dibutyl carboxyl toluene is well mixed, added
Heat is melted and is passed through nitrogen, then adds dimethylbenzene, and diethylenetriamine is added dropwise after heating and is well mixed and heats up, after being added dropwise
Continue to heat up, be then incubated, be subsequently added into diatomite, sepiolite, active lime, lime stone, copper sulphate, iron chloride, manganese oxide,
Sodium citrate, potassium citrate and silane coupler KH-560 are well mixed, and are incubated after heating, are evaporated under reduced pressure, are cooled to room temperature, obtain
To material b；
S3, material b is added in material a and stirred, be then placed in Muffle furnace, dried, is incubated after continuing heating, then
400-600 DEG C is warming up to 15 DEG C/min speed, calcines 1-3h, is cooled to normal temperature taking-up, is fully ground that to produce modification combustion-supporting
Agent.
Preferably, in the preparation technology of modified combustion adjuvant, in S1, by tetra-n-butyl titanate, absolute ethyl alcohol, diethanol amine and
Distilled water is well mixed, and in 850-1500r/min rotating speed magnetic agitation 20-40min, obtains material a.
Preferably, in the preparation technology of modified combustion adjuvant, in S2, by stearic acid, amide waxe, dibutyl tin laurate,
Polypropylene and dibutyl carboxyl toluene are well mixed, and heating and melting is simultaneously passed through nitrogen, then adds dimethylbenzene, is warming up to 95-105
DEG C, diethylenetriamine is then added dropwise and is well mixed, is warming up to 105-125 DEG C, 135-155 DEG C is warming up to after being added dropwise, insulation
2-3h, then add diatomite, sepiolite, active lime, lime stone, copper sulphate, iron chloride, manganese oxide, sodium citrate, lemon
Sour potassium and silane coupler KH-560 is well mixed, and is warming up to 98-112 DEG C, is incubated 0.5-1.5h, is evaporated under reduced pressure, is cooled to room
Temperature, obtain material b.
Preferably, in the preparation technology of modified combustion adjuvant, in S3, material b is added in material a, in 1500-2500r/
Min rotating speeds stir 20-40min, are then placed in Muffle furnace, in 80-120 DEG C of dry 1-3h, after being continuously heating to 180-220 DEG C
0.5-1.5h is incubated, is then warming up to 400-600 DEG C with 15 DEG C/min speed, calcines 1-3h, is cooled to normal temperature taking-up, fully
Grind and produce modified combustion adjuvant.
Preferably, modified filler is prepared by following technique：Aluminium hydroxide, carborundum, chitosan and distilled water are mixed
Close uniformly, stirred in 850-1050r/min speed, then add sodium lignosulfonate, polyolefin and polyvinyl alcohol
Uniformly, 4-6h is stirred with 280-320r/min speed in 65-75 DEG C of water bath with thermostatic control, is subsequently cooled to room temperature, suction filtration obtains
Sediment, then sediment is cooled to room temperature and obtains modified filler in 45-55 DEG C of dry 44-52h.
Preferably, in the preparation technology of modified filler, aluminium hydroxide, carborundum, chitosan, sodium lignosulfonate, polyolefin
Weight ratio with polyvinyl alcohol is 3-6：2-5：1-3：2-4：3-6：4-8.
A kind of preparation method of biomass barred body fuel with excellent resistive connection slag of the present invention, comprises the following steps：
S1, by rice straw, wheat stalk, palm shell, sawmilling slag, Rape Straw, corncob, fluororesin, polymethyl
Acid esters, terephthaldehyde's base resin, silicones and NC Nitroncellulose carry out being dried to obtain material a after crushing；
S2, by material a, coal, lanthana, copper nitrate, cobalt nitrate, Silane coupling reagent KH-570, modified combustion adjuvant, modification
It is put into after filler, adhesive, sulphur-fixing agent and dedusting agent are well mixed in charing groove, is subsequently placed into pyrolysis oven and is carbonized, mistake
1-3mm sieve, with 1mol/L hydrochloric acid solutions soak 20-28h, remove floating object, then be washed with deionized water to pH value close to neutrality, so
After be put into compressing under 20-50kPa in forming machine, then in 120-140 DEG C of dry 6-8h, being cooled to room temperature is had
The biomass barred body fuel of excellent resistive connection slag.
Preferably, in S2, the concrete operations of charing are：Nitrogen is kept to pass through flow 0.3-0.5m in stove3/ h, start
Temperature is 50-60 DEG C, is warming up to 190 DEG C with 8 DEG C/min, keeps 40-60min, be then warming up to 400- according still further to 8 DEG C/min
500 DEG C, 3-6h is kept, then keeps the state of logical nitrogen to be cooled to room temperature.
A kind of biomass barred body fuel with excellent resistive connection slag proposed by the present invention, its raw material include rice straw, small
Wheat Straw, palm shell, sawmilling slag, Rape Straw, corncob, coal, lanthana, copper nitrate, cobalt nitrate, fluororesin, poly- methyl-prop
Olefin(e) acid ester, terephthaldehyde's base resin, silicones, NC Nitroncellulose, Silane coupling reagent KH-570, modified combustion adjuvant, modified filler,
Adhesive, sulphur-fixing agent and dedusting agent.Wherein, modified combustion adjuvant is by by tetra-n-butyl titanate, absolute ethyl alcohol, diethanol amine and steaming
Distilled water is well mixed, and magnetic agitation obtains material a；Then by stearic acid, amide waxe, dibutyl tin laurate, polypropylene and
Dibutyl carboxyl toluene is well mixed, and heating and melting is simultaneously passed through nitrogen, then adds dimethylbenzene, diethylenetriamine is added dropwise after heating
It is well mixed and heats up, follow-up temperature of continuing rising is added dropwise, is then incubated, is subsequently added into diatomite, sepiolite, active lime, stone
Lime stone, copper sulphate, iron chloride, manganese oxide, sodium citrate, potassium citrate and silane coupler KH-560 are well mixed, after heating
Insulation, it is evaporated under reduced pressure, is cooled to room temperature, obtains material b；Then material b is added in material a and stirred, be then placed in Muffle
In stove, dry, be incubated after continuing heating, then heated up with certain speed, calcining, be cooled to normal temperature taking-up, be fully ground i.e.
Combustion adjuvant must be modified, is applied in the preparation of biomass barred body fuel of the present invention, effectively increases biomass barred body combustion of the present invention
The combustibility of material so that biomass barred body fuel combustion of the invention is more abundant, improves its environmental-protecting performance.It is wherein modified
Filler is stirred by the way that aluminium hydroxide, carborundum, chitosan and distilled water are well mixed, then add sodium lignosulfonate,
Polyolefin and polyvinyl alcohol are uniform, are stirred in water bath with thermostatic control, are subsequently cooled to room temperature, and suction filtration obtains sediment, then
By drying precipitate, it is cooled to room temperature and obtains modified filler, applies in the preparation of biomass barred body fuel of the present invention, effectively carry
The high combustibility of biomass barred body fuel of the present invention so that biomass barred body fuel combustion processability of the invention, carry
High anti-slagging properties, it is engaged with modified combustion adjuvant, and in the presence of the Silane coupling reagent KH-570 that the present invention adds,
Further increase the anti-slagging properties of biomass barred body fuel of the present invention.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of rice straw can be 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46
Part, 47 parts, 48 parts, 49 parts, 50 parts, 51 parts, 52 parts, 53 parts, 54 parts, 55 parts, 56 parts, 57 parts, 58 parts, 59 parts, 60 parts；Wheat
The parts by weight of stalk can be 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts；Palm
The parts by weight of shell can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of sawmilling slag can be 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of Rape Straw can be 1 part, 1.5 parts, 2 parts, 2.5 parts,
3 parts, 3.5 parts, 4 parts；The parts by weight of corncob can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of coal can be 2 parts, 3
Part, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The parts by weight of lanthana can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；
The parts by weight of copper nitrate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of cobalt nitrate can be 1
Part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of fluororesin can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts,
5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；The parts by weight of polymethacrylates can be 2 parts, 2.5
Part, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of terephthaldehyde's base resin can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5
Part, 5.5 parts, 6 parts；The parts by weight of silicones can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；NC Nitroncellulose
Parts by weight can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of Silane coupling reagent KH-570 can be 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of modified combustion adjuvant can be 3 parts, 3.5 parts, 4 parts,
4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of modified filler can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts,
13 parts, 14 parts, 15 parts；The parts by weight of adhesive can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8
Part；The parts by weight of sulphur-fixing agent can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of dedusting agent can be 3 parts, 3.5 parts, 4 parts,
4.5 parts, 5 parts.
Embodiment 1
A kind of biomass barred body fuel with excellent resistive connection slag proposed by the present invention, its raw material include by weight：Water
50 parts of rice straw, 20 parts of wheat stalk, 4.5 parts of palm shell, 6 parts of sawmilling slag, 2.5 parts of Rape Straw, 4 parts of corncob, 5 parts of coal,
4.5 parts of lanthana, 3.5 parts of copper nitrate, 2.5 parts of cobalt nitrate, 6 parts of fluororesin, 3.5 parts of polymethacrylates, terephthaldehyde's base
4.5 parts of resin, 3.5 parts of silicones, 5 parts of NC Nitroncellulose, 6 parts of Silane coupling reagent KH-570,4.5 parts of combustion adjuvant of modification, modification
10 parts of filler, 6 parts of adhesive, 4 parts of sulphur-fixing agent, 4 parts of dedusting agent.
Embodiment 2
A kind of biomass barred body fuel with excellent resistive connection slag proposed by the present invention, its raw material include by weight：Water
40 parts of rice straw, 25 parts of wheat stalk, 3 parts of palm shell, 8 parts of sawmilling slag, 1 part of Rape Straw, 6 parts of corncob, 2 parts of coal, oxidation
6 parts of lanthanum, 2 parts of copper nitrate, 4 parts of cobalt nitrate, 3 parts of fluororesin, 5 parts of polymethacrylates, 3 parts of terephthaldehyde's base resin, silicon tree
5 parts of fat, 4 parts of NC Nitroncellulose, 8 parts of Silane coupling reagent KH-570, modified 3 parts of combustion adjuvant, 15 parts of modified filler, adhesive 4
Part, 6 parts of sulphur-fixing agent, 3 parts of dedusting agent.
A kind of preparation method of biomass barred body fuel with excellent resistive connection slag of the present invention, comprises the following steps：
S1, by rice straw, wheat stalk, palm shell, sawmilling slag, Rape Straw, corncob, fluororesin, polymethyl
Acid esters, terephthaldehyde's base resin, silicones and NC Nitroncellulose carry out being dried to obtain material a after crushing；
S2, by material a, coal, lanthana, copper nitrate, cobalt nitrate, Silane coupling reagent KH-570, modified combustion adjuvant, modification
It is put into after filler, adhesive, sulphur-fixing agent and dedusting agent are well mixed in charing groove, is subsequently placed into pyrolysis oven and is carbonized, charcoal
The concrete operations of change are：Nitrogen is kept to pass through flow 0.3m in stove3/ h, start-up temperature are 60 DEG C, are warming up to 8 DEG C/min
190 DEG C, 40min is kept, is then warming up to 500 DEG C according still further to 8 DEG C/min, keeps 3h, then keeps the state cooling of logical nitrogen
To room temperature, 3mm sieves are crossed, 20h is soaked with 1mol/L hydrochloric acid solutions, removes floating object, then are washed with deionized water to pH value in
Property, be then placed in forming machine it is compressing under 50kPa, then in 120 DEG C of dry 8h, be cooled to room temperature obtain having it is excellent
The biomass barred body fuel of resistive connection slag.
Embodiment 3
A kind of biomass barred body fuel with excellent resistive connection slag proposed by the present invention, its raw material include by weight：Water
60 parts of rice straw, 15 parts of wheat stalk, 6 parts of palm shell, 4 parts of sawmilling slag, 4 parts of Rape Straw, 2 parts of corncob, 8 parts of coal, oxidation
3 parts of lanthanum, 5 parts of copper nitrate, 1 part of cobalt nitrate, 9 parts of fluororesin, 2 parts of polymethacrylates, 6 parts of terephthaldehyde's base resin, silicon tree
2 parts of fat, 6 parts of NC Nitroncellulose, 4 parts of Silane coupling reagent KH-570, modified 6 parts of combustion adjuvant, 5 parts of modified filler, 8 parts of adhesive,
2 parts of sulphur-fixing agent, 5 parts of dedusting agent.
The preparation method of modified combustion adjuvant, comprises the following steps：
S1,15 parts of tetra-n-butyl titanates, 2 parts of absolute ethyl alcohols, 6 parts of diethanol amine and 1 part of distilled water are mixed by weight
Uniformly, in 1500r/min rotating speed magnetic agitation 20min, material a is obtained；
S2, by 5 parts of stearic acid, 1 part of amide waxe, 6 parts of dibutyl tin laurates, 4 parts of polypropylene and 5 parts of dibutyl carboxyls
Toluene is well mixed, and heating and melting is simultaneously passed through nitrogen, then adds dimethylbenzene, is warming up to 95 DEG C, and 4 parts of divinyls three are then added dropwise
Amine is well mixed, and is warming up to 105 DEG C, and 155 DEG C are warming up to after being added dropwise, and is incubated 2h, then adds 4 parts of diatomite, 2 parts of Hai Pao
Stone, 6 parts of active limes, 1 part of lime stone, 6 parts of copper sulphate, 2 parts of iron chloride, 8 parts of manganese oxide, 2 parts of sodium citrates, 6 parts of citric acids
Potassium and 4 parts of silane coupler KH-560 are well mixed, and are warming up to 112 DEG C, are incubated 0.5h, are evaporated under reduced pressure, are cooled to room temperature, obtain
Material b；
S3, material b is added in material a, stirs 20min in 2500r/min rotating speeds, be then placed in Muffle furnace, in
120 DEG C of dry 1h, are incubated 0.5h after being continuously heating to 220 DEG C, be then warming up to 600 DEG C with 15 DEG C/min speed, calcine 1h,
Normal temperature taking-up is cooled to, is fully ground and produces modified combustion adjuvant.
Modified filler is prepared by following technique：By weight by 6 parts of aluminium hydroxides, 2 parts of carborundum, 3 parts of chitosans
It is well mixed with distilled water, is stirred in 850r/min speed, then adds 4 parts of sodium lignosulfonates, 3 parts of polyolefin and 8
Part polyvinyl alcohol is uniform, stirs 4h with 320r/min speed in 65 DEG C of waters bath with thermostatic control, is subsequently cooled to room temperature, filters
Sediment is obtained, then sediment is cooled to room temperature and obtains modified filler in 55 DEG C of dry 44h.
Embodiment 4
A kind of biomass barred body fuel with excellent resistive connection slag proposed by the present invention, its raw material include by weight：Water
45 parts of rice straw, 22 parts of wheat stalk, 4 parts of palm shell, 7 parts of sawmilling slag, 2 parts of Rape Straw, 5 parts of corncob, 3 parts of coal, oxidation
5 parts of lanthanum, 3 parts of copper nitrate, 3 parts of cobalt nitrate, 4 parts of fluororesin, 4 parts of polymethacrylates, 4 parts of terephthaldehyde's base resin, silicon tree
4 parts of fat, 4.5 parts of NC Nitroncellulose, 7 parts of Silane coupling reagent KH-570, modified 4 parts of combustion adjuvant, 12 parts of modified filler, adhesive 5
Part, 5 parts of sulphur-fixing agent, 3.5 parts of dedusting agent.
The preparation method of modified combustion adjuvant, comprises the following steps：
S1,8 parts of tetra-n-butyl titanates, 5 parts of absolute ethyl alcohols, 4 parts of diethanol amine and 3 parts of distilled water are mixed by weight
It is even, in 880r/min rotating speed magnetic agitation 35min, obtain material a；
S2, by 3 parts of stearic acid, 2.5 parts of amide waxes, 3 parts of dibutyl tin laurates, 7 parts of polypropylene and 3.5 parts of dibutyl
Carboxyl toluene is well mixed, and heating and melting is simultaneously passed through nitrogen, then adds dimethylbenzene, is warming up to 102 DEG C, is then added dropwise 2.5 parts
Diethylenetriamine is well mixed, and is warming up to 122 DEG C, and 138 DEG C are warming up to after being added dropwise, and is incubated 2.8h, then adds 2 portions of diatoms
Soil, 4 parts of sepiolites, 3 parts of active limes, 3 parts of lime stones, 4 parts of copper sulphate, 4 parts of iron chloride, 5 parts of manganese oxide, 5 parts of sodium citrates,
4 parts of potassium citrates and 7 parts of silane coupler KH-560 are well mixed, and are warming up to 99 DEG C, are incubated 1.2h, are evaporated under reduced pressure, are cooled to
Room temperature, obtain material b；
S3, material b is added in material a, stirs 35min in 1800r/min rotating speeds, be then placed in Muffle furnace, in
88 DEG C of dry 2.5h, are incubated 1.2h after being continuously heating to 185 DEG C, be then warming up to 450 DEG C with 15 DEG C/min speed, calcining
2.5h, normal temperature taking-up is cooled to, is fully ground and produces modified combustion adjuvant.
Modified filler is prepared by following technique：4 parts of aluminium hydroxides, 4 parts of carborundum, 1.5 parts of shells are gathered by weight
Sugar and distilled water are well mixed, and are stirred in 1020r/min speed, then add 2.5 parts of sodium lignosulfonates, 5 parts of polyenes
Hydrocarbon and 5 parts of polyvinyl alcohols are uniform, stir 5.5h with 290r/min speed in 72 DEG C of waters bath with thermostatic control, are subsequently cooled to room
Temperature, suction filtration obtain sediment, are then cooled to room temperature and obtain modified filler sediment in 48 DEG C of dry 51h.
A kind of preparation method of biomass barred body fuel with excellent resistive connection slag of the present invention, comprises the following steps：
S1, by rice straw, wheat stalk, palm shell, sawmilling slag, Rape Straw, corncob, fluororesin, polymethyl
Acid esters, terephthaldehyde's base resin, silicones and NC Nitroncellulose carry out being dried to obtain material a after crushing；
S2, by material a, coal, lanthana, copper nitrate, cobalt nitrate, Silane coupling reagent KH-570, modified combustion adjuvant, modification
It is put into after filler, adhesive, sulphur-fixing agent and dedusting agent are well mixed in charing groove, is subsequently placed into pyrolysis oven and is carbonized, charcoal
The concrete operations of change are：Nitrogen is kept to pass through flow 0.35m in stove3/ h, start-up temperature are 58 DEG C, are warming up to 8 DEG C/min
190 DEG C, 45min is kept, is then warming up to 480 DEG C according still further to 8 DEG C/min, keeps 4h, then keeps the state cooling of logical nitrogen
To room temperature, 2.5mm sieves are crossed, 22h is soaked with 1mol/L hydrochloric acid solutions, removes floating object, then be washed with deionized water to pH value and approach
Neutrality, is then placed in compressing under 45kPa in forming machine, and then in 125 DEG C of dry 7.5h, being cooled to room temperature is had
The biomass barred body fuel of excellent resistive connection slag.
Embodiment 5
A kind of biomass barred body fuel with excellent resistive connection slag proposed by the present invention, its raw material include by weight：Water
55 parts of rice straw, 18 parts of wheat stalk, 5 parts of palm shell, 5 parts of sawmilling slag, 3 parts of Rape Straw, 3 parts of corncob, 7 parts of coal, oxidation
4 parts of lanthanum, 4 parts of copper nitrate, 2 parts of cobalt nitrate, 8 parts of fluororesin, 3 parts of polymethacrylates, 5 parts of terephthaldehyde's base resin, silicon tree
3 parts of fat, 5.5 parts of NC Nitroncellulose, 5 parts of Silane coupling reagent KH-570, modified 5 parts of combustion adjuvant, 8 parts of modified filler, adhesive 7
Part, 3 parts of sulphur-fixing agent, 4.5 parts of dedusting agent.
The preparation method of modified combustion adjuvant, comprises the following steps：
S1,12 parts of tetra-n-butyl titanates, 3 parts of absolute ethyl alcohols, 5 parts of diethanol amine and 2 parts of distilled water are mixed by weight
Uniformly, in 1200r/min rotating speed magnetic agitation 25min, material a is obtained；
S2, by 4 parts of stearic acid, 1.5 parts of amide waxes, 5 parts of dibutyl tin laurates, 5 parts of polypropylene and 4.5 parts of dibutyl
Carboxyl toluene is well mixed, and heating and melting is simultaneously passed through nitrogen, then adds dimethylbenzene, is warming up to 98 DEG C, is then added dropwise 3.5 part two
Ethene triamine is well mixed, and is warming up to 108 DEG C, and 152 DEG C are warming up to after being added dropwise, and is incubated 2.2h, then adds 3 portions of diatoms
Soil, 3 parts of sepiolites, 5 parts of active limes, 2 parts of lime stones, 5 parts of copper sulphate, 3 parts of iron chloride, 7 parts of manganese oxide, 3 parts of sodium citrates,
5 parts of potassium citrates and 5 parts of silane coupler KH-560 are well mixed, and are warming up to 111 DEG C, are incubated 0.8h, are evaporated under reduced pressure, are cooled to
Room temperature, obtain material b；
S3, material b is added in material a, stirs 25min in 2200r/min rotating speeds, be then placed in Muffle furnace, in
115 DEG C of dry 1.5h, are incubated 0.8h after being continuously heating to 215 DEG C, be then warming up to 550 DEG C with 15 DEG C/min speed, calcining
1.5h, normal temperature taking-up is cooled to, is fully ground and produces modified combustion adjuvant.
Modified filler is prepared by following technique：5 parts of aluminium hydroxides, 3 parts of carborundum, 2.5 parts of shells are gathered by weight
Sugar and distilled water are well mixed, and are stirred in 880r/min speed, then add 3.5 parts of sodium lignosulfonates, 4 parts of polyolefin
It is uniform with 7 parts of polyvinyl alcohols, 4.5h is stirred with 310r/min speed in 68 DEG C of waters bath with thermostatic control, is subsequently cooled to room
Temperature, suction filtration obtain sediment, are then cooled to room temperature and obtain modified filler sediment in 52 DEG C of dry 45h.
A kind of preparation method of biomass barred body fuel with excellent resistive connection slag of the present invention, comprises the following steps：
S1, by rice straw, wheat stalk, palm shell, sawmilling slag, Rape Straw, corncob, fluororesin, polymethyl
Acid esters, terephthaldehyde's base resin, silicones and NC Nitroncellulose carry out being dried to obtain material a after crushing；
S2, by material a, coal, lanthana, copper nitrate, cobalt nitrate, Silane coupling reagent KH-570, modified combustion adjuvant, modification
It is put into after filler, adhesive, sulphur-fixing agent and dedusting agent are well mixed in charing groove, is subsequently placed into pyrolysis oven and is carbonized, charcoal
The concrete operations of change are：Nitrogen is kept to pass through flow 0.45m in stove3/ h, start-up temperature are 52 DEG C, are warming up to 8 DEG C/min
190 DEG C, 55min is kept, is then warming up to 420 DEG C according still further to 8 DEG C/min, keeps 5h, then keeps the state cooling of logical nitrogen
To room temperature, 1.5mm sieves are crossed, 26h is soaked with 1mol/L hydrochloric acid solutions, removes floating object, then be washed with deionized water to pH value and approach
Neutrality, is then placed in compressing under 25kPa in forming machine, and then in 135 DEG C of dry 6.5h, being cooled to room temperature is had
The biomass barred body fuel of excellent resistive connection slag.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (10)
1. a kind of biomass barred body fuel with excellent resistive connection slag, it is characterised in that its raw material includes by weight：Rice straw
Stalk 40-60 parts, wheat stalk 15-25 parts, palm shell 3-6 parts, sawmilling slag 4-8 parts, Rape Straw 1-4 parts, corncob 2-6 parts, coal
Charcoal 2-8 parts, lanthana 3-6 parts, copper nitrate 2-5 parts, cobalt nitrate 1-4 parts, fluororesin 3-9 parts, polymethacrylates 2-5 parts,
Terephthaldehyde base resin 3-6 parts, silicones 2-5 parts, NC Nitroncellulose 4-6 parts, Silane coupling reagent KH-570 4-8 parts, modification help
Fire agent 3-6 parts, modified filler 5-15 parts, adhesive 4-8 parts, sulphur-fixing agent 2-6 parts, dedusting agent 3-5 parts.
2. the biomass barred body fuel according to claim 1 with excellent resistive connection slag, it is characterised in that modified combustion adjuvant
Raw material include by weight：Tetra-n-butyl titanate 5-15 parts, absolute ethyl alcohol 2-6 parts, diethanol amine 3-6 parts, distilled water 1-4
Part, stearic acid 2-5 parts, amide waxe 1-3 parts, dibutyl tin laurate 2-6 parts, polypropylene 4-8 parts, dibutyl carboxyl toluene 3-
5 parts, diethylenetriamine 2-4 parts, diatomite 1-4 parts, sepiolite 2-5 parts, active lime 2-6 parts, lime stone 1-4 parts, copper sulphate
3-6 parts, iron chloride 2-5 parts, manganese oxide 4-8 parts, sodium citrate 2-6 parts, potassium citrate 3-6 parts, silane coupler KH-560 4-
8 parts.
3. the biomass barred body fuel according to claim 1 or 2 with excellent resistive connection slag, it is characterised in that modification helps
The preparation method of agent is fired, is comprised the following steps：
S1, tetra-n-butyl titanate, absolute ethyl alcohol, diethanol amine and distilled water is well mixed, magnetic agitation obtains material a；
S2, stearic acid, amide waxe, dibutyl tin laurate, polypropylene and dibutyl carboxyl toluene is well mixed, heating is melted
Change and be passed through nitrogen, then add dimethylbenzene, diethylenetriamine is added dropwise after heating and is well mixed and heats up, continues after being added dropwise
Heating, is then incubated, is subsequently added into diatomite, sepiolite, active lime, lime stone, copper sulphate, iron chloride, manganese oxide, lemon
Sour sodium, potassium citrate and silane coupler KH-560 are well mixed, and are incubated after heating, are evaporated under reduced pressure, are cooled to room temperature, obtain thing
Expect b；
S3, material b is added in material a and stirred, be then placed in Muffle furnace, dried, is incubated after continuing heating, then with 15
DEG C/min speed is warming up to 400-600 DEG C, 1-3h is calcined, normal temperature taking-up is cooled to, is fully ground and produces modified combustion adjuvant.
4. the biomass barred body fuel with excellent resistive connection slag according to claim any one of 1-3, it is characterised in that change
In the preparation technology of property combustion adjuvant, in S1, tetra-n-butyl titanate, absolute ethyl alcohol, diethanol amine and distilled water are well mixed, in
850-1500r/min rotating speed magnetic agitation 20-40min, obtain material a.
5. the biomass barred body fuel with excellent resistive connection slag according to claim any one of 1-4, it is characterised in that change
In the preparation technology of property combustion adjuvant, in S2, by stearic acid, amide waxe, dibutyl tin laurate, polypropylene and dibutyl carboxyl
Toluene is well mixed, and heating and melting is simultaneously passed through nitrogen, then adds dimethylbenzene, is warming up to 95-105 DEG C, divinyl is then added dropwise
Triamine is well mixed, and is warming up to 105-125 DEG C, and 135-155 DEG C is warming up to after being added dropwise, and is incubated 2-3h, is then added diatom
Soil, sepiolite, active lime, lime stone, copper sulphate, iron chloride, manganese oxide, sodium citrate, potassium citrate and silane coupler
KH-560 is well mixed, and is warming up to 98-112 DEG C, is incubated 0.5-1.5h, is evaporated under reduced pressure, is cooled to room temperature, obtains material b.
6. the biomass barred body fuel with excellent resistive connection slag according to claim any one of 1-5, it is characterised in that change
Property combustion adjuvant preparation technology in, in S3, material b is added in material a, in 1500-2500r/min rotating speeds stir 20-
40min, it is then placed in Muffle furnace, in 80-120 DEG C of dry 1-3h, 0.5-1.5h is incubated after being continuously heating to 180-220 DEG C,
Then 400-600 DEG C is warming up to 15 DEG C/min speed, calcines 1-3h, be cooled to normal temperature taking-up, be fully ground and produce modification
Combustion adjuvant.
7. the biomass barred body fuel with excellent resistive connection slag according to claim any one of 1-6, it is characterised in that change
Property filler is prepared by following technique：Aluminium hydroxide, carborundum, chitosan and distilled water are well mixed, in 850-
1050r/min speed stirs, and then addition sodium lignosulfonate, polyolefin and polyvinyl alcohol are uniform, in 65-75 DEG C
4-6h is stirred with 280-320r/min speed in water bath with thermostatic control, is subsequently cooled to room temperature, suction filtration obtains sediment, then will be heavy
Starch is cooled to room temperature and obtains modified filler in 45-55 DEG C of dry 44-52h.
8. the biomass barred body fuel with excellent resistive connection slag according to claim any one of 1-7, it is characterised in that change
In the preparation technology of property filler, aluminium hydroxide, carborundum, chitosan, sodium lignosulfonate, the weight ratio of polyolefin and polyvinyl alcohol
For 3-6：2-5：1-3：2-4：3-6：4-8.
A kind of 9. preparation side of biomass barred body fuel with excellent resistive connection slag according to claim any one of 1-8
Method, it is characterised in that comprise the following steps：
S1, by rice straw, wheat stalk, palm shell, sawmilling slag, Rape Straw, corncob, fluororesin, polymethacrylates,
Terephthaldehyde's base resin, silicones and NC Nitroncellulose carry out being dried to obtain material a after crushing；
S2, material a, coal, lanthana, copper nitrate, cobalt nitrate, Silane coupling reagent KH-570, modified combustion adjuvant, modification filled out
It is put into after material, adhesive, sulphur-fixing agent and dedusting agent are well mixed in charing groove, is subsequently placed into pyrolysis oven and is carbonized, crosses 1-
3mm sieve, with 1mol/L hydrochloric acid solutions soak 20-28h, remove floating object, then be washed with deionized water to pH value close to neutrality, then
Be put into it is compressing under 20-50kPa in forming machine, then in 120-140 DEG C of dry 6-8h, be cooled to room temperature obtain having it is excellent
The biomass barred body fuel of different resistive connection slag.
10. the preparation method of the biomass barred body fuel according to claim 9 with excellent resistive connection slag, its feature exist
In in S2, the concrete operations of charing are：Nitrogen is kept to pass through flow 0.3-0.5m in stove3/ h, start-up temperature 50-60
DEG C, 190 DEG C are warming up to 8 DEG C/min, keeps 40-60min, is then warming up to 400-500 DEG C according still further to 8 DEG C/min, keeps 3-
6h, the state of logical nitrogen is then kept to be cooled to room temperature.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108219885A (en) * | 2017-12-30 | 2018-06-29 | 安徽大地节能科技有限公司 | A kind of processing method for improving stalk solid particle fuel combustion rate |
| CN109022097A (en) * | 2018-07-09 | 2018-12-18 | 安徽冠建新能源科技有限公司 | A kind of additive improving biology burning matter particle burning degree |
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| US20120304530A1 (en) * | 2011-06-03 | 2012-12-06 | Pallavi Chitta | Bio-Oil Upgrading Process |
| CN105087098A (en) * | 2015-07-30 | 2015-11-25 | 格薪源生物质燃料有限公司 | Efficient slag-accumulation resistance biomass composite fuel |
| CN105969444A (en) * | 2016-03-22 | 2016-09-28 | 安徽徽明建设集团有限公司 | Anti-slagging biomass briquette with mosquito-repellent effect and manufacturing method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101775324A (en) * | 2010-03-23 | 2010-07-14 | 农业部规划设计研究院 | Biomass solid formed fuel anti-slagging additive and preparation method thereof |
| US20120304530A1 (en) * | 2011-06-03 | 2012-12-06 | Pallavi Chitta | Bio-Oil Upgrading Process |
| CN105087098A (en) * | 2015-07-30 | 2015-11-25 | 格薪源生物质燃料有限公司 | Efficient slag-accumulation resistance biomass composite fuel |
| CN105969444A (en) * | 2016-03-22 | 2016-09-28 | 安徽徽明建设集团有限公司 | Anti-slagging biomass briquette with mosquito-repellent effect and manufacturing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108219885A (en) * | 2017-12-30 | 2018-06-29 | 安徽大地节能科技有限公司 | A kind of processing method for improving stalk solid particle fuel combustion rate |
| CN109022097A (en) * | 2018-07-09 | 2018-12-18 | 安徽冠建新能源科技有限公司 | A kind of additive improving biology burning matter particle burning degree |
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| Publication number | Publication date |
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| CN107365609B (en) | 2019-05-21 |
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