CN107361596A - A kind of intelligently filters cup - Google Patents

A kind of intelligently filters cup Download PDF

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Publication number
CN107361596A
CN107361596A CN201710809323.9A CN201710809323A CN107361596A CN 107361596 A CN107361596 A CN 107361596A CN 201710809323 A CN201710809323 A CN 201710809323A CN 107361596 A CN107361596 A CN 107361596A
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China
Prior art keywords
cup
water
parts
intelligently filters
adsorbent equipment
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CN201710809323.9A
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CN107361596B (en
Inventor
梅玉杰
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Yongkang Fulan Industry And Trade Co Ltd
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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G19/00Table service
    • A47G19/22Drinking vessels or saucers used for table service
    • A47G19/2205Drinking glasses or vessels
    • A47G19/2211Lip- or moustache-protecting devices for drinking glasses; Strainers set in a movable or fixed manner in the glasses
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/105Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances combined with inorganic substances

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The invention discloses a kind of intelligently filters cup, and it includes cup lid and cup, and cup lid has adsorbent equipment, has water quality sensor, temperature sensor and liquid level sensor in cup.Described cup includes following control method:The water hardness in water quality sensor automatic detection cup, when hardness is above standard value in water, then processor starts filter, and liquid level sensor detects the liquid level of water, and filter sinks to the center of water by expansion link;Adsorbed by the filtering of adsorbent equipment, when hardness meets standard value in water, adsorbent equipment is retracted in cup lid by expansion link.

Description

A kind of intelligently filters cup
Technical field
The present invention relates to a kind of intelligently filters cup.
Background technology
In society now, the water container with filter is very welcomed by the people, but band filtering dress on the market at present The water container put generally all is sufficiently bulky, it has not been convenient to is carried with;And its mechanism is also more complicated, will generally wait certain Time could the filtered clean water of output, if emergency totally use water in the case of, conventional automaticity device for filtering water is simultaneously It is impossible to meet urgent need, and current cup function is more single, without determined function.
The content of the invention
For above-mentioned problem, the present invention provides a kind of intelligently filters cup, easy to use, has automatic fitration net Change function, and user can be identified, prevent stranger from will using, catch.
To achieve these goals, technical scheme provided by the invention is:A kind of intelligently filters cup, it include cup lid with And cup, described cup lid have adsorbent equipment,
Described cup surface has display screen,
There is water quality sensor, temperature sensor and liquid level sensor in described cup.
Intelligence control system is embedded with cup and is used cooperatively with cup lid, intelligence control system includes control chip, control The display module for showing the time, key-press module, alarm module, communication module, memory module are connected with chip.
Described cup includes following control method:The water hardness in water quality sensor automatic detection cup,
When hardness is above standard value in water, then processor starts filter, and liquid level sensor detects the liquid level of water, filter The center of water is sunk to by expansion link;
Adsorbed by the filtering of adsorbent equipment, when hardness meets standard value in water, adsorbent equipment retracts to cup lid by expansion link In.
Also there is heater inside described cup.
Described adsorbent equipment includes fixed cover and filter cartridge, and fixed cover and filter cartridge surface are respectively provided with micropore, filter cartridge Equipped with water purification nano material, filter cartridge is threadedly coupled with fixed cover, and described fixed cover is fixed on telescopic rod end so that fixed Lid can be moved up and down by expansion link.
After there is telescopic pin, bodies top there is fixing hole, cup lid to be screwed with cup at the top of described expansion link, telescopic pin It is inserted into fixing hole and completes locking.
Described cup surface also has fingerprint identification module, when identification fingerprint for me in use, telescopic pin contraction, complete Into unblock.
The present invention has the water hardness in water quality sensor automatic detection cup, is when hardness is excessive, by the way that absorption is filled Put to stretch into water and complete filtering absorption so that water quality reaching standard, its is simple and convenient, and described cup surface also has fingerprint recognition mould Block, when identification fingerprint for me in use, telescopic pin is shunk, completion unlocks, and prevents stranger from using infection bacterial disease etc..
Brief description of the drawings
Fig. 1 is Intelligent water cup schematic diagram provided in an embodiment of the present invention;
Fig. 2 is Fig. 1 partial schematic diagrams.
In figure:1st, cup, 2, cup lid, 3, expansion link, 4, fingerprint identification module, 5, filter cartridge, 6, fixed cover, 7, flexible Pin, 8, display screen, 9, fixing hole.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made Embodiment, belong to the scope of protection of the invention.
Referring to Fig. 1, a kind of intelligently filters cup, easy to use, there is automatic fitration purification function, and can identify User, prevent stranger from will using, catch.
To achieve these goals, technical scheme provided by the invention is:A kind of intelligently filters cup, it include cup lid with And cup 1, described cup lid 2 have adsorbent equipment,
Described cup surface has display screen 8,
There is water quality sensor, temperature sensor and liquid level sensor in described cup.
Intelligence control system is embedded with cup and is used cooperatively with cup lid, intelligence control system includes control chip, control The display module for showing the time, key-press module, alarm module, communication module, memory module are connected with chip.
Described cup includes following control method:The water hardness in water quality sensor automatic detection cup,
When hardness is above standard value in water, then processor starts filter, and liquid level sensor detects the liquid level of water, filter The center of water is sunk to by expansion link;
Adsorbed by the filtering of adsorbent equipment, when hardness meets standard value in water, adsorbent equipment retracts to cup lid by expansion link In.
Also there is heater inside described cup.
Described adsorbent equipment includes fixed cover 6 and filter cartridge 5, and fixed cover and filter cartridge surface are respectively provided with micropore, filtering Box is equipped with water purification nano material, and filter cartridge is threadedly coupled with fixed cover, and described fixed cover is fixed on the end of expansion link 3 so that Fixed cover can be moved up and down by expansion link.When not needing adsorbent equipment, expansion link is contracted in cup lid body,
There is telescopic pin 7 at the top of described expansion link, bodies top, which has, fixes 9 holes, after cup lid screws with cup, telescopic pin energy Enough insert fixing hole and complete locking.
Described cup surface also has fingerprint identification module 4, when identification fingerprint for me in use, telescopic pin shrink, Complete unblock.
Described water purification nano material is SAPO-5/MCM-36 composite purification materials.
It is that the processing of SAPO-5/MCM-36 zeolite molecular sieves couplingization carried out into phenolic resin again is organically-modified, weakens mixed Adhesion between molecular sieve, interlayer lattice is split, change the highly polar of surface, interlayer is changed into parent by hydrophily Oiliness, its surface energy is reduced, while expand interlamellar spacing, specific surface area is big, porosity is high, nanofiber has macropore and micropore etc. Advantage, the contact area with metal ion can be increased, improve adsorbance, effectively adsorb the calcium and magnesium metal ion in water, coupling Molecular sieve in the phenolic resin modified stage by abundant intercalation and stripping, adsorption process and sun by zeolite molecular sieve to calcium ions and magnesium ions Ion exchange resin and calcium chloride are combined together to the desalination processes of water, can improve the exchange capacity of filter medium and to calcium The exchange efficiency of magnesium ion, also extend the service life of cationic ion-exchange resin.
Specific preparation method is as follows:
Embodiment 1
The preparation method of SAPO-5/MCM-36 composite purification materials, comprises the following steps:
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 30 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 18 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Described coupling SAPO-5/MCM-36 zeolite molecular sieve preparing methods are as follows:
Step 1, the grinding of 50 parts of SAPO-5 zeolites is screened to 100 mesh, then the SAPO-5 zeolite powders after sieving are placed in electric furnace and added After being heated to 1000 DEG C of insulation 3h in thermal with 10 DEG C/min heating rate, SAPO-5 powder is made;
Step 2,30 parts of MCM-36 zeolite molecular sieves powder are mixed with obtained SAPO-5 powder, then add 45 parts the third three Alcohol fusion agent stirs, the oil bath 2h at 300 DEG C, stands more than 1h at room temperature, discards supernatant, lower floor is cleaned with ultra-pure water Material, obtain mixed molecular sieve;
Step 3, above-mentioned mixing molecular sieve is placed in and analyzed in pure toluene, mass ratio 1:15, ultrasonic disperse 1h, equipped with water In four mouthfuls of reaction bulbs of condenser pipe, 120 DEG C are warming up to, under magnetic stirring, silane coupler is added dropwise dropwise, silane coupler accounts for The 10% of mesopore molecular sieve weight, is stirred and steady temperature is kept for 2 hours, is filtered, and is washed 3 times with analysis pure toluene, is dried, obtain To the SAPO-5/MCM-36 zeolite mesopore molecular sieves of coupling processing.
The silane coupler is gamma-aminopropyl-triethoxy-silane(KH-550).
Described modified phenolic epoxy acrylic resin preparation method is as follows:
Step 1,100 parts of novolac epoxy resins are added in four-hole boiling flask, while add 20 parts of modifying agent IPDs, 5 Part p methoxy phenol and 5 parts of catalyst triethanolamines, stirring makes resin all dissolve;
Step 2,80 DEG C are warming up to, 55 parts of acrylic acid are slowly added dropwise with separatory funnel, controlled to be added dropwise in 3h and be warming up to 90 DEG C and be incubated, strict controlling reaction temperature maintenance reaction, until reaction acid number is less than 15mg KOH/g, stop reacting;
Step 3, appropriate 90 DEG C of hot water is added, stir 20min, upper solution is gone in stratification hypsokinesis, to remove unreacted third Olefin(e) acid, modifying agent, p methoxy phenol and catalyst, in triplicate, finally the moisture in removing system obtains modified phenolic Epoxy acrylic resin.
Embodiment 2
Step 1, by 20 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 10 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 8 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEOs are successively It is dissolved in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 3
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 5 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 10 parts of modified phenolic epoxy acrylic resins, 6 parts of carboxymethyl chitosans and 7 parts of APEO elder generations It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 4
Step 1, by 40 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 30 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 28 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 5
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 50 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 38 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 6
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 15 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 15 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 7
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 7 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 11 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 8
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 18 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 5 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEOs are successively It is dissolved in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 9
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 3 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 8 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEOs are successively It is dissolved in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 10
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 23 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 14 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 11
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 30 parts of couplingization SAPO-5/ MCM-36 zeolite molecular sieves, 15 parts of modified nano montmorillonites, 18 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans Sugar and 7 parts of APEOs are successively dissolved in the deionized water of nano-silica-containing, ultrasonic disperse 1h, are spun after deaeration Silk liquid;
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns;
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium The porous nanometer material of ion.
Described modified nano montmorillonite preparation method is as follows:
15 parts of montmorillonites are put into the liquor alumini chloridi of mass fraction 8% at 90 DEG C and stirred 5 hours, filters, washs to neutrality, Drying, is dispersed in the deionized water solution of ethanol one, adds 18 parts of octadecylamines in 60 DEG C of stirred in water bath 4 hours, ultrasound It is scattered 30 minutes, filter, washing, be dried under vacuum to constant weight, grind, sieve and produce modified nano montmorillonite.
Reference examples 1
It is with the difference of embodiment 1:In prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves, by SAPO-5 and MCM- 36 mass ratioes make 1 into:3, remaining step is identical with embodiment 1.
Reference examples 2
It is with the difference of embodiment 1:In prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves, by SAPO-5 and MCM- 36 mass ratioes make 10 into:3, remaining step is identical with embodiment 1.
Reference examples 3
It is with the difference of embodiment 1:The step of prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves:In 3, molecule is mixed Sieve and analysis pure toluene mass ratio are 4:7, remaining step is identical with embodiment 1.
Reference examples 4
It is with the difference of embodiment 1:In step 3 prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves, molecular sieve is mixed It is 10 with analysis pure toluene mass ratio:1, remaining step is identical with embodiment 1.
Reference examples 5
It is with the difference of embodiment 1:In step 3 prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves, do not adding Gamma-aminopropyl-triethoxy-silane, octadecylamine is changed to, dosage keeps constant, and remaining step is identical with embodiment 1.
Reference examples 6
It is with the difference of embodiment 1:In step 3 prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves, silane coupler Gamma-aminopropyl-triethoxy-silane accounts for the 30% of mesopore molecular sieve weight, and remaining step is identical with embodiment 1.
Reference examples 7
It is with the difference of embodiment 1:In step 1 prepared by modified phenolic epoxy acrylic resin, 50 parts of novolac epoxy resins, Add 10 parts of modifying agent IPDs, 5 parts of p methoxy phenols and 5 parts of catalyst triethanolamines simultaneously, remaining step with Embodiment 1 is identical.
Reference examples 8
It is with the difference of embodiment 1:In step 1 prepared by modified phenolic epoxy acrylic resin, 100 parts of epoxy novolac trees Fat, while 30 parts of modifying agent IPDs, 10 parts of p methoxy phenols and 6 parts of catalyst triethanolamines are added, remaining step Suddenly it is identical with embodiment 1.
Reference examples 9
It is with the difference of embodiment 1:In step 1 prepared by modified phenolic epoxy acrylic resin, it is different that modifying agent is not added Isophoronediamine, remaining step are identical with embodiment 1.
Reference examples 10
It is with the difference of embodiment 1:In step 2 prepared by modified phenolic epoxy acrylic resin, slowly dripped with separatory funnel Add 15 parts of acrylic acid, remaining step is identical with embodiment 1.
Choose the nano composite material being prepared and carry out adsorption of metal ions performance detection, foundation respectively《Drinking Water mark Quasi- method of inspection》GB5750-85, testing result reflected by the hardness of water, the hardness of water refer to calcium ion in water, magnesium ion it is dense Degree, stiffness units are ppm, and 1ppm represents calcium carbonate content 1mg/L in water.
The assay of calcium ions and magnesium ions absorption test
Test result indicates that nano adsorption material provided by the invention has good calcium ions and magnesium ions clean-up effect, material is in standard Under test condition, the hardness after water process is lower, illustrates that clean-up effect is better, conversely, effect is poorer;Embodiment 1 arrives embodiment 10, calcium ions and magnesium ions clearance has exceeded 90%, changes the proportioning of each raw material composition in scavenging material, the suction to material respectively Attached performance has different degrees of influence, in couplingization SAPO-5/MCM-36 zeolite molecular sieves and modified phenolic epoxy acrylic Resin proportioning is 15:14, when other dispensing dosages are fixed, absorption property and calcium ions and magnesium ions removal effect are best;It is noticeable It is that embodiment 11 adds modified nano montmorillonite, clean-up effect significantly improves, and illustrates absorption of the nano imvite to filling-material structure Performance has more preferable optimization function;Reference examples 1 to reference examples 4 change the proportioning of two kinds of zeolite molecular sieves and analyze the use of methanol Amount, clean-up effect are decreased obviously, and illustrate that the structural property of mixed molecular sieve receives the considerable influence of the two proportioning;Reference examples 5 arrive Reference examples 6 change SAPO-5/MCM-36 zeolite molecular sieves coupling agent and dosage, and effect is also bad, illustrates the dosage pair of coupling agent The adsorption of modification for mixing molecular sieve plays an important role;Reference examples 7 and example 9 change epoxy novolac acrylic resin modified feedstock Proportioning, clean-up effect substantially reduce, and it is very big to illustrate that modifying agent IPD influences on the absorption property of phenolic resin;Control Example 10, the dosage of acrylic acid is reduced, effect is still bad, illustrates that the intensity of acid produces important shadow to the modified of phenolic resin Ring;Therefore the nano composite material prepared using the present invention has good calcium ions and magnesium ions clean-up effect.

Claims (8)

  1. A kind of 1. intelligently filters cup, it is characterised in that it includes cup lid and cup, and described cup lid has adsorbent equipment,
    Described cup surface has display screen,
    There is water quality sensor, temperature sensor and liquid level sensor in described cup.
  2. A kind of 2. intelligently filters cup according to claim 1, it is characterised in that
    Intelligence control system is embedded with cup and is used cooperatively with cup lid, intelligence control system includes control chip, control chip On be connected with the display display module of time, key-press module, alarm module, communication module, memory module.
  3. 3. a kind of intelligently filters cup according to claim 1, it is characterised in that described cup includes following controlling party Method:The water hardness in water quality sensor automatic detection cup,
    When hardness is above standard value in water, then processor starts filter, and liquid level sensor detects the liquid level of water, filter The center of water is sunk to by expansion link;
    Adsorbed by the filtering of adsorbent equipment, when hardness meets standard value in water, adsorbent equipment retracts to cup lid by expansion link In.
  4. 4. a kind of intelligently filters cup according to claim 1, it is characterised in that also there is heating inside described cup Device.
  5. 5. a kind of intelligently filters cup according to claim 1, it is characterised in that described adsorbent equipment includes fixed cover And filter cartridge, fixed cover and filter cartridge surface are respectively provided with micropore, filter cartridge is equipped with water purification nano material, filter cartridge and fixed cover spiro Line connects, and described fixed cover is fixed on telescopic rod end so that fixed cover can be moved up and down by expansion link.
  6. 6. a kind of intelligently filters cup according to claim 1, it is characterised in that have at the top of described expansion link and stretch Contracting pin, after there is bodies top fixing hole, cup lid to be screwed with cup, telescopic pin is inserted into fixing hole and completes locking.
  7. 7. a kind of intelligently filters cup according to claim 1, it is characterised in that described cup lid top surface also has There is fingerprint identification module, when identification fingerprint for me in use, telescopic pin is shunk, completion unlocks.
  8. 8. a kind of intelligently filters cup according to claim 5, it is characterised in that described water purification nano material is SAPO-5/MCM-36 composite purification materials.
CN201710809323.9A 2017-09-10 2017-09-10 A kind of intelligent filtering cup Active CN107361596B (en)

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CN107822445A (en) * 2017-12-16 2018-03-23 宁波科邦华诚技术转移服务有限公司 A kind of cup lid spiral agitating type fluorine-filtering cup
CN107960820A (en) * 2017-12-16 2018-04-27 宁波科邦华诚技术转移服务有限公司 A kind of spiral fluorine-filtering cup
CN108209423A (en) * 2017-12-07 2018-06-29 广州市科卡通信科技有限公司 A kind of quick self-heating type cup
CN108523578A (en) * 2018-04-26 2018-09-14 中山市红杉企业信息咨询有限公司 A kind of teacup
CN108572204A (en) * 2018-03-28 2018-09-25 浙江沁园水处理科技有限公司 A kind of sensor and its water filter cup of detection water quality
CN108816132A (en) * 2018-08-06 2018-11-16 王潞杨 Fast cooling agitating device for cup

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CN108209423A (en) * 2017-12-07 2018-06-29 广州市科卡通信科技有限公司 A kind of quick self-heating type cup
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CN108572204A (en) * 2018-03-28 2018-09-25 浙江沁园水处理科技有限公司 A kind of sensor and its water filter cup of detection water quality
CN108523578A (en) * 2018-04-26 2018-09-14 中山市红杉企业信息咨询有限公司 A kind of teacup
CN108816132A (en) * 2018-08-06 2018-11-16 王潞杨 Fast cooling agitating device for cup

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