CN107361596A - A kind of intelligently filters cup - Google Patents
A kind of intelligently filters cup Download PDFInfo
- Publication number
- CN107361596A CN107361596A CN201710809323.9A CN201710809323A CN107361596A CN 107361596 A CN107361596 A CN 107361596A CN 201710809323 A CN201710809323 A CN 201710809323A CN 107361596 A CN107361596 A CN 107361596A
- Authority
- CN
- China
- Prior art keywords
- cup
- water
- parts
- intelligently filters
- adsorbent equipment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 97
- 239000003463 adsorbent Substances 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 238000001914 filtration Methods 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000001514 detection method Methods 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 22
- 238000000746 purification Methods 0.000 claims description 9
- 239000002086 nanomaterial Substances 0.000 claims description 5
- 238000004891 communication Methods 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 125000003003 spiro group Chemical group 0.000 claims 1
- 239000002808 molecular sieve Substances 0.000 description 34
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 34
- 239000012528 membrane Substances 0.000 description 33
- 238000009987 spinning Methods 0.000 description 32
- 239000010457 zeolite Substances 0.000 description 27
- 229910021536 Zeolite Inorganic materials 0.000 description 26
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 26
- 239000008367 deionised water Substances 0.000 description 23
- 229910021641 deionized water Inorganic materials 0.000 description 23
- 238000004108 freeze drying Methods 0.000 description 22
- 239000004593 Epoxy Substances 0.000 description 20
- 239000004925 Acrylic resin Substances 0.000 description 19
- 229920000178 Acrylic resin Polymers 0.000 description 19
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 18
- 229910001424 calcium ion Inorganic materials 0.000 description 18
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 18
- 238000010521 absorption reaction Methods 0.000 description 17
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 13
- 229910052791 calcium Inorganic materials 0.000 description 13
- 239000011575 calcium Substances 0.000 description 13
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 12
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000001110 calcium chloride Substances 0.000 description 12
- 229910001628 calcium chloride Inorganic materials 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 12
- 239000002121 nanofiber Substances 0.000 description 12
- 238000005406 washing Methods 0.000 description 12
- 229920001661 Chitosan Polymers 0.000 description 11
- 241000209094 Oryza Species 0.000 description 11
- 235000007164 Oryza sativa Nutrition 0.000 description 11
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 11
- 238000002242 deionisation method Methods 0.000 description 11
- 238000010041 electrostatic spinning Methods 0.000 description 11
- 239000012535 impurity Substances 0.000 description 11
- 150000002500 ions Chemical class 0.000 description 11
- 239000011777 magnesium Substances 0.000 description 11
- 229910052749 magnesium Inorganic materials 0.000 description 11
- 239000005543 nano-size silicon particle Substances 0.000 description 11
- 235000009566 rice Nutrition 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 239000003643 water by type Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 8
- 229910001425 magnesium ion Inorganic materials 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000008859 change Effects 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 229910052901 montmorillonite Inorganic materials 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 4
- 208000024875 Infantile dystonia-parkinsonism Diseases 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 208000001543 infantile parkinsonism-dystonia Diseases 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229910000077 silane Inorganic materials 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical class CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical class COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002114 nanocomposite Substances 0.000 description 2
- 229920003986 novolac Polymers 0.000 description 2
- 239000004843 novolac epoxy resin Substances 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- 208000035143 Bacterial infection Diseases 0.000 description 1
- 101100327917 Caenorhabditis elegans chup-1 gene Proteins 0.000 description 1
- 241000190070 Sarracenia purpurea Species 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G19/00—Table service
- A47G19/22—Drinking vessels or saucers used for table service
- A47G19/2205—Drinking glasses or vessels
- A47G19/2211—Lip- or moustache-protecting devices for drinking glasses; Strainers set in a movable or fixed manner in the glasses
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/105—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances combined with inorganic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention discloses a kind of intelligently filters cup, and it includes cup lid and cup, and cup lid has adsorbent equipment, has water quality sensor, temperature sensor and liquid level sensor in cup.Described cup includes following control method：The water hardness in water quality sensor automatic detection cup, when hardness is above standard value in water, then processor starts filter, and liquid level sensor detects the liquid level of water, and filter sinks to the center of water by expansion link；Adsorbed by the filtering of adsorbent equipment, when hardness meets standard value in water, adsorbent equipment is retracted in cup lid by expansion link.
Description
Technical field
The present invention relates to a kind of intelligently filters cup.
Background technology
In society now, the water container with filter is very welcomed by the people, but band filtering dress on the market at present
The water container put generally all is sufficiently bulky, it has not been convenient to is carried with；And its mechanism is also more complicated, will generally wait certain
Time could the filtered clean water of output, if emergency totally use water in the case of, conventional automaticity device for filtering water is simultaneously
It is impossible to meet urgent need, and current cup function is more single, without determined function.
The content of the invention
For above-mentioned problem, the present invention provides a kind of intelligently filters cup, easy to use, has automatic fitration net
Change function, and user can be identified, prevent stranger from will using, catch.
To achieve these goals, technical scheme provided by the invention is：A kind of intelligently filters cup, it include cup lid with
And cup, described cup lid have adsorbent equipment,
Described cup surface has display screen,
There is water quality sensor, temperature sensor and liquid level sensor in described cup.
Intelligence control system is embedded with cup and is used cooperatively with cup lid, intelligence control system includes control chip, control
The display module for showing the time, key-press module, alarm module, communication module, memory module are connected with chip.
Described cup includes following control method：The water hardness in water quality sensor automatic detection cup,
When hardness is above standard value in water, then processor starts filter, and liquid level sensor detects the liquid level of water, filter
The center of water is sunk to by expansion link；
Adsorbed by the filtering of adsorbent equipment, when hardness meets standard value in water, adsorbent equipment retracts to cup lid by expansion link
In.
Also there is heater inside described cup.
Described adsorbent equipment includes fixed cover and filter cartridge, and fixed cover and filter cartridge surface are respectively provided with micropore, filter cartridge
Equipped with water purification nano material, filter cartridge is threadedly coupled with fixed cover, and described fixed cover is fixed on telescopic rod end so that fixed
Lid can be moved up and down by expansion link.
After there is telescopic pin, bodies top there is fixing hole, cup lid to be screwed with cup at the top of described expansion link, telescopic pin
It is inserted into fixing hole and completes locking.
Described cup surface also has fingerprint identification module, when identification fingerprint for me in use, telescopic pin contraction, complete
Into unblock.
The present invention has the water hardness in water quality sensor automatic detection cup, is when hardness is excessive, by the way that absorption is filled
Put to stretch into water and complete filtering absorption so that water quality reaching standard, its is simple and convenient, and described cup surface also has fingerprint recognition mould
Block, when identification fingerprint for me in use, telescopic pin is shunk, completion unlocks, and prevents stranger from using infection bacterial disease etc..
Brief description of the drawings
Fig. 1 is Intelligent water cup schematic diagram provided in an embodiment of the present invention；
Fig. 2 is Fig. 1 partial schematic diagrams.
In figure：1st, cup, 2, cup lid, 3, expansion link, 4, fingerprint identification module, 5, filter cartridge, 6, fixed cover, 7, flexible
Pin, 8, display screen, 9, fixing hole.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on
Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made
Embodiment, belong to the scope of protection of the invention.
Referring to Fig. 1, a kind of intelligently filters cup, easy to use, there is automatic fitration purification function, and can identify
User, prevent stranger from will using, catch.
To achieve these goals, technical scheme provided by the invention is：A kind of intelligently filters cup, it include cup lid with
And cup 1, described cup lid 2 have adsorbent equipment,
Described cup surface has display screen 8,
There is water quality sensor, temperature sensor and liquid level sensor in described cup.
Intelligence control system is embedded with cup and is used cooperatively with cup lid, intelligence control system includes control chip, control
The display module for showing the time, key-press module, alarm module, communication module, memory module are connected with chip.
Described cup includes following control method：The water hardness in water quality sensor automatic detection cup,
When hardness is above standard value in water, then processor starts filter, and liquid level sensor detects the liquid level of water, filter
The center of water is sunk to by expansion link；
Adsorbed by the filtering of adsorbent equipment, when hardness meets standard value in water, adsorbent equipment retracts to cup lid by expansion link
In.
Also there is heater inside described cup.
Described adsorbent equipment includes fixed cover 6 and filter cartridge 5, and fixed cover and filter cartridge surface are respectively provided with micropore, filtering
Box is equipped with water purification nano material, and filter cartridge is threadedly coupled with fixed cover, and described fixed cover is fixed on the end of expansion link 3 so that
Fixed cover can be moved up and down by expansion link.When not needing adsorbent equipment, expansion link is contracted in cup lid body,
There is telescopic pin 7 at the top of described expansion link, bodies top, which has, fixes 9 holes, after cup lid screws with cup, telescopic pin energy
Enough insert fixing hole and complete locking.
Described cup surface also has fingerprint identification module 4, when identification fingerprint for me in use, telescopic pin shrink,
Complete unblock.
Described water purification nano material is SAPO-5/MCM-36 composite purification materials.
It is that the processing of SAPO-5/MCM-36 zeolite molecular sieves couplingization carried out into phenolic resin again is organically-modified, weakens mixed
Adhesion between molecular sieve, interlayer lattice is split, change the highly polar of surface, interlayer is changed into parent by hydrophily
Oiliness, its surface energy is reduced, while expand interlamellar spacing, specific surface area is big, porosity is high, nanofiber has macropore and micropore etc.
Advantage, the contact area with metal ion can be increased, improve adsorbance, effectively adsorb the calcium and magnesium metal ion in water, coupling
Molecular sieve in the phenolic resin modified stage by abundant intercalation and stripping, adsorption process and sun by zeolite molecular sieve to calcium ions and magnesium ions
Ion exchange resin and calcium chloride are combined together to the desalination processes of water, can improve the exchange capacity of filter medium and to calcium
The exchange efficiency of magnesium ion, also extend the service life of cationic ion-exchange resin.
Specific preparation method is as follows：
Embodiment 1
The preparation method of SAPO-5/MCM-36 composite purification materials, comprises the following steps：
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 30 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 18 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations
It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Described coupling SAPO-5/MCM-36 zeolite molecular sieve preparing methods are as follows：
Step 1, the grinding of 50 parts of SAPO-5 zeolites is screened to 100 mesh, then the SAPO-5 zeolite powders after sieving are placed in electric furnace and added
After being heated to 1000 DEG C of insulation 3h in thermal with 10 DEG C/min heating rate, SAPO-5 powder is made；
Step 2,30 parts of MCM-36 zeolite molecular sieves powder are mixed with obtained SAPO-5 powder, then add 45 parts the third three
Alcohol fusion agent stirs, the oil bath 2h at 300 DEG C, stands more than 1h at room temperature, discards supernatant, lower floor is cleaned with ultra-pure water
Material, obtain mixed molecular sieve；
Step 3, above-mentioned mixing molecular sieve is placed in and analyzed in pure toluene, mass ratio 1：15, ultrasonic disperse 1h, equipped with water
In four mouthfuls of reaction bulbs of condenser pipe, 120 DEG C are warming up to, under magnetic stirring, silane coupler is added dropwise dropwise, silane coupler accounts for
The 10% of mesopore molecular sieve weight, is stirred and steady temperature is kept for 2 hours, is filtered, and is washed 3 times with analysis pure toluene, is dried, obtain
To the SAPO-5/MCM-36 zeolite mesopore molecular sieves of coupling processing.
The silane coupler is gamma-aminopropyl-triethoxy-silane（KH-550）.
Described modified phenolic epoxy acrylic resin preparation method is as follows：
Step 1,100 parts of novolac epoxy resins are added in four-hole boiling flask, while add 20 parts of modifying agent IPDs, 5
Part p methoxy phenol and 5 parts of catalyst triethanolamines, stirring makes resin all dissolve；
Step 2,80 DEG C are warming up to, 55 parts of acrylic acid are slowly added dropwise with separatory funnel, controlled to be added dropwise in 3h and be warming up to 90
DEG C and be incubated, strict controlling reaction temperature maintenance reaction, until reaction acid number is less than 15mg KOH/g, stop reacting；
Step 3, appropriate 90 DEG C of hot water is added, stir 20min, upper solution is gone in stratification hypsokinesis, to remove unreacted third
Olefin(e) acid, modifying agent, p methoxy phenol and catalyst, in triplicate, finally the moisture in removing system obtains modified phenolic
Epoxy acrylic resin.
Embodiment 2
Step 1, by 20 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 10 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 8 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEOs are successively
It is dissolved in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 3
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 5 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 10 parts of modified phenolic epoxy acrylic resins, 6 parts of carboxymethyl chitosans and 7 parts of APEO elder generations
It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 4
Step 1, by 40 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 30 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 28 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations
It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 5
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 50 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 38 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations
It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 6
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 15 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 15 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations
It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 7
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 7 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 11 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations
It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 8
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 18 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 5 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEOs are successively
It is dissolved in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 9
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 3 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 8 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEOs are successively
It is dissolved in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 10
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 23 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 14 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans and 7 parts of APEO elder generations
It is dissolved in afterwards in the deionized water of nano-silica-containing, ultrasonic disperse 1h, spinning solution is obtained after deaeration；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Remaining is prepared and embodiment 1 is identical.
Embodiment 11
Step 1, by 10 parts of nano silicon ultrasonic disperses in 50 parts of deionized waters, then by 30 parts of couplingization SAPO-5/
MCM-36 zeolite molecular sieves, 15 parts of modified nano montmorillonites, 18 parts of modified phenolic epoxy acrylic resins, 3 parts of carboxymethyl chitosans
Sugar and 7 parts of APEOs are successively dissolved in the deionized water of nano-silica-containing, ultrasonic disperse 1h, are spun after deaeration
Silk liquid；
Step 2, spinning solution obtained above is injected into needle tubing, obtaining a diameter of 500 by high-voltage electrostatic spinning technology receives
The nanofiber of rice, the thickness for controlling spinning time-controllable nano fibrous membrane are 50 microns；
Step 3, nano fibrous membrane obtained above is dipped into 30% calcium chloride water it is crosslinked 30min, uses deionization
Water simply rinses 2 calcium ions for washing away excess surface, macroporous structure is obtained by freeze-drying, then by after freeze-drying
Nano fibrous membrane is dipped into 24h in deionized water again, washes away impurity and obtains microcellular structure, so as to obtain a kind of absorption calcium and magnesium
The porous nanometer material of ion.
Described modified nano montmorillonite preparation method is as follows：
15 parts of montmorillonites are put into the liquor alumini chloridi of mass fraction 8% at 90 DEG C and stirred 5 hours, filters, washs to neutrality,
Drying, is dispersed in the deionized water solution of ethanol one, adds 18 parts of octadecylamines in 60 DEG C of stirred in water bath 4 hours, ultrasound
It is scattered 30 minutes, filter, washing, be dried under vacuum to constant weight, grind, sieve and produce modified nano montmorillonite.
Reference examples 1
It is with the difference of embodiment 1：In prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves, by SAPO-5 and MCM-
36 mass ratioes make 1 into:3, remaining step is identical with embodiment 1.
Reference examples 2
It is with the difference of embodiment 1：In prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves, by SAPO-5 and MCM-
36 mass ratioes make 10 into:3, remaining step is identical with embodiment 1.
Reference examples 3
It is with the difference of embodiment 1：The step of prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves:In 3, molecule is mixed
Sieve and analysis pure toluene mass ratio are 4：7, remaining step is identical with embodiment 1.
Reference examples 4
It is with the difference of embodiment 1：In step 3 prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves, molecular sieve is mixed
It is 10 with analysis pure toluene mass ratio：1, remaining step is identical with embodiment 1.
Reference examples 5
It is with the difference of embodiment 1：In step 3 prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves, do not adding
Gamma-aminopropyl-triethoxy-silane, octadecylamine is changed to, dosage keeps constant, and remaining step is identical with embodiment 1.
Reference examples 6
It is with the difference of embodiment 1：In step 3 prepared by couplingization SAPO-5/MCM-36 zeolite molecular sieves, silane coupler
Gamma-aminopropyl-triethoxy-silane accounts for the 30% of mesopore molecular sieve weight, and remaining step is identical with embodiment 1.
Reference examples 7
It is with the difference of embodiment 1：In step 1 prepared by modified phenolic epoxy acrylic resin, 50 parts of novolac epoxy resins,
Add 10 parts of modifying agent IPDs, 5 parts of p methoxy phenols and 5 parts of catalyst triethanolamines simultaneously, remaining step with
Embodiment 1 is identical.
Reference examples 8
It is with the difference of embodiment 1：In step 1 prepared by modified phenolic epoxy acrylic resin, 100 parts of epoxy novolac trees
Fat, while 30 parts of modifying agent IPDs, 10 parts of p methoxy phenols and 6 parts of catalyst triethanolamines are added, remaining step
Suddenly it is identical with embodiment 1.
Reference examples 9
It is with the difference of embodiment 1：In step 1 prepared by modified phenolic epoxy acrylic resin, it is different that modifying agent is not added
Isophoronediamine, remaining step are identical with embodiment 1.
Reference examples 10
It is with the difference of embodiment 1：In step 2 prepared by modified phenolic epoxy acrylic resin, slowly dripped with separatory funnel
Add 15 parts of acrylic acid, remaining step is identical with embodiment 1.
Choose the nano composite material being prepared and carry out adsorption of metal ions performance detection, foundation respectively《Drinking Water mark
Quasi- method of inspection》GB5750-85, testing result reflected by the hardness of water, the hardness of water refer to calcium ion in water, magnesium ion it is dense
Degree, stiffness units are ppm, and 1ppm represents calcium carbonate content 1mg/L in water.
The assay of calcium ions and magnesium ions absorption test
Test result indicates that nano adsorption material provided by the invention has good calcium ions and magnesium ions clean-up effect, material is in standard
Under test condition, the hardness after water process is lower, illustrates that clean-up effect is better, conversely, effect is poorer；Embodiment 1 arrives embodiment
10, calcium ions and magnesium ions clearance has exceeded 90%, changes the proportioning of each raw material composition in scavenging material, the suction to material respectively
Attached performance has different degrees of influence, in couplingization SAPO-5/MCM-36 zeolite molecular sieves and modified phenolic epoxy acrylic
Resin proportioning is 15：14, when other dispensing dosages are fixed, absorption property and calcium ions and magnesium ions removal effect are best；It is noticeable
It is that embodiment 11 adds modified nano montmorillonite, clean-up effect significantly improves, and illustrates absorption of the nano imvite to filling-material structure
Performance has more preferable optimization function；Reference examples 1 to reference examples 4 change the proportioning of two kinds of zeolite molecular sieves and analyze the use of methanol
Amount, clean-up effect are decreased obviously, and illustrate that the structural property of mixed molecular sieve receives the considerable influence of the two proportioning；Reference examples 5 arrive
Reference examples 6 change SAPO-5/MCM-36 zeolite molecular sieves coupling agent and dosage, and effect is also bad, illustrates the dosage pair of coupling agent
The adsorption of modification for mixing molecular sieve plays an important role；Reference examples 7 and example 9 change epoxy novolac acrylic resin modified feedstock
Proportioning, clean-up effect substantially reduce, and it is very big to illustrate that modifying agent IPD influences on the absorption property of phenolic resin；Control
Example 10, the dosage of acrylic acid is reduced, effect is still bad, illustrates that the intensity of acid produces important shadow to the modified of phenolic resin
Ring；Therefore the nano composite material prepared using the present invention has good calcium ions and magnesium ions clean-up effect.
Claims (8)
- A kind of 1. intelligently filters cup, it is characterised in that it includes cup lid and cup, and described cup lid has adsorbent equipment,Described cup surface has display screen,There is water quality sensor, temperature sensor and liquid level sensor in described cup.
- A kind of 2. intelligently filters cup according to claim 1, it is characterised in thatIntelligence control system is embedded with cup and is used cooperatively with cup lid, intelligence control system includes control chip, control chip On be connected with the display display module of time, key-press module, alarm module, communication module, memory module.
- 3. a kind of intelligently filters cup according to claim 1, it is characterised in that described cup includes following controlling party Method：The water hardness in water quality sensor automatic detection cup,When hardness is above standard value in water, then processor starts filter, and liquid level sensor detects the liquid level of water, filter The center of water is sunk to by expansion link；Adsorbed by the filtering of adsorbent equipment, when hardness meets standard value in water, adsorbent equipment retracts to cup lid by expansion link In.
- 4. a kind of intelligently filters cup according to claim 1, it is characterised in that also there is heating inside described cup Device.
- 5. a kind of intelligently filters cup according to claim 1, it is characterised in that described adsorbent equipment includes fixed cover And filter cartridge, fixed cover and filter cartridge surface are respectively provided with micropore, filter cartridge is equipped with water purification nano material, filter cartridge and fixed cover spiro Line connects, and described fixed cover is fixed on telescopic rod end so that fixed cover can be moved up and down by expansion link.
- 6. a kind of intelligently filters cup according to claim 1, it is characterised in that have at the top of described expansion link and stretch Contracting pin, after there is bodies top fixing hole, cup lid to be screwed with cup, telescopic pin is inserted into fixing hole and completes locking.
- 7. a kind of intelligently filters cup according to claim 1, it is characterised in that described cup lid top surface also has There is fingerprint identification module, when identification fingerprint for me in use, telescopic pin is shunk, completion unlocks.
- 8. a kind of intelligently filters cup according to claim 5, it is characterised in that described water purification nano material is SAPO-5/MCM-36 composite purification materials.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710809323.9A CN107361596B (en) | 2017-09-10 | 2017-09-10 | A kind of intelligent filtering cup |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710809323.9A CN107361596B (en) | 2017-09-10 | 2017-09-10 | A kind of intelligent filtering cup |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107361596A true CN107361596A (en) | 2017-11-21 |
| CN107361596B CN107361596B (en) | 2019-04-12 |
Family
ID=60311277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710809323.9A Active CN107361596B (en) | 2017-09-10 | 2017-09-10 | A kind of intelligent filtering cup |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107361596B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107822445A (en) * | 2017-12-16 | 2018-03-23 | 宁波科邦华诚技术转移服务有限公司 | A kind of cup lid spiral agitating type fluorine-filtering cup |
| CN107960820A (en) * | 2017-12-16 | 2018-04-27 | 宁波科邦华诚技术转移服务有限公司 | A kind of spiral fluorine-filtering cup |
| CN108209423A (en) * | 2017-12-07 | 2018-06-29 | 广州市科卡通信科技有限公司 | A kind of quick self-heating type cup |
| CN108523578A (en) * | 2018-04-26 | 2018-09-14 | 中山市红杉企业信息咨询有限公司 | A kind of teacup |
| CN108572204A (en) * | 2018-03-28 | 2018-09-25 | 浙江沁园水处理科技有限公司 | A kind of sensor and its water filter cup of detection water quality |
| CN108816132A (en) * | 2018-08-06 | 2018-11-16 | 王潞杨 | Fast cooling agitating device for cup |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10137127A (en) * | 1996-11-14 | 1998-05-26 | Seretsuku Kk | Cup with lid containing filler screen |
| CN103865460A (en) * | 2014-03-13 | 2014-06-18 | 漳州市奈特新型建材有限责任公司 | Resin composition as well as preparation method and application thereof |
| CN105559484A (en) * | 2015-12-31 | 2016-05-11 | 上海禹清环境技术有限公司 | Water filtering cup capable of improving water quality and taste |
| CN106178690A (en) * | 2016-08-05 | 2016-12-07 | 安徽嘉乐斯乐净化工程有限公司 | A kind of high water suction humidifier filter material of toughness reinforcing enhancing |
| CN106473432A (en) * | 2016-10-30 | 2017-03-08 | 宁波科邦华诚技术转移服务有限公司 | Field illuminating filtering cup |
| CN106691090A (en) * | 2017-02-23 | 2017-05-24 | 蒋菊生 | Smart cup with fingerprint identification function and method for opening and locking cap of smart cup |
| CN106724604A (en) * | 2017-03-21 | 2017-05-31 | 深圳汉华科技股份有限公司 | A kind of multifunctional intellectual cup and its health management system arranged |
| CN107031968A (en) * | 2016-09-02 | 2017-08-11 | 深圳纳感科技有限公司 | A kind of pollutant monitoring water bottle with filter and monitoring function |
-
2017
- 2017-09-10 CN CN201710809323.9A patent/CN107361596B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10137127A (en) * | 1996-11-14 | 1998-05-26 | Seretsuku Kk | Cup with lid containing filler screen |
| CN103865460A (en) * | 2014-03-13 | 2014-06-18 | 漳州市奈特新型建材有限责任公司 | Resin composition as well as preparation method and application thereof |
| CN105559484A (en) * | 2015-12-31 | 2016-05-11 | 上海禹清环境技术有限公司 | Water filtering cup capable of improving water quality and taste |
| CN106178690A (en) * | 2016-08-05 | 2016-12-07 | 安徽嘉乐斯乐净化工程有限公司 | A kind of high water suction humidifier filter material of toughness reinforcing enhancing |
| CN107031968A (en) * | 2016-09-02 | 2017-08-11 | 深圳纳感科技有限公司 | A kind of pollutant monitoring water bottle with filter and monitoring function |
| CN106473432A (en) * | 2016-10-30 | 2017-03-08 | 宁波科邦华诚技术转移服务有限公司 | Field illuminating filtering cup |
| CN106691090A (en) * | 2017-02-23 | 2017-05-24 | 蒋菊生 | Smart cup with fingerprint identification function and method for opening and locking cap of smart cup |
| CN106724604A (en) * | 2017-03-21 | 2017-05-31 | 深圳汉华科技股份有限公司 | A kind of multifunctional intellectual cup and its health management system arranged |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108209423A (en) * | 2017-12-07 | 2018-06-29 | 广州市科卡通信科技有限公司 | A kind of quick self-heating type cup |
| CN107822445A (en) * | 2017-12-16 | 2018-03-23 | 宁波科邦华诚技术转移服务有限公司 | A kind of cup lid spiral agitating type fluorine-filtering cup |
| CN107960820A (en) * | 2017-12-16 | 2018-04-27 | 宁波科邦华诚技术转移服务有限公司 | A kind of spiral fluorine-filtering cup |
| CN108572204A (en) * | 2018-03-28 | 2018-09-25 | 浙江沁园水处理科技有限公司 | A kind of sensor and its water filter cup of detection water quality |
| CN108523578A (en) * | 2018-04-26 | 2018-09-14 | 中山市红杉企业信息咨询有限公司 | A kind of teacup |
| CN108816132A (en) * | 2018-08-06 | 2018-11-16 | 王潞杨 | Fast cooling agitating device for cup |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107361596B (en) | 2019-04-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107361596A (en) | A kind of intelligently filters cup | |
| CN107930600A (en) | A kind of preparation method of nano combined water-purifying material | |
| Zhai et al. | Fabrication of chitosan microspheres for efficient adsorption of methyl orange | |
| Wang et al. | Fabrication of porous polyacrylamide/polystyrene fibrous membranes for efficient oil-water separation | |
| CN103933929B (en) | A kind of mesopore silicon oxide adsorbent adsorbing hydrophobic organic compound and its preparation method and application | |
| CN104587852B (en) | A kind of heavy metal ion adsorbed type PS hollow fiber ultrafiltration membrane and preparation method thereof | |
| CN107376849A (en) | A kind of application of ethylenediamine tetraacetic acid modified diatomite adsorbant and preparation method thereof and processing heavy metal ions in wastewater | |
| CN106084273A (en) | The preparation method of oleophilic drainage type water hyacinth fibre element aeroge | |
| CN101864021B (en) | Preparation method of nanometer silicon gel surface gastrodin molecular engram polymers | |
| CN104945555B (en) | Prepare method and its application of Modified with Polar Monomer superhigh cross-linking type interpenetrating polymer networks | |
| CN105504131A (en) | Preparing method for resin for clearing away beta2-microglobulin in blood purification | |
| CN104226274A (en) | Adsorbing agent for removing petroleum type pollutants in environmental water sample and preparation method of adsorbing agent | |
| CN109704432B (en) | One-pot method for preparing UIO-66-NH2Method for preparing functional monomer composite material and application of functional monomer composite material in adsorption of antibiotics | |
| CN115554986B (en) | Metal organic framework material with efficient adsorption effect and preparation method and application thereof | |
| CN109289531A (en) | A kind of preparation method of the dimethyl silicone polymer for organic solvent nanofiltration/meso-porous nano silicon composite membrane | |
| CN106496418A (en) | A kind of chitosan magnetic lead ion imprinted polymer and preparation method thereof | |
| Li et al. | Hydrophobic nanocellulose aerogels with high loading of metal-organic framework particles as floating and reusable oil absorbents | |
| Liu et al. | Micro-mesoporous divinyl benzene-based polymer for ultrafast, effective and selective removal of cationic dyes | |
| CN107374255A (en) | A kind of catamaran type intelligently filters cup | |
| CN102114401B (en) | Arsenic removal adsorbent and preparation method thereof | |
| CN108905970B (en) | Preparation method and application of clinoptilolite modification-based water body cadmium removal adsorbent | |
| CA2767437C (en) | Oil adsorbent and method of manufacturing oil adsorbent | |
| CN116809013A (en) | Titanium lithium ion sieve particle and preparation method thereof | |
| CN201244380Y (en) | Accurate dewatering filter element for insulating oil | |
| CN116440876A (en) | Amidoxime MOFs composite membrane material, and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190319 Address after: 321306 No. 36 Huabao Road, Industrial Functional Zone, Zhiying Town, Yongkang City, Jinhua City, Zhejiang Province Applicant after: Yongkang Fulan Industry and Trade Co., Ltd. Address before: 234000 Research Institute of Government Cooperation of Zhulan Town, Longqiao District, Suzhou City, Anhui Province Applicant before: Mei Yujie |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: No.36, Huabao Road, Zhiying Town, Yongkang City, Jinhua City, Zhejiang Province Patentee after: Yongkang Fulan industry and Trade Co.,Ltd. Address before: 321306 No. 36 Huabao Road, Industrial Functional Zone, Zhiying Town, Yongkang City, Jinhua City, Zhejiang Province Patentee before: YONGKANG FULAN INDUSTRY AND TRADE Co.,Ltd. |