CN107354744A - Extraordinarily thick nubuck resin of a kind of wear-resisting scratch resistance of use for synthetic leather and preparation method thereof - Google Patents

Extraordinarily thick nubuck resin of a kind of wear-resisting scratch resistance of use for synthetic leather and preparation method thereof Download PDF

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Publication number
CN107354744A
CN107354744A CN201710713760.0A CN201710713760A CN107354744A CN 107354744 A CN107354744 A CN 107354744A CN 201710713760 A CN201710713760 A CN 201710713760A CN 107354744 A CN107354744 A CN 107354744A
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parts
yangbuck
resin
synthetic leather
resistant
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CN201710713760.0A
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Chinese (zh)
Inventor
陈勇刚
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Jiangsu Baoze Polymer Materials Co Ltd
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Jiangsu Baoze Polymer Materials Co Ltd
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Priority to CN201710713760.0A priority Critical patent/CN107354744A/en
Publication of CN107354744A publication Critical patent/CN107354744A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D06M13/03Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons with unsaturated hydrocarbons, e.g. alkenes, or alkynes
    • D06M13/07Aromatic hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12Aldehydes; Ketones
    • D06M13/127Mono-aldehydes, e.g. formaldehyde; Monoketones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35Abrasion, pilling or fibrillation resistance
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The present invention relates to a kind of extraordinarily thick nubuck resin of the wear-resisting scratch resistance of use for synthetic leather, it is used for the FEOL of synthetic leather, includes following components:Nubuck resin, butanone, toluene, sheep bar powder, polymethylphenyl siloxane fluid.The invention further relates to the preparation method of the extraordinarily thick nubuck resin of the wear-resisting scratch resistance of the use for synthetic leather.The extraordinarily thick nubuck resin of the wear-resisting scratch resistance of use for synthetic leather of the present invention each component is mutually coordinated, collective effect, after sheep bar foaming, uniform foam cell, color development is bright-coloured, and velvet is good, and wear-resisting scratch resistance is strong, available for imitating the techniques such as release liners textured surface printing resin, roller coating.The extraordinarily thick nubuck resin of the wear-resisting scratch resistance of use for synthetic leather of the present invention is a kind of new material of leading portion printing, can be used in existing synthetic leather production line, technique is simple, without changing production equipment, will not increase production cost.

Description

Wear-resistant scratch-resistant extra-coarse Yangbuck resin for synthetic leather and preparation method thereof
Technical Field
The invention relates to the field of surface treatment agents for synthetic leather, in particular to wear-resistant and scratch-resistant extra-coarse nubuck resin for synthetic leather for a front-stage process of the synthetic leather, and simultaneously relates to a preparation method of the wear-resistant and scratch-resistant extra-coarse nubuck resin for the synthetic leather.
Background
The synthetic leather surface treating agent can be used for surface coating according to the category of products, and can improve the brightness, the color and the hand feeling of the synthetic leather. However, as consumers have higher requirements on the brightness, color and feel of the leather surface, the touch feeling of the synthetic leather is increased, and the wear resistance and scratch resistance of the synthetic leather surface are ensured. The existing surface treating agent can not meet the increasing requirements of consumers, so that the treating agent which can improve the touch feeling of the synthetic leather and can improve the wear resistance and the scratch resistance of the synthetic leather is urgently needed.
Disclosure of Invention
In order to solve the problems and the defects, the invention aims to provide wear-resistant and scratch-resistant extra-coarse nubuck resin for synthetic leather. The invention also provides a preparation method of the wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather.
The invention is realized by the following technical scheme:
a wear-resistant scratch-resistant extra-coarse nubuck resin for synthetic leather is used for a front-stage process of the synthetic leather, and comprises the following components: yangbuck resin, butanone, toluene, Yangbuck powder and benzyl silicone oil.
Further, the mixture ratio of each component is as follows: 52-54 parts of Yangbuck resin, 21-24 parts of butanone, 16-18 parts of toluene, 2-4 parts of Yangbuck powder and 0-1 part of benzyl silicone oil.
Furthermore, the mixture ratio of the components is as follows: 54 parts of Yangbuck resin, 23 parts of butanone, 18 parts of toluene, 4 parts of Yangbuck powder and 1 part of benzyl silicone oil.
Furthermore, the mixture ratio of the components is as follows: 53 parts of Yangbuck resin, 21 parts of butanone, 16 parts of toluene, 2 parts of Yangbuck powder and 0 part of benzyl silicone oil; or,
the proportion of each component is as follows: 52 parts of Yangbuck resin, 24 parts of butanone, 17 parts of toluene, 3 parts of Yangbuck powder and 0.5 part of benzyl silicone oil; or,
the proportion of each component is as follows: 54 parts of Yangbuck resin, 22 parts of butanone, 16 parts of toluene, 3 parts of Yangbuck powder and 1 part of benzyl silicone oil.
Further, the Yangbuck powder is extra coarse Yangbuck powder; and/or the Yangbuck resin is high-film Yangbuck resin.
The preparation method of the wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather comprises the following steps:
1) weighing the components according to the weight ratio, stirring part of Yangbuck resin, toluene and Yangbuck powder, and filtering;
2) adding butanone and benzyl silicone oil into the mixture obtained in the step 1), and uniformly stirring;
3) adding the rest Yangbuck resin into the mixture obtained in the step 2), and uniformly stirring.
Further, the mixture ratio of each component is as follows: 52-54 parts of Yangbuck resin, 21-24 parts of butanone, 16-18 parts of toluene, 2-4 parts of Yangbuck powder and 0-1 part of benzyl silicone oil.
Furthermore, the mixture ratio of the components is as follows: 54 parts of Yangbuck resin, 23 parts of butanone, 18 parts of toluene, 4 parts of Yangbuck powder and 1 part of benzyl silicone oil; or
The proportion of each component is as follows: 53 parts of Yangbuck resin, 21 parts of butanone, 16 parts of toluene, 2 parts of Yangbuck powder and 0 part of benzyl silicone oil; or,
the proportion of each component is as follows: 52 parts of Yangbuck resin, 24 parts of butanone, 17 parts of toluene, 3 parts of Yangbuck powder and 0.5 part of benzyl silicone oil; or,
the proportion of each component is as follows: 54 parts of Yangbuck resin, 22 parts of butanone, 16 parts of toluene, 3 parts of Yangbuck powder and 1 part of benzyl silicone oil.
Furthermore, the part of the Yangbuck resin is 42-46 parts by weight.
Further, the residual Yangbuck resin accounts for 6-12 parts by weight, and the sum of the partial Yangbuck resin and the residual Yangbuck resin accounts for 52-54 parts by weight.
Due to the adoption of the technical scheme, compared with the prior art, the invention has the following beneficial technical effects:
1. the components of the wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather are coordinated and acted together, so that after nubuck foaming, the nubuck holes are uniform, the color is bright, the velvet feeling is good, the wear resistance and the scratch resistance are high, and the resin can be used for processes such as resin printing and roll coating on the surface of a release-simulated paper line;
2. the wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather is a novel material with a front section printed, can be used for the existing synthetic leather production line, is simple in process, does not need to change production equipment, and does not increase production cost.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Example 1
The wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather consists of the following components in proportion: 54 parts of high-film Yangbuck resin, 23 parts of butanone, 18 parts of toluene, 4 parts of extra coarse Yangbuck powder and 1 part of benzyl silicone oil.
The preparation method of the wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather comprises the following steps: mixing 42 parts by weight of high-membrane Yangbuck resin, 18 parts by weight of toluene and 4 parts by weight of extra coarse Yangbuck powder, stirring until the mixture is uniformly mixed, and filtering; then, 23 parts by weight of butanone and 1 part by weight of benzyl silicone oil were added to the obtained solid mixture, and the mixture was stirred until the mixture was uniformly mixed; and finally, adding the rest 12 parts by weight of high-film Yangbuck resin into the obtained mixture, and stirring until the mixture is uniformly mixed to obtain the wear-resistant scratch-resistant extra-coarse Yangbuck resin for the synthetic leather. The performance indexes of the obtained wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather are shown in table 1.
The methods of stirring and filtration used in the above-mentioned production process are all methods commonly used in the art.
Example 2
The wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather consists of the following components in proportion: 53 parts of high-film Yangbuck resin, 21 parts of butanone, 16 parts of toluene and 2 parts of extra coarse Yangbuck powder.
The preparation method of the wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather comprises the following steps: mixing 44 parts by weight of high-membrane Yangbuck resin, 16 parts by weight of toluene and 2 parts by weight of extra coarse Yangbuck powder, stirring until the mixture is uniformly mixed, and filtering; then, 21 parts by weight of butanone is added into the obtained solid mixture, and the mixture is stirred until the mixture is uniformly mixed; and finally, adding the remaining 9 parts by weight of high-film Yangbuck resin into the obtained mixture, and stirring until the mixture is uniformly mixed to obtain the wear-resistant scratch-resistant extra-coarse Yangbuck resin for the synthetic leather. The performance indexes of the obtained wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather are shown in table 1.
The methods of stirring and filtration used in the above-mentioned production process are all methods commonly used in the art.
Example 3
The wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather consists of the following components in proportion: 52 parts of high-film Yangbuck resin, 24 parts of butanone, 17 parts of toluene, 3 parts of extra coarse Yangbuck powder and 0.5 part of benzyl silicone oil.
The preparation method of the wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather comprises the following steps: mixing 46 parts by weight of high-membrane Yangbuck resin, 17 parts by weight of toluene and 3 parts by weight of extra coarse Yangbuck powder, stirring until the mixture is uniformly mixed, and filtering; then, 24 parts by weight of butanone and 0.5 part by weight of benzyl silicone oil are added into the obtained solid mixture, and the mixture is stirred until the mixture is uniformly mixed; and finally, adding the rest 6 parts by weight of high-film Yangbuck resin into the obtained mixture, and stirring until the mixture is uniformly mixed to obtain the wear-resistant scratch-resistant extra-coarse Yangbuck resin for the synthetic leather. The performance indexes of the obtained wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather are shown in table 1.
The methods of stirring and filtration used in the above-mentioned production process are all methods commonly used in the art.
Example 4
The wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather consists of the following components in proportion: 54 parts of high-film Yangbuck resin, 22 parts of butanone, 16 parts of toluene, 3 parts of extra coarse Yangbuck powder and 1 part of benzyl silicone oil.
The preparation method of the wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather comprises the following steps: mixing 43 parts by weight of high-membrane Yangbuck resin, 16 parts by weight of toluene and 3 parts by weight of extra coarse Yangbuck powder, stirring until the mixture is uniformly mixed, and filtering; then, 22 parts by weight of butanone and 1 part by weight of benzyl silicone oil are added into the obtained solid mixture, and the mixture is stirred until the mixture is uniformly mixed; and finally, adding the rest 11 parts by weight of high-film Yangbuck resin into the obtained mixture, and stirring until the mixture is uniformly mixed to obtain the wear-resistant scratch-resistant extra-coarse Yangbuck resin for the synthetic leather. The performance indexes of the obtained wear-resistant scratch-resistant extra-coarse nubuck resin for the synthetic leather are shown in table 1.
The methods of stirring and filtration used in the above-mentioned production process are all methods commonly used in the art.
TABLE 1
The above description is only for the preferred embodiment of the present invention, and is not intended to limit the scope of the present invention; it is intended that the following claims be interpreted as including all such alterations, modifications, and equivalents as fall within the true spirit and scope of the invention.

Claims (10)

1. The wear-resistant and scratch-resistant extra-coarse nubuck resin for the synthetic leather is used for the front-stage process of the synthetic leather and is characterized by comprising the following components: yangbuck resin, butanone, toluene, Yangbuck powder and benzyl silicone oil.
2. The wear-resistant scratch-resistant super-coarse Yangbuck resin for synthetic leather according to claim 1 is characterized in that the mixture ratio of the components is as follows: 52-54 parts of Yangbuck resin, 21-24 parts of butanone, 16-18 parts of toluene, 2-4 parts of Yangbuck powder and 0-1 part of benzyl silicone oil.
3. The wear-resistant scratch-resistant super-coarse Yangbuck resin for synthetic leather according to claim 2 is characterized in that the mixture ratio of the components is as follows: 54 parts of Yangbuck resin, 23 parts of butanone, 18 parts of toluene, 4 parts of Yangbuck powder and 1 part of benzyl silicone oil.
4. The wear-resistant scratch-resistant super-coarse Yangbuck resin for synthetic leather according to claim 2 is characterized in that the mixture ratio of the components is as follows: 53 parts of Yangbuck resin, 21 parts of butanone, 16 parts of toluene, 2 parts of Yangbuck powder and 0 part of benzyl silicone oil; or,
the proportion of each component is as follows: 52 parts of Yangbuck resin, 24 parts of butanone, 17 parts of toluene, 3 parts of Yangbuck powder and 0.5 part of benzyl silicone oil; or,
the proportion of each component is as follows: 54 parts of Yangbuck resin, 22 parts of butanone, 16 parts of toluene, 3 parts of Yangbuck powder and 1 part of benzyl silicone oil.
5. The abrasion-resistant scratch-resistant super-coarse Yangbuck resin for synthetic leather according to any one of claims 1 to 4, wherein the Yangbuck powder is super-coarse Yangbuck powder; and/or the Yangbuck resin is high-film Yangbuck resin.
6. The preparation method of the wear-resistant scratch-resistant extra-coarse nubuck resin for synthetic leather as claimed in the preceding claim, which is characterized by comprising the following steps:
1) weighing the components according to the weight ratio, stirring part of Yangbuck resin, toluene and Yangbuck powder, and filtering;
2) adding butanone and benzyl silicone oil into the mixture obtained in the step 1), and uniformly stirring;
3) adding the rest Yangbuck resin into the mixture obtained in the step 2), and uniformly stirring.
7. The preparation method of the wear-resistant scratch-resistant extra-coarse Yangbuck resin for synthetic leather according to claim 6, wherein the mixture ratio of the components is as follows: 52-54 parts of Yangbuck resin, 21-24 parts of butanone, 16-18 parts of toluene, 2-4 parts of Yangbuck powder and 0-1 part of benzyl silicone oil.
8. The preparation method of the wear-resistant scratch-resistant super-coarse Yangbuck resin for synthetic leather according to claim 7, wherein the mixture ratio of the components is as follows: 54 parts of Yangbuck resin, 23 parts of butanone, 18 parts of toluene, 4 parts of Yangbuck powder and 1 part of benzyl silicone oil; or the mixture ratio of the components is as follows: 53 parts of Yangbuck resin, 21 parts of butanone, 16 parts of toluene, 2 parts of Yangbuck powder and 0 part of benzyl silicone oil; or,
the proportion of each component is as follows: 52 parts of Yangbuck resin, 24 parts of butanone, 17 parts of toluene, 3 parts of Yangbuck powder and 0.5 part of benzyl silicone oil; or,
the proportion of each component is as follows: 54 parts of Yangbuck resin, 22 parts of butanone, 16 parts of toluene, 3 parts of Yangbuck powder and 1 part of benzyl silicone oil.
9. The method for preparing the abrasion-resistant scratch-resistant super-coarse Yangbuck resin for synthetic leather according to claim 6, wherein the part of Yangbuck resin is 42-46 parts by weight.
10. The method for preparing the abrasion-resistant scratch-resistant super-coarse Yangbuck resin for synthetic leather according to claim 6, wherein the residual Yangbuck resin accounts for 6-12 parts by weight, and the sum of the partial Yangbuck resin and the residual Yangbuck resin accounts for 52-54 parts by weight.
CN201710713760.0A 2017-08-18 2017-08-18 Extraordinarily thick nubuck resin of a kind of wear-resisting scratch resistance of use for synthetic leather and preparation method thereof Pending CN107354744A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796578A (en) * 2019-01-22 2019-05-24 华大化学(安徽)有限公司 A kind of thick nubuck resin and its preparation method and application of wear-resisting, the wide blowing temperature of scratch resistance
CN110670370A (en) * 2019-11-06 2020-01-10 山东同大海岛新材料股份有限公司 Preparation method of imitated leather microfiber leather, imitated leather microfiber leather and imitated leather product

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102382450A (en) * 2011-08-11 2012-03-21 苏州鼎润复合材料有限公司 Nap-up and nap-down brushed yarn buck foaming resin for synthetic leather and preparation method thereof
CN102850767A (en) * 2011-06-27 2013-01-02 江苏宝泽高分子材料股份有限公司 Oily reverse/smooth hair nubuck resin for synthetic leather and its preparation method
CN105239403A (en) * 2015-11-10 2016-01-13 江苏宝泽高分子材料股份有限公司 Bright black polishing treating agent for synthetic leather and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850767A (en) * 2011-06-27 2013-01-02 江苏宝泽高分子材料股份有限公司 Oily reverse/smooth hair nubuck resin for synthetic leather and its preparation method
CN102382450A (en) * 2011-08-11 2012-03-21 苏州鼎润复合材料有限公司 Nap-up and nap-down brushed yarn buck foaming resin for synthetic leather and preparation method thereof
CN105239403A (en) * 2015-11-10 2016-01-13 江苏宝泽高分子材料股份有限公司 Bright black polishing treating agent for synthetic leather and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796578A (en) * 2019-01-22 2019-05-24 华大化学(安徽)有限公司 A kind of thick nubuck resin and its preparation method and application of wear-resisting, the wide blowing temperature of scratch resistance
CN110670370A (en) * 2019-11-06 2020-01-10 山东同大海岛新材料股份有限公司 Preparation method of imitated leather microfiber leather, imitated leather microfiber leather and imitated leather product

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Application publication date: 20171117